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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
DOE OSTI2012

Utility-Scale Concentrating Solar Power and Photovoltaic Projects: A Technology and Market Overview

Over the last several years, solar energy technologies have been, or are in the process of being, deployed at unprecedented levels. A critical recent development, resulting from the massive scale of projects in progress or recently completed, is having the power sold directly to electric utilities. Such 'utility-scale' systems offer the opportunity to deploy solar technologies far faster than thetraditional 'behind-the-meter' projects designed to offset retail load. Moreover, these systems have employed significant economies of scale during construction and operation, attracting financial capital, which in turn can reduce the delivered cost of power. This report is a summary of the current U.S. utility-scale solar state-of-the-market and development pipeline. Utility-scale solar energysystems are generally categorized as one of two basic designs: concentrating solar power (CSP) and photovoltaic (PV). CSP systems can be further delineated into four commercially available technologies: parabolic trough, central receiver (CR), parabolic dish, and linear Fresnel reflector. CSP systems can also be categorized as hybrid, which combine a solar-based system (generally parabolictrough, CR, or linear Fresnel) and a fossil fuel energy system to produce electric power or steam.

14 SOLAR ENERGY↗
DOE OSTI2025

Understanding the Active Site Structures and Achieving Catalytic Activity Tuning of Atomically Dispersed FeN 4 Sites for Oxygen Reduction Reaction

Atomically dispersed Fe–—N—C catalysts with high oxygen reduction reaction (ORR) activity have attracted great attention since the last decade. Due to comparable ORR activity and low material cost, they are promising platinum group metal (PGM)-free catalysts that can replace the commercialized Pt/C materials; furthermore, it can facilitate the efficiency of the fuel cell technologies and mitigate dependence on fossil fuels. Great advancements have been made to experimentally optimize the synthesis approach of the Fe–—N—C catalysts, enhance the ORR activity, and improve the catalyst stability. Similarly, recent theoretical studies also provide enriched understanding of the active site structures, properties, and reaction mechanisms. In this review, discussions are made upon utilizing combined experimental and computational spectroscopy to reveal the active site structures, employing mechanistic studies to investigate reaction thermodynamics and kinetics, as well as developing scaling relationships to assist the design and development of future PGM-free catalyst materials. Furthermore, recent advances in studying Fe–—N—C catalysts utilizing electrified surface models and explicit solvation models are also discussed. Not only can these aspects improve the accuracy of theoretical simulation and predictions but also deepen the understanding of the catalyst properties and reaction mechanisms under the effect of surface charges and solvent molecules.

Fe single-atom catalysts↗
DOE OSTI2020

Model Validation and Demonstration of a Hydrogen Fuel Cell Parcel Delivery Truck

With an emphasis on reducing fossil fuel consumption and emissions, major delivery service corporations have begun deploying and operating Class 6 battery electric delivery vans. Fuel cell hybrid delivery vans offer a zero emissions solution with extended range and route planning flexibility. This paper follows a prior publication [1] on the vehicle modeling and design and presents demonstration data and a validation of the prior modeling and design effort. Here, the validation exercise shows that the modeling tools predict performance and energy efficiency within 5% for most of the routes, while the demonstration data shows that in service operation fuel economy was over 14 km/kg of hydrogen gas. In addition, results from a range test showed the vehicle design and onboard hydrogen storage was able to surpass the design target range of 200 km.

08 HYDROGEN↗
DOE OSTI2018

Characterization of Fossil and Renewable Fuels

The special issue aims to provide contributions from a variety of topics relating to the characterization of properties, structures or molecular compositions of fossil fuels, and biomass, as well as the corresponding derivatives or products through thermal, chemical, and biochemical methods

02 PETROLEUM↗
DOE OSTI2012

Hooper Bay Housing Analysis and Energy Feasibility Report

Sea Lion applied for and received a grant from the Department of Energy (DOE) towards this end titled Energy Efficiency Development and Deployment in Indian Country. The initial objectives of the Hooper Bay Energy Efficiency Feasibility Study were to demonstrate a 30% reduction in residential/commercial energy usage and identify the economic benefits of implementing energy efficiency measures to the Tribe through: (1) partnering with Whitney Construction and Solutions for Healthy Breathing in the training and hire of 2 local energy assessors to conduct energy audits of 9 representative housing models and 2 commercial units in the community. These homes are representative of 52 homes constructed across different eras. (2) partnering with Cold Climate Housing Research Center to document current electrical and heating energy consumption and analyze data for a final feasibility report (3) assessing the economics of electricity & heating fuel usage; (4) projecting energy savings or fossil fuel reduction by modeling of improvement scenarios and cost feasibility The following two objectives will be completed after the publication of this report: (5) the development of materials lists for energy efficiency improvements (6) identifying financing options for the follow-up energy efficiency implementation phase.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2020

Novel Homogeneous Electrocatalysts for the Nitrogen Reduction Reaction

This project funded a broad range of fundamental studies in the research labs of Prof. John Berry at the University of Wisconsin – Madison. The overall goals of this research are to identify and explore promising new fundamental chemistry of metal-metal bonded coordination compounds in catalysis, with a particular focus on exploring the technologies needed for the transition to a nitrogen economy. We focus on two key technologies for this overall goal: Electrochemical synthesis of ammonia from nitrogen and water, and Electrochemical ammonia oxidation to produce nitrogen. Ammonia is the most hydrogen-rich material known aside from hydrogen itself, and is therefore an ideal fuel unit. Currently, ammonia synthesis uses significant fossil fuel inputs, has a large carbon footprint, and is performed in large, centralized facilities, mandating the exploration of carbon-neutral approaches that can be done in a distributable manner so that ammonia transportation does not pose a bottleneck. Our work towards these goals is organized as follows: Goal 1: Synthesis and characterization of new catalysts and N2RR intermediates; Goal 2: Thermodynamic investigations of all catalysts and intermediates; Goal 3: Exploration of the electrocatalytic N¬2RR using new catalysts. We additionally made progress toward a related Goal 4: Exploration of new types of catalysts with other, cheaper transition metals. We had a major setback in year 1 of the grant due to the student driving this project (Tristan Brown) contracting an incurable disease that made it impossible for him to perform lab work. Tristan transitioned to a computational chemistry project and was subsequently able to complete his PhD.

02 PETROLEUM↗
DOE OSTI2021

Adhesion of Titanium Coatings on Additively Manufactured Stainless Steel

The ongoing global climate change crisis has brought attention to the urgent need to reduce greenhouse gas emissions from vehicles by providing alternative zero-emission fueling technologies. Prevailing vehicles are dependent on fossil fuels and contribute to climate change by creating emissions of carbon dioxide. In 2019, transportation was the largest contributing economic sector to the U.S. greenhouse gas emissions total at 29% [1]. By converting vehicle fueling to an alternative method, major reductions in greenhouse gas emissions can be achieved. Hydrogen fuel cells are one potential alternative capable of generating electricity from hydrogen while emitting only water. Several obstacles hinder the development of hydrogen fuel cells as a viable alternative, including the manufacturability of bipolar plates.

08 HYDROGEN↗
DOE OSTI2017

Chapter 10: Research and Deployment of Renewable Bioenergy Production from Microalgae

Recent progress towards the implementation of renewable bioenergy production has included microalgae, which have potential to significantly contribute to a viable future bioeconomy. In a current challenging energy landscape, where an increased demand for renewable fuels is projected and accompanied by plummeting fossil fuels' prices, economical production of algae-based fuels becomes more challenging. However, in the context of mitigating carbon emissions with the potential of algae to assimilate large quantities of CO2, there is a route to drive carbon sequestration and utilization to support a sustainable and secure global energy future. This chapter places international energy policy in the context of the current and projected energy landscape. The contribution that algae can make, is summarized as both a conceptual contribution as well as an overview of the commercial infrastructure installed globally. Some of the major recent developments and crucial technology innovations are the results of global government support for the development of algae-based bioenergy, biofuels and bioproduct applications, which have been awarded as public private partnerships and are summarized in this chapter.

09 BIOMASS FUELS↗
DOE OSTI2020

Conversion, Stability, and Selectivity Improvements Through Catalyst Development for the Reductive Etherification Reaction

Economical pathways from lignocellulosic non-food biomass feedstocks to biofuels with appropriate fuel properties are necessary for displacing fossil-fuel derived diesel use in medium-/heavy duty vehicles. Oxygenated compounds have recently shown promise due to low sooting tendencies and autoignition properties and molecules with sufficiently high carbon numbers can meet the requisite standards for water solubility and flash point. Coupling waste biomass derived small molecules into bioblendstock targets through the reductive etherification reaction shows potential for increasing molecular weight without losing the advantages of oxygenates. However, the transition to industrial viability for this process is limited by strong catalyst deactivation in typical flow reactor systems. Strong acid resins such as Amberlyst-15 (A-15) show excellent activity in batch reactions but are limited to low temperatures and are poisoned by the side-product, water. In this talk, I will describe our recent work in catalyst synthesis and testing to select superior options with improved aqueous and thermal stability in reductive etherification flow reactions. Water-tolerant solid acid catalysts have potential to improve the conversion and selectivity to the ether target at temperatures above the degradation point of A-15. Analysis techniques such as physisorption, chemisorption, x-ray diffraction and transmission electron microscopy are being used to characterize the active sites. These techniques are also being used to evaluate degradation of the catalyst after extensive flow reactions in addition to comparative efficiency testing with standardized cyclohexene hydrogenation reactions. Finally, I will discuss a demonstration of the full pathway from bio-derived butyric acid to the performance-advantaged ether product and the additional obstacles from side-products and purification limitations in the preliminary upgrading reactions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

Component level modeling of materials degradation for insights into operational flexibility of Existing Coal Power Plants

Increasingly, coal-fired power plants are required to balance power grids by compensating for the variable electricity supply from renewable energy sources. Fossil-fueled power plants, originally designed to be base loaded, will increasingly need to operate on a load following or cyclic basis. This demanding requirement for operational flexibility needs insights into accelerated material degradation arising due to the harsh operating conditions (e.g., fatigue, early oxide exfoliation due to stresses) along with current damage mechanisms (fireside corrosion, creep and erosion) observed in service. Our research objective is to develop component level modeling toolkit for materials-based degradation for two key mechanisms that can accelerate with cyclic operations. In more detail, this includes the fireside corrosion/steam oxidation/erosion/creep/fatigue of superheaters/reheaters and steam pipework and also the water droplet erosion/ fatigue of last stage steam turbine blades degradation mechanisms, that demand routine and sometimes unplanned maintenance and repair. The innovation is in developing a computational fluid dynamics/finite element (CFD/FE) modeling toolkit for the component level models of the boilers and low-pressure steam turbines in coal power plants that can tackle multidisciplinary failure mechanisms occurring concurrently for extreme environment materials. Lifetime assessment in such environments also needs to account for the unit-specific analyses, operational history and fuel feedstock; this can only be obtained by destructive analysis of components. This, in turn, enables validation of the model toolkits utilizing service feedback data, improving the probability of time/temperature dependent life prediction.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2017

Hydrogen Energy California (Final Scientific and Technical Report)

Hydrogen Energy California ("HECA") is an Integrated Gasification Combined-Cycle (IGCC) “polygeneration” project. The Project gasifies a 75 percent coal and 25 percent petroleum coke (petcoke) fuel blend to produce synthesis gas (syngas). Syngas produced via gasification is purified to hydrogen-rich fuel, which is used to generate low-carbon baseload electricity in a Combined Cycle Power Block, low-carbon nitrogen-based products in an integrated manufacturing Complex, and carbon dioxide (CO 2 ) for use in enhanced oil recovery (EOR). The power and products produced by HECA have a lower carbon footprint compared to power and products produced from more traditional fossil fuel facilities. This low-carbon footprint is achieved by capturing more than 90 percent of the CO 2 in the production of the hydrogen fuel and transporting it for use in EOR, which results in simultaneous sequestration (storage) of the CO 2 in a secure geologic formation in the adjacent Elk Hills Oil Field (EHOF), a hydrocarbon producing area. Highlights of HECA as conceived during the execution of FEED are as follows: The Project is designed to operate on a fuel blend consisting of 75 percent western subbituminous coal and 25 percent California petcoke based on thermal input to the gasifier on a higher heating value (HHV) basis; The feedstocks are gasified to produce syngas that is further processed and cleaned to produce hydrogen-rich fuel; More than 90 percent of the carbon in the raw syngas is captured in a high-purity CO 2 stream during steady-state operation; High purity CO 2 is compressed and transported by pipeline to the EHOF for injection into deep underground hydrocarbon reservoirs for CO 2 EOR; The Combined Cycle Power Block produces over 420 megawatts (MW) of gross power, which yields during periods of maximum power production over 270 MW of low-carbon baseload electricity to the grid; An integrated Manufacturing Complex produces approximately 1 million tons per year of low-carbon nitrogen-based products, including urea, urea ammonium nitrate (UAN), and anhydrous ammonia, to be used in agricultural, transportation, and industrial applications.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2020

Empirical Evidence for the Potential Climate Benefits of Decarbonizing Light Vehicle Transport in the U.S. with Bioenergy from Purpose-Grown Biomass with and without BECCS

Climate mitigation scenarios limiting global temperature increases to 1.5 °C rely on decarbonizing vehicle transport with bioenergy production plus carbon capture and storage (BECCS), but climate impacts for producing different bioenergy feedstocks have not been directly compared experimentally or for ethanol vs electric light-duty vehicles. A field experiment at two Midwest U.S. sites on contrasting soils revealed that feedstock yields of seven potential bioenergy cropping systems varied substantially within sites but little between. Bioenergy produced per hectare reflected yields: miscanthus > poplar > switchgrass > native grasses ≈ maize stover (residue) > restored prairie ≈ early successional. Greenhouse gas emission intensities for ethanol vehicles ranged from 20 to -179 g CO 2 e MJ –1 : maize stover $\gg$ miscanthus ≈ switchgrass ≈ native grasses ≈ poplar > early successional ≥ restored prairie; direct climate benefits ranged from ~80% (stover) to 290% (restored prairie) reductions in CO 2 e compared to petroleum and were similar for electric vehicles. With carbon capture and storage (CCS), reductions in emission intensities ranged from 204% (stover) to 416% (restored prairie) for ethanol vehicles and from 329 to 558% for electric vehicles, declining 27 and 15%, respectively, once soil carbon equilibrates within several decades of establishment. Extrapolation based on expected U.S. transportation energy use suggests that, once CCS potential is maximized with CO 2 pipeline infrastructure, negative emissions from bioenergy with CCS for light-duty electric vehicles could capture >900 Tg CO 2 e year –1 in the U.S. In the future, as other renewable electricity sources become more important, electricity production from biomass would offset less fossil fuel electricity, and the advantage of electric over ethanol vehicles would decrease proportionately.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Alkaline hydrothermal liquefaction of swine carcasses to bio-oil

Highlights: • Swine carcasses can be converted to bio-oil by alkaline hydrothermal liquefaction. • It seems that the use of the bio-oil for heat or CHP is technically suitable. • Some valuable chemicals were found in the bio-oils. • The bio-oil and the solid residue constituted an energy efficiency of 93.63% for the feedstock. • The solid residue can be used as a soil amendment, to sequester C and for preparing activated carbon. - Abstract: It is imperative that swine carcasses are disposed of safely, practically and economically. Alkaline hydrothermal liquefaction of swine carcasses to bio-oil was performed. Firstly, the effects of temperature, reaction time and pH value on the yield of each liquefaction product were determined. Secondly, liquefaction products, including bio-oil and solid residue, were characterized. Finally, the energy recovery ratio (ERR), which was defined as the energy of the resultant products compared to the energy input of the material, was investigated. Our experiment shows that reaction time had certain influence on the yield of liquefaction products, but temperature and pH value had bigger influence on the yield of liquefaction products. Yields of 62.2 wt% bio-oil, having a high heating value of 32.35 MJ/kg and a viscosity of 305cp, and 22 wt% solid residue were realized at a liquefaction temperature of 250 °C, a reaction time of 60 min and a pH value of 9.0. The bio-oil contained up to hundreds of different chemical components that may be classified according to functional groups. Typical compound classes in the bio-oil were hydrocarbons, organic acids, esters, ketones and heterocyclics. The energy recovery ratio (ERR) reached 93.63%. The bio-oil is expected to contribute to fossil fuel replacement in stationary applications, including boilers and furnaces, and upgrading processes for the bio-oil may be used to obtain liquid transport fuels.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

It's Not Just About the Megawatts - ARC Industry Forum, The Future of Power Generation

As the world transitions to less carbon intensive energy portfolios, much of the attention understandably centers on generating capacity – replacing megawatts of fossil fuel with megawatts of solar, wind, nuclear, hydroelectric, hydrogen, and more. The actual operation of a reliable grid needs more than just megawatts though: adequate quantities of a portfolio of essential reliability services; flexible and capable power delivery systems; governance to operate in 5-10 minute intervals, forecast hourly, and plan and build on a generational time horizon; and dependable and secure communications. We can choose our fuel mix for climate reasons, but the grid itself and the society that relies upon it impose constraints on those choices that we ignore at our peril.

13 HYDRO ENERGY↗
DOE OSTI2025

NETL Energy Related Diagrams 2024 Edition [Slides]

This illustrative report uses Sankey type diagrams to illustrates energy use and CO 2 generation within the U.S. for the year 2024. The diagrams show primary energy consumption from coal, natural gas, nuclear, petroleum, and renewables for the electric, residential, commercial, industrial, and transportation sectors; fossil fuel trade/domestic production; and CO 2 generation by fuel and end use.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2017

Electrification and Decarbonization: Exploring U.S. Energy Use and Greenhouse Gas Emissions in Scenarios with Widespread Electrification and Power Sector Decarbonization

Electrification of end-use services in the transportation, buildings, and industrial sectors coupled with decarbonization of electricity generation has been identified as one of the key pathways to achieving a low-carbon future in the United States. By lowering the carbon intensity of the electricity generation and substituting electricity for higher-emissions fossil fuels in end-use sectors, significant reductions in carbon dioxide emissions can be achieved. This report describes a preliminary analysis that examines the potential impacts of widespread electrification on the U.S. energy sector. We develop a set of exploratory scenarios under which electrification is aggressively pursued across all end-use sectors and examine the impacts of achieving these electrification levels on electricity load patterns, total fossil energy consumption, carbon dioxide emissions, and the evolution of the U.S. power system.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2017

LCA to Evaluate the Environmental Impact for Chemical Pre-treatment in Plastics Metallization

The life cycle assessment methodology was used to calculate the environmental impacts of the current chemical pre-treatment with chromium(VI) for electroplating acrylonitrile butadiene styrene. The inventory comprised: the procurement of chemicals; the manufacturing process with successive baths and rinses that requires, in addition to chemicals, energy to heat baths, air agitation, filtration, and so forth, wastewater treatment and air emissions; and also the treatment of sludges from wastewater treatment and exhausted baths. Chromic acid was almost the unique responsible of eco-toxicity (97.5 %) and human toxicity-cancer (99.8 %) and it was one of the highest contributor to climate change, cumulative energy demand, fossil fuel depletion, human toxicity non-cancer, and in abiotic depletion.

54 ENVIRONMENTAL SCIENCES↗