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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29

Modification of Caloris ejecta blocks by long-lived mass-wasting: A volatile-driven process?

The Caloris basin is the largest well-preserved impact basin on Mercury. As such, Caloris ejecta afford us an opportunity to study material from Mercury's deep interior with remote sensing. We have made observations of the geomorphology, colour, distribution, and flank slopes of the circum-Caloris knobs. Our observations suggest that these circum-Caloris knobs are modified ejecta blocks from the Caloris impact. High-resolution MESSENGER images show that knobs are conical and relatively uncratered compared with the surrounding plains, which implies the knobs have undergone resurfacing. We have observed material that has sloughed off knobs superposing impact craters that demonstrably postdate the Caloris impact, which requires some knob modification to have been more recent. We have observed hollows, depressions in Mercury's surface generally believed to have been caused by volatile-loss, on and closely associated with several knobs, which indicates that many knobs contain volatile material and that knob modification could extend into Mercury's recent past. Our measurements show that knob flanks typically have slopes of ∼21°, which is steep for a mound of unconsolidated material that was originally emplaced ∼3.8 Ga. The conical shape of knobs, their steep slopes, the dearth of superposed craters on knobs, and knob superposition relationships with other landforms suggest that Caloris ejecta blocks of arbitrary original shape were modified into their present shapes by long-lived mass-wasting. Mass-wasting must have dominated over impact gardening, which would have produced domal morphologies only. We suggest that mass-wasting was probably driven by volatile-loss, in a manner analogous to terrestrial landforms called ‘molards’. If the circum-Caloris knobs are analogous to molards, then they represent a landform and a process hitherto undocumented on Mercury, with implications for the volatile content of the planet's interior. These knobs therefore are prime targets for BepiColombo, which could search for fresh failures and volatile exposures in the knobs.

Mercury; Caloris basin; impact ejecta; volatiles; ↗

TOPEX Microwave Radiometer Thermal Control: Post-System-Test Modifications and On-Orbit Performance

The Topex Microwave Radiometer has had an excellent thermal performance since launch. The instrument, however, went through a hardware modification right before launch to correct for athermal design inadequacy that was uncovered during the spacecraft thermal vacuum test. This paper reports on how the initially obscure problem was tracked down, and how the thermal models were revised, validated, and utilized to investigate the solution options and guide the hardware modification decisions. Details related to test data interpretation, analytical uncertainties, and model-prediction vs. test-data correlation, are documented. Instrument/spacecraft interface issues, where the problem originated and where in general pitfalls abound, are dealt with specifically. Finally, on-orbit thermal performance data are presented, which exhibit good agreement with flight predictions, and lessons learned are discussed.

Lin, Edward I.↗

NASA Universal Waste Management System and Toilet Integration Hardware Operations on ISS – Issues, Modifications and Accomplishments

The Universal Waste Management System (UWMS), which has the ISS operational nomenclature “Toilet”, was initially installed on the International Space Station (ISS) in 2020with final installation completed in 2021. Although technical issues were encountered that delayed installation and operations, progress was made towards the objectives of the project. Technical issue work arounds resulted in operation of the Toilet with use by male and female crew members in a controlled extended checkout and a longer nominal use. This paper will summarize operations of the Toilet and Toilet Integration Hardware in both of those configurations, problems encountered during installation and checkout, the modifications made to allow further usage on ISS, and the future modifications planned for nominal use. It will also describe the portions of the technology demonstration that were completed and the benefits from that work and how that knowledge informs the Orion-installed UWMS unit and future manifesting of consumables for both Orion and ISS.

life support↗

NASA Universal Waste Management System and Toilet Integration Hardware Operations on ISS – Issues, Modifications and Accomplishments

The Universal Waste Management System (UWMS), which has the ISS operational nomenclature “Toilet”, was initially installed on the International Space Station (ISS) in 2020 with final installation completed in 2021. Although technical issues were encountered that delayed installation and operations, progress was made towards the objectives of the project. Technical issue work-arounds resulted in operation of the Toilet with use by male and female crew members in a controlled extended checkout. This paper will summarize operations of the Toilet and Toilet Integration Hardware in this limited configuration, problems encountered during installation and checkout, the modifications made to allow further usage on ISS, and the future modifications planned for nominal use. It will also describe the portions of the technology demonstration that were completed and the benefits from that work and how that knowledge informs the Orion-installed UWMS unit and future manifesting of consumables for both Orion and ISS.

Toilet↗

Surface modification agents for lithium batteries

A method includes modifying a surface of an electrode active material including providing a solution or a suspension of a surface modification agent; providing the electrode active material; preparing a slurry of the solution or suspension of the surface modification agent, the electrode active material, a polymeric binder, and a conductive filler; casting the slurry in a metallic current collector; and drying the cast slurry.

25 ENERGY STORAGE↗

Organic light emitting diode with surface modification layer

An organic light emitting diode (10) includes a substrate (12) having a first surface (14) and a second surface (16), a first electrode (32), and a second electrode (38). An emissive layer (36) is located between the first electrode (32) and the second electrode (38). The organic light emitting diode (10) further includes a surface modification layer (18). The surface modification layer (18) includes a non-planar surface (30, 52).

36 MATERIALS SCIENCE↗

Surface modification agents for lithium batteries

An active material for an electrochemical device wherein a surface of the active material is modified by a surface modification agent, wherein the surface modification agent is an organometallic compound.

36 MATERIALS SCIENCE↗

JLab cryomodule assembly infrastructure modifications for LCLS-II

The Thomas Jefferson National Accelerator Facility is currently engaged, along with several other DOE national laboratories, in the Linac Coherent Light Source II project (LCLS II). The SRF Institute at Jefferson Lab will be building 1 prototype and 17 production cryomodules based on the TESLA / ILC / XFEL design. Each cryomodule will contain eight nine cell cavities with coaxial power couplers operating at 1.3 GHz. New and modified infrastructure and assembly tooling is required to construct cryomodules in accordance with LCLS-II requirements. The approach for modifying assembly infrastructure included evaluating the existing assembly infrastructure implemented at laboratories world-wide in support of ILC and XFEL production activities and considered compatibility with existing infrastructure at JLab employed for previous cryomodule production projects. These modifications include capabilities to test cavities, construct cavity strings in a class 10 cleanroom environment, assemble cavity strings into cryostats, and prepare cryomodules for cryogenic performance testing. This paper will give a detailed description of these modifications.

Daly, Edward F.↗

WTP Modifications to Support DFLAW: LAW, BOF, Lab - 16219

The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is a one-of-a-kind nuclear waste treatment facility being designed and constructed for the U.S. Department of Energy by Bechtel National, Inc. and principal subcontractor URS to process and vitrify radioactive waste stored in underground tanks at the Hanford Site. The Tank Operations Contractor, Washington River Protection Solutions, has responsibility to retrieve, stage, pretreat, and deliver the tank waste feed to WTP. To treat tank waste as soon as practicable, a scenario is being considered to deliver pretreated feed straight to WTP's Low-Activity Waste (LAW) Vitrification Facility. This scenario is called the Direct Feed LAW (DFLAW) program. Balance of Facility utility and system facilities are designed for full WTP operation. Thirteen of these are needed to support reduced throughput during DFLAW operation, of which eight require moderate to extensive changes. Extensive changes include permanent plant modifications that allow DFLAW to operate if the Pretreatment (PT) Facility is unavailable. Under full WTP operation, effluents from the LAW Facility will be returned to the PT Facility for further processing and/or transfer to the Liquid Effluent Retention Facility/Effluent Treatment Facility. The PT Facility also handles all flush water from the tank farm transfers. To address these requirements, a Value Improvement Project was performed. The recommended approach is to provide a 'split stream' Effluent Management Facility (EMF) with an evaporator to support DFLAW. The required modifications for DFLAW facilities are discussed in this paper. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Across the Scales of the Nucleus: Understanding Short Range Correlations from Medium Modification to Probe Independence

The atomic nucleus presents an intricate system due to the non-linear forces described by Quantum Chromodynamics (QCD) that govern its structure. The range of scales involved is remarkable; the most massive nuclei weigh approximately five orders of magnitude more than the quarks that compose them. The nucleus can be analyzed at various levels, from quarks to hadrons to the nucleus as a whole. Short-Range Correlations (SRCs) within the nucleus play a significant role that spans these diverse scales. At the most fundamental level, SRCs influence the interaction between nucleons. The nucleon-nucleon (NN) interaction, arising from QCD, is crucial in determining nuclear properties. SRCs serve as valuable probes for measuring this NN interaction, as the nucleons within SRCs become effectively decoupled from the rest of the nucleus. Multiple experimental techniques, including electron scattering, have been employed to investigate the NN interaction through SRCs. However, our first project demonstrates that inclusive measurements alone are inadequate to constrain this interaction fully. Moving to the scale of the nucleus, SRCs contribute to the high-momentum tail of the nuclear spectral function. While the low-momentum region is characterized by nucleons exhibiting bulk properties, nucleons begin to pair into SRCs at higher momenta. Our research aims to bridge the understanding between the mean-field portion of the nucleus and its high-momentum SRC components. Additionally, SRCs affect the quark structure of protons, as evidenced by the EMC effect, which indicates that quarks behave differently when protons are embedded within a nucleus—an effect referred to as medium modification. This thesis explores the correlation between SRCs and medium modification across various experimental setups. Finally, we seek to establish an interpretation of the nuclear ground state. Accomplishing this requires demonstrating that our SRC observables are independent of the probe’s scale and scheme. The concluding project of this thesis illustrates how we utilize triple coincidence quasi-elastic scattering across a range of (Q2) values to develop a model-dependent framework for understanding SRC distributions within the nucleus’s ground-state wavefunction.

Denniston, A. W. Denniston [University of Tel Aviv↗

Post-translational modifications: emerging directors of cell-fate decisions during endoplasmic reticulum stress in Arabidopsis thaliana

Homeostasis of the endoplasmic reticulum (ER) is critical for growth, development, and stress responses. Perturbations causing an imbalance in ER proteostasis lead to a potentially lethal condition known as ER stress. In ER stress situations, cell-fate decisions either activate pro-life pathways that reestablish homeostasis or initiate pro-death pathways to prevent further damage to the organism. Understanding the mechanisms underpinning cell-fate decisions in ER stress is critical for crop development and has the potential to enable translation of conserved components to ER stress-related diseases in metazoans. Post-translational modifications (PTMs) of proteins are emerging as key players in cell-fate decisions in situations of imbalanced ER proteostasis. In this review, we address PTMs orchestrating cell-fate decisions in ER stress in plants and provide evidence-based perspectives for where future studies may focus to identify additional PTMs involved in ER stress management.

59 BASIC BIOLOGICAL SCIENCES↗

Simultaneously Enhanced Hydrophilicity and Stability of a Metal-Organic Framework via Post-Synthetic Modification for Water Vapor Sorption/Desorption

With increasing demands for high-performance water sorption materials, metal-organic frameworks (MOFs) have gained considerable attention due to their high maximum uptake capacities. In many cases, however, high overall capacity is not necessarily accomplishing high working capacity under operating conditions, due to insufficient hydrophilicity and/or water stability. Herein, we present a post-synthetic modification (PSM) of MOF-808, with di-sulfonic acids enhancing simultaneously its hydrophilicity and water stability without sacrificing its uptake capacity of ≈30 mmol g -1 . Further, di-sulfonic acid PSM enabled a shift of the relative humidity (RH) associated with a sharp step in water vapor sorption from 35–40 % RH in MOF-808 to below 25 % RH. While MOF-808 lost uptake capacity and crystallinity over multiple sorption/desorption cycles, the di-sulfonic acid PSM MOF-808 retained >80 % of the original capacity. PSM MOF-808 exhibited good hydrothermal stability up to 60 °C and high swing capacity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Modification of ZIF‐8 Membranes for Gas Separation Using X‐ray Radiation

Here, we report an X-ray radiation-induced modification of the structure and gas permeation behavior of ZIF-8 membranes. With 300 min irradiation time, CO 2 permeance decreases by only 9 %, while N 2 and CH 4 permeances reduce by 75 and 65 %, respectively, leading to 3.7- and 2.6-fold enhancements in ideal selectivity for CO 2 /N 2 and CO 2 /CH 4 .

ZIF-8 membranes↗

Understanding the Effects of Bi Modification on the Properties of Ni-Rich Cathodes

With the skyrocketing market demands for energy storage, lithium ions batteries (LIB) with higher energy density are urgently needed. Cathodes play a critical role in determining the energy density of LIB, and the most popular one is Ni-rich cathode due to its high capacity. However, due to the fast structural degradation, Ni-rich cathode materials should be further modified to achieve higher stability. Herein, we introduce bismuth ions in LiNi 0.83 Co 0.11 Mn 0.06 O 2 cathodes by adding Bi 2 O 3 during sintering to optimize the specific capacity and cycle stability. By adding 0.1% mol Bi, the Li + diffusion and structural stability are effectively optimized, leading to improved electrochemical performances. Further, the modified sample delivers much higher specific capacity (222.9 mAhg -1 , 0.05 C) than unmodified sample (204 mAhg -1 , 0.05 C). Meanwhile, the specific capacity of optimized sample after 100 cycles at 0.33 C is 27.75 mAhg -1 higher than that of unmodified sample. Therefore, this work demonstrates that Bi modification can be regarded as a possible solution to optimizing the electrochemical performance of Ni-rich cathodes.

25 ENERGY STORAGE↗

Selective Covalent Basal Plane Modification as a Probe of Hydroxide Ion Conduction Pathways in Magnesium Aluminum Layered Double Hydroxides

Understanding ionic conduction in layered double hydroxides (LDHs) is a crucial step towards utilizing them as solid, hydroxide ion‐conducting electrolytes in energy conversion applications. We selectively modified the interlayer and external surfaces of MgAl LDHs with tris(hydroxymethyl)aminomethane (TRIS) ligands. By adjusting the concentration of the TRIS surface modifier, the LDH basal plane surfaces could be functionalized everywhere (internally and externally) or only externally. External modification resulted in loss of OH‐conductivity compared to pristine LDHs, confirming that external platelet surfaces are the primary ion conduction pathway.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Temporal dynamics of protein and post-translational modification abundances in Populus leaf across a diurnal period

Populus spp. are dedicated woody biomass feedstocks for advanced biofuels and bioproducts. Proper growth and fitness of poplar as a sustainable feedstock depends on timely perception and response to environmental signals (e.g., light, temperature, water). Poplar leaves, like other C3 photosynthesis plants, have evolved oscillating or circadian rhythms that play important roles in synchronizing biological processes with external cues. To characterize this phenomenon at a molecular level, we employed bottom-up proteomics using high-resolution mass spectrometry and de novo-assisted database searching to identify abundance changes in proteins and post-translational modifications in poplar leaf tissue sampled across a 12/12-hour light/dark diurnal period.

09 BIOMASS FUELS↗

Thiol redox proteomics: Characterization of thiol-based post-translational modifications

Redox post-translational modifications on cysteine thiols (redox PTMs) have profound effects on protein structure and function, thus enabling regulation of various biological processes. Redox proteomics approaches aim to characterize the landscape of redox PTMs at the systems level. These approaches facilitate studies of condition-specific, dynamic processes implicating redox PTMs and have furthered our understanding of redox signaling and regulation. Mass spectrometry (MS) is a powerful tool for such analyses which has been demonstrated by significant advances in redox proteomics during the last decade. A group of well-established approaches involves the initial blocking of free thiols followed by selective reduction of oxidized PTMs and subsequent enrichment for downstream detection. Alternatively, novel chemoselective probe-based approaches have been developed for various redox PTMs. Direct detection of redox PTMs without any enrichment has also been demonstrated given the sensitivity of contemporary MS instruments. This review discusses the general principles behind different analytical strategies and covers recent advances in redox proteomics. Several applications of redox proteomics are also highlighted to illustrate how large-scale redox proteomics data can lead to novel biological insights.

59 BASIC BIOLOGICAL SCIENCES↗

Modification of the plasma-prepared As–Se–Te films and creation on their base the planar waveguides by continuous laser writing

As a result of the previous experiments (Mochalov et al. in Opt Quant Electron 49(8):274:1–274:11, 2017), it was found that the Te-based chalcogenide films prepared by plasma deposition have a transparency window in the range from 1.2 to 20 μm and cannot be modified in the two-photon absorption mode, and in the linear absorption mode only the thermal effects were observed leading to crystallization of the films or their destruction. In this work, PECVD-prepared As–Se–Te films were modified by continuous laser irradiation of different wavelengths—473, 632.8 and 808 nm. For the modification, samples with compositions As{sub 40}Se{sub 50}Te{sub 10} and As{sub 40}Se{sub 44}Te{sub 16} were deposited on a substrate of epi-polished crystalline sapphire. This paper presents the results of studying of the effect of continuous laser radiation on the optical and structural properties of the chalcogenide films samples. Also, planar waveguided structures based on the As–Se–Te films were formed and investigated.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗