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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Chemical consequences of major impact events on earth

Violent cometary or asteroidal impact events comparable to that which terminated the Cretaceous era must produce large amounts of nitrogen oxides, sufficient to provide NOx mole fractions much larger than 100 ppm over areas of millions of square kilometers. Rapid production of NO2, and subsequent rainout of HNO3 and other strong acids can acidify surface waters, selectively destroying CaCO3 shells. This scenario holds the promise of explaining both the scope of Cretaceous biological extinctions and their extraordinary selectivity.

Lewis, J. S.↗
NASA NTRS1984

Pressure and temperature dependence of the reaction NO2 + NO3 + M yields N2O5 + M

The pressure and temperature dependences of the reaction NO2 + NO3 + M which yields N2O5 + M are investigated by using the flash photolysis/visible absorption technique in which the pseudo-first-order decay of NO3 is monitored as a function of total pressure (20-700 torr), diluent gas (M = He and N2), and temperature (236-358 K). The reaction is found to be in the falloff region in the 20-700 torr pressure range with collision efficiencies increasing in the order He less than N2. Falloff parameters are obtained by fitting the experimental data to the falloff equation of Troe and co-workers. The expression for k1(N2 concentration, T) is obtained and compared with the evaluations presented in the NASA (DeMore, 1983) and CODATA (Baulch et al., 1982) reviews of kinetic data for atmospheric chemistry. Both evaluations are based on N2O5 thermal decomposition data coupled with estimates of the equilibrium constant. The significance of the reactions for atmospheric chemistry rests not only on their rates but on the extent to which they result in a permanent sink for NOX.

Kircher, C. C.↗
NASA NTRS1986

Combustion characteristics in the transition region of liquid fuel sprays

A number of important effects have been observed in the droplet size transition region in spray combustion systems. In this region, where the mechanism of flame propagation is transformed from diffusive to premixed dominated combustion, the following effects have been observed: (1) maxima in burning velocity; (2) extension of flammability limits; (3) minima in ignition energy; and (4) minima in NOx formation. A monodisperse aerosol generator has been used to form and deliver a well controlled liquid fuel spray to the combustion test section where measurements of ignition energy have been made. The ignition studies were performed on monodisperse n-heptane sprays at atmospheric pressure over a range of equivalence ratios and droplet diameters. A capacitive discharge spark ignition system was used as the ignition source, providing independent control of spark energy and duration. Preliminary measurements were made to optimize spark duration and spark gap, optimum conditions being those at which the maximum frequency or probability of ignition was observed. Using the optimum electrode spacing and spark duration, the frequency of ignition was determined as a function of spark energy for three overall equivalence ratios (0.6, 0.8, and 1.0) and for initial droplet diameters of 25, 40, 50, 60, and 70 micro m.

Cernansky, N. P.↗
NASA NTRS1985

Laser radar observation of the polar stratospheric aerosol layer

The polar stratosphere has been speculated to be an active sink region of various stratospheric materials; ozone, water vapor, NOX, aerosol particles and so on, but this process is not theoretically and/or observationally made clear. The observation of the polar stratospheric aerosol layer using laser radar certainly contributes to the study of the global transport of these stratospheric minor constituents. In addition to this, from the viewpoint of aerosol science, there may be many interesting phenomena which cannot be found in the stratosphere at mid and low latitudes; the effect of precipitation of high energy molecules and atoms, of very cold winter stratosphere, of very cold mesopause in summer. Laser radar observation is one of the main activities of the Antarctic Middle Atmosphere (AMA) project at Syowa Station (69.00 deg S, 39.35 deg E), Antarctica since May 1983. Laser radar measurement at Syowa Station is discussed in detail.

Iwasaka, Y.↗
NASA NTRS1986

Observations of the effect of solar protons on the chemistry of the middle atmosphere

Ozone profile measurements made by backscattered ultraviolet instruments during two solar maxima are examined. Analysis of data from the BUV instrument on Nimbus 4 (1970-1978) showed three cases of ozone destruction associated with SPEs near the maximum of solar cycle 20: during events on January 25 and September 2, 1971, and during the giant event of August 4-8, 1972. Data from the SBUV instrument on Nimbus 7 (1978 present) show ozone destruction during five SPEs near the maximum of solar cycle 21: on June 7, 1979, August 21, 1979, October 13-14, 1981, July 13, 1982, and December 8, 1982. The observed response of ozone to the production of HOx and NOx by solar protons is used to better understand the complex chemistry of the middle atmosphere.

Mcpeters, R. D.↗
NASA NTRS1986

Concentrations and uncertainties of stratospheric trace species inferred from limb infrared monitor of the stratosphere data. I - Methodology and application to OH and HO2. II - Monthly averaged OH, HO2, H2O2, and HO2NO2

Difficulties arise in connection with the verification of multidimensional chemical models of the stratosphere. The present study shows that LIMS data, together with a photochemical equilibrium model, may be used to infer concentrations of a variety of zonally averaged trace Ox, OHx, and NOx species over much of the stratosphere. In the lower stratosphere, where the photochemical equilibrium assumption for HOx species breaks down, inferred concentrations should still be accurate to about a factor of 2 for OH and 2.5 for HO2. The algebraic nature of the considered model makes it possible to see easily to the first order the effect of variation of any model input parameter or its uncertainty on the inferred concontration of the HOx species and their uncertainties.

Kaye, J. A.↗
NASA NTRS1987

The potential impact on atmospheric ozone and temperature of increasing trace gas concentrations

The response of the atmosphere to emissions of chlorofluorocarbons (CFCs) and other chlorocarbons, and to increasing concentrations of other radiatively active trace gases such as CO2, CH4, and N2O is calculated by a coupled chemical-radiative transport one-dimensional model. It is shown that significant reductions in the ozone concentration and in the temperature are expected in the upper stratosphere as a result of increasing concentrations of active chlorine produced by photodecomposition of the CFCs. The ozone content is expected to increase in the troposphere, as a consequence of increasing concentrations of methane and nitrogen oxides. Due to enhanced greenhouse effects, the Earth's surface should warm up by several degrees. The amplitude and even the sign of future changes in the ozone column are difficult to predict as they are strongly scenario-dependent. An early detection system to prevent noticeable ozone changes as a result of increasing concentrations of source gases should thus be based on a continuous monitoring of the ozone amount in the upper stratosphere rather than on measurements of the ozone column only. Measurements of NOx, Clx, and HOx are also required for unambiguous trend detection and interpretation.

Brasseur, G.↗
NASA NTRS1987

Climate-chemical interactions and effects of changing atmospheric trace gases

The paper considers trace gas-climate effects including the greenhouse effect of polyatomic trace gases, the nature of the radiative-chemical interactions, and radiative-dynamical interactions in the stratosphere, and the role of these effects in governing stratospheric climate change. Special consideration is given to recent developments in the investigations of the role of oceans in governing the transient climate responses, and a time-dependent estimate of the potential trace gas warming from the preindustrial era to the early 21st century. The importance of interacting modeling and observational efforts is emphasized. One of the problems remaining on the observational front is the lack of certainty in current estimates of the rate of growth of CO, O3, and NOx; the primary challenge is the design of a strategy that will minimize the sampling errors.

Ramanathan, V.↗
NASA NTRS1987

Solar proton events as tests for the fidelity of middle atmosphere models

Ozone depletions associated with solar proton events have now been observed in nine events: November 1969, January and September 1971, August 1972, June and August 1979, October 1981, and July and December 1982. Since the proton fluxes during these events are fairly well known from satellite observations, modelers have been able to compare model predictions with observations of ozone behavior during these events to test the validity of atmospheric photochemical models. Ozone decreases initially follow approximately their theoretically predicted behavior below about 45 km (where NOx is thought to cause the ozone decrease), but after about two weeks the observed decrease appears to be larger than the computed decrease. Above 45 km, where HOx is thought to cause the ozone decrease, the picture of model validity is not as clear. The observed ozone decreases between about 45 and 60 km are substantially more than that predicted by present photochemical models while between about 60 and 85 km the observed ozone decrease is approximately equal to that predicted.

Jackman, Charles H.↗
NASA NTRS1988

Infrared measurements of column amounts of stratospheric constituents in the Antarctic winter, 1987

The discovery of Farman et al. of recent large depletions of ozone in the Antarctic stratosphere in the austral spring has aroused great interest because of its serious potential consequences, as well as its surprising nature. An airborne expedition, including 21 experiments on two aircraft, was mounted for Punta Arenas, Chile, in August and September, 1987, to gather a wide range of data to understand the origins and implications of this phenomenon, known as the ozone hole. As a part of this expedition, a high resolution Fourier transform spectrometer was flown on the DC-8, measuring the column amount of a number of trace gases above the flight altitude. Column results are presented only from the flight of September 21; results from other flights are included in an accompanying paper. The deduced column for ozone HCl, and NO2 deduced from the spectra, plotted as a function of latitude are shown. It should be noted that there are many other factors varying as well as the latitude, but latitude seems to be the variable which most clearly provides a passage across the vortex boundary. It can be seen that south 76 degrees S., the column of ozone, HCl, and NO2, all decreas markedly, The ratio of HCl to Hf, normally about 5:1 in midlatitudes, approaches unity. Clearly the chemistry of chlorine and nitrogen are disturbed in the region of low ozone. While dynamical theories could perhaps explain a reduction of these three gases in the same region, since all are of stratospheric origin, it is difficult to see how any purely dynamical mechanism could produce the observed HCl:HF ratio, since the two gases have similar origins. A close look at other species to be reported as well as the correlation with other measurements, such as ClO supports the conclusion that the ozone depletion is a result of chemical processes which deplete HCl and NOx relative to the midlatitude situation.

Mankin, William G.↗
NASA NTRS1988

Multi-year global climatic effects of atmospheric dust from large bolide impacts

The global climatic effects of dust generated by the impact of a 10 km-diameter bolide was simulated using a one-dimensional (vertical only) globally-averaged climate model by Pollack et al. The goal of the simulation is to examine the regional climate effects, including the possibility of coastal refugia, generated by a global dust cloud in a model having realistic geographic resolution. The climate model assumes the instantaneous appearance of a global stratospheric dust cloud with initial optical depth of 10,000. The time history of optical depth decreases according to the detailed calculations of Pollack et al., reaching an optical depth of unity at day 160, and subsequently decreasing with an e-folding time of 1 year. The simulation is carried out for three years in order to examine the atmospheric effects and recovery over several seasons. The simulation does not include any effects of NOx, CO2, or wildfire smoke injections that may accompany the creation of the dust cloud. The global distribution of surface temperature changes, freezing events, precipitation and soil moisture effects and sea ice increases will be discussed.

Thompson, Starley L.↗
NASA NTRS1988

Acute effects of a large bolide impact simulated by a global atmospheric circulation model

The goal is to use a global three-dimensional atmospheric circulation model developed for studies of atmospheric effects of nuclear war to examine the time evolution of atmospheric effects from a large bolide impact. The model allows for dust and NOx injection, atmospheric transport by winds, removal by precipitation, radiative transfer effects, stratospheric ozone chemistry, and nitric acid formation and deposition on a simulated Earth having realistic geography. Researchers assume a modest 2 km-diameter impactor of the type that could have formed the 32 km-diameter impact structure found near Manson, Iowa and dated at roughly 66 Ma. Such an impact would have created on the order of 5 x 10 to the 10th power metric tons of atmospheric dust (about 0.01 g cm(-2) if spread globally) and 1 x 10 to the 37th power molecules of NO, or two orders of magnitude more stratospheric NO than might be produced in a large nuclear war. Researchers ignore potential injections of CO2 and wildfire smoke, and assume the direct heating of the atmosphere by impact ejecta on a regional scale is not large compared to absorption of solar energy by dust. Researchers assume an impact site at 45 N in the interior of present day North America.

Thompson, Starley L.↗
NASA NTRS1990

Critical evaluation of Jet-A spray combustion using propane chemical kinetics in gas turbine combustion simulated by KIVA-II

Numerical solutions of the Jet-A spray combustion were obtained by means of the KIVA-II computer code after Jet-A properties were added to the 12 chemical species the program had initially contained. Three different reaction mechanism models are considered. The first model consists of 131 reactions and 45 species; it is evaluated by comparing calculated ignition delay times with available shock tube data, and it is used in the evaluation of the other two simplified models. The simplified mechanisms consider 45 reactions and 27 species and 5 reactions and 12 species, respectively. In the prediction of pollutants NOx and CO, the full mechanism of 131 reactions is considered to be more reliable. The numerical results indicate that the variation of the maximum flame temperature is within 20 percent as compared with that of the full mechanism of 131 reactions. The chemical compositions of major components such as C3H8, H2O, O2, CO2, and N2 are of the same order of magnitude. However, the concentrations of pollutants are quite different.

Nguyen, H. L.↗
NASA NTRS1991

NASA aeropropulsion research in support of propulsion systems of the 21st century

A review is given of the NASA's ongoing and planned research and technology programs leading to advanced air breathing propulsion systems of the next century. The primary focus is on efforts being performed or sponsored by NASA-Lewis, with emphasis on civil, subsonic, and supersonic transportation systems which should begin to enter service within 10 to 20 years. Subsonic transport propulsion program elements, including ducted UltraHigh Bypass (UHB) engines and high efficiency cores are discussed in terms of goals, technical issues and problems, approaches and plans. Similarly, The Supersonic Cruise Propulsion Program is reviewed via discussion of near term and far term goals; barrier issues such as NOx and noise reduction and the consequent Phase 1 (near term) research plans are described; and finally, emerging technologies such as the supersonic through-flow fan are considered for their potential long term impact.

Ziemianski, Joseph A.↗
NASA NTRS1991

Numerical simulation of Jet-A combustion approximated by improved propane chemical kinetics

Through the effort devoted to the chemical kinetics for propane air combustion, three mechanisms are developed. The full mechanism consists of 131 reactions. This mechanism is used as a guide for the evaluation of other mechanisms, but because of the long expected cpu time, it is not to be incorporated into the computer code KIVA-II for actual simulation. Through the sensitivity analysis, a reduced mechanism of 45 reactions is produced. But the calculated results from the 45 reaction mechanism are always low in temperature. Some efforts are devoted to correct this situation and details are included in this report. A simplified mechanism of reactions is successfully improved and computed results are compared with experimental data. Contour plots of physical parameters and species concentrations and results for emission indices of CO and NOx are presented.

Ying, Shuh-Jing↗
NASA NTRS1991

A two-dimensional study of ethane and propane oxidation in the troposphere

The chemistry of ethane and propane is studied using a global two-dimensional 'zonally averaged' height- and latitude-dependent tropospheric model. The purpose of the study is to derive theoretical estimates of the seasonal and latitudinal distributions of a variety of intermediate organic compounds formed by the photochemical oxidation of C2H6 and C3H8. It is shown that C2H6 and C3H8 emitted at rates of 16 Tg C2H6/a and 23 Tg C3H8/a do not affect the overall photochemistry of the troposphere significantly. Major global effects on O3 and OH concentrations are suggested to be coming from the formation of peroxyacetyl nitrate by the interactions of NOx with other hydrocarbons with strong and spatially correlated anthropogenic or natural sources at the earth's surface. It is pointed out that attention should be given to organic nitrates produced by the oxidation of NMHC other than C2H6 and C3H8.

Kanakidou, M.↗
NASA NTRS1993

Nitrates in SNCs: Implications for the nitrogen cycle on Mars

Nitrogen is the second most abundant constituent of the Martian atmosphere, after CO2, present at a level of ca. 2.7 percent. Several authors have hypothesized that earlier in the planet's history, nitrogen was more abundant, but has been removed by processes such as exospheric loss from the atmosphere. However, an alternative sink for atmospheric nitrogen is the regolith; model calculations have predicted that, via the formation of NOx, HNO2 and HNO3 in the lower layers of the Martian atmosphere, the regolith might trap nitrite and nitrate anions, leading to the build-up of involatile nitrates. Integrated over 4.5 x 10(exp 9) yr, such a mechanism would contribute the equivalent of a layer of nitrates up to 0.3 cm thick distributed across the Martian surface. Features in thermal emission spectra of the surface of Mars have been interpreted tentatively as emanating from various anions (carbonates, bicarbonates, sulphates, etc.), and the presence of nitrates has also been addressed as a possibility. The identification of carbonates in SCN meteorites has allowed inferences to be drawn concerning the composition and evolution of the Martian atmosphere in terms of its carbon isotope systematics; if nitrites, nitrates, or other nitrogen-bearing salts could be isolated from SNC's, similar conclusions might be possible for an analogous nitrogen cycle. Nitrates are unstable, being readily soluble in water, and decomposed at temperatures between 50 C and 600 C, depending on composition. Any nitrates present in SNC's might be removed during ejection from the planet's surface, passage to Earth, or during the sample's terrestrial history, by weathering etc. The same might have been said for carbonates, but pockets of shock-produced glass (lithology C) from within the EET A79001 shergottite and bulk samples of other SNC contain this mineral, which did apparently survive. Nitrates occurring within the glassy melt pockets of lithology C in EET A79001 might likewise be protected. Lithology C glass was therefore selected for nitrate analysis, first by non-destructive infra red spectroscopy, and then by stepped combustion.

Grady, Monica M.↗
NASA NTRS1994

Theoretical determination of chemical rate constants using novel time-dependent methods

The work completed within the grant period 10/1/91 through 12/31/93 falls primarily in the area of reaction dynamics using both quantum and classical mechanical methodologies. Essentially four projects have been completed and have been or are in preparation of being published. The majority of time was spent in the determination of reaction rate coefficients in the area of hydrocarbon fuel combustion reactions which are relevant to NASA's High Speed Research Program (HSRP). These reaction coefficients are important in the design of novel jet engines with low NOx emissions, which through a series of catalytic reactions contribute to the deterioration of the earth's ozone layer. A second area of research studied concerned the control of chemical reactivity using ultrashort (femtosecond) laser pulses. Recent advances in pulsed-laser technologies have opened up a vast new field to be investigated both experimentally and theoretically. The photodissociation of molecules adsorbed on surfaces using novel time-independent quantum mechanical methods was a third project. And finally, using state-of-the-art, high level ab initio electronic structure methods in conjunction with accurate quantum dynamical methods, the rovibrational energy levels of a triatomic molecule with two nonhydrogen atoms (HCN) were calculated to unprecedented levels of agreement between theory and experiment.

Dateo, Christopher E.↗