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At least 523 records · Page 29

Far Field Modeling Methods For Characterizing Surface Detonations

Savannah River National Laboratory (SRNL) analyzed particle samples collected during experiments that were designed to replicate tests of nuclear weapons components that involve detonation of high explosives (HE). SRNL collected the particle samples in the HE debris cloud using innovative rocket propelled samplers. SRNL used scanning electronic microscopy to determine the elemental constituents of the particles and their size distributions. Depleted uranium composed about 7% of the particle contents. SRNL used the particle size distributions and elemental composition to perform transport calculations that indicate in many terrains and atmospheric conditions the uranium bearing particles will be transported long distances downwind. This research established that HE tests specific to nuclear proliferation should be detectable at long downwind distances by sampling airborne particles created by the test detonations.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

JWL Equation of State

The JWL equation of state (EOS) is frequently used for the products (and sometimes reactants) of a high explosive (HE). Here we review and systematically derive important properties. The JWL EOS is of the Mie-Grueneisen form with a constant Grueneisen coefficient and a constants specific heat. It is thermodynamically consistent to specify the temperature at a reference state. However, increasing the reference state temperature restricts the EOS domain in the (V, e)-plane of phase space. The restrictions are due to the conditions that P ≥ 0, T ≥ 0, and the isothermal bulk modulus is positive. Typically, this limits the low temperature regime in expansion. The domain restrictions can result in the P-T equilibrium EOS of a partly burned HE failing to have a solution in some cases. For application to HE, the heat of detonation is discussed. Example JWL parameters for an HE, both products and reactions, are used to illustrate the restrictions on the domain of the EOS.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

The concentrations of radionuclides, heavy metals, and poloychlorinated biphenyls in field mice collected from regional background areas. Revision 3

Field mice are effective indicators of contaminant presence. This paper reports the concentrations of various radionuclides, heavy metals, polychlorinated biphenyls, high explosives, perchlorate, and dioxin/furans in field mice (mostly deer mice) collected from regional background areas in northern New Mexico. These data, represented as the regional statistical reference level (the mean plus three standard deviations = 99% confidence level), are used to compare with data from field mice collected from areas potentially impacted by Laboratory operations, as per the Environmental Surveillance Program at Los Alamos National Laboratory.

59 BASIC BIOLOGICAL SCIENCES↗

Shock Detector for SURF model

SURF and its extension SURFplus are reactive burn models aimed at shock initiation and propagation of detonation waves in high explosives. A distinctive feature of these models is that the burn rate depends on the lead shock pressure. A key part of the models is an algorithm to detect the lead shock. Typically, shock capturing hydro algorithms have small oscillations behind a shock. Here we investigate how well the shock detection algorithm works for a nearly steady propagating detonation wave in one-dimension using the Eulerian xRage code.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Results from Second Round of Remediated Nitrate Salt Surrogate Formulation and Testing

High Explosives and Technology (M-7) completed the second round of formulation and testing of Remediated Nitrate Salt (RNS) surrogates on March 17, 2016. This report summarizes the results of the work and also includes additional documentation required under test plan PLAN-TA9-2443 Rev B, "Remediated Nitrate Salt (RNS) Surrogate Formulation and Testing Standard Procedure", released February 16, 2016. All formulation and testing was carried out according to PLAN-TA9-2443 Rev B. Results from the first round of formulation and testing were documented in memorandum M7-16-6042, "Results from First Round of Remediated Nitrate Salt Surrogate Formulation and Testing."

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Initial Results from the Third Round of Remediated Nitrate Salt Surrogate Formulation and Testing

High explosives science and technology (M-7) is currently working on the third round of formulation and testing of Remediated nitrate salt (RNS) surrogates. This report summarizes the calorimetry results from the 15% sWheat mixtures. All formulation and testing was carried out according to PLAN-TA9-2443 Rev B, "Remediated Nitrate Salt (RNS) surrogate formulation and testing standard procedure", released February 16, 2016. Results from the first and second rounds of formulation and testing were documented in memoranda M7-16-6042 and M7-16-6053.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Summary of Remediated Nitrate Salt Surrogate Formulation and Testing

High Explosives Science and Technology (M-7) completed all required formulation and testing of Remediated Nitrate Salt (RNS) surrogates on April 27, 2016 as specified in PLAN-TA9-2443 Rev B, "Remediated Nitrate Salt (RNS) Surrogate Formulation and Testing Standard Procedure", released February 16, 2016. This report summarizes the results of the work and also includes additional documentation required in that test plan. All formulation and testing was carried out according to PLAN-TA9-2443 Rev B. The work was carried out in three rounds, with the full matrix of samples formulated and tested in each round. Results from the first round of formulation and testing were documented in memorandum M7-J6-6042, " Results from First Round of Remediated Nitrate Salt Surrogate Formulation and Testing." Results from the second round of formulation and testing were documented in M7-16-6053 , "Results from the Second Round of Remediated Nitrate Salt Surrogate Formulation and Testing." Initial results from the third round were documented in M7-16-6057, "Initial Results from the Third Round of Remediated Nitrate Salt Formulation and Testing."

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

SPE5 Sub-Scale Test Series Summary Report

A series of 2 SPE5 sub-scale tests were performed to experimentally confirm that a booster system designed and evaluated in prior tests would properly initiate the PBXN-110 case charge fill. To conduct the experiments, a canister was designed to contain the nominally 50 mm diameter booster tube with an outer fill of approximately 150 mm diameter by 150 mm in length. The canisters were filled with PBXN-110 at NAWS-China Lake and shipped back to LLNL for testing in the High Explosives Applications Facility (HEAF). Piezoelectric crystal pins were placed on the outside of the booster tube before filling, and a series of piezoelectric crystal pins along with Photonic Doppler Velocimetry (PDV) probes were placed on the outer surface of the canister to measure the relative timing and magnitude of the detonation. The 2 piezoelectric crystal pins integral to the booster design were also utilized along with a series of either piezoelectric crystal pins or piezoelectric polymer pads on the top of the canister or outside case that utilized direct contact, gaps, or different thicknesses of RTV cushions to obtain time of arrival data to evaluate the response in preparation for the large-scale SPE5 test. To further quantify the margin of the booster operation, the 1st test (SPE5SS1) was functioned with both detonators and the 2nd test (SPE5SS2) was functioned with only 1 detonator. A full detonation of the material was observed in both experiments as observed by the pin timing and PDV signals. The piezoelectric pads were found to provide a greater measured signal magnitude during the testing with an RTV layer present, and the improved response is due to the larger measurement surface area of the pad. This report will detail the experiment design, canister assembly for filling, final assembly, experiment firing, presentation of the diagnostic results, and a discussion of the results.

36 MATERIALS SCIENCE↗

Floodplain statement of findings for corrective actions in Potrillo Canyon technical area-36, Los Alamos National Laboratory, Los Alamos, New Mexico

In 2014, baseline storm water monitoring samples for Potrillo Canyon Sample Management Area at Los Alamos National Laboratory (LANL) exceeded the National Pollutant Discharge Elimination System Individual Permit No. NM0030759 target action level (TAL) of 15 picocuries per liter (pCi/L) for gross-alpha radioactivity (393 pCi/L) and a TAL of 30 pCi/L for radium-226 and radium-228 (95.9 pCi/L). Consequently, erosion control measures within the management area are proposed to minimize sediment migration, a corrective action under the permit that is a requirement of the New Mexico Environment Department consent decree and a good management practice to limit off-site sediment migration. The area proposed for erosion controls consists of portions of Technical Area 36 that were used as firing sites primarily involving high explosives (HE) and metal (e.g., depleted uranium, lead, copper, aluminum, and steel), small-explosives experiments and burn pits (burn pits were used for burning and disposal of test debris). In addition, underground explosive tests at an approximate depth of 100 feet were also conducted. These watershed-based storm water controls will focus on addressing erosion occurring within the floodplain through mitigating and reducing both current and future channelization and head cutting.

54 ENVIRONMENTAL SCIENCES↗

Guide to Using Onionskin Analysis Code (U)

This document is a guide to using R-code written for the purpose of analyzing onionskin experiments. We expect the user to be very familiar with statistical methods and the R programming language. For more details about onionskin experiments and the statistical methods mentioned in this document see Storlie, Fugate, et al. (2013). Engineers at LANL experiment with detonators and high explosives to assess performance. The experimental unit, called an onionskin, is a hemisphere consisting of a detonator and a booster pellet surrounded by explosive material. When the detonator explodes, a streak camera mounted above the pole of the hemisphere records when the shock wave arrives at the surface. The output from the camera is a two-dimensional image that is transformed into a curve that shows the arrival time as a function of polar angle. The statistical challenge is to characterize a baseline population of arrival time curves and to compare the baseline curves to curves from a new, so-called, test series. The hope is that the new test series of curves is statistically similar to the baseline population.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Development and Execution of a Large-scale DDT Tube Test for IHE Material Qualification

Insensitive High Explosive (IHE) Materials are defined in Chapter IX of the DOE Explosive Safety Standard (DOE-STD-1212-2012) as being materials that are massdetonable explosives that are so insensitive that the probability of accidental initiation or transition from burning to detonation is negligible1. There are currently a number of tests included in the standard that are required to qualify a material as IHE, however, none of the tests directly evaluate for the transition from burning to detonation (aka deflagration-to-detonation transition, DDT). Currently, there is a DOE complex-wide effort to revisit the IHE definition in DOE-STD-1212-2012 and change the qualification requirements. The proposal lays out a new approach, requiring fewer, but more appropriate tests, for IHE Material qualification. One of these new tests is the Deflagration-to-Detonation Test. According to the redefinition proposal, the purpose of the new deflagration-todetonation test is “to demonstrate that an IHE material will not undergo deflagration-to-detonation under stockpile relevant conditions of scale, confinement, and material condition. Inherent in this test design is the assumption that ignition does occur, with onset of deflagration. The test design will incorporate large margins and replicates to account for the stochastic nature of DDT events.” In short, the philosophy behind this approach is that if a material fails to undergo DDT in a significant over-test, then it is extremely unlikely to do so in realistic conditions. This effort will be valuable for the B61 LEP to satisfy their need qualify the new production lots of PBX 9502. The work described in this report is intended as a preliminary investigation to support the proposed design of an overly conservative, easily fielded DDT test for updated IHE Material Qualification standard. Specifically, we evaluated the aspects of confinement, geometry, material morphology and temperature. We also developed and tested a thermally robust igniter system.

36 MATERIALS SCIENCE↗

Parameterization of a Cookoff Model for LX-07

A thermal decomposition model for PBX 9501 (95% HMX, 2.5% Estane® binder, 2.5% BDNPA/F nitro-plasticizer) was implemented by Dickson, et. al. The objective in this study is to estimate parameters associated with this kinetics model so it can be applied to carry out thermal ignition predictions for LX-07 (90% HMX, 10% Viton binder). LX-07 thermal ignition experiments have been carried out using the “Sandia Instrumented Thermal Ignition Apparatus”, SITI. The SITI design consists of solid cylinders (1” diameter × 1” height) of high explosive (HE) confined by a cylindrical aluminum case. An electric heater is wrapped around the outer surface of the case. This heater produces a temperature heating ramp on the outer surface of the case. Internal thermocouples measure the HE temperature rise from the center to locations close to the HE-aluminum interface. The energetic material is heated until thermal ignition occurs. A two–dimensional axisymmetric heat conduction finite element model is used to simulate these experiments. The HE thermal decomposition kinetics is coupled to a heat conduction model trough the definition of an energy source term. The parameters used to define the HE thermal decomposition model are optimized to obtain a good agreement with the experimental time to thermal ignition and temperatures. Also, heat capacity and thermal conductivity of the LX-07 mixture were estimated using temperatures measured at the center of the HE before the solid to solid HMX phase transition occurred.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

LAFD: TA-16 HE Facility Familiarization Tour, OJT 55258

Los Alamos National Laboratory (LANL) will conduct familiarization tours for personnel of the Los Alamos County Fire Department (LAFD) at TA-16 high explosives (HE) facilities. These familiarization tours are official LANL business; the purpose of these tours is to orient LAFD firefighters to the facility so that they can respond efficiently and quickly to a variety of emergency situations. This orientation includes, among other topics, ingress and egress of the area and buildings, layout and organization of the facility, evacuation procedures and assembly points, and areas of concern within the various buildings at the facility. LAFD firefighters have the skills and abilities to perform firefighting operations and other emergency response tasks that cannot be provided by LANL personnel who have the required clearance. This handout provides details of the information, along with maps and diagrams, to be presented during the familiarization tours. The handout will be distributed to the trainees at the time of the tour. A corresponding checklist will also be used as guidance during the familiarization tours to ensure that all required information is presented to LAFD personnel.

99 GENERAL AND MISCELLANEOUS↗

FINAL DESIGN REVIEW REPORT Subcritical Experiments Gen 2, 3-ft Confinement Vessel Weldment

A Final Design Review (FDR) of the Subcritical Experiments (SCE) Gen 2, 3-ft. Confinement Vessel Weldment was held at Los Alamos National Laboratory (LANL) on September 14, 2017. The review was a focused review on changes only to the confinement vessel weldment (versus a system design review). The changes resulted from lessons-learned in fabricating and inspecting the current set of confinement vessels used for the SCE Program. The baseline 3-ft. confinement vessel weldment design has successfully been used (to date) for three (3) high explosive (HE) over-tests, two (2) fragment tests, and five (5) integral HE experiments. The design team applied lessons learned from fabrication and inspection of these vessel weldments to enhance fit-up, weldability, inspection, and fitness for service evaluations. The review team consisted of five (5) independent subject matter experts with engineering design, analysis, testing, fabrication, and inspection experience. The

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Theory, Solution Methods, and Implementation of the HERMES Model

The HERMES (high explosive response to mechanical stimulus) model was developed over the past decade to enable computer simulation of the mechanical and subsequent energetic response of explosives and propellants to mechanical insults such as impacts, perforations, drops, and falls. The model is embedded in computer simulation programs that solve the non-linear, large deformation equations of compressible solid and fluid flow in space and time. It is implemented as a user-defined model, which returns the updated stress tensor and composition that result from the simulation supplied strain tensor change. Although it is multi-phase, in that gas and solid species are present, it is single-velocity, in that the gas does not flow through the porous solid. More than 70 time-dependent variables are made available for additional analyses and plotting. The model encompasses a broad range of possible responses: mechanical damage with no energetic response, and a continuous spectrum of degrees of violence including delayed and prompt detonation. This paper describes the basic workings of the model.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Developing Lathing Parameters for PBX 9501

This thesis presents the work performed on lathing PBX 9501 to gather and analyze cutting force and temperature data during the machining process. This data will be used to decrease federal-regulation-constrained machining time of the high explosive PBX 9501. The effects of machining parameters depth of cut, surface feet per minute, and inches per revolution on cutting force and cutting interface were evaluated. Cutting tools of tip radius 0.005 -inches and 0.05 -inches were tested to determine what effect the tool shape had on the machining process as well. A consistently repeatable relationship of temperature to changing depth of cut and surface feet per minute is found, while only a weak dependence was found to changing inches per revolution. Results also show the relation of cutting force to depth of cut and inches per revolution, while weak dependence on SFM is found. Conclusions suggest rapid, shallow cuts optimize machining time for a billet of PBX 9501, while minimizing temperature increase and cutting force.

42 ENGINEERING↗

Investigation of Parameters on Thermally Cycled EBW Detonators

Working towards an optimal exploding bridge wire (EBW) detonator design, three parameters were varied among two detonator platforms. These three parameters were bridge wire diameter, high explosive (HE) density, and sleeve material. These parameters were chosen due to their potential to benefit initiation characteristics. The performance of each parameter was characterized at pristine conditions and after thermal cycling and firing cold. The overall performance as well as the severity of performance loss observed after thermal conditioning were considered. The results of this parameter study are presented and trends related to parameter variation are examined.

42 ENGINEERING↗