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At least 523 records · Page 29

Laboratory IR Detection of H2O, CO2 in Ion-Irradiated Ices Relevant to Europa

Hydrogen peroxide has been identified on Europa (Carlson et al. 1999) based in part on the 3.50 micron absorption feature observed in Galileo NIMS spectra. The observed feature was fitted with laboratory reflectance spectra of H2O + H2O2. Since condensed phase molecules on Europa (H2O, CO2, SO2, and H2O2) are bombarded with a significant flux of energetic particles (H(+), O(n+), S(n+) and e-), we examined the proton irradiation of H2O at 80 K and the conditions for the IR detection of H2O2 near 3.5 microns. Contrary to expectations, H2O2 was not detected if pure H2O ice was irradiated at 80 K. This was an unexpected result since, H2O2 was detected if pure H2O was irradiated at 18 K. We find, however, that if H2O ice contains either O2 or CO2 then H2O2 is detected after irradiation at 80 K (Moore and Hudson, 1999). The source of O2 for the H2O ice on Europa could come from surface interactions with the tenuous oxygen atmosphere, or from the bombardment of the surface by O(n+).

Moore, Marla H.↗

A High Spatial Resolution Study of Far IR Emission of Galaxies

This grant funded observations, data reduction, professional publications and travel for scientific efforts on the Kuiper Airborne Observatory. The research project was successfully completed. New insights into the distribution of far infrared emission across star forming regions was obtained, and student training was achieved. The efforts contributed towards new observing strategies, such as calibration and intercomparison of data from different infrared astronomical observing platforms, that will impact future NASA missions, such as SOFIA. The results of the effort have been presented in several papers in the refereed literature, including: "The Structure of IR Luminous Galaxies at 100 Microns". " Far Infrared Thermal Emission from the Inner Cooling Flow Region of NGC1275". "Distribution of Light in the "Dusty Hand" Galaxy NGC2146".

Caldwell, Barrie A.↗

IR Spectra and Bond Energies Computed Using DFT

The combination of density functional theory (DFT) frequencies and infrared (IR) intensities and experimental spectra is a very powerful tool in the identification of molecules and ions. The computed and measured isotopic ratios make the identification much more secure than frequencies and intensities alone. This will be illustrated using several examples, such as Mn(CO)n and Mn(CO)n-. The accuracy of DFT metal-ligand bond energies will also be discussed.

Bauschlicher, Charles↗

Effects of Palagonitic Dust Coatings on Visible, Near-IR, and Mossbauer Spectra of Rocks and Minerals: Implication for Mineralogical Remote Sensing of Mars

Visible, near-IR, and Mossbauer measurements on dust coated rocks and minerals show that a 300 5m thick layer is required to obscure the substrate for VNIR measurements and that a greater than 2000-micron-thick layer is required to obscure the substrate for Mossbauer measurements. Additional information is contained in the original extended abstract.

Morris, R.↗

Tropospheric Ozone Near-Nadir-Viewing IR Spectral Sensitivity and Ozone Measurements from NAST-I

Infrared ozone spectra from near nadir observations have provided atmospheric ozone information from the sensor to the Earth's surface. Simulations of the NPOESS Airborne Sounder Testbed-Interferometer (NAST-I) from the NASA ER-2 aircraft (approximately 20 km altitude) with a spectral resolution of 0.25/cm were used for sensitivity analysis. The spectral sensitivity of ozone retrievals to uncertainties in atmospheric temperature and water vapor is assessed in order to understand the relationship between the IR emissions and the atmospheric state. In addition, ozone spectral radiance sensitivity to its ozone layer densities and radiance weighting functions reveals the limit of the ozone profile retrieval accuracy from NAST-I measurements. Statistical retrievals of ozone with temperature and moisture retrievals from NAST-I spectra have been investigated and the preliminary results from NAST-I field campaigns are presented.

Zhou, Daniel K.↗

Cloud Overlapping Detection Algorithm Using Solar and IR Wavelengths with GOES Data Over ARM/SGP Site

One of the most perplexing problems in satellite cloud remote sensing is the overlapping of cloud layers. Although most techniques assume a one layer cloud system in a given retrieval of cloud properties, many observations are affected by radiation from more than one cloud layer. As such, cloud overlap can cause errors in the retrieval of many properties including cloud height, optical depth, phase, and particle size. A variety of methods have been developed to identify overlapped clouds in a given satellite imager pixel. Baum et al used CO2 slicing and a spatial coherence method to demonstrate a possible analysis method for nighttime detection of multilayered clouds. Jin and Rossow also used a multispectral CO2 slicing technique for a global analysis of overlapped cloud amount. Lin et al. used a combination infrared (IR), visible (VIS), and microwave data to detect overlapped clouds over water. Recently, Baum and Spinhirne proposed a 1.6 and 11 micron bispectral threshold method. While all of these methods have made progress in solving this stubborn problem none have yet proven satisfactory for continuous and consistent monitoring of multilayer cloud systems. It is clear that detection of overlapping clouds from passive instruments such as satellite radiometers is in an immature stage of development and requires additional research. Overlapped cloud systems also affect the retrievals of cloud properties over the Atmospheric Radiation Measurement (ARM) domains and hence should be identified as accurately as possible. To reach this goal, it is necessary to determine which information can be exploited for detecting multilayered clouds from operational meteorological satellite data used by ARM. This paper examines the potential information available in spectral data available on the Geostationary Operational Environmental Satellite (GOES) imager and the National Oceanic Atmospheric Administration (NOAA) Advanced Very High Resolution Radiometer (AVHRR) used over the ARM Program's Southern Great Plains (SGP), and North Slope of Alaska (NSA) sites to study the capability of detecting overlapping clouds.

Kawamoto, K.↗

High Resolution 4.7 Micron Keck/NIRSPEC Spectra of Protostars: Ices and Infalling Gas in the Disk of L1489 IRS - 1

We explore the infrared M band (4.7 micron) spectrum of the class I protostar L1489 IRS in the Taurus Molecular Cloud. This is the highest resolution wide coverage spectrum at this wavelength of a low mass protostar observed to date (R =25,000; (Delta)v =12 km s(exp -1). A large number of narrow absorption lines of gas phase (12)CO, (13)CO, and C(sup 18)O are detected, as well as a prominent band of solid (12)CO. The gas phase (12)CO lines have red shifted absorption wings (up to 100 km s(exp -1)), which likely originate from warm disk material falling toward the central object. Both the isotopes and the extent of the (12)CO line wings are successfully fitted with a contracting disk model of this evolutionary transitional object. This shows that the inward motions seen in millimeter wave emission lines continue to within approx. 0.1 AU from the star. The amount of high velocity infalling gas is however overestimated by this model, suggesting that only part of the disk is infalling, e.g. a hot surface layer or hot gas in magnetic field tubes. The colder parts of the disk are traced by the prominent CO ice band. The band profile results from CO in 'polar' ices (CO mixed with H2O), and CO in 'apolar' ices. At the high spectral resolution, the 'apolar' component is, for the first time, resolved into two distinct components, likely due to pure CO and CO mixed with CO2, O2 and/or N2. The ices have probably experienced thermal processing in the upper disk layer traced by our pencil absorption beam: much of the volatile 'apolar' ices has evaporated, the depletion factor of CO onto grains is remarkably low (approx. 7%), and the CO2 traced in the CO band profile was possibly formed energetically. This study shows that high spectral resolution 4.7 micron observations provide important and unique information on the dynamics and structure of protostellar disks and the origin and evolution of ices in these disks.

Boogert, A. C. A.↗

Mid- and Far-IR Spectroscopy of the Nebular Phase of SN1987A

The mid- and far-infrared (IR) spectra of the nebular phase of SM 987A spans 250 days through more than 1000 days after the event. Analysis of the spectra, largely obtained from the Kuiper Airborne Observatory, leads to a rich picture of the structure of the supernebula. The evidence for dust grain formation. In the nebula after about 580 days will be reviewed. The dust continuum emission spectrum was gray and dust appears to have condensed in optically thick 'clumps' throughout a significant fraction of the nebula. Additional information is contained in the original extended abstract.

Wooden, Diane↗

Seasonal and Global Variations of Water Vapor and High Clouds Observed with MODIS near-IR Channels

The NASA Moderate Resolution Imaging Spectrometer (MODIS) on the Terra Spacecraft has been collecting scientific data since February of 2000. MODIS is a major facility instrument for remote sensing of the atmosphere, land surfaces, and ocean color. On the MODIS instruments, there are five channels located within and around the .0.94 micron water vapor band absorption region for remote sensing of atmospheric water vapor. There is also a channel located at 1.375 micron for detecting thin cirrus clouds. We will describe the basic principles for using these near-IR channels for remote sensing of water vapor and high clouds. Based on our analysis of two years# measurements with these channels, we have found that reliable observations of water vapor and high clouds on regional and global scales can be made. We will present results on daily, seasonal and annual variations of water vapor and high clouds.

Gao, Bo-Cai↗

Use of FT-IR Analysis to Support Contamination Studies for Bonding Surfaces

The FT-IR analysis technique has become increasingly important for measuring and verifying coating levels on calibration standards and bonding specimens used to evaluate the effects of contamination on rocket motor bondlines. Use of this technique for evaluating solvent effectiveness for contamination removal is also increasing. Typical testing scenarios, analysis techniques and instrumentation used at MSFC will be described.

Boothe, Richard↗

Optical Testing of Diamond Machined, Aspheric Mirrors for Groundbased, Near-IR Astronomy

The Infrared Multi-Object Spectrometer (IRMOS) is a facility-class instrument for the Kitt Peak National Observatory 4 and 2.1 meter telescopes. IRMOS is a near-IR (0.8-2.5 micron) spectrometer and operates at approximately 80 K. The 6061-T651 aluminum bench and mirrors constitute an athermal design. The instrument produces simultaneous spectra at low- to mid-resolving power (R=lambda/delta lambda= 300-3000) of approximately 100 objects in its 2.8 x 2.0 arcmin field. We describe ambient and cryogenic optical testing of the IRMOS mirrors across a broad range in spatial frequency (figure error, mid-frequency error, and microroughness). The mirrors include three rotationally symmetric, off-axis conic sections, one off-axis biconic, and several flat fold mirrors. The symmetric mirrors include convex and concave prolate and oblate ellipsoids. They range in aperture from 94x86 mm to 286x269 mm and in f-number from 0.9 to 2.4. The biconic mirror is concave and has a 94x76 mm aperture, R(sub x)=377 mm, k(sub x)=0.0778, R(sub y)=407 mm, and k(sub y)=0.1265 and is decentered by -2 mm in X and 227 mm in Y. All of the mirrors have an aspect ratio of approximately 6:1. The surface error fabrication tolerances are less than 10 nm RMS microroughness, 'best effort' for mid-frequency error, and less than 63.3 nm RMS figure error. Ambient temperature (approximately 293 K) testing is performed for each of the three surface error regimes, and figure testing is also performed at approximately 80 K. Operation of the ADE Phaseshift MicroXAM white light interferometer (micro-roughness) and the Bauer Model 200 profilometer (mid-frequency error) is described. Both the sag and conic values of the aspheric mirrors make these tests challenging. Figure testing is performed using a Zygo GPI interferometer, custom computer generated holograms (CGH), and optomechanical alignment fiducials. Cryogenic CGH null testing is discussed in detail. We discuss complications such as the change in prescription with temperature and thermal gradients. Correction for the effect of the dewar window is also covered. We discuss the error budget for the optical test and alignment procedure. Data reduction is accomplished using commercial optical design and data analysis software packages. Results from CGH testing at cryogenic temperatures are encouraging thus far.

Chambers, V. John↗

On the Prospects of Measuring the Cosmic History of Element Synthesis with Future Far-IR/Submillimeter Observatories

To understand the cosmic history of element synthesis it will be important to obtain extinction-free measures of the heavy element contents of high-redshift objects and to chart two monumental events: the collapse of the first metal-free clouds to form stars, and the initial seeding of the universe with dust. The information needed to achieve these objectives is uniquely available in the far-infrared/submillimeter (FIR/SMM) spectral region. Following the Decadal Report and anticipating the development of the Single Aperature Far-IR (SAFIR) telescope capabilities of a large-aperature, background-limited FIR/SMM observatory and an interferometer on a boom, and discuss how such instruments could be used to measure the element synthesis history of the universe.

Leisawitz, David↗

Limitations on Space-based Air Fluorescence Detector Apertures obtained from IR Cloud Measurements

The presence of clouds between an airshower and a space-based detector can dramatically alter the measured signal characteristics due to absorption and scattering of the photonic signals. Furthermore, knowledge of the cloud cover in the observed atmosphere is needed to determine the instantaneous aperture of such a detector. Before exploring the complex nature of cloud-airshower interactions, we examine a simpler issue. We investigate the fraction of ultra-high energy cosmic ray events that may be expected to occur in volumes of the viewed atmosphere non-obscured by clouds. To this end, we use space-based IR data in concert with Monte Carlo simulated 10(exp 20) eV airshowers to determine the acceptable event fractions. Earth-observing instruments, such as MODIS, measure detailed cloud configurations via a CO2-slicing technique that can be used to determine cloud-top altitudes over large areas. Thus, events can be accepted if their observed 3-dimensional endpoints occur above low clouds as well as from areas of cloud-free atmosphere. An initial analysis has determined that by accepting airshowers that occur above low clouds, the non-obscured acceptance can be increased by approximately a factor of 3 over that obtained using a cloud-free criterion.

White, Nicholas E.↗

HST/STIS results on circumstellar disks and jets, future coronography and technology for IR multi-object spectroscopy

Results of studies of circumstellar disks and jets obtained by HST/STIS visible coronagraphy and UV spectroscopy, and by ground-based Fabry-Perot coronagraphy will be presented. Future improvements in coronagraphy will be discussed. The development of microshutter arrays as programmable multi-object selectors for the NGST near IR spectrograph will be described.

Woodgate, Bruce E.↗

Palagonitic Mars from Rock Rinds to Dust: Evidence from Visible, Near-IR, and Thermal Emission Spectra of Poorly Crystalline Materials

Visible and near-IR (VNIR) spectral data for Martian bright regions are characterized by a general shape consisting of a ferric absorption edge extending from about 400 to 750 nm and relatively constant reflectivity extending from about 750 nm to beyond 2000 nm . Among terrestrial geologic materials, the best spectral analogues are certain palagonic tephras from Mauna Kea Volcano (Hawaii). By definition, palagonite is a yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass. The ferric pigment in palagonite is nanometer-sized ferric oxide particles (np-Ox) dispersed throughout the hydrated basaltic glass matrix. The hydration state of the np-Ox particles is not known, and the best Martian spectral analogues contain allophane-like materials and not crystalline phyllosilicates. We show here that laboratory VNIR and TES spectra of palagonitic alteration rinds developed on basaltic rocks are spectral endmembers that provide a consistent explanation for both VNIR and TES data of Martian dark regions.

Morris, R. V.↗

Formations of Tethered Spacecraft as Stable Platforms for Far IR and Sub-mm Astronomy

In this paper we describe current research in tethered formations for interferometry, and a roadmap to demonstrating the required key technologies via on-ground and in-orbit testing. We propose an integrated kilometer-size tethered spacecraft formation flying concept which enables Far IR and Sub-mm astronomy observations from space. A rather general model is used to predict the dynamics, control, and estimation performance of formations of spacecraft connected by tethers in LEO and deep space. These models include the orbital and tethered formation dynamics, environmental models, and models of the formation estimator/controller/commander. Both centralized and decentralized control/sensing/estimation schemes are possible, and dynamic ranges of interest for sensing/control are described. Key component/subsystem technologies are described which need both ground-based and in-orbit demonstration prior to their utilization in precision space interferometry missions using tethered formations. Defining an orbiting formation as an ensemble of orbiting spacecraft performing a cooperative task, recent work has demonstrated the validity of the tethering the spacecraft to provide both the required formation rigidity and satisfy the formation reconfiguration needs such as interferometer baseline control. In our concept, several vehicles are connected and move along the tether, so that to reposition them the connecting tether links must vary in length. This feature enables variable and precise baseline control while the system spins around the boresight. The control architecture features an interferometer configuration composed of one central combiner spacecraft and two aligned collector spacecraft. The combiner spacecraft acts as the formation leader and is also where the centralized sensing and estimation functions reside. Some of the issues analyzed with the model are: dynamic modes of deformation of the distributed structure, architecture of the formation sensor, and sources of dynamical perturbation that need to be mitigated for precision operation in space. Examples from numerical simulation of an envisioned scenario in heliocentric orbit demonstrate the potential of the concept for space interferometry.

Quadrelli, Marco B.↗

Probing the Invisible Universe: The Case for Far-IR/Submillimeter Interferometry

The question "How did we get here and what will the future bring?"captures the human imagination and the attention of the National Academy of Science's Astronomy and Astrophysics Survey Committee (AASC). Fulfillment of this fundamental goal requires astronomers to have sensitive, high angular and spectral resolution observations in the far-infrared/submillimeter (far- IR/sub-mm) spectral region. With half the luminosity of the universe and vital information about galaxy, star and planet formation, observations in this spectral region require capabilities similar to those currently available or planned at shorter wavelengths. In this paper we summarize the scientific motivation, some mission concepts and technology requirements for far-IR/sub-mm space interferometers that can be developed in the 2010-2020 timeframe.

Leisawitz, D.↗