Thermal fragmentation of quinoline and isoquinoline N-oxides in the ion source of a mass spectrometer.
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The mineralogy and petrology of sixteen Apollo 15 soil samples from six stations are described together with the mineralogy, petrology, and chemistry of nineteen 4 to 10 mm basaltic lithic particles from nine stations. The lithic samples are classified, and relative abundances of the various rock types in the different samples are determined. The data are used to discuss the origin of the lithic types and their distribution according to selenological terranes. Population studies on particles in the 0.5 to 4 mm size range reveal systematic differences among three selenological terranes corresponding to the Appenine Front, the Mare/Rille, and the ridge or ray locations.
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General petrographic description of a large regolith specimen collected at the Taurus-Littrow landing site of Apollo 17. The specimen consists of a large clast of olivine micronorite hornfels with well-devepoled porphyroblastic texture, surrounded by highly vesicular olivine micronorite hornfels with incipient development of the porphyroblastic textures. Pink spinels with radial anorthite rims occur in both the clast and the surrounding matrix.
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Basalt and single-mineral particles, ranging from 150 to 425 microns, from the Luna-16 sample are studied by electron microanalysis, X-ray fluorescence analysis, and petrographic techniques. Three basalt species of different structure are identified. The structure and composition of the individual minerals (in particular of pyroxenes) indicate that the basalts have crystallized under conditions similar to those established for Apollo-11 samples.
Mineralogical, petrological, and chemical analyses, along with Rb-Sr age and Ar-40/Ar-39 measurements, were carried out with the B-1 sample returned from the Luna 16 mission. The sample, weighing 62 mg, is a fine-grain basalt of ophitic structure. It differs from the Apollo samples in that the pyroxene and plagioclass contents are almost identical, and the ilmenite content (7%) lies between those of the Apollo-11 and Apollo-12 samples. Chemically, it is characterized by a high Sr content and a high K/U ratio.
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A volumetric adsorption system incorporating a pressure gauge was employed to determine nitrogen adsorption and evaluate surface areas. The water adsorption of the lunar samples was measured with the aid of a gravimetric adsorption system including a microbalance. The results obtained in the investigation for the three samples are discussed in detail, giving attention to aspects of dehydroxylation and rehydroxylation.
Production of hydrogen and carbon atoms in metastable and high-lying Rydberg states by electron-impact dissociation of methane and deuterated methane is investigated for incident electron energies ranging from threshold values to 300 eV. Threshold energies for five different processes resulting in metastable hydrogen and carbon atoms are determined in the energy range from 20 to 70 eV, and it is shown that metastable hydrogen atoms are produced in four of these collisional processes while metastable carbon atoms are produced in the other. The nature of each collisional process is described, differential cross sections are derived for the dissociative excitation of both types of atoms to metastable and high-Rydberg states at 100 eV, and the onset energy for UV photon production is measured. Much of the data is interpreted in terms of the ion core model suggested by Kupriyanov (1968) and developed by Freund (1971).
Technology needed to predict damage and hazards from explosions of propellant tanks and bursts of pressure vessels, both near and far from these explosions is introduced. Data are summarized in graphs, tables, and nomographs.