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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Design, Synthesis and Characterization of Triptycene-Containing Macromolecules with Hierarchically Controlled Architectures as Functional Membrane Materials for Energy Applications

This DOE CAREER award supported the Guo research group at the University of Notre Dame in its efforts to develop hierarchically functional polymer membrane materials based on iptycene unit to enable energy-efficient molecular separations and fast ion transport in polymeric membranes. To do this, the Guo group engaged in three major research objectives, each exploiting a unique molecular motif offered by iptycene units: (1) developing glassy microporous polymers with exquisitely tailored free volume microporosity for ultra-fast and selective gas transport; (2) developing robust PEO-rich multicomponent polymers via supramolecular reinforcement for CO 2 -selective membranes; and (3) developing ion-containing, nanophase separated multiblock copolymers with suppressed water swelling and fast proton transport for hydrogen fuel cells. Through the research in this project, the iptycene strategy has established a new paradigm of macromolecular design for harnessing free volume microporosity and specific structure motifs to facilitate fast and selective molecular and ion transport in polymers. The results from this project not only provide new fundamental knowledge to the membrane community and broader materials community, but also bridge the technical gaps via providing robust high performance polymer materials for a wide range of applications that impact energy and environmental sustainability. This technical report summarizes the major accomplishments of the study of these innovative polymer membrane materials in this project. For example, introducing triptycene unit into polybenzoxazole structures led to superior size sieving properties, which, along with their ultrahigh gas permeability, placed these polymers among the best gas separation membranes ever reported; the study of PEO-based model network structures demonstrated for the first time that crosslink inhomogeneity (i.e., uneven distribution of crosslink sites)–an previously unexplored structure parameter, plays a significant role in regulating gas transport, ushering in a completely new dimension in the design of crosslinked polymers with broad applicability; exploiting the unique supramolecular interlocking and chain threading interactions and the internal free volume offered by iptycene units addressed the grand challenge of excessive water swelling encountered by conventional ion-containing polymers while allowing nanophase separated membrane morphologies enabling fast ion transport. The new polymer membrane materials and the new macromolecular design strategies developed from this project hold great potential for a much wider applicability beyond gas separations and polyelectrolyte membranes.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Analysis of Structural Options for Bench Measurement of AGU Segment Prototype

Refer to Tech Note TN #257 for an introduction to the mechanics and structure for the proposed prototype of a multi-segment Adaptive-Gap Undulator (AGU). Here we investigate various proposed design options for a magnet structure intended to prototype the upper and lower halves of a single segment: A) Assembly SLS-15.55-004, the historic X9 platen (0.6m long, with integral strongback) and single large centric mechanical feed-through post; B) Initial assembly SR-ID-SAGU-4300 with three pairs of feed-throughs spaced along platen length (0.7m); C) That assembly SR-ID-SAGU-4300 with increased base plate thickness. All options have “base plate” affixed to the same actuated gap-drive system with single driven axis as was on NSLS X9 MGU. As shown in Figure 1, design criteria like Gap Tolerance, Taper Error, and the critical Planarity of the pole plane within the gap are used to evaluate performance. The error in planarity to be minimized is the differential in vertical displacement (Y direction) along the Platen length (beam Z direction). Applied loads are magnetic pressure and gravity.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Deuterium Concentration Effects on Cell Cycle Progression

Deuterium (D), which is found in natural water at ~ 150 ppm, seems to play an important role in biology. For example, D concentrations above 150 ppm are known to produce toxic effects in many organisms. There is also evidence to suggest D levels significantly less than 150 ppm can cause delays in progression through the normal mitotic cell cycle. Some have even theorized that the D:H ratio in cells may impact an organism’s radiation resistance. Therefore, evaluating the role of D and the D:H ratio in eukaryotic and prokaryotic cells should lead to a better understanding of cell cycle progression and radiation resistance in these organisms. Research in this field has likely been stalled by the limited availability of D 2 O with varying D concentrations needed to accurately study the deuterium effects. However, SRNL can currently manufacture D 2 O in varying concentrations, and we have assembled a unique team of radiation biologists, microbiologists, radiochemists, and health physics to form an interdisciplinary research group to study the cell cycle as a function of D concentration in order to address several fundamental science questions. Proposed work in FY20 was a collaborative effort with Augusta University to utilized BSL-2 mammalian cell lines. Lab work was halted due to the COVID-19 pandemic. An intensive literature review was performed and identified pertinent knowledge gaps that could be filled in future research efforts.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2022

Beam Dynamics Simulations of Transient Beam Loading Effects in the 10GeV EIC Electron Storage Ring

We report on beam dynamics studies of transient beam loading effects in the 10 GeV EIC electron storage ring [1]. The studies are carried out with time-dependent Vlasov-Fokker-Planck simulations performed with the parallel, particle tracking code SPACE [2], which allows to follow self-consistently the dynamics of h bunches, where h in the number of RF buckets, in arbitrary multi-bunch configurations. The specific goal of the numerical simulations is to determine stable RF cavity settings under heavy beam loading. We also study the option to operate with a passive, third-harmonic cavity (3HC) system for bunch lengthening, addressing both stability and the performance limitation due to a gap in the uniform filling pattern for ion clearing.

43 PARTICLE ACCELERATORS↗
DOE OSTI2025

Solid Amine CO2 Adsorbent Degradation: Insights from Experiments and Atomistic Simulations

Direct air capture (DAC) has received significant attention this decade as a viable solution to limit global warming, although large-scale deployment is currently not economically feasible. To reach the ambitious cost target set by the U.S. of $100/ton CO2 captured and stored, significant improvements must be made to sorbent lifetime and capacity. Aminosilanes grafted onto silica supports are promising candidates for deployment in DAC systems due to their relatively high oxidative stability and low regeneration temperature. Despite myriad advancements in the field, there still exists a fundamental knowledge gap relating sorbent structure to performance. In this work, we grafted various aminosilanes onto the highly porous silica SBA-15 and characterized both oxidative stability and CO2 capacity. Material properties systematically investigated included amine moiety (primary vs. secondary), silane group structure, number of linkages to the silica support, and co-addition of impregnated amines (e.g., PEI), among others. A fixed bed system was used to execute accelerated degradation studies in the presence of humidity and varying temperatures to simulate realistic operating conditions. Atomistic simulations were combined with the experimental results to gain mechanistic insight, ultimately informing the design of next-generation materials

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Memoirs of Mass Accretion: Probing the Edges of Intracluster Light in Simulated Galaxy Clusters

The diffuse starlight extending throughout massive galaxy clusters, known as intracluster light (ICL), has the potential to be read as a memoir of mass accretion: informative, individual, and yet imperfect. Here, we combine dark-matter-only zoom-in simulations from the Symphony suite with the Nimbus “star-tagging” model of the stellar halo to assess how much information about the mass assembly of an individual galaxy cluster can be gleaned from idealized measurements of ICL outskirts. We show that the edges of a cluster’s stellar profile—the primary (R sp⋆,1 ) and secondary (R sp⋆,2 ) stellar “splashback” radii—are sensitive to both continuous mass accretion histories (MAHs) and discrete merger events, making them potentially powerful probes of a cluster’s past. We find that R sp⋆,1 strongly correlates with the cluster’s mass ∼1 dynamical time ago, while R sp⋆,2 traces more recent MAH to a slightly lesser degree. In combination, these features can further distinguish between clusters that have and have not undergone a major merger within the past dynamical time. We use both to predict realistic cluster MAHs with the MultiCAM framework. These outer ICL features are significantly more sensitive to mass accretion and merger histories than the stellar mass gap and halo concentration, and perform comparably to the commonly used X-ray-based tracer of relaxedness, x off . While our analysis is idealized, the relevant ICL features are potentially detectable in next-generation deep imaging of nearby clusters. This work highlights the promise of ICL measurements and lays the groundwork for more detailed forecasts of their power.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Multi-scale assessment of a grassland productivity model

Grasslands provide many important ecosystem services globally, and projecting grassland productivity in the coming decades will provide valuable information to land managers. Productivity models can be well calibrated at local scales but generally have some maximum spatial scale in which they perform well. Here we evaluate a grassland productivity model to find the optimal spatial scale for parameterization and thus for subsequently applying it in future productivity projections for North America. We also evaluated the model on new vegetation types to ascertain its potential generality. We find the model most suitable when incorporating only grasslands, as opposed to also including agriculture and shrublands, and only in the Great Plains and eastern temperate forest ecoregions of North America. The model was not well suited to grasslands in North American deserts or northwest forest ecoregions. It also performed poorly in agriculture vegetation, likely due to management activities, and shrubland vegetation, likely because the model lacks representation of deep water pools. This work allows us to perform long-term projections in areas where model performance has been verified, with gaps filled in by future modeling efforts.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1975

Process-induced defects in terrestrial solar cells

Experimental and theoretical work on low resistivity, high efficiency solar cells indicates the dominant role that defects take in determining performance. High doping mechanisms produce gap shrinkage by band tailing, impurity band widening and impurity misfit; altered interband transmission rates result from Auger impact, SRH processes, or from electronic tunneling via defects. Characterizations of cell materials for their defects and their relations to the chosen fabrication processes are proposed.

Lindholm, F. A.↗
NASA NTRS1994

Hyflite TPS Domain Test Results Ames 2x9 Turbulent Flow Duct

Detailed experimental data have been obtained on several advanced TUFI systems during their exposure to high temperature high shear supersonic turbulent flow. Dimensional stability of these systems were determined at surface temperatures above 3000 F. Effect of step gap configuration on the thermal performance of the TUFI systems were also evaluated.

Stewart, David A.↗
NASA NTRS2002

Memory-Intensive Benchmarks: IRAM vs. Cache-Based Machines

The increasing gap between processor and memory performance has lead to new architectural models for memory-intensive applications. In this paper, we explore the performance of a set of memory-intensive benchmarks and use them to compare the performance of conventional cache-based microprocessors to a mixed logic and DRAM processor called VIRAM. The benchmarks are based on problem statements, rather than specific implementations, and in each case we explore the fundamental hardware requirements of the problem, as well as alternative algorithms and data structures that can help expose fine-grained parallelism or simplify memory access patterns. The benchmarks are characterized by their memory access patterns, their basic control structures, and the ratio of computation to memory operation.

Biswas, Rupak↗
NASA NTRS2005

Development Status of the Advanced Life Support On-Line Project Information System

The Advanced Life Support Program has recently accelerated an effort to develop an On-line Project Information System (OPIS) for research project and technology development data centralization and sharing. The core functionality of OPIS will launch in October of 2005. This paper presents the current OPIS development status. OPIS core functionality involves a Web-based annual solicitation of project and technology data directly from ALS Principal Investigators (PIS) through customized data collection forms. Data provided by PIs will be reviewed by a Technical Task Monitor (TTM) before posting the information to OPIS for ALS Community viewing via the Web. The data will be stored in an object-oriented relational database (created in MySQL(R)) located on a secure server at NASA ARC. Upon launch, OPIS can be utilized by Managers to identify research and technology development gaps and to assess task performance. Analysts can employ OPIS to obtain.

Levri, Julie A.↗
NASA NTRS2005

Development Approach of the Advanced Life Support On-line Project Information System

The Advanced Life Support (ALS) Program has recently accelerated an effort to develop an On-line Project Information System (OPIS) for research project and technology development data centralization and sharing. There has been significant advancement in the On-line Project Information System (OPIS) over the past year (Hogan et al, 2004). This paper presents the resultant OPIS development approach. OPIS is being built as an application framework consisting of an uderlying Linux/Apache/MySQL/PHP (LAMP) stack, and supporting class libraries that provides database abstraction and automatic code generation, simplifying the ongoing development and maintenance process. Such a development approach allows for quick adaptation to serve multiple Programs, although initial deployment is for an ALS module. OPIS core functionality will involve a Web-based annual solicitation of project and technology data directly from ALS Principal Investigators (PIs) through customized data collection forms. Data provided by PIs will be reviewed by a Technical Task Monitor (TTM) before posting the information to OPIS for ALS Community viewing via the Web. Such Annual Reports will be permanent, citable references within OPIS. OPlS core functionality will also include Project Home Sites, which will allow PIS to provide updated technology information to the Community in between Annual Report updates. All data will be stored in an object-oriented relational database, created in MySQL(Reistered Trademark) and located on a secure server at NASA Ames Research Center (ARC). Upon launch, OPlS can be utilized by Managers to identify research and technology development (R&TD) gaps and to assess task performance. Analysts can employ OPlS to obtain the current, comprehensive, accurate information about advanced technologies that is required to perform trade studies of various life support system options. ALS researchers and technology developers can use OPlS to achieve an improved understanding of the NASA and ALS Program needs and to understand how other researchers and technology developers are addressing those needs. OPlS core functionality will launch for 'Ihe ALS Program in October, 2005. However, the system has been developed with the ability to evolve with Program needs. Because of open-source construction, software costs are minimized. Any functionality that is technologically feasible can be built into OPIS, and OPlS can expand through module cloning and adaptation, to any level deemed useful to the Agency.

Levri, Julie A.↗
NASA NTRS2007

Fluorescence Visualization of Hypersonic Flow Past Triangular and Rectangular Boundary-layer Trips

Planar laser-induced fluorescence (PLIF) flow visualization has been used to investigate the hypersonic flow of air over surface protrusions that are sized to force laminar-to-turbulent boundary layer transition. These trips were selected to simulate protruding Space Shuttle Orbiter heat shield gap-filler material. Experiments were performed in the NASA Langley Research Center 31-Inch Mach 10 Air Wind Tunnel, which is an electrically-heated, blowdown facility. Two-mm high by 8-mm wide triangular and rectangular trips were attached to a flat plate and were oriented at an angle of 45 degrees with respect to the oncoming flow. Upstream of these trips, nitric oxide (NO) was seeded into the boundary layer. PLIF visualization of this NO allowed observation of both laminar and turbulent boundary layer flow downstream of the trips for varying flow conditions as the flat plate angle of attack was varied. By varying the angle of attack, the Mach number above the boundary layer was varied between 4.2 and 9.8, according to analytical oblique-shock calculations. Computational Fluid Dynamics (CFD) simulations of the flowfield with a laminar boundary layer were also performed to better understand the flow environment. The PLIF images of the tripped boundary layer flow were compared to a case with no trip for which the flow remained laminar over the entire angle-of-attack range studied. Qualitative agreement is found between the present observed transition measurements and a previous experimental roughness-induced transition database determined by other means, which is used by the shuttle return-to-flight program.

Danehy, Paul M.↗
NASA NTRS2010

Psychosocial Characteristics of Optimum Performance in Isolated and Confined Environments (ICE)

The Behavioral Health and Performance (BHP) Element addresses human health risks in the NASA Human Research Program (HRP), including the Risk of Adverse Behavioral Conditions and the Risk of Psychiatric Disorders. BHP supports and conducts research to help characteristics and mitigate the Behavioral Medicine risk for exploration missions, and in some instances, current Flight Medical Operations. The Behavioral Health and Performance (BHP) Element identified research gaps within the Behavioral Medicine Risk, including Gap BMed6: What psychosocial characteristics predict success in an isolated, confined environment (ICE)? To address this gap, we conducted an extensive and exhaustive literature review to identify the following: 1) psychosocial characteristics that predict success in ICE environments; 2) characteristics that are most malleable; and 3) specific countermeasures that could enhance malleable characteristics.

Palinkas, Lawrence A.↗
NASA NTRS2019

Hazards Analysis and Failure Modes and Effects Criticality Analysis (FMECA) of Four Concept Vehicle Propulsion Systems

The primary objective of this research effort is to identify failure modes and hazards associated with the concept vehicles and to perform functional hazard analyses (FHA) and failure modes and effects criticality analyses (FMECA) for each. Boeing also created a Fault Tree Analysis (FTA) for each of the concept vehicles, as the FTA contains the connectivity between systems and is an accepted, top-down method to analyze the safety of an air-vehicle. Conceptual design of notional powertrain configuration for each of four (4) NASA RVLT (Revolutionary Vertical Lift Technology) Concept Vehicles were developed in as much detail as was necessary to support the reliability and safety analysis for this project. Functional block diagrams from each of the conceptual powertrain configurations were created and used to order the FHA, FMECA, and FTA. Hazards were identified and the severity of each were categorized in the FHA for use in a follow-up FMECA. The FTA took inputs from the FMECA and the functional block diagrams to develop the connectivity and develop a quantitative architecture that could be used to perform sensitivity studies, as related to vehicle safety.Guidelines for reliability targets for both the air vehicle and the operation in the UAM (Urban Air Mobility) mission are discussed. An industry literature search was performed in order to assess gaps in existing government regulations and industry specifications. The industry literature search led to air-vehicle and operational reliability discussions, as related to Distributed Electric/Hybrid-Electric Propulsion (DE/HEP) system operating in the UAM role. A discussion of results and recommendations for future work is also provided.

Hazards Analysis↗
NASA NTRSDate not supplied

Overview of Ablation Modeling at NASA

The ambitious scientific payload and crew delivery goals of imminent and future NASA missions are associated with challenging and complex vehicle entries. Advanced ablative Thermal Protection System (TPS) materials will be required for such missions, and, as such, a robust ablation modeling capability is critical to assessing performance by bridging the wide gap between ground testing and entry conditions. The traditional ablation modeling toolset - continuum thermal/materials response analysis - has grown recently to include high-fidelity, multi-scale, and multi-physics techniques that provide a more complete description of the rich physics and chemistry of ablation to better drive down risks related to extreme entries. The present talk provides a snapshot of ongoing NASA activities in ablation modeling, including a review of the current technical capabilities and tools at play within the Agency, the important role academia plays in supporting technical area advancements, and how such internal and external investments intersect with upcoming missions to drive down risks.

TPS↗