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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Exoplanet Sciences with Nulling Interferometers and a Single-mode Fiber-fed Spectrograph

Understanding the atmospheres of exoplanets is a milestone to decipher their formation history and potential habitability. High-contrast imaging and spectroscopy of exoplanets is the major pathway toward the goal. Direct imaging of an exoplanet requires high spatial resolution. Interferometry has proven to be an effective way of improving spatial resolution. However, means of combining interferometry, high-contrast imaging, and high-resolution spectroscopy have been rarely explored. To fill in the gap, we present the dual-aperture fiber nuller (FN) for current-generation 8–10 m telescopes, which provides the necessary spatial and spectral resolution to (1) conduct follow-up spectroscopy of known exoplanets and (2) detect planets in debris-disk systems. The concept of feeding an FN to a high-resolution spectrograph can also be used for future space and ground-based missions. We present a case study of using the dual-aperture FN to search for biosignatures in rocky planets around M stars for a future space interferometry mission. Moreover, we discuss how an FN can be equipped on future extremely large telescopes by using the Giant Magellan Telescope as an example.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Th IV –Desferrioxamine: characterization of a fluorescent bacterial probe

Diversifying our ability to guard against emerging pathogenic threats is essential for keeping pace with global health challenges, including those presented by drug-resistant bacteria. Some modern diagnostic and therapeutic innovations to address this challenge focus on targeting methods that exploit bacterial nutrient sequestration pathways, such as the desferrioxamine (DFO) siderophore used by Staphylococcus aureus (S. aureus) to sequester Fe III . Building on recent studies that have shown DFO to be a versatile vehicle for chemical delivery, we show proof-of-principle that the Fe III sequestration pathway can be used to deliver a potential radiotherapeutic. Our approach replaces the FeIII nutrient sequestered by H 4 DFO + with Th IV and made use of a common fluorophore, FITC, which we covalently bonded to DFO to provide a combinatorial probe for simultaneous chelation paired with imaging and spectroscopy, H 3 DFO_FITC. Combining insight provided from FITC-based imaging with characterization by NMR spectroscopy, we demonstrated that the fluorescent DFO_FITC conjugate retained the Th IV chelation properties of native H4DFO+. Fluorescence microscopy with both [Th(DFO_FITC)] and [Fe(DFO_FITC)] complexes showed similar uptake by S. aureus and increased intercellular accumulation as compared to the FITC and unchelated H 3 DFO_FITC controls. Collectively, these results demonstrate the potential for the newly developed H 3 DFO_FITC conjugate to be used as a targeting vector and bacterial imaging probe for S. aureus. The results presented within provide a framework to expand H 4 DFO + and H 3 DFO_FITC to relevant radiotherapeutics (like 227Th).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Space-Time Quantum Information from the Entangled States of Magnetic Molecule (STI Product)

This collaborative project combines synthesis, measurement, and theory by three faculty members at the Eddleman Quantum Institute of UC Irvine to effectively investigate the quantum properties of molecules in the space, time, and frequency domains. Through synthetic chemistry, molecules are tailored for their magnetic and coherent properties. By combining femtosecond (fs) terahertz (THz) light and a continuous wave (cw) THz laser with a low temperature scanning tunneling microscope (STM), quantum phenomena are probed with simultaneous femtosecond temporal and atomic-scale spatial resolution. In particular, the invention of the quantum superposition microscope (QSM) advances quantum sensing for enhanced spectroscopy and imaging capabilities. Coupling theory to the experimental efforts offers a deeper understanding and predictive power for the molecular systems. The phenomena of superposition, entanglement, and coherence is central to quantum information science and can be realized in qubit states. Many systems can be modeled by a double-well potential in which two levels are formed in the two lowest energy states interacting with the environment and external radiation. In focusing on molecules as two-level systems, the underlying expectation is that their tunable composition and structure allows an effective parameter space to optimize their use as qubits for quantum sensing and computing. The THz radiation induces the superposition between the two states, appearing as temporal oscillations that damp in amplitude. Enhanced spectroscopy and imaging in the time and frequency domains is achieved through the extreme sensitivity of the frequency and damping of coherence of two-level systems to its environment. A single hydrogen molecule trapped in the STM tunneling gap experiences a double-well potential and absorption of THz femtosecond pulses of light creates the superposition of its two levels, appearing as damped oscillations in the light induced direct current (DC). The oscillation frequency depends sensitively on the electric field distribution of the copper nitride (Cu 2 N) surface, through the Stark effect, and associated with the different charge distributions at the copper and nitrogen sites and in between. This QSM can resolve variation in the surface electric field with 0.02 nanometer resolution. In addition, the single hydrogen molecule entaes with nearby hydrogen molecules as seen in the avoided level crossings of energy (oscillation frequency) versus the voltage across the tunneling gap. Thus, the first application of the QSM senses and images the surface electric field at the atomic scale. Results from this project advance fundamental understanding of quantum phenomena, develop novel synthesis, measurement, and theory, provide the knowledge foundation for molecule-based qubits and sensing that enable the development of the QSM and emergent technologies. This project trained researchers in quantum information science, extended knowledge in classrooms, and outreached to the community.

47 OTHER INSTRUMENTATION↗
DOE OSTI2025

In-orbit performance of the soft X-ray imaging telescope Xtend aboard XRISM

Here, we present a summary of the in-orbit performance of the soft X-ray imaging telescope Xtend onboard the X-Ray Imaging and Spectroscopy Mission (XRISM), based on in-flight observation data, including first-light celestial objects, calibration sources, and results from the cross-calibration campaign with other currently operating X-ray observatories. XRISM/Xtend has a large field of view of ${38{^{\prime }_{.}}5}$ $\times$ ${38{^{\prime }_{.}}5}$, covering an energy range of 0.4–13 keV, as demonstrated by the first-light observation of the galaxy cluster Abell 2319. It also features an energy resolution of 170–180 eV at 6 keV, which meets the mission requirement and enables us to resolve He-like and H-like Fe K$\alpha$ lines. Throughout the observation during the performance verification phase, we confirm that two issues identified in the Soft X-ray Imager (SXI) onboard the previous Hitomi mission—light leakage and crosstalk events—are addressed and suppressed in the case of Xtend. A joint cross-calibration observation of the bright quasar 3C 273 results in an effective area measured to be $\sim$420 cm$^{2}$ at1.5 keV and $\sim$310 cm$^{2}$ at 6.0 keV, which matches values obtained in ground tests. We also continuously monitor the health of Xtend by analyzing overclocking data, calibration source spectra, and day-Earth observations; the readout noise is stable and low, and contamination is negligible even one year after launch. A low background level compared with other major X-ray instruments onboard satellites, combined with the largest grasp ($\Omega _{\rm eff}\sim 60$ cm$^2$ deg$^2$) of Xtend, will not only support Resolve analysis, but also enable significant scientific results on its own. This includes near-future follow-up observations and transient searches in the context of time-domain and multi-messenger astrophysics.

instrumentation: detectors: Xtend↗
NASA NTRS1987

The impact of infrared arrays on 1-5 microns spectroscopy

The use of two-dimensional infrared arrays for astronomical imaging and spectroscopy is now occurring and immensely changing the field. In view of this 'revolution' in infrared astronomy, some of the implications for future infrared spectroscopy are discussed in this paper. A method is presented for comparing the infrared background to future spectrometers at 1-5 microns. Some of the current developments in infrared spectroscopy at Mauna Kea are discussed.

Tokunaga, Alan↗
NASA NTRS1993

Narrow band imaging and long slit spectroscopy of UGC 5101

UGC 5101 (z = 0.04; D is approximately equal to 240 Mpc) is one of the so called Ultraluminous IRAS sources. Two important properties of the members of this group are their L(sub IR) is greater than or equal to 10(exp 12) solar luminosity, and their space density in the universe up to z is less than 0.1 is equal or even larger than the space density of the quasars. Further noteworthy features of the Ultraluminous IRAS sources are their being morphologically peculiar and the fact that they all seem to host active nuclei in their center. We have observed UGC 5101 in an effort to study the interplay between the gas ionized by the central active nucleus and that gas ionized by other processes which may hold important clues to the understanding of the entire picture of this object. In particular these other ionizing processes could well be massive stars formed recently after the galactic encounter and shocks possibly also related to the galaxy collision. The data that we discuss were obtained between Dec. 1989 and Jan. 1992 with the WHT 4.2 m telescope using the two-arm spectrograph ISIS. Several spectral frames were obtained at three different position angles: PA 84--along the tail of the galaxy; PA 32--along the dust lane; and PA 110. The blue spectra are centered on the H beta line, while the red spectra are centered on the H alpha line. In the configuration we used for the long slit spectra, the spectral scale was 0.74 A per pixel, and the spatial scale was .37 arcsec per pixel; we also observed the H alpha region with a spectral scale of .37 A per pixel, at position angle 84. The narrow band images were obtained at the auxiliary port of ISIS, with a scale of .2 arcsec per pixel, and were centered at the H alpha wavelength, and on the adjacent continuum. The H alpha images and the spectra support the following model. UGC 5101 hosts an active nucleus; the NLR extends up to about 1.5 kpc and shows a complex velocity field, superimposed on the rotation curve of the galaxy. Besides the NLR, in the H alpha image are visible tow bright cones that extend up to 3 kpc along PA 32. The long slit spectra at PA 32 show that the velocity field of the gas in these regions is peculiar, while the ionization structure of the gas is similar to that of the NLR.

Stanga, R. M.↗
NASA NTRS1987

Measurements of OH(X2pi) in the stratosphere by high resolution UV spectroscopy

This paper reports the first results obtained using high spectral resolution imaging ultraviolet spectroscopy to observe multiple rotational lines of OH A2 Sigma-X2pi (0-0) band. A 9.2 A spectral segment from 3075.8 A to 3085.0 A is imaged at 0.08 A FWHM spectral resolution, allowing the simultaneous acquisition of six of the brightest OH resonance fluorescence emission lines. The high spectral resolution and low scattered light design of the instrument allows these lines to be detected above the Rayleigh scattered sunlight background. The technique permits remote sensing of stratospheric OH from a high altitude instrument. The instrument was flown to an altitude of 40 km on Aug. 25, 1983, and again on June 12, 1986, on scientific balloons from Palestine, TX. The OH profiles inverted from the limb scans made during these flights are reported here. These profiles represent the first measurements of the temporal variation of OH over an extended height range. The results demonstrate that the technique can be used to monitor OH from orbit.

Torr, D. G.↗
NASA NTRS2019

Development of the WFIRST CGI Integral Field Spectrograph

The principal science goal of directly imaging exoplanets is spectroscopy. Future mission concepts such as LU- VOIR and HabEx have baselined their science instruments to use an integral field spectrograph (IFS) to maximize observing efficiency. Coronagraphic imaging with an IFS has strong heritage at ground observatories, having produced planet and brown dwarf near-infrared spectra at contrast floors as low as high 1 × 10-6 levels. As a technology demonstration for future missions the WFIRST coronagraph instrument (CGI) will demonstrate the ability to measure spectra in visible light with at contrast levels sufficient for detecting Earth-like planets. The spectrograph was originally meant to match that of future missions; an independent IFS channel for wavefront control and imaging spectroscopy. Due to a series of de-scopes as the project progressed, the baseline spectroscopic capability of CGI is no longer an IFS but a zero deviation optical prism and slit used in conjunction with the direct imaging camera. Regardless, CGI advanced a lenslet IFS through the preliminary design phase of a flight project. Here we present that development as the challenges and requirements of an IFS for coronagraphy are quite unique and relevant to future missions. With that development in place, we also present the initial design of the zero optical deviation prism, highlighting the relative challenges and performance of each concept.

Tyler D Groff↗
DOE OSTI2026

The scientific case for concurrent neutron and X-ray scattering and spectroscopy

The interrogation of materials with X-rays or neutrons to determine structure, energetics, and dynamics is fundamental to advancing physical and chemical materials science and enabling innovative material technologies. A persistent challenge in materials development is that progress depends on understanding structure and dynamics across multiple length and time scales in increasingly complex, multicomponent systems featuring interfaces, heterogeneity, and hierarchical organization. Despite rapidly growing demands on materials characterization, current experimental approaches are almost exclusively based on isolated X-ray or neutron scattering and spectroscopy, reflecting a paradigm largely unchanged for decades. To assess the scientific need for a new experimental paradigm, a 3-day workshop sponsored by the U.S. National Science Foundation (NSF) was held at the SpringHill Suites, San Jose, California, from June 2 to 4, 2022. The workshop brought together 70 national and international experts who critically evaluated opportunities enabled by concurrent neutron and X-ray (NeX) scattering, spectroscopy, and imaging experiments. The participants reached a clear consensus that establishing NeX capabilities is crucial for advancing the science of complex materials in the United States. This report illustrates the scientific drivers for NeX experiments through representative examples spanning biomaterials, energy materials, soft matter, nanomaterials, quantum materials, geoscience, and applied materials research. The complementarity of neutrons and X-rays is essential for robust model development and refinement, particularly in multiphase and multicomponent systems. While joint refinement of data from separate experiments is valuable, concurrent measurements uniquely eliminate uncertainties arising from sample evolution, environmental drift, and irreproducibility associated with experiments performed at different locations and times. Realizing NeX capabilities will require the development of new instrumentation, data analysis frameworks, and robust sample environments compatible with both neutron and X-ray probes. Addressing these challenges will enable unambiguous interpretation of complex materials behavior and open new frontiers in materials research.

X-ray↗
NASA NTRS1982

The Pinhole/Occulter facility

The outer solar atmosphere exhibits a great variety of dynamic and energetic plasma phenomena, from the catastrophic energy release of solar flares to the steady acceleration of the solar wind. The Pinhole/Occulter Facility contains the instruments necessary for broadband X-ray imaging, combined with simultaneous ultraviolet and white light spectroscopy and imaging.

Dabbs, J. R.↗
NASA NTRS1990

Supernovae - Some observational goals of the 21st century

Key issues pertaining to the study of supernovae are listed, and the characteristics of instruments for addressing the issues are discussed with reference given to the present status of supernova investigation. Understanding type-Ia supernovae requires study of the progenitor star, the isotopic composition of the ejecta, and the radiation transport. Issues relevant to type Ib's include identifying clumping and fragmentation in the model light curves and determining whether mixing occurs. Identifying progenitor stars and observing neutrino bursts are found to be keys to understanding the supernovae, and appropriate analyses include optical imaging, bolometry, spectroscopy, and most importantly, high-resolution IR imaging. Gamma- and X-ray studies are also important, and examples of suitable telescopes are listed; investigation of neutrinos requires an observatory away from terrestrial nuclear reactors.

Woosley, S. E.↗
NASA NTRS2012

MgB2-Based Bolometer Array for Far Infra-Red Thermal Imaging and Fourier Transform Spectroscopy Applications

The mid-superconducting critical temperature (T(sub c) approximately 39 K) of the simple binary, intermetallic MgB, [1] makes it a very good candidate for the development of the next generation of electrooptical devices (e.g. [2]). In particular, recent advances in thin film deposition teclmiques to attain higb quality polycrystalline thin film MgB, deposited on SiN-Si substrates, with T(sub c) approximately 38K [3] coupled with the low voltage noise performance of the film [4] makes it higbly desirable for the development of moderately cooled bolometer arrays for integration into future space-bourne far infra-red (FIR) spectrometers and thermal mappers for studying the outer planets, their icy moons and other moons of interest in the 17-250 micrometer spectral wavelength range. Presently, commercially available pyroelectric detectors operating at 300 K have specific detectivity, D(*), around 7 x 10(exp 8) to 2 x 10(exp 9) centimeters square root of Hz/W. However, a MgB2 thin film based bolometer using a low-stress (less than 140 MPa) SiN membrane isolated from the substrate by a small thermal conductive link, operating at 38 K, promises to have two orders of magnitude higher specific detectivity [5][6].

Lakew, B.↗
DOE OSTI2023

Capacitance Transients, Photoconductive Decay, and Impedance Spectroscopy on 19% to 22% Efficient Silicon Solar Cells

High efficiency silicon solar cells are characterized using current-voltage curves, electroluminescence imaging, impedance spectroscopy, capacitance transients, microwave photoconductive decay, and time-resolved photoluminescence imaging. The sample set is composed of cells from different manufacturers and includes an n-type silicon heterojunction (SHJ), an n-type passivated emitter rear totally diffused (PERT), and five different p-type passivated emitter rear contact (PERC) cells. Carrier lifetimes, both photoconductivity and photoluminescence, are measured co-located with the light excitation pulse and within the cell but away from the light spot. Luminescence intensity and excess carrier lifetimes correlate to cell voltage. The capacitance transient time constants correlate to the capacitance values extracted from impedance spectroscopy.

capacitance↗
DOE OSTI2023

Capacitance Transients, Photoconductive Decay, and Impedance Spectroscopy on 19% to 22% Efficient Silicon Solar Cells

High efficiency silicon solar cells are characterized using current-voltage curves, electroluminescence imaging, impedance spectroscopy, capacitance transients, microwave photoconductive decay, and time-resolved photoluminescence imaging. The sample set is composed of cells from different manufacturers and includes an n-type silicon heterojunction (SHJ), an n-type passivated emitter rear totally diffused (PERT), and five different p-type passivated emitter rear contact (PERC) cells. Carrier lifetimes, both photoconductivity and photoluminescence, are measured co-located with the light excitation pulse and within the cell but away from the light spot. Luminescence intensity and excess carrier lifetimes correlate to cell voltage. The capacitance transient time constants correlate to the capacitance values extracted from impedance spectroscopy.

capacitance↗
NASA NTRS1993

Optical imaging and long-slit spectroscopy of Markarian galaxies with multiple nuclei. I - Basic data

Optical CCD images and long-slit spectroscopic data are presented for over 100 Markarian (UV-excess) galaxies reported in early studies to possess multiple optical nuclei or extreme morphological peculiarities suggestive of galaxy collisions and mergers. Stacked broad-band images are presented with histogram equalization in order to show simultaneously the nuclei and features at very low surface-brightness levels. Morphological properties, luminosities and colors of the integral systems are given. Photometric and image properties of over 200 individual nuclei and giant H II regions have been measured with respect to the local backgrounds in the galaxies using an objective image finding algorithm. Labeled contour plots identify the measured subcomponents. Two-dimensional spectral data are presented, in addition to intensity profiles along the slit in the light of H-alpha + forbidden N II emission lines and adjacent continuum. Nuclear emission-line measurements, reddening estimates, monochromatic continuum magnitudes, and colors are given.

Mazzarella, Joseph M.↗