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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

A comparison of measured and inferred temperatures from AEROS-B

The neutral composition and the temperature data obtained from the AEROS-B Neutral Atmosphere Temperature Experiment (NATE) and the Neutral and Ion Mass Spectrometer (NIMS) are compared, and the general validity of inferring gas temperatures from N2 and Ar density profiles is examined by comparing them with the in situ measured values of the neutral kinetic temperature (NATE). At times serious discrepancies are noted between the inferred and the measured temperature. This is particularly evident during periods of increased magnetic activity when the normally observed latitudinal variations are apparently modulated by waves propagating from the polar region to low latitudes. Under these conditions the N2 and Ar densities and temperature oscillations are usually out of phase, and the temperatures inferred from N2 and Ar at a given point become meaningless.

Chandra, S.↗
NASA NTRS1977

Air radiation in photographic meteor spectra

Air radiation (N, O, N2) is present in major amounts in the spectra of three high-geocentric-velocity photographic meteor spectra. These spectra are high-definition spectra with over 50 identifiable features in each. These meteor spectra are compared with N2 radiation from a Geissler tube and with calculated N2 first-positive band intensities. An 'effective vibrational temperature' of about 20,000 K is obtained from the nitrogen first-positive band relative intensities. Electron excitation is indicated as the primary excitation process.

Harvey, G. A.↗
NASA NTRS1978

Nuclear pumping of a neutral carbon laser

Nuclear pumped lasing on the neutral carbon line at 1.45 micron was achieved in mixtures of He-CO, He-N2-CO, He-CO2, and Ne-CO and Ne-CO2. A minimum thermal neutron flux of 2 x 10 to the 14th power sq cm-sec was sufficient for oscillation in the helium mixtures. The peak of the laser output was delayed up to 5.5 ms relative to the neutron pulse in He-CO2, He-N2-CO, Ne-CO, and Ne-CO2 mixtures while no delay was observed in He-CO mixtures. Lasing was obtained with helium pressures from 20 to 800 T, Ne pressures from 100 to 200 T, CO from 0.25 to 20 mT, N2 from 0.5 mT, and CO2 from 0.1 to 25 mT in the respective mixtures.

Prelas, M. A.↗
NASA NTRS1978

Airglow from the inner comas of comets

The intensities of radiation from the inner comas of comets which are composed primarily of water and carbon monoxide have been calculated. Only 'airglow' emissions initiated by the absorption of EUV radiation have been considered. The photoionizations of H2O, CO, CO2, and N2 are the most important emission sources, although photoelectron excitation is also considered. Among the emission features for which intensities were calculated are H2O(+), CO(+) (first negative), CO (fourth positive), CO (Cameron), CO2(+), N2 (Vegard-Kaplan), N2(+) (first negative), and O I (1304 A). In the inner coma (collision region) these airglow mechanisms are shown to be possible competitors with the usually assumed resonance-scattering and fluorescence-excitation mechanisms appropriate for the outer coma and tail.

Cravens, T. E.↗
NASA NTRS1978

Review of rate coefficients of ionic reactions determined from measurements made by the atmosphere explorer satellites

The large data base of aeronomic parameters measured by the Atmosphere Explorer C, D, and E satellites since December 1973 has been used to determine a number of reaction rate coefficients highly relevant to our understanding of thermospheric chemistry. In this paper the results are reviewed for ionic rate coefficients for recombination of NO(+), O2(+), for reactions of O(+) + N2, N2(+) + O, and O(++) + O, and for various reactions involving O(+)(2D) and O(+)(2P) ions with O and N2.

Torr, D. G.↗
NASA NTRS1978

Temperature effect on nitrogen-induced absorption of oxygen in the Herzberg continuum

The effect of temperature on the total absorption of O2 induced by collisions with N2 has been measured at various temperatures in the Herzberg continuum using a one-meter normal-incidence grating monochromator. It is observed that absorption increases as the temperature decreases, which is ascribed to changes in the rate of formation of the dimers O2-O2 and O2-N2. The interaction constants for these dimers are determined as functions of temperature and then utilized to calculate the heats of dissociation of O2-O2 and O2-N2. Their respective values are found to be 0.0146 + or - 0.001 and 0.425 + or - 0.002 eV. Also, the interaction constants for these dimers measured at 200 + or - 1 K are utilized to investigate their effect on the absorption of solar radiation in the stratosphere.

Shardanand, MR.↗
NASA NTRS1978

Nuclear pumping of a neutral carbon laser

Nuclear pumped lasing on the neutral carbon line at 1.45 microns has been achieved in mixtures of He-CO, He-N2-CO, He-CO2, and Ne-CO and Ne-CO2. A minimum thermal neutron flux of 2 x 10 to the 14th n/sq cm-sec was sufficient for oscillation in the helium mixtures. The peak of the laser output was delayed up to 5.5 ms relative to the neutron pulse in He-CO2, He-N2-CO, Ne-CO and Ne-CO2 mixtures while no delay was observed in He-CO mixtures. Lasing was obtained with helium pressures from 20 to 800 T, Ne pressures from 100 to 200 T, CO from 0.25 to 20 mT, N2 from 0.5 to 5 mT, and CO2 from 0.1 to 25 mT in the respective mixtures.

Prelas, M. A.↗
NASA NTRS1978

Atmospheric absorption spectra near 2200 kayser and 2400 kayser

Quantitative interpretation of radiometric measurements for temperature profiling requires the ability to accurately calculate the average transmittance across the sounding channel. Therefore, an accurate calculation of atmospheric absorption due to broad banded or continuum absorption features is as significant as one of features due to individual lines. The important broad banded features affecting atmospheric absorption in the 4.3 micrometer region are due to the pressure induced N2 fundamental (called the N2 continuum) and to wings of relatively nearby very saturated CO2 lines. Attention is given to the N2 continuum, the CO2 line shape, and calculated and observed line spectra.

Susskind, J.↗
NASA NTRS1979

Charge exchange of metastable 2D oxygen ions with molecular oxygen - A new source of thermospheric O2/+/ ions

Reactions involving metastable ions are difficult to study in the laboratory. Much new information on these reactions has been derived from satellite measurements of aeronomic parameters. In this paper, Atmosphere Explorer D data are used to study charge exchange of metastable O(+)(2D) ions with O2. Using direct measurements of the O2 at 200 km to compute O2 densities at 300 km and supporting ionic concentrations and temperature observations, we find the rate coefficient for this reaction to be 1 + or - 0.6 times 10 to the minus 9th cu cm/sec. The process constitutes a significant source of O2(+) ions in the F2 layer at times when the N2 and O2 densities are enhanced. This finding leads to the conclusion that charge exchange with O2 must be a major sink for O(+)(2D) and an important source of O2(+) ions in the E region, because of the increase in the O2 concentration/N2 concentration ratio with decreasing altitude. The results imply that 80% of all O(+) ions formed in the E region are converted to O2(+) and that only about 20% of the metastable O(+) ions are converted into N2(+) through charge exchange with N2.

Torr, D. G.↗
NASA NTRS1979

Determination of the sources and sinks of N/+/ ions in the thermosphere

Measurements of atmospheric parameters made by the Atmosphere Explorer-C satellite used to identify mechanisms for the production and loss of N(+) ions in the ionosphere are presented. Photo-dissociative ionization of N2 is the main source below 250 km. Above 250 km the reaction O(+)(4S) + N(2D) yields N(+)(3P) + O(3P) is dominant, and a possible minor source of N(+) is the reaction O(+)(2P) + N2 yields N(+) + NO. Photoionization of N(4S) and dissociative charge exchange of He(+) with N2 constitute detectable sources above 350 km. Charge exchange of N(+) with O is a significant sink above 300 km, and the rate coefficients for these reactions are derived.

Torr, D. G.↗
NASA NTRS1979

Determination of the auroral O/1S/ production sources from coordinated rocket and satellite measurements

This paper examines the auroral excitation mechanisms using data collected in a satellite/rocket/aurora coordination. Past theories considered that variation with altitude of the emission from the O(1S) state is the same as that from the N2(+) first negative band system. Actually, the source function for O(1S) does not covary with N2(+) but has a smaller scale height. The covariation is due to quenching of the source function by O(3P). The steadiness of the aurora in a flight of the Michigan Airglow Payload allows the profile to be differentiated for direct comparison with theory. It is concluded that when most of the relevant variables for production of the O(1S) state are simultaneously measured in aurora, the major source functions are dissociative recombination of O2(+) above 210 km to apogee at 250 km, and below 180 km the energy transfer from N2(A3sigma) in the oxygen atom quenching reaction.

Sharp, W. E.↗
NASA NTRS1979

Some effects of gas adsorption on the high temperature volatile release behavior of a terrestrial basalt, tektite and lunar soil

Mass pyrograms obtained from high-temperature, mass psectrometric pyrolysis of a glassy theoleiitic submarine basalt and a tektite, ground in air to less than 64 microns, have shown N2 and SO release patterns very similar to those from the pyrolysis of mature lunar soil fines. The N2 and CO release behavior from the terrestrial samples reproduces the biomodal, high-temperature (approximately 700 and 1050 C) features from the lunar samples. Unground portions of the basalt and tektite show no release of N2 and CO during pyrolysis. Grinding also alters the release behavior and absolute amounts of H2O and CO2. It is suggested that adsorption of atmospheric gases in addition to solar wind implantation of ions may account for the wide range of values in previously reported concentrations of carbon and nitrogen from lunar fines.

Graham, D. G.↗
NASA NTRS1980

Satellite studies of N/D-2/ emission and ion chemistry in aurorae

The incident particle flux ion and neutral composition data taken on the AE-D satellite have been used to investigate the quantal emission of N2(plus) at 4278 A, N(D-2) at 5200 A, and the ion chemistry in aurorae. The results of a time dependent auroral model have been compared to the data. The calculated 4278 A emission of N2(plus), the 5200 A emission of N(D-2), the densities of O2(plus), NO(plus), N2(plus), O(plus), and the electron density are generally in agreement with the measured values. These results are consistent with the branching ratios and quenching rates deduced from previous studies of the N(D-2) densities in the day-time, mid-latitude ionosphere. It is found that in an auroral arc, the measured atomic oxygen density is lower than predicted by the MSIS model.

Rusch, D. W.↗
NASA NTRS1980

Causes of the F region winter anomaly

Measurements made by the Atmosphere Explorer satellites are used to determine the causes of the F-region winter anomaly, i.e., seasonal variations which result in peak electron densities which are larger in winter than in summer. It is found that for the data examined there are three causes of the winter anomaly: (1) seasonal changes in neutral composition; (2) an increase in the vibrational temperature of N2 and hence in the rate coefficient for the reaction O(+)(4S) + N2 yields NO(+) + N; (3) an increase in winter in the production of O(+)(4S) due to enhanced electron quenching of O(+)(2D). The presence of vibrational excitation is inferred from an increase in the rate coefficient for the reaction O(+) + N2 yields NO(+) + N from winter to summer at heights above 260 km. It is demonstrated quantitatively that the initial increase in electron density produced in winter by causes (1) and (2) results in an increase in the quenching of O(+)(4S), thereby enhancing the source of O(+)(4S) ions. It is estimated that causes (1) to (3) account for approximately 55%, 20% and 25% respectively of the seasonal change in O(+)(4S) from summer to winter at solar minimum.

Torr, D. G.↗
NASA NTRS1980

The chemistry of excited NO/+/ in an aurora

The six most significant production and seven most significant loss mechanisms are identified for NO(+)(a3 Sigma) in the aurora. Rate constants are given for these reactions as well as for the 14 most important reactions competing with the production of NO(+)(a). Using available data and certain crucial deductions on chemical reaction rates to simulate a number of altitude profiles, it is concluded that the two predominant sources of NO(+)(a3 Sigma) are probably N(+) + O2 yields NO(+)(a) + O and N2(+) + NO yields NO(+)(a) + N2. Radiative decay is not the primary loss mechanism but can dominate above 150 km. Destruction via charge exchange with N2 and O are most important below 150 km.

Young, E. R.↗
NASA NTRS1982

Spectroscopic requirements for HALOE: An analysis of the HCl and HF channels

Spectral line parameters that have absorption features within the HCl and HF channels of the Halogen Occultation Experiment (HALOE) were evaluated. Line positions and identification of stratospheric and solar absorption features in both channels are presented based on an analysis of high-resolution, balloon-borne solar occultation spectra. For the relevant HCl and HF lines and for transitions of the interfering species, the accuracy of the following spectral parameters was assessed: line positions, line strengths, lower state energies, air-broadened collisional half-widths, and temperature dependence of the air-broadened half-widths. In addition, since the HALOE instrument and calibration cells are filled with mixtures of HCl in N2 and HF in N2, the self-broadened and N2-broadened HF and HCl half-widths were also considered.

Rinsland, C. P.↗
NASA NTRS1981

Energy accommodation of 5-50 eV ions within an enclosure

Beams of 5-50 eV He(+), Ar(+), Ne(+), O(+), and N2(+) ions were directed into an aluminum sphere, and the equilibrium number density of the atom or molecules was measured inside the sphere using a quadrupole mass spectrometer and signal averaging techniques. The equilibrium number density is inversely proportional to the average speed of the atoms; thus, the results are expressed in terms of the speed ratio, R = V(i)/V(s), where V(i) is the average speed within the enclosure, and V(s) is the average speed of atoms fully accommodated to the temperature of the wall. The speed ratios vary between 1.0 and 1.8. For N2, several values of R were less than 1; this was largely due to desorbed N2. There was no detectable number density for O, which is explained by the reaction of O with the surface.

Humphris, R. R.↗
NASA NTRS1982

EUV emission from Titan's upper atmosphere - Voyager 1 encounter

Most of the observed emission short of Lyman-alpha is shown to be accounted for by electron impact on N2 above 3600 km, in an analysis of Titan's EUV emission spectra obtained at the Voyager 1 encounter. It is determined that N2 is the major component of Titan's upper atmosphere, with 3900-km upper limit mixing ratios of NeI, ArI, CO, H2, and HI of 0.01, 0.06, 0.05, 0.06 and 0.1, respectively. Magnetospheric electron precipitation produces an average dayside electron density of about 3000/cu cm between 3600 and 4000 km, which is the region of bright limb emission, and magnetospheric electron impact dissociation of N2 generates an N atom escape rate of 3 x 10 to the 26th/sec from Titan's exosphere when Titan is within Saturn's magnetosphere.

Strobel, D. F.↗