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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
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NASA NTRS1981

Matrix spectroscopic studies of chlorine atom-ozone reaction products

A spectroscopic study is presented of the matrix-isolated products of the direct combination reaction of chlorine atoms with ozone and of the microwave discharge reaction of chlorine and oxygen. Infrared spectra in the wavenumber range 2000 to 200 per cm were recorded for reaction products trapped by the condensation of a matrix of solid argon. Evidence for the formation of the ClO radical as well as the ClOO and ClClO radicals during the direct chlorine-ozone reaction is obtained, however no evidence is found for the presence of asymmetric ClO3 under conditions thought favorable for its formation. The ClO molecule is also observed following the microwave discharge reaction of chlorine and oxygen in argon in the isotopic forms (Cl-35)(O-16), (Cl-37)(O-16), (Cl-35)(O-18), and (Cl-37)(O-18). It is noted that the vibrational frequency for the (Cl-35)(O-16) radical at 849.2 per cm is blue-shifted 5 per cm above its gas-phase fundamental.

Carter, R. O., III↗
NASA NTRS1982

Radiative transfer and remote sensing

Radiative transfer, the basic theoretical tool for the quantitative interpretation of planetary infrared spectra, is discussed. The function it plays in linking the remotely sensed data to the properties of the atmosphere (composition, thermal structure, dynamics, etc.), is inferred. A brief overview of the remote sensing problem as it pertains to the interpretation of planetary spectra is presented. The presentation is tutorial rather than exhaustive.

Conrath, B. J.↗
NASA NTRS1982

Rayleigh, Raman and particulate scattering

Analysis of the visible and near infrared spectra of planetary atmospheres and the multiple scattering of photons within the atmosphere are discussed. Photons detected within the spectral region are solar photons which were scattered by the gas and particles in the planetary atmosphere. An example is given for the incident and emitted fluxes for a hypothetical planet with an effective temperature of 100 K. The absorption spectrum of the planetary atmosphere is discussed in terms of the various scattering processes photons undergo within the atmosphere. Three different physical processes are considered. Rayleigh scattering and Raman scattering by the gas molecules, and scattering by any cloud or dust aerosol particles in the atmosphere. The physics of each of these processes is examined.

Cochran, W. D.↗
NASA NTRS1982

Long-pathlength absorption spectroscopy of CH4

Infrared spectra of methane and ammonia are taken. The methane data base accumulated is described. The spectral region from 4,000 to 6,500 cm is covered at moderate resolution (0.15 cm), working at three temperatures (118, 191, and 272K), and with the (pressure - pathlength) product ranging over a factor of a thousand. Methane spectra broadened by hydrogen and helium have also been taken. Normalized spectra are stored on magnetic tapes, at a resolution slightly better than 0.25 cm.

Silvaggio, P.↗
NASA NTRS1981

Spectroscopic detection of stratospheric hydrogen cyanide

A number of features have been identified as absorption lines of hydrogen cyanide in infrared spectra of stratospheric absorption obtained from a high-altitude aircraft. Column amounts of stratospheric hydrogen cyanide have been derived from spectra recorded on eight flights. The average vertical column amount above 12 kilometers is 7.1 + or - 0.8 x 10 to the 14th molecules per square centimeter, corresponding to an average mixing ratio of 170 parts per trillion by volume.

Coffey, M. T.↗
NASA NTRS1981

Albedo, internal heat, and energy balance of Jupiter - Preliminary results of the Voyager infrared investigation

Full disk measurements recorded by the 0.4-1.7 micron radiometer on Voyager 1 indicate a geometric albedo of 0.274 + or - 0.013. This measurement and the Pioneer-based phase integral of 1.25 yield a Jovian Bond albedo of 0.343 + or - 0.032. Infrared spectra yield a thermal emission of 1.359 + or - 0.014 x .001 W/sq cm, which corresponds to an equivalent blackbody temperature of 124.4 + or - 0.3 K. In addition, the internal heat flux of Jupiter is estimated to be 5.444 + or - 0.425 x .0001 W/sq cm, and the energy balance defined as the ratio of emitted thermal to absorbed solar energy is 1.668 + or - 0.085.

Hanel, R. A.↗
NASA NTRS1981

4-8 micron spectrophotometry of OH 0739-14

Spectrophotometry of the dust-embedded late-type star OH 0739-14 shows an absorption feature at 6.0 microns characteristic of H2O ice at temperatures significantly lower than 150 K, confirming the identification of H2O ice in the circumstellar shell in this source. The differences in the infrared spectra of HO 0739-14 and embedded molecular cloud sources are attributed to the different cloud lifetimes and temperature regimes in which the molecules are formed. A lower limit to the mass loss rate of 0.0001 solar mass per year is derived, based on the column density of ice and the size and the expansion velocity of the circumstellar cloud.

Soifer, B. T.↗
NASA NTRS1981

Analysis of infrared emission from thin adsorbates

Fuel and lubricant deposits on solid surfaces, though often of similar visual appearance, differ in composition, depending on the nature of the deposit formers and the circumstances of deposition. To help establish these relations an Infrared Emission Fourier Polarization Microspectrophotometer was constructed to record infrared spectra from the deposits on their original support. By focussing on small aggregates with a reflecting microscope objective and by discriminating against the randomly polarized blackbody radiation with a rotating polarizing filter phase-locked to an amplifier, excellent Fourier emission spectra of polarized bands could be obtained. In many instances, the microscope objective was adequate without the polarizer. The analysis was calibrated against a very thin film of polyethylene terephthalate attached to a highly reflective aluminum mirror on the sample positioner.

Lauer, J. L.↗
NASA NTRS1982

Remote sensing studies of lunar dark-halo impact craters - Preliminary results and implications for early volcanism

A summary of the nature and origin of lunar dark-halo craters is presented. New remote sensing data for dark-haloed impact craters were obtained and interpreted. A variety of spectral, thermal, radar, and photogeologic data are presented which confirm the hypothesis that Copernicus H crater excavated mare basalt from beneath lighter deposits emplaced by the Copernicus impact event. Multispectral imagery suggests that analogous impact re-exposure of basaltic material on the ejecta blankets of other large Copernican and Eratosthenian craters resulted in the formation of other dark-halo craters. Preliminary analyses of near-infrared spectra of dark-haloed impact craters in the Schickard-Schiller region are consistent with the hypothesis that basaltic material was excavated from beneath light plains. These light plains may have been emplaced as a result of the Orientale impact event. Additional evidence is presented which suggests that both pre- and post-Orientale volcanic activity was more prevalent in this region than has previously been recognized.

Hawke, B. R.↗
NASA NTRS1982

Forced torsional properties of PMR composites with varying nadic ester concentrations and processing histories

PMR polyimide resin was prepared from 4,4'-methylenedianiline, the dimethyl ester of 3,3',4,4'-benzophenonetetracarboxylic acid and the monomethyl ester of 5-norbornene-2,3-dicarboxylic acid (NE). The NE group serves as a chain terminator and crosslinking site. PMR/Celion 6000 composites were fabricated from resins having varying NE concentrations using two molding processes, and the laminates characterized in forced torsion. Glass transition temperatures (T(g)) of 360-390 C were observed in the crosslinked resins, as compared with the literature value of 284 C reported for the uncrosslinked system. T(g) did not decrease with decreasing NE concentrations over the range from 2.0 to 1.25 moles. Stoichiometry, within the range studied, showed little influence on shear properties; however, a 25% variation in matrix shear modulus with processing was observed. The G(12) values determined in forced torsion were in excellent agreement with those reported from tensile tests of + or - 45 deg laminates. A branching and possible secondary crosslink mechanism is proposed based on dynamic mechanical behavior and infrared spectra of the composites.

Hurwitz, F. I.↗
NASA NTRS1983

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

The infrared spectra of H2O ice VII and D2O ice VII were studied and techniques were developed for measuring adiabats of phases of NH3-H2O to 5 GPa. A mixing system for pressurized fluids was constructed in which liquid solutions of definite compositions can be prepared and loaded reliably into diamond cells in a project which seeks to determine the properties and boundaries of several high pressure phases of the H2-He-H2O-NH3-CH4 system. These data are needed to constrain theoretical models of the interiors of the major planets.

Nicol, M. F.↗
NASA NTRS1982

Infrared photometry of periodic comets Encke, Chernykh, Kearns-Kwee, Stephan-Oterma, and Tuttle

Nearly simultaneous photometry of the reflected and thermal infrared spectra of periodic comets Encke, Chernykh, Kearns-Kwee, Stephan-Oterma, and Tuttle are presented. The 10-micron silicate emission feature has been detected for the first time in periodic comets and was observed in three of these objects. The albedo of the dust particles in the comae of these comets is calculated and compared to that of Comet Kohoutek. The peculiar behavior of the dust in Comet Encke is discussed.

Campins, H.↗
NASA NTRS1982

Composition of the surfaces of the Galilean satellites

Sulfur chemistry on Io and the surface chemistry of the icy Galilean satellites are discussed in terms of laboratory chemical findings and spectral investigations. Gaseous, liquid, and solid allotropes of sulfur are described and related to spectral data for Io. Compounds of sulfur identified on Io's surface are given and possible mechanisms for their formation are evalutated. Laboratory studies of water frost, ice, and mixtures with other minerals are discussed and their relevance in interpreting infrared spectra of the icy Galilean satellites and the apparent solid water absorption band profiles is shown.

Sill, G. T.↗
NASA NTRS1983

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

Progress is reported in the development of the P-T-X diagram for 0 less than or = X less than or = 0.50 and in the development of techniques for measuring adiabats of phases of NH3-H2O. The partial phase diagram is presented, investigations of the compositions of ammonia ices are described, and methods for obtaining the infrared spectra of ices are discussed.

Nicol, M. F.↗
NASA NTRS1983

CO2 on Titan

A sharp stratospheric emission feature at 667/cm in the Voyager infrared spectra of Titan is associated with the nu2 Q branch of CO2. A coupling of photochemical and radiative-transfer theory yields an average mole fraction above the 110 mbar level of (1.5 + 1.5 or - 0.8) x 10 to the -9th, with most of the uncertainty being due to imprecise knowledge of the vertical distribution. CO2 is found to be in a steady state, with its abundance being regulated principally by the 72 K cold trap near the tropopause and secondarily by the rate at which water-bearing meteoritic material enters the top of the atmosphere. An influx of water about 0.4 times that at the top of the terrestrial atmosphere is consistent with a combination of the observed CO2 abundance and a steady-state CO mole fraction of 0.00011; the thoeretical value for CO is close to the value observed by Lutz et al. (1983), although there are large margins for error in both numbers. If steady-state conditions for CO prevail, little information is available regarding the evolution of Titan's atmosphere.

Samuelson, R. E.↗
NASA NTRS1983

Properties of ices and grains - An experimental study

Proton irradiation of a variety of ice mixtures was carried out to study the effect of galactic cosmic ray irradiation of comets in the Oort Cloud. Three significant effects were noted: (1) production of new molecules; (2) production of a more energetic ice at low temperatures; (3) production of a non-volatile, complex organic residue. These phenomena suggest various effects on new comets approaching the sun including enhanced activity. Experiments on the condensation of silicate grains provide information on the condensation mechanism and properties of grains. Controlled annealing of the amorphous condensates shows how crystallization occurs. Infrared spectra of different stages of crystallization contain features that may identify composition, structure and history of refractory material.

Donn, B.↗
NASA NTRS1985

Spectral Reflectance Studies of the Orientale Basin

Twelve near-infrared spectra were obtained at the Mauna Kea Observatory 2.2-m telescopy using the Planetary Geosciences Division indium antimonide spectrometer. These include spectra obtained for two fresh surfaces on the inner Rook ring, two fresh craters in the outer Rook Mts., and two inner Rook ring, two fresh craters in the outer Rook Mts., and two fresh 11-km. craters (Eichstadt G and H) which are located between the outer Rook ring and the Cordillera ring and exposed material from within the knobby facies of the Montes Rook Formation. In addition, spectra were collected for portions of the Maunder Formation. Special attention was paid to the spectra collected for six immature features within the Cordillers ring. Analyses of the 1-micron band positions and shapes as well as continuum slopes indicate that the spectra for craters in the knobby facies and in the outer Rook Mts., while differing in detail, exhibit many common spectral characteristics. These spectra represent relatively fresh highlands rocks dominated by abundant Fe-bearing plagioclase feldspar and Ca-poor orthopyroxene. Compositions ranging between noritic anorthosite and anorthositic norite are indicated.

Hawke, B. R.↗
NASA NTRS1984

Prepreg cure monitoring using diffuse reflectance-FTIR

An in situ diffuse reflectance-Fourier transform infrared technique was developed to determine infrared spectra of graphite fiber prepregs as they were being cured. A bismaleimide, an epoxy, and addition polyimide matrix resin prepregs were studied. An experimental polyimide adhesive was also examined. Samples were positioned on a small heater at the focal point of diffuse reflectance optics and programmed at 15 F/min while FTIR spectra were being scanned, averaged, and stored. An analysis of the resulting spectra provided basic insights into changes in matrix resin molecular structure which accompanied reactions such as imidization and crosslinking. An endo-exothermal isomerization involving reactive end-caps was confirmed for the addition polyimide prepregs. The results of this study contribute to a fundamental understanding of the processing of composites and adhesives. Such understanding will promote the development of more efficient cure cycles.

Young, P. R.↗