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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Experimental measurements of the viscosity and melt structure of alkali basalts at high pressure and temperature

Abstract Volcanic eruptions are shallow phenomena that represent the final stage of density- and viscosity- driven processes of melt migration from source rocks at upper mantle depths. In this experimental study, we investigated the effect of pressure (0.7–7.0 GPa) and temperature (1335–2000 °C) on the viscosity and the atomic melt structure of a synthetic anhydrous primitive alkaline basalt, an analogue of the pre-eruptive magma that likely feeds the Campi Flegrei Volcanic District at present day. Obtained viscosities (0.5–3.0 Pa s), mobility (0.1–0.4 g cm 3 Pa −1 s −1 ) and ascent velocity (1.5–6.0 m yr −1 ) are presented to support geochemical and geophysical observations of Campi Flegrei as a critical volcanic district currently undergoing gradual magma recharge at depth.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Potential Challenges of HyBlend Storage in a Methane Reservoir Located in Southwestern United States

Hydrogen has been identified as a flexible energy carrier with zero or negative emissions across multiple energy systems. It is possible to utilize hydrogen by storing Hyblend, or hydrogen gas blended with methane, in existing natural gas infrastructure. However, the compatibility of adapting the current CH4 storage strategies to include H2 injection has not been fully demonstrated. It is essential that we understand the impact of H2 gas on the naturally occurring microbial community of subsurface storage reservoirs before deploying large-scale H2-CH4 storage. We designed a series of experiments that allowed us to identify potential geochemical and microbial challenges of HyBlend Storage in existing methane reservoirs. First, we collected and characterized field fluid samples from a methane reservoir located in southwestern United States. Next, we used these field fluid samples to complete a series of short-term reactor experiments at reservoir conditions (80 °C and ~1,000 psi) for a natural gas (100% CH4) and HyBlend(80% CH4/20% H2) storage environment to measure the transformation of gas content. We conducted both biotic and abiotic (sterilized) measurements to accurately understand and decouple abiotic and microbially driven processes. Overall, we found that our field sample was characterized by a diverse microbial community with the metabolic capacity for sulfur reduction, iron reduction, and acetogenesis. Across our reactors, there was minimal change in geochemistry.

hydrogen storage↗
NASA NTRS2023

Mineralogical, Elemental, and Tomographic Reconnaissance Investigation for CLPS (METRIC)

METRIC is a robotic science laboratory that can determine the mineralogy, elemental chemistry, micromorphology, and thermophysical properties of planetary regolith. The METRIC suite comprises METRIC XRD/F, an X-ray diffraction/X-ray fluorescence instrument that can determine the mineralogy and elemental chemistry of regolith samples; METRIC XCT, a micro X-ray computed tomography instrument that can be used to evaluate grain/crystallite sizes and textures; METRIC IRS, an imaging spectrometer mounted on a rover that can determine mineralogy and thermophysical properties at the landing site; and a pneumatic sample collection, processing, distribution system developed by Honeybee Robotics. The payload elements could be deployed on a static lander or a rover. Data returned from the METRIC payload would inform origin, formation, and evolution of rocky planetary bodies. METRIC XRD/F draws on heritage from the CheMin instrument on the Mars Science Laboratory (MSL) Curiosity rover [1], with a few important improvements. Like CheMin, METRIC XRD/F operates in transmission geometry and uses piezoelectric actuators on sample cells in a tuning fork geometry to induce convective grain motion of the regolith to create a randomly oriented powder. MSL CheMin uses an energy-sensitive CCD to collect XRD patterns and XRF spectra simultaneously from the same sample cell, resulting in qualitative XRF data. METRIC XRD/F uses two different sample cells, one optimized for XRD and one optimized for XRF, and a silicon drift detector to detect fluoresced X-rays. This improvement to the XRF capabilities provides quantitative geochemical data of major elements down to Z = 11 and allows for the detection of minor and trace elements that are critical for evaluating geologic evolution of the Moon (e.g., P and Th). Modest improvements to the XRD geometry and hardware allow for better angular resolution and the ability to distinguish between members of the pyroxene group. METRIC XCT uses the same geometry and much of the same hardware as METRIC XRD/F, where a CCD would capture images of a regolith sample in a 3 mm diameter sample tube that is rotated 360° in steps <1°. Image brightness can be used to infer compositional data, where brighter materials indicate a higher Z, much like scanning electron microscopy. Data from METRIC XCT complement those from METRIC XRD/F. Particle size, shape, and texture can provide petrologic and provenance information, whereas vesicle size and morphology in volcanic or impact melt lithologies can inform cooling rates. METRIC IRS is a hyperspectral thermal imager that can be mounted to a lander or rover to provide mineralogical data from the broader landing site and help determine whether the samples analyzed by METRIC XRD/F and XCT are representative. The METRIC IRS spectral range (8–14 μm) and resolution (10.8 cm-1) allow for quantitative mineralogy from modelling Reststrahlen bands of major rock-forming minerals (e.g., silicates, phosphates). Radiance cubes can be processed and modelled with an onboard high-performance computer to determine mineral abundances of plagioclase, high-Ca pyroxene, pigeonite, orthopyroxene, olivine, and glass. Regolith samples can be acquired, processed, and delivered to the X-ray instruments via multiple sample handling systems, but the pneumatic sampling systems developed by Honeybee Robotics [e.g., 2] are best suited for relatively low-cost missions that are being competed for the Moon (e.g., NASA’s Payloads and Research Investigations for the Surface of the Moon program). There are pneumatic sampling systems that collect surface material and other systems that pneumatically drill up to ~1 m below the surface, providing material that has not been space weathered and has not been affected by the lander’s exhaust. [1] Blake, D. F., Vaniman, D., Achilles, C., Anderson, R., Bish, D., et al. (2012). Space Sci. Rev. 170, 341-478. https://doi.org/10.1007/s11214-012-9905-1. [2] Zacny, K., Betts, B., Hedlund, M., Long, P., Gramlich, M., Tura, K., Chu, P., Jacob, A., Garcia, A. (2014). IEEE Aerospace Conference, 3-7 March 2014, Big Sky, MT, U.S.A.

X-ray diffraction↗
DOE OSTI2025

Molecular Insights into Geochemical Reactions of Iron-Bearing Minerals: Implications for Hydrogen Geo-Storage

Here, this study investigates the reaction of hydrogen (H 2 ) with pyrite (FeS 2 ), focusing on how temperature and the presence of water influence the reaction pathways and kinetics. Utilizing computational molecular simulations and kinetic analyses, we explore the impact of these factors on the formation of hydrogen sulfide (H 2 S) and related species. First, grand canonical Monte Carlo/molecular dynamics (GCMC/MD) simulations reveal that physical H 2 adsorption occurs in distinct layers on the pyrite surface. In addition, increased temperatures reduce the absolute adsorption capacities. Reactive MD simulations demonstrate that H 2 interacts differently with pyrite under varying conditions. At 298 K, H 2 reacts with pyrite to form HS – , leading to the formation of HS – through covalent bonding with sulfur of pyrite. However, no H 2 S is produced at this temperature, suggesting that a kinetic barrier (i.e., activation energy) may prevent this reaction. At higher temperatures, H 2 S production significantly increases. The presence of water introduces additional complexity to the reaction mechanism. Unlike dry conditions, water enhances H 2 S generation, even at low temperatures. Water also facilitates the formation of additional products, such as SOH, indicating a more intricate chemical environment on the pyrite surface. Our findings identify the association of HS – ions to form H 2 S as the rate-limiting step, with temperature influencing this process. This finding suggests that while the presence of water can create a more dynamic reaction environment, the overall mechanisms leading to H 2 S formation remain consistent. These outcomes suggest the need for developing targeted strategies to manage and control H 2 S emissions within the context of underground hydrogen storage.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1996

Evidence for Life on Earth before 3,800 Million Years Ago

It is unknown when life first appeared on Earth. The earliest known microfossils (approx. 3,500 Myr before present) are structurally complex, and if it is assumed that the associated organisms required a long time to develop this degree of complexity, then the existence of life much earlier than this can be argued. But the known examples of crustal rocks older than approx. 3,500 Myr have experienced intense metamorphism, which would have obliterated any fragile microfossils contained therein. It is therefore necessary to search for geochemical evidence of past biotic activity that has been preserved within minerals that are resistant to metamorphism. Here we report ion-microprobe measurements of the carbon-isotope composition of carbonaceous inclusions within grains of apatite (basic calcium phosphate) from the oldest known sediment sequences a approx. 3,800 Myr-old banded iron formation from the Isua supracrustal belt, West Greenland, and a similar formation from the nearby Akilia island that is possibly older than 3,850 Myr. The carbon in the carbonaceous inclusions is isotopically light, indicative of biological activity; no known abiotic process can explain the data. Unless some unknown abiotic process exists which is able both to create such isotopically light carbon and then selectively incorporate it into apatite grains, our results provide evidence for the emergence of life on Earth by at least 3,800 Myr before present.

Mojzsis, S. J.↗
NASA NTRSDate not supplied

Preliminary Characterization of Spinel Troctolite Clast Identified in Apollo Next Generation Sample Analysis (ANGSA) Core 73002

The lunar magnesian (Mg-) suite is a diverse lithological group composed of Mg-rich mafic minerals. The Mg-suite consists primarily of troctolites, norites, gabbronorites, and spinel troctolites. These rocks exhibit contradictory geochemical traits, with mafic minerals bearing high Mg# (molar 100×Mg/[Mg+Fe]) indicating primitive parental magmas, but also plagioclase saturation and enrichments in incompatible trace elements (i.e., KREEP) indicate more evolved parental magmas. A variety of models have been invoked to explain the occurrence and petrogenesis of the Mg-suite. Here, we report on a new spinel troctolite clast found in Apollo Next Generation Sample Analysis (ANGSA) program core 73002. Sample 73002 was acquired at Station 3 during Apollo 17 as the upper part of a double-drive tube with sample 73001. During processing, the spinel troctolite clast (0.066 g) was found at the 4.0–4.5 cm depth interval.

A. C. Stadermann↗
DOE OSTI2024

Critical mineral source potential from oil & gas produced waters in the United States

The volume of produced water, a by-product of oil & gas operations and other energy processes, has been growing across the United States (U.S.) along with the need to manage or recycle this wastewater. Produced water contains many naturally occurring elements of varying concentrations, including critical minerals which are essential to the clean energy transition. However, the current understanding of critical mineral concentrations in produced water and the associated volumes across the U.S. is limited. This study has assessed available databases and literature to gain insight into the presence and concentration of five high priority critical minerals, namely cobalt, lithium, magnesium, manganese, and nickel. The U.S. Geological Survey's National Produced Waters Geochemical Database was the main data source used for determining average critical mineral concentrations in produced water from the major oil and gas reservoirs in the U.S. The volumes of produced water for these major reservoirs were coupled with these concentrations to provide insights into where critical minerals are likely to have high abundance and therefore more recovery options. The analysis indicated the highest recovery potential for lithium and magnesium from produced water in the Permian basin and the Marcellus shale region. However, these assessments should be considered conservative due to the limited availability of reliable concentration data. Finally, it is expected more critical mineral recovery options could emerge with comprehensive characterization data from more recent and representative sources of produced water.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

New Direct Limit on Neutrinoless Double Beta Decay Half-Life of 128 $\mathrm{Te}$ with CUORE

The Cryogenic Underground Observatory for Rare Events (CUORE) at Laboratori Nazionali del Gran Sasso of INFN in Italy is an experiment searching for neutrinoless double beta (0νββ) decay. Its main goal is to investigate this decay in 130 Te, but its ton-scale mass and low background make CUORE sensitive to other rare processes as well. Here, in this Letter, we present our first results on the search for 0νββ decay of 128 Te, the Te isotope with the second highest natural isotopic abundance. We find no evidence for this decay, and using a Bayesian analysis we set a lower limit on the 128 Te 0νββ decay half-life of T 1/2 > 3.6 x 10 24 yr (90% CI). This represents the most stringent limit on the half-life of this isotope, improving by over a factor of 30 the previous direct search results, and exceeding those from geochemical experiments for the first time.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1977

Geochemical and mineralogical interpretation of the Viking inorganic chemical results

The current status of geochemical, mineralogical, petrological interpretation of refined Viking Lander data is reviewed, and inferences that can be drawn from data on the composition of Martian surface materials are presented. The materials are dominantly fine silicate particles admixed with, or including, iron oxide particles. Both major element and trace element abundances in all samples are indicative of mafic source rocks (rather than more highly differentiated salic materials). The surface fines are nearly identical in composition at the two widely separated Lander sites, except for some lithologic diversity at the 100-m scale. This implies that some agency (presumably aeolian processes) has thoroughly homogenized them on a planetary scale. The most plausible model for the mineralogical constitution of the fine-grained surface materials at the two Lander sites is a fine-grained mixture dominated by iron-rich smectites, or their degradation products, with ferric oxides, probably including maghemite and carbonates (such as calcite), but not such less stable phases as magnesite or siderite.

Toulmin, P., III↗
NASA NTRS1980

Time-dependent lunar density models

Simple models of the geochemical and geophysical evolution of the moon were constructed with the particular aim of investigating the mass density distribution within the moon as a function of time. The strongly inverted (densest material on top) density distribution resulting from fractional crystallization of the lunar magma ocean was found to rearrange itself into a highly stable stratification. Density stratification due to compositional variation dominated gravitational stability; thus, thermally driven convection was found to be suppressed in regions with relaxed (rearranged so as to minimize the gravitational potential energy) compositional density variation. The suppression of convection as a heat transfer process results in considerable modification of thermal evolution. The models produced sufficient density segregation from magma oceans of a few hundred km thickness, such that relaxation to the most stable rearrangement yielded a polar moment of inertia approximating that measured for the present-day moon. Thus, lunar models matching moment-of-inertia constraints but lacking a metallic core are motivated.

Herbert, F.↗
NASA NTRS1988

An illustration of the complexity of continent formation

It was pointed out that a consensus may be emerging in crustal growth models, considering the clustering of most growth curves and their uncertainties. Curves most distant from this clustering represent models involving extensive recycling of continental material back into the mantle, but the author wondered if geochemical signatures for this would be recognizable considering the lack of evidence from seismic tomography for discrete mantle reservoirs, and the likelihood of core-mantle interaction based on recent high pressure experiments. Unreactivated Archean rocks represent only 2 percent of present continental area, and the author was uncomfortable about basing inferences on what the early Earth was like on such a small amount of information. He feels that the hypothesis of continental assembly that needs testing is that of banging together of island arcs, such as in Indonesia today. As an example of how complex this process can be, the author described the geology of the Caribbean arc system, which shows evidence for reversals of subduction polarity, numerous collisional events, and substantial strike-slip movements. It seemed unlikely to the author that Archean examples would have been less complicated.

Burke, Kevin↗
NASA NTRS1999

Mineralogy of the Solar System

The coming decade will witnesses the first sample return missions from solar system bodies in 30 years. These samples will all be very small, some missions return only a few milligrams of total mass. Fortunately, the capability of modem methods to characterize ultra-small samples is well established from analysis of interplanetary dust particles (IDPs), interstellar grains recovered from meteorites, and other materials requiring ultra-sensitive analytical capabilities. Powerful analytical techniques are available that require, under favorable circumstances, single particles of only a few nanograms for entire suites of fairly comprehensive characterizations. A returned sample of greater than 1,000 particles with total mass of just one microgram permits comprehensive quantitative geochemical measurements that are impractical to can-y out in situ by flight instruments. With the Galileo flybys of Gaspra and Ida, it is now recognized that even very small airless bodies have indeed developed a particulate regolith. Acquiring a sample of the bulk regolith, a simple sampling strategy, provides two critical pieces of information about the body. Regolith samples are excellent bulk samples since they normally contain all the key components of the local environment, albeit in particulate form. Furthermore, since this fine fraction dominates remote measurements, regolith samples also provide information about surface alteration processes and are a key link to remote sensing of other bodies. Studies indicate that a statistically significant number of nanogram-sized particles should be able to characterize the regolith of a primitive asteroid, although the presence of larger components within even primitive meteorites (e.g.. Murchison), e.g. chondrules, CAI, large crystal fragments, etc., points out the limitations of using data obtained from nanogram-sized samples to characterize entire primitive asteroids. However, most important asteroidal geological processes have left their mark on the matrix, since this is the finest-grained portion and therefore most sensitive to chemical and physical changes. Thus, the following information can be learned from this fine grain size fraction alone: (1) mineral paragenesis; (2) regolith processes, (3) bulk composition; (4) conditions of thermal and aqueous alteration (if any); (5) relationships to planets, comets, meteorites (via isotopic analyses, including oxygen; (6) abundance of water and hydrated material; (7) abundance of organics; (8) history of volatile mobility, (9) presence and origin of presolar and/or interstellar material.

Zolensky, Michael E.↗
NASA NTRS1985

Planetary ecology; Proceedings of the Sixth International Symposium on Environmental Biogeochemistry, Santa Fe, NM, October 10-14, 1983

Topics presented include biological evolution and planetary chemistry; C-1 compounds; transport, deposition, and weathering; sulfur transformations; ground water; transformation processes for nitrogen oxides; and soils. Papers are presented on immunological studies on the organic matrix of recent and fossil invertebrate shells; biogenic gases in sediments deposited since Miocene times on the Walvis Ridge, South Atlantic Ocean; aspects of the biogeochemistry of Big Soda Lake, NV; mesophilic manganese-oxidizing bacteria from hydrothermal discharge areas at 21 deg North on the East Pacific Rise; and autotrophic growth and iron oxidation and inhibition kinetics of Leptospirillum ferrooxidans. Consideration is also given to thermophilic archaebacteria occurring in submarine hydrothermal areas; fate of sulfate in a soft-water, acidic lake; geochemical conditions in the ground water environment; microbial transformations as sources and sinks for nitrogen oxides; and the biogeochemistry of soil phosphorus.

Caldwell, D. E.↗
NASA NTRS2017

Feldspar Variability in Northwest Africa 7034

The martian meteorite Northwest Africa 7034 (and pairings) is a breccia that provides important information about the rocks and processes of the martian crust (e.g., 1-3). Additional information can be gleaned from the components of the breccia. These components, specifically those designated as clasts, record the history of their parent rock (i.e., the rock that has been physically broken down to produce the clasts). In order to study these parent rocks, we must first determine which clasts within the breccia are de-rived from the same parent. Previous studies have be-gun this process (e.g., 4), but the search for genetic linkages between clasts has not integrated clasts with different grain sizes. We begin to take this approach here, incorporating igneous-textured clasts with both fine and coarse mineral grains. In NWA 7034, almost all materials (clasts and breccia matrix) are composed of the same mineral assemblages (feldspar, pyroxene, Fe-Ti oxides, apatite) with largely the same mineral compositions [1, 4-6]. Bulk breccia Sm-Nd systematics define a single isochron [7]. These observations are consistent with a majority of the components within NWA 7034 originating from the same geochemical source and crystallizing at roughly the same time.

Santos, A. R.↗
DOE OSTI2025

Changuinola peat soil characteristics and gas emission raw data October 2019

This dataset comprises radiocarbon and geochemical measurements from peat and porewater samples collected across various depths at a site in Bocas del Toro, Panama. The study focuses on carbon cycling dynamics in tropical peatlands by examining carbon isotopic signatures (¹⁴C and ¹³C) and elemental compositions of bulk peat, dissolved organic carbon (DOC), carbon dioxide (CO₂), and methane (CH₄). Key parameters include radiocarbon ages and isotopic ratios (δ¹³C) of bulk peat, concentrations of carbon (%C) and nitrogen (%N), and radiocarbon content of porewater gases and dissolved organic carbon (DOC). The data provide insights into the vertical and spatial distribution of carbon sources and possible preservation and decomposition processes within tropical peat profiles, offering critical information for understanding carbon storage and greenhouse gas emissions in these ecosystems.This dataset is comprised of one main data folder containing (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) carbon isotopic signatures (¹⁴C and ¹³C); (5) concentrations of carbon (%C) and nitrogen (%N); (6) radiocarbon content of porewater carbon dioxide (CO₂), and methane (CH₄) ; (7) porewater DOC; (8) bulk peat sampling protocol; (9) porewater sampling protocol; (10) porewater gas collection methods; and (11) gas extraction methods. All files are in .csv format and can be opened with any software that supports this file types.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2012

Chondritic Models of 4 Vesta: Comparison of Predicted Internal Structure and Surface Composition/Mineralogy with Data from the Dawn Mission

Understanding the physical and chemical processes which led to the formation of the terrestrial planets remains one of the principal challenges of the Earth and planetary science communities. However, direct traces of the earliest stages of planet building have generally been wiped out on larger bodies such as the Earth or Mars, obscuring our view of how that process occurred. On the other hand, the planet building process would appear to have been arrested prematurely in the region between Mars and Jupiter, now populated by several hundred thousand compositionally diverse objects that escaped accretion into larger planets. Of these, the asteroid 4 Vesta is of particular interest as it is large (520 km diameter), and known to have a basaltic surface dominated by pyroxenes [1, 2]. Furthermore, visible-IR spectra of Vesta obtained by ground and space-based telescopes are remarkably similar to laboratory spectra measured on meteorites of the Howardite-Eucrite-Diogenite clan (HED), leading to the paradigm that the HEDs came from Vesta [2]. Geochemical and petrological studies of the HEDs confirm the differentiated nature of the near-surface region of their parent body, and imply that crust extraction occurred well within the first 10Ma of solar system history [3]. Vesta is therefore a prime target for studies that aim to constrain the earliest stages of planet building, and for that reason it is currently the subject of the Dawn mission [4].

Toplis, M. J.↗
NASA NTRS1983

Ancient crustal components in the Fra Mauro breccias

Texturally pristine clasts preserve primary petrographic relationships and mineral compositions, yielding insights into igneous processes of the early lunar crust that cannot be gained from highly shocked and brecciated 'chemically pristine' samples. The use of texture as a prime criterion allows for expansion of the data base derived solely from chemical criteria, and provides complementary data. Texturally pristine clasts from the Apollo 14 site studied here include anorthosite, troctolites, gabbronorites, and basalts. Alkali anorthosites are plagioclase orthocumulates and may form by flotation in Mg-suite plutons. Ferroan anorthosite was cataclastically deformed and metamorphosed to granulite facies. Troctolites include both 01 + Plg and 01 + En + Plg cumulates. Major and trace element analyses of two troctolites reveal 'eastern' geochemical affinities that contrast other 'western' troctolites. Gabbronorites are Pig + Plg + or - Sp cumulates whose parent magmas may range from high-Al to intermediate-Ti mare basalt. At least three varieties of mare basalt are found at Apollo 14: high-Al, low-Ti; low-Al, intermediate-Ti; and low-Al, Ti VHK basalt. VHK (Very High Potassium) basalt is a new variety indigenous to Apollo 14.

Shervais, J. W.↗