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At least 523 records · Page 29

MALDI TOF MS: An Exobiology Surface-Science Approach for Europa

If Europa is to be of primary exobiological interest, namely as a habitat for extant life, it is obvious that: (i) a hydrosphere must prevail beneath the cryosphere for a long time, (ii) internal energy sources must be present in a sufficient state of activity, and (iii) a reasonable technical means must be available for assessing if indeed life does exist in the hypothesized hydrosphere. This discussion focuses on technological issues, because the compounding evidence about Europa indicates that the first two are highly likely to be true. We present a consideration of time-of-flight mass spectroscopy (TOF MS) conducted in-situ on the cryosphere surface of Europa during a landed robotic mission. We assert that this is a reasonable technical means not only for exploring the composition of the cryosphere itself, but also for locating any biomolecular indicators of extant life brought to the surface through cryosphere activity. We also describe a MALDI (MAtrix Laser Desorption and Ionization) TOF MS system that we are constructing as a proof-of-concept prototype for conducting TOF MS measurements on Europa.

Gerakines, Perry A.↗

Point to Point Control of the Hydrogen Mixer

We continue to build on the theoretical modelling of a liquid hydrogen (LH2) and gas hydrogen (GH2) mixer subsystem. The mixer described in this work is responsible for combining high pressure LH2 and GH2 to produce a hydrogen flow that meets certain thermodynamic properties. The desired properties are maintained by precise control of the LH2 and GH2 flows. The mixer is modelled as a general multi-flow lumped volume for single constituent fluids using density and internal energy as states. The set of nonlinear differential equations is modelled in the SIMULINK environment including a table look-up feature of the fluid thermodynamic properties. A small signal (linear) model is developed based on the nonlinear model and simulated as well. Pulse disturbances are introduced to the valve positions and the quality of the linear model is ascertained by comparing its behavior against the nonlinear model simulations. Valve control strategies that simulate an operator-in-the-loop scenario are then explored demonstrating the need for automatic feedback control. Finally, optimal single-output and multi-output Proportional/Integral controllers are designed based on the linear model and applied to the nonlinear model with excellent results to track simultaneous, constant setpoint changes in desired exit flow, exit temperature, and mixer pressure, as well as to reject unmeasureable but bounded additive step perturbations in the valve positions.

Barbieri, Enrique↗

Modeling, Simulation and Control of a Propellant Mixer

This paper addresses some modeling and control issues for a mixing chamber used in rocket engine testing at NASA Stennis Space Center. The mixer must combine high pressure liquid hydrogen (LH2) and gaseous hydrogen (GH2) to produce and output flow that meets certain thermodynamic properties before it is fed into a test article. More precisely, this paper considers that the quantities to be tracked and/or regulated are mixer internal pressure, exit mass flow, and exit temperature. The available control inputs are given by three value positions, namely those of the GH2, LH2 and exit valves. The mixer is modelled by a system of two nonlinear ordinary differential equations having density and internal energy as states. The model must be simple enough to lend itself to subsequent feedback controller design, yet its accuracy must be tested against real data. For this reason, the model includes function calls to thermodynamic property data. Some structural properties of the resulting model that pertain to controller design, such as controllability and uniqueness of the equilibrium point are shown to hold. Validation of the model against real data is also provided. As a first control approach, a small-signal (linear) model is developed based on the nonlinear model and simulated as well. Pulse disturbances are introduced to the valve positions and the quality of the linear model is ascertained by comparing its behavior against the nonlinear model simulations. Valve control strategies that simulate an operator-in-the-loop scenario are then explored demonstrating the need for automatic feedback control. Classical optimal single-output and multi-output Proportional/Integral controllers are designed based on the linear model and applied to the nonlinear model with excellent results to track simultaneous, constant setpoint changes in desired exit flow, exit temperature, and mixer pressure, as well as to reject unmeasurable but bounded additive step perturbations in the valve positions. A feedback linearization controller is designed and used to achieve tracking and regulation of the outputs over an extended range of the variables of interest.

Richter, Hanz↗

Small Signal Point-to-Point Tracking of a Propellant Mixer

This paper addresses some theoretical modelling and control issues for a mixing chamber used in rocket engine testing at NASA Stennis Space Center. The mixer is responsible for combining high pressure LH2 and GH2 to produce a hydrogen flow that meets certain thermodynamic properties before it is fed into a test article. The desired properties are maintained by precise control of the LH2 and GH2 flows. The mixer is modelled as a general multi-flow lumped volume for single constituent fluids using density and internal energy as states. The set of nonlinear differential equations is modelled in the SIMULINK environment including a table look-up feature of the fluid thermodynamic properties. a small-signal (linear) model is developed based on the nonlinear model and simulated as well. Pulse disturbances are introduced to the valve positions and the quality of the linear model is ascertained by comparing its behavior against the nonlinear model simulations. Valve control strategies that simulate an operator-in-the-loop scenario are then explored demonstrating the need for automatic feedback control. Finally, classical optimal single-output and multi-output Proportional/Integral controllers are designed based on the linear model and applied to the nonlinear model with excellent results to track simultaneous, constant setpoint changes in desired exit flow, exit temperature, and mixer pressure, as well as to reject unmeasurable but bounded additive step perturbations in the valve positions.

Barbieri, Enrique↗

Small Signal Modelling and Control of the Hydrogen Mixer for Facility E1

We have undertaken the theoretical modelling of an existing liquid hydrogen (LH2) and gas hydrogen (GH2) mixer subsystem of the E1 Ground Test Facility at NASA John C. Stennis Space Center. The E1 test facility carries out comprehensive ground-based testing and certification of various liquid rocket engines and their components. The mixer described in this work is responsible for combining high pressure LH2 and GH2 to produce a hydrogen flow that meets certain thermodynamic properties before it is fed into a test article. The desired properties are maintained by precise control of the mixture of LH2 and GH2 flows. The mixer is modelled as a general multi-flow lumped volume for single constituent fluids using density and internal energy as states. The set of nonlinear differential equations is linearized about an equilibrium point and the resulting two-state, 3-input linear model is analyzed as a possible candidate for control design.

Barbieri, Enrique↗

Small Signal Modeling and Control of the Hydrogen Mixer for Facility E1

We have undertaken the theoretical modelling of an existing liquid hydrogen (LH2) and gas hydrogen (GH2) mixer subsystem of the E1 Ground Test Facility at NASA John C. Stennis Space Center. The E1 test facility carries out comprehensive ground-based testing and certification of various liquid rocket engines and their components. The mixer described in this work is responsible for combining high pressure before it is fed into a test article. The desired properties are maintained by precise control of the mixture of LH2 and GH2 flows. The mixer is modelled as a general multi-flow lumped volume for single constituent fluids using density and internal energy as states. The set of nonlinear differential equations is linearized about an equilibrium point and the resulting two-state, 3-input linear model is analyzed as a possible candidate for control design.

Barbieri, Enrique↗

Distributed Relaxation Multigrid and Defect Correction Applied to the Compressible Navier-Stokes Equations

The distributed-relaxation multigrid and defect- correction methods are applied to the two- dimensional compressible Navier-Stokes equations. The formulation is intended for high Reynolds number applications and several applications are made at a laminar Reynolds number of 10,000. A staggered- grid arrangement of variables is used; the coupled pressure and internal energy equations are solved together with multigrid, requiring a block 2x2 matrix solution. Textbook multigrid efficiencies are attained for incompressible and slightly compressible simulations of the boundary layer on a flat plate. Textbook efficiencies are obtained for compressible simulations up to Mach numbers of 0.7 for a viscous wake simulation.

Thomas, J. L.↗

A 3D Convective Model for the Jovian Wind Bands

In an earlier paper, we proposed that Jupiter's alternating wind bands are a manifestation of the global interaction between rotation and convection in a shallow layer. The model, however, was obtained from linearization of the 2D equations of motions. At HKUST/Hong Kong, we are now trying to study this problem by rigorous numerical simulation. Using a three-dimensional spectral numerical code, we compute models for the outermost layer of Jupiter's convective envelope. Two cases have been studied. In one the atmospheric pressure varies from 1 to 23 bar, and in the other from 1 to 115 bar. The physical parameters (internal energy flux, rotation rate) are chosen to be close to those expected, but solar heating, chemistry, as well as dynamical influences from deeper layers are ignored. The models generate wind field patterns that contain alternating jet streams with resemblance to the Jovian bands. Instantaneous values of the mean zonal flow at the equator reach 80 m/sec. Yet the mean meridional flows are less than 1% of such value. The meridional temperature profile at the cloud top level also shows a double hump structure of a few degrees (as observed) in the subtropics. Though there is not complete quantitative agreement (caused perhaps by neglected effects like solar radiation), these models demonstrate, in principle, the feasibility of generating a Jovian type wind pattern through the interaction of fast rotation and convection in a thin shell.

Mayr, H. G.↗

A Kernel-Free Particle-Finite Element Method for Hypervelocity Impact Simulation

An improved hybrid particle-finite element method has been developed for the simulation of hypervelocity impact problems. Unlike alternative methods, the revised formulation computes the density without reference to any kernel or interpolation functions, for either the density or the rate of dilatation. This simplifies the state space model and leads to a significant reduction in computational cost. The improved method introduces internal energy variables as generalized coordinates in a new formulation of the thermomechanical Lagrange equations. Example problems show good agreement with exact solutions in one dimension and good agreement with experimental data in a three dimensional simulation.

Park, Young-Keun↗

A Novel Porosity Model for Use in Hydrocode Simulations

Introduction: Numerical modeling of impact cratering has reached a high degree of sophistication; however, the treatment of porous materials still poses a large problem in hydrocode calculations. Porosity plays only a minor role in the formation of large craters on most planetary objects, but impacts on comets are believed to be highly affected by the presence of porosity, which may be as much as 80%. The upcoming Deep Impact Mission (launched January 2005) will provide more detailed data about the composition of a comet (Tempel 1) by shooting a approx.370 kg projectile onto the surface of its nucleus. The numerical simulations of such impact events requires an appropriate model for how pore space in the comet is crushed out during the violent initial stage of the impact event. Most hydro-codes compute the pressure explicitly using an "equation of state" (EOS) for each material, which relates changes in density and internal energy to changes in pressure. The added complication introduced by porosity is that changes in a material s density are due to both the closing of pore space (compaction) and compression of the matrix. The amount of resistance to volume change and the amount of irreversible work done during these two processes is very different; it is far easier to compact a porous material sample than to compress a non-porous sample of the same material. As an alternative to existing porosity models, like the Pdot(alpha) model [1], we present a novel approach for dealing with the compaction of porosity in hydrocode calculations.

Wuennemann, K.↗

Numerical Modelling of the Deep Impact Mission Experiment

NASA s Deep Impact Mission (launched January 2005) will provide, for the first time ever, insights into the interior of a comet (Tempel 1) by shooting a approx.370 kg projectile onto the surface of a comets nucleus. Although it is usually assumed that comets consist of a very porous mixture of water ice and rock, little is known about the internal structure and in particular the constitutive material properties of a comet. It is therefore difficult to predict the dimensions of the excavated crater. Estimates of the crater size are based on laboratory experiments of impacts into various target compositions of different densities and porosities using appropriate scaling laws; they range between 10 s of meters up to ~250 m in diameter [1]. The size of the crater depends mainly on the physical process(es) that govern formation: Smaller sizes are expected if (1) strength, rather than gravity, limits crater growth; and, perhaps even more crucially, if (2) internal energy losses by pore-space collapse reduce the coupling efficiency (compaction craters). To investigate the effect of pore space collapse and strength of the target we conducted a suite of numerical experiments and implemented a novel approach for modeling porosity and the compaction of pores in hydrocode calculations.

Wuennemann, K.↗

Advanced Electrical Materials and Components Development: An Update

The primary means to develop advanced electrical components is to develop new and improved materials for magnetic components (transformers, inductors, etc.), capacitors, and semiconductor switches and diodes. This paper will give an update of the Advanced Power Electronics and Components Technology being developed by the NASA Glenn Research Center for use in future Power Management and Distribution subsystems used in space power systems for spacecraft and lunar and planetary surface power. The initial description and status of this technology program was presented two years ago at the First International Energy Conversion Engineering Conference held at Portsmouth, Virginia, August 2003. The present paper will give a brief background of the previous work reported and a summary of research performed the past several years on soft magnetic materials characterization, dielectric materials and capacitor developments, high quality silicon carbide atomically smooth substrates, and SiC static and dynamic device characterization under elevated temperature conditions. The rationale for and the benefits of developing advanced electrical materials and components for the PMAD subsystem and also for the total power system will also be briefly discussed.

Schwarze, Gene E.↗

Mestastable State Population in Laser Induced Plasmas

Laser induced plasma has been used as a source of neutrals and ions in the study of astrophysical plasmas. The purity of state of this source is essential in the determination of collision parameters such as the charge transfer rate coefficients between ions and neutrals. We will show that the temperature of the laser induced plasma is a rapidly decreasing function of time. The temperature is initially high but cools off rapidly through collisions with the expanding plasma electrons as the plasma recombines and streams into the vacuum. This rapid expansion of the plasma, similar to a supersonic jet, drastically lowers the internal energy of the neutrals and ions.

Kwong, V. H. S.↗

Microfabrication of a Segmented-Involute-Foil Regenerator, Testing in a Sunpower Stirling Convertor and Supporting Modeling and Analysis

Under Phase II of a NASA Research Award contract, a prototype nickel segmented-involute-foil regenerator was microfabricated via LiGA and tested in the NASA/Sunpower oscillating-flow test rig. The resulting figure-of-merit was about twice that of the approx.90% porosity random-fiber material currently used in the small 50-100 W Stirling engines recently manufactured for NASA. That work was reported at the 2007 International Energy Conversion Engineering Conference in St. Louis, was also published as a NASA report, NASA/TM-2007-2149731, and has been more completely described in a recent NASA Contractor Report, NASA/CR-2007-2150062. Under a scaled-back version of the original Phase III plan, a new nickel segmentedinvolute- foil regenerator was microfabricated and has been tested in a Sunpower Frequency-Test-Bed (FTB) Stirling convertor. Testing in the FTB convertor produced about the same efficiency as testing with the original random-fiber regenerator. But the high thermal conductivity of the prototype nickel regenerator was responsible for a significant performance degradation. An efficiency improvement (by a 1.04 factor, according to computer predictions) could have been achieved if the regenerator been made from a low-conductivity material. Also the FTB convertor was not reoptimized to take full advantage of the microfabricated regenerator's low flow resistance; thus the efficiency would likely have been even higher had the FTB been completely reoptimized. This report discusses the regenerator microfabrication process, testing of the regenerator in the Stirling FTB convertor, and the supporting analysis. Results of the pre-test computational fluid dynamics (CFD) modeling of the effects of the regenerator-test-configuration diffusers (located at each end of the regenerator) is included. The report also includes recommendations for accomplishing further development of involute-foil regenerators from a higher-temperature material than nickel.

Ibrahim, Mounir B.↗

Cleaning Carbon Nanotubes by Use of Mild Oxygen Plasmas

Experiments have shown that it is feasible to use oxygen radicals (specifically, monatomic oxygen) from mild oxygen plasmas to remove organic contaminants and chemical fabrication residues from the surfaces of carbon nanotubes (CNTs) and metal/CNT interfaces. A capability for such cleaning is essential to the manufacture of reproducible CNT-based electronic devices. The use of oxygen radicals to clean surfaces of other materials is fairly well established. However, previously, cleaning of CNTs and of graphite by use of oxygen plasmas had not been attempted because both of these forms of carbon were known to be vulnerable to destruction by oxygen plasmas. The key to success of the present technique is, apparently, to ensure that the plasma is mild . that is to say, that the kinetic and internal energies of the oxygen radicals in the plasma are as low as possible. The plasma oxygen-radical source used in the experiments was a commercial one marketed for use in removing hydrocarbons and other organic contaminants from vacuum systems and from electron microscopes and other objects placed inside vacuum systems. In use, the source is installed in a vacuum system and air is leaked into the system at such a rate as to maintain a background pressure of .0.56 torr (.75 Pa). In the source, oxygen from the air is decomposed into monatomic oxygen by radio-frequency excitation of a resonance of the O2 molecule (N2 is not affected). Hence, what is produced is a mild (non-energetic) oxygen plasma. The oxygen radicals are transported along with the air molecules in the flow created by the vacuum pump. In the experiments, exposure to the oxygen plasma in this system was shown to remove organic contaminants and chemical fabrication residues from several specimens. Many high-magnification scanning electron microscope (SEM) images of CNTs were taken before and after exposure to the oxygen plasma. As in the example shown in the figure, none of these images showed evidence of degradation of CNT structures.

Petkov, Mihail↗

Thermodynamic Properties of Nitrogen Including Liquid and Vapor Phases from 63K to 2000K with Pressures to 10,000 Bar

Tables of thermodynamic properties of nitrogen are presented for the liquid and vapor phases for temperatures from the freezing line to 2000K and pressures to 10,000 bar. The tables include values of density, internal energy, enthalpy, entropy, isochoric heat capacity, isobaric heat capacity velocity of sound, the isotherm derivative, and the isochor derivative. The thermodynamic property tables are based on an equation of state, P=P (p,T), which accurately represents liquid and gaseous nitrogen for the range of pressures and temperatures covered by the tables. Comparisons of property values calculated from the equation of state with measured values for P-p-T, heat capacity, enthalpy, latent heat, and velocity of sound are included to illustrate the agreement between the experimental data and the tables of properties presented here. The coefficients of the equation of state were determined by a weighted least squares fit to selected P-p-T data and, simultaneously, to isochoric heat capacity data determined by corresponding states analysis from oxygen data, and to data which define the phase equilibrium criteria for the saturated liquid and the saturated vapor. The vapor pressure equation, melting curve equation, and an equation to represent the ideal gas heat capacity are also presented. Estimates of the accuracy of the equation of state, the vapor pressure equation, and the ideal gas heat capacity equation are given. The equation of state, derivatives of the equation, and the integral functions for calculating derived thermodynamic properties are included.

Thermodynamic properties↗

Analysis of Photospheric Convection Cells with SDO/HMI

Supergranulation is a component of solar convection that assists in the outward transportation of internal energy. Supergranule cells are approximately 35 Mm across, have lifetimes on the order of a day and have divergent horizontal velocities of around 300 m/s, a factor of 10 higher than their central radial components. While they have been observed using Doppler methods for around half a century, their existence is also observed in other datasets such as magnetograms and Ca II K images. These datasets clearly show the influence of supergranulation on solar magnetism and how the local field is organized by the flows of supergranule cells. The Heliospheric and Magnetic Imager (HMI) aboard SDO is making fresh observations of convection phenomena at a higher cadence and a higher resolution that should make granular features visible. Granulation and supergranulation characteristics can now be compared within the same datasets, which may lead to further understanding of any mutual influences. The temporal and spatial enhancements of HMI will also reduce the noise level within studies of convection so that more detailed studies of their characteristics may be made. We present analyses of SDO/HMI Dopplergrams that provide new estimates of convection cell sizes, lifetimes, and velocity flows, as well as the rotation rates of the convection patterns across the solar disk. We make comparisons with previous data produced by MDI, as well as from data simulations.

Williams, Peter E.↗

Updated Chemical Kinetics and Sensitivity Analysis Code

An updated version of the General Chemical Kinetics and Sensitivity Analysis (LSENS) computer code has become available. A prior version of LSENS was described in "Program Helps to Determine Chemical-Reaction Mechanisms" (LEW-15758), NASA Tech Briefs, Vol. 19, No. 5 (May 1995), page 66. To recapitulate: LSENS solves complex, homogeneous, gas-phase, chemical-kinetics problems (e.g., combustion of fuels) that are represented by sets of many coupled, nonlinear, first-order ordinary differential equations. LSENS has been designed for flexibility, convenience, and computational efficiency. The present version of LSENS incorporates mathematical models for (1) a static system; (2) steady, one-dimensional inviscid flow; (3) reaction behind an incident shock wave, including boundary layer correction; (4) a perfectly stirred reactor; and (5) a perfectly stirred reactor followed by a plug-flow reactor. In addition, LSENS can compute equilibrium properties for the following assigned states: enthalpy and pressure, temperature and pressure, internal energy and volume, and temperature and volume. For static and one-dimensional-flow problems, including those behind an incident shock wave and following a perfectly stirred reactor calculation, LSENS can compute sensitivity coefficients of dependent variables and their derivatives, with respect to the initial values of dependent variables and/or the rate-coefficient parameters of the chemical reactions.

Radhakrishnan, Krishnan↗