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At least 523 records · Page 29

Aerodynamic effects on outer ash deposition rates in second generation atmospheric pressure oxy-coal combustion systems

Recent measurements in scenarios representative of second generation atmospheric pressure oxy-coal combustion systems have shown a significant increase in ash deposition rates in comparison to combustion in air. However, the causative mechanisms behind this increase have not been well understood. To fill this void, well-characterized experiments including fuel and deposit particle size distributions (PSDs) were coupled with highly resolved numerical simulations to isolate the aerodynamic effects impacting the deposition process such that mechanisms could be hypothesized. Three combustion scenarios (AIR, OXY27, OXY70) spanning a factor of three variation in flue gas volumetric flow rates were simulated and the deposition characteristics (impaction rates, deposit PSD, temperature, residence times, capture rates) tracked/predicted using a customized deposition module. The measured deposit PSD was significantly different from the PSD of the parent fuel indicating significant physio-chemical transformations (coalescence and particle growth in particular) at play. The use of simplistic modeling approaches (swelling parameter variations) to model particle growth led to inaccurate deposit ash PSD and rate predictions. A more satisfactory agreement between the measurements and simulations was obtained when the functional form of the parent fuel PSD (spread parameter) was modified to conform closely to the deposit PSD while still ensuring the fidelity of temperature and velocity predictions. Based on the measured ash compositions, identical capture criteria were employed across all three scenarios. Here this study further supports the theory that the ash deposition rates in these systems are dominated by aerodynamic effects with the ash PSD playing a dominant role.

42 ENGINEERING↗

Test of model of equivalence of tree height growth and transpiration rates in percolation-based phenomenology for root-soil interaction

We recently introduced a phenomenological model to represent root-soil interactions that accounts for variability in tree growth on local scales and within species (Hunt et al., 2020). Here, using publicly available datasets, we examine the developed model to provide additional empirical evidence, which also gives novel insight into two particular tree species, Eucalyptus regnans and Eucalyptus sieberri. In particular, we discovered two novel aspects of the model: a power-law time dependence with a different power-law exponent than usually heretofore applied, and apparently a direct equivalence of results for transpiration and growth rates. Also, although our original expectation was that growth and transpiration were merely proportional, comparison of the entire BAAD data set (Falster et al., 2015) for tree height with our model (Hunt et al., 2020; Fig. 1) already suggested approximate equality of these disparate measurements (volume/area, height). In this present manuscript we find further evidence for equivalence of the two measurements and provide additional theoretical basis for a model assumption regarding constancy of sap flow rates.

54 ENVIRONMENTAL SCIENCES↗

Diurnal observations of basal stem CO2 efflux in three canopy dominant trees in the central Amazon

We explored mechanisms responsible for disturbance-induced shifts in carbon metabolism in forests north of Manaus, Brazil (S2º 38' 17", W60º 09' 25"), using data from a selective logging experiment (BIONTE). BIONTE (the BIOmass and NuTrient Experiment) selective logging treatments were initiated in the mid-1980s and comprised variable removal of commercial tree (not total) species basal area (T1 =32%, T2 = 42%, T3 = 69%), and control plots with no logging (T0). Raw data including tree base diameter (Db), CO2 concentration versus time inside a static stem chamber, and wood density were used to derive stem respiration rates (Rw), wood production rates (Pw), and wood carbon use efficiency (CUE). Changes in tree base diameter (Db; measured at 1.3 m height, or above the buttresses) was used to calculate wood production for individual trees (Pw). Wood density enabled calculation of stem growth rate in the same units as stem respiration (mmol C m-2 s-1). Four trees were randomly selected from five tree growth rate classes for each treatment block, for a total of 20 trees per treatment block, or 80 trees total from the BIONTE plots. Each of the 80 trees selected for the Rw study were outfitted with dendrometer bands (da Silva et al. 2002). Stem respiration was measured using the method described in Chambers et al. (2004). Briefly, an infra-red gas analyzer (LiCor 820) was operated as a closed dynamic chamber with a flow rate of 1.0 L min-1. Polyvinyl chloride (PVC) semi-cylindrical chambers (250–400 mL) were secured to the tree stem near the dendrometer bands using nylon straps. The measurement interval spanned 1–2 min, and the CO2 flux from the stem of each tree was quantified using the enclosed stem area and slope of the stem CO2 concentration versus time.

54 ENVIRONMENTAL SCIENCES↗

Wire-coil insert optimization for high-heat-load/flux synchrotron components

Many synchrotron components require high levels of internal-flow, forced-convection heat transfer to minimize surface temperatures, thermal gradients, and thermally induced stress on high-power beam-interacting surfaces. Wire-coil inserts, physically similar to a common spring, are mechanically fitted inside of component cooling passages to optimize heat transfer performance. They are routinely used in Advanced Photon Source (APS) front end and beamline high-heat-load/flux components to significantly enhance convection heat transfer-up to 400% compared to plain open passages. This has the additional benefit of greatly reducing coolant flow requirements for these components. Using several cooling passage sizes, five different wire sizes, and a range of pitch values, an experimental investigation conducted at the APS has determined the average heat transfer coefficient and resulting pressure loss as a function of water flow rate for 65 different wire-coil inserts. Data from this study have been non-dimensionalized and generalized to yield relationships that can be used to determine the heat transfer performance and resulting pressure loss for any given wire-coil insert that may be used at the APS. Through data reduction, the wire-coil insert characteristic dimensions have also been optimized to yield the highest heat transfer enhancement while minimizing the coolant flow requirements. These generalized expressions for wirecoil inserts will be presented, and they can be used by scientists and engineers during the component design process to evaluate achievable heat transfer performance and associated pressure loss, aiding in the establishment of optimized operating parameters and cooling passage flow distribution schemes.

43 PARTICLE ACCELERATORS↗

SWIFT - Shaped-Waveform Interrogation of Fluids Technique

Researchers at Los Alamos have developed the Shaped-Waveform Interrogation of Fluids Technique (SWIFT), a technology enabling unprecedented process control capability. This technology provides important composition, flow rate, and pipe thickness measurements in real-time, at an extremely low cost and maintenance cycle. By utilizing a specialized shaped-waveform, as well as state-of-the-art signal processing, this information can be gathered without any frequency-domain signal processing, allowing for simplified electronics compared to nearly any other meter on the market. Since this technology is in expensive and non-invasive, with the capability of measuring liquids in both flow pipes and sealed containers, it is perfect for several industrial applications in the oil and gas, beverage, chemical, and pharmaceutical spaces. We are seeking a commercialization partner to license the technology or fund us through a Cooperative Research and Development Agreement (CRADA) to a further develop a usable product for commercial purposes.

47 OTHER INSTRUMENTATION↗

Reaction Temperature Manipulation as a Process Intensification Approach for CO 2 Absorption

Reactor temperature manipulation to increase product yields of chemical reactions is a known technique used in many industrial processes. In the case of exothermic chemical reactions, the well-known Le Chatelier’s principle predicts that a decrease in temperature will displace the chemical reaction toward the formation of products by increasing the value of the equilibrium constant. The reverse is true for endothermic reactions. Reactor temperature manipulation in an industrial system, however, affects the values of many variables, including physical properties, transport parameters, reaction kinetic parameters, etc. In the case of reactive absorption, some variables change with increasing temperatures due to solute absorption, while others change in such a way that the solute absorption rate decreases. For example, temperature drop increases product formation for exothermic reactions but reduces the value of transport parameters, leading to decreasing interfacial concentrations and absorption rates. Therefore, temperature manipulation strategies must be designed carefully to achieve the process goals. In this work, we theoretically study the use of temperature as a tool to increase CO 2 absorption by solvents in a semi-batch reactor. A computer code has been developed and validated using reported experimental data. Calculated results demonstrate an increase in absorbed CO 2 of more than 28% with respect to the highest temperature used. Despite high agitation and high gas flow rate, the system is mass transfer controlled at short times, becoming kinetically controlled as time increases. An operating strategy to decrease cooling energy costs is also proposed. This study reveals that reactor temperature manipulation can be an effective process to improve CO 2 absorption by solvents in two-phase semi-batch reactors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Innovating High Throughput Hydrogen Stations: Cooperative Research and Development Final Report, CRADA Number CRD-18-00773

Hydrogen stations today serve the emerging market of light duty fuel cell vehicles, primarily in California with over 30 public retail locations. There has been a steady increase in the number of stations open and hydrogen dispensed, especially in the last two years. From 2015 to 2016, the annual amount of hydrogen dispensed increased from 27,400 kg to 109,200 kg, a nearly fourfold increase in just one year. One station dispensed nearly 12,000 kg in the second quarter of 2017. Despite the significant progress, gaps exist between current infrastructure capabilities and future requirements. For example, fuel cell vehicle applications such as buses, medium-duty, and heavy-duty trucks will gain market share and this must be considered as future customers at hydrogen stations. The expected number of light duty fuel cell vehicles in California alone are expected to grow from approximately 4,000 to over 13,000 by 2020, and 37,000 by 2023. To serve the multiple mobile fuel cell technologies and increased demand, hydrogen stations will have to increase output, decrease cost, and improve reliability. To address these challenges, the project team will demonstrate a hydrogen-focused integrated renewable energy production, storage, and transportation fuel distribution/retailing system. The proposed R&D tasks address key challenges related to light duty station/component reliability and development and validation of high flow rate system models for new applications like medium and heavy-duty truck fueling.

08 HYDROGEN↗

Methane foam performance in oil-wet unconsolidated porous media: A systematic experimental investigation at reservoir conditions

Methane foam performance was systematically evaluated using high-pressure and high-temperature experiments performed on oil-wet proppant packs. The sensitivities of foam performance to various key factors, including surfactant concentration, foam quality, total injection rate, salinity, operating pressure, and initial oil saturation were examined. The results showed that even though the foamability and foam strength in oil-wet proppant packs were adversely affected by wettability and presence of oil, the steady-state pressure drops across the proppant packs were insensitive to the quantity of oil initially present. The presence of oil above the critical oil saturation impeded the onset of foam generation. This suggested that the foamability of surfactants depends on the synergetic effects of surfactant’s ionic nature and foam parameters, such as foam quality and total injection rate, on their ability to reduce the oil saturation to a threshold value below which favorable bubble generation sites could be created. It was observed that, for low injection rate, anionic surfactant was ineffective at low salinity conditions, while amphoteric agent performed well at all salinities. Additionally, an increase in salinity resulted in enhanced pressure drop across the proppant packs for both anionic and amphoteric surfactants. Further, the results also established that too high operating pressures are somewhat detrimental to the foam strength and stability, irrespective of the ionic nature of foaming agents and the wettability of the porous medium. For the anionic surfactant, the increase in the total flow rate was found to mitigate the adverse effects of low salt concentration and operating pressure. Results from quality-sensitivity foam tests identified two regions for the foam behavior, named low-quality and high-quality regimes, separated by the transition foam quality. Finally, we discuss the implications of the results for the design and effective implementation of enhanced oil recovery (EOR) schemes that deploy hydrocarbon-based foams.

02 PETROLEUM↗

Numerical Simulation and Experimental Comparison of System Analysis Module 1D Mixing Model for Cold Shock Transients in the Gallium Thermal-Hydraulic Mixing Facility

Abstract Liquid metals are being investigated as coolants in many advanced reactor designs because of their high thermal conductivity and effectiveness at high temperatures. However, they often pose challenges to reactor operation and safety because of the complex thermal mixing and stratification in the plenum of pool-type reactor designs. The advanced system analysis code System Analysis Module (SAM) currently under development at Argonne National Laboratory aims to develop and implement thermal mixing models to accurately capture these complex thermal fluid behaviors. In this study, the SAM thermal mixing model was compared against experimental data from the Gallium Thermal-Hydraulic Experiment facility, a scaled liquid metal test facility that uses gallium as a surrogate fluid to investigate the stratification and thermal mixing of low-Prandtl-number fluids in the upper plenum of a liquid metal-cooled reactor. Two cold shock transient cases were used: one with stable stratified flow (Ri = 32) and one with stronger thermal mixing (Ri = 0.5). The resultant temperatures were then compared with the experimental temperatures over the entire plenum to assess the ability of the mixing models to capture the thermal behavior and to better correspond mixing parameters to various flow scenarios. Generally, the zero-dimensional mixing model was more capable of capturing the bulk temperature of the component modeled assuming that an accurate mass flow rate was provided, but it was inherently unable to capture thermal gradients in space. The one-dimensional mixing model was capable of capturing that the thermal gradients provided accurate selection of the mixing coefficients. Further, the temperature at the outlet junction was compared over time for each of the mixing models with the recorded experimental temperature. The implemented mixing models demonstrated the ability to effectively capture the overall thermal behavior for stronger mixing scenarios but struggled with more stably stratified flows. It was found that a system analysis code's covering of the entire range of different operating conditions still remains a challenging task, and it is suggested that further model and closure improvements are necessary to accurately capture complex thermal mixing and stratification phenomena.

stratification↗

Benchmarking the design of the cryogenics system for the underground argon in DarkSide-20k

DarkSide-20k (DS-20k) is a dark matter detection experimentunder construction at the Laboratori Nazionali del Gran Sasso (LNGS)in Italy. It utilises ∼ 100 t of low radioactivity argon from anunderground source (UAr) in its inner detector, with half serving astarget in a dual-phase time projection chamber (TPC). The UArcryogenics system must maintain stable thermodynamic conditionsthroughout the experiment's lifetime of over10 years. Continuous removal ofimpurities and radon from the UAr is essential for maximising signalyield and mitigating background. We are developing an efficient andpowerful cryogenics system with a gas purification loop with atarget circulation rate of1000 slpm. Central to itsdesign is a condenser operated with liquid nitrogen which is pairedwith a gas heat exchanger cascade, delivering a combined coolingpower of more than 8 kW. Here wepresent the design choices in view of the DS-20k requirements, inparticular the condenser's working principle and the coolingcontrol, and we show test results obtained with a dedicatedbenchmarking platform at CERN and LNGS. We find that the thermalefficiency of the recirculation loop, defined in terms of nitrogenconsumption per argon flow rate, is95 % and the pressure in the testcryostat can be maintained within±(0.1–0.2) mbar. Wefurther detail a 5-day cool-down procedure of the test cryostat,maintaining a cooling rate typically within-2 K/h, as required for theDS-20k inner detector. Additionally, we assess the circuit's flowresistance, and the heat transfer capabilities of two heat exchangergeometries for argon phase change, used to provide gas forrecirculation. We conclude by discussing how our findings influencethe finalisation of the system design, including necessarymodifications to meet requirements and ongoing testing activities.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Thermo-Hydro-Mechanical Modeling of Brine Migration in a Heated Borehole Test in Bedded Salt

Abstract This research paper focuses on the thermo-hydro-mechanical (THM) modeling of brine migration in a heated borehole test conducted as part of the ongoing Brine Availability Test in Salt (BATS) at the Waste Isolation Pilot Plant (WIPP) in New Mexico. It is a component of the international collaboration project DECOVALEX-2023 (DEvelopment of COupled models and their VALidation against EXperiments), which aims to understand the THM processes governing brine flow in heated rock salt repositories through collaborative analysis by multiple research teams. Using the TOUGH–FLAC simulator, THM simulations were performed and compared with data from the BATS phase 1a. This experiment involved two identical horizontal-borehole arrays, one heated and one serving as a control, both equipped with sensor arrays. Analysis of measurements revealed water flow rate surges during heater power transitions, with the highest jump observed during cooling. Acoustic emission activity exhibited distinct patterns in response to heater power changes, suggesting that damage to rock salt is particularly pronounced during the cooling phase. The THM simulations successfully captured these phenomena, highlighting the significance of thermal effects, brine migration, and mechanical behavior in predicting brine availability in heated and damaged rock salt. Our modeling also revealed the critical interplay between heating and cooling-induced damage and its influence on flow properties, particularly affecting brine inflow estimation. Notably, we found that cooling-induced brine inflow spikes result from increased permeability due to tensile dilatancy. These findings have important implications for the development of robust containment strategies and enhance our understanding of the complex processes involved in repository performance.

58 GEOSCIENCES↗

Vacuum-assisted carbon molecular sieve membrane reactor for non-oxidative ethane dehydrogenation

Non-oxidative ethane dehydrogenation (EDH) is equilibrium-limited and endothermic. Selective hydrogen removal using a gas-permeable membrane within the EDH reaction zone can overcome the thermodynamic equilibrium, enabling higher ethane conversions. Employing vacuum as the permeation driving force, rather than a sweep gas, enhances the industrial viability of membrane reactors by eliminating additional post-reaction separation units. This study presents a membrane reactor that integrates H 2 -permeable carbon molecular sieve (CMS) hollow fiber membranes embedded in a fixed bed of cobalt in a dealuminated beta zeolite (Co@DeAl-BEA) catalyst, utilizing a vacuum to remove hydrogen efficiently. The CMS membrane exhibits high hydrogen permeance and an excellent H 2 /C 2 H 6 separation factor. The membrane reactor significantly enhanced the ethane conversion under reaction conditions comparable to those reported in the literature. A Langmuir-Hinshelwood kinetic rate expression was developed and incorporated into a one-dimensional steady-state reactor model. The experimentally validated model indicates that increasing the number of hollow fibers improves ethane conversion, although ethane loss to the permeate limits the benefit. The contact area between the catalyst and the membrane limits the reactor performance more than the catalytic throughput. Furthermore, we find that the location of the catalyst packing relative to the hollow fiber membranes influences ethane loss and conversion. Higher reactor pressures and inlet ethane flow rates improve space-time yield at the expense of lower ethane conversion. Increasing reactor temperature or packing length promotes both performance metrics. The EDH membrane reactor demonstrated durability over 200 h of continuous operation, maintaining record-low deactivation rates and high ethylene selectivity. Protocols for catalyst regeneration were developed.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

An experimental system and procedure of unsteady-state relative permeability test for gas hydrate-bearing sediments

Reliable estimations of the relative permeability of gas and water in hydrate-bearing sediments (HBS) and the dependency of the relative permeability on hydrate saturation are critical to predict the productivity of a hydrate reservoir. Yet, this remains poorly estimated owing to lack of experimental data associated with difficulties in conducting multiphase flow experiments in HBS. Recognizing the experimental challenges, this study intends to develop and validate a new experimental system and procedure of unsteady-state relative permeability test that can generate reliable and reproducible flow measurements in HBS. Furthermore, gas hydrate is considered as a part of solid matrix in the sediment, so one of the challenges is to maintain a constant hydrate saturation, which is achieved in this experimental study using tight pressure-temperature (P-T) control near the hydrate stability boundary. The measured differential pressure across the specimen, methane injection flow rate, and volume of displaced brine are used to calculate the relative permeability by adopting a conventional Buckley-Leverett theory-based interpretation method. Residual brine saturation calculated for the hydrate-bearing specimen is higher than that of hydrate-free specimen, presumably due to decrease in pore size, increase in heterogeneity of solid matrix, and increase in size distribution of solid matrix and pore in the presence of hydrates. Further studies are necessary to represent the results of the unsteady-state flow experiment in HBS with a gas hydrate-dependent relative permeability model.

03 NATURAL GAS↗

Effects of surface runoff and infiltration partition methods on hydrological modeling: A comparison of four schemes in two watersheds in the Northeastern US

The ratio according to which the precipitation/snowmelt is divided into surface and subsurface water is of primary importance to watershed scale hydrological modeling. The present study compared four different surface runoff and infiltration partition methods in the Richards-equation-based SWAT model (RSWAT), i.e., daily curve number method (DC-RSWAT), hourly curve number method (HC-RSWAT), Green-Ampt method (GA-RSWAT), and effective infiltration capacity method (EIC-RSWAT). These four versions of RSWAT and a daily-curve-number-based SWAT (DC-SWAT) were used to simulate daily flow rate (from 2001 to 2015) at the outlets of the Tuckahoe Creek Watershed (TCW) and Greensboro Watershed (GW) of the Chesapeake Bay in Maryland. Parameter sensitivity analysis, calibration, and prediction uncertainty analysis were conducted. The results indicate that surface runoff and infiltration partition methods have pronounced impacts on model performance. Comparative analysis showed that DC-RSWAT outperformed other versions of RSWAT for both calibration (from 2001 to2007) and validation (from 2008 to 2015) periods in the two test watersheds. In general, DC-RSWAT achieved more accurate deterministic flow simulation and reliable uncertainty estimation than other versions. As such, daily-curve-number method is recommended for surface runoff and infiltration partition in RSWAT for simulating stream flow.

hydrology, modeling, streamflow↗

Effect of Hydrogen on Steady-State and Transient Combustion Instability Characteristics

This paper examines the effects of steady-state and transient hydrogen enrichment on thermoacoustic instability in a model gas turbine combustor. Combustion instability, a feedback loop between flame heat release rate oscillations and combustor acoustics, is characterized in a swirl-stabilized flame operated at a range of hydrogen–natural gas fuel blends and heat rates. Measurements of combustor chamber pressure fluctuations and CH* chemiluminescence imaging are used to characterize instability at a range of operating conditions. Steady-state tests show that both mixture heat rate and hydrogen content affect system stability. At a given heat rate, higher levels of hydrogen result in unstable combustion. As heat rate increases, instability occurs at lower concentrations of hydrogen in the fuel. Transient operation was tested in two directions—instability onset and decay—and two hydrogen-addition times—a short time of 1 ms and a longer time of 4 s. Results show that instability onset processes, through the transient addition of hydrogen, are highly repeatable regardless of the timescale of hydrogen addition. Certain instability decay processes are less repeatable, resulting in cases that do not fully transition from unstable to stable combustion despite similar changes in hydrogen fuel flow rate. Flame behavior before, during, and after the transient is characterized using high-speed CH* chemiluminescence imaging. Analysis of the high-speed images shows changes in flame stabilization and dynamics during the onset and decay processes. Finally, the results of this study can have implications for systems that experience variations in fuel composition, particularly in light of growing interest in hydrogen as a renewable fuel.

42 ENGINEERING↗

SAS4A/SASSYS-1 Validation with the FFTF LOFWOS Tests #10-12

The FFTF liquid sodium cooled test reactor was built to assist the development and testing of advanced fuels and material for fast reactors. The goals of the FFTF Passive Safety Testing program included confirming the safety margins of FFTF as a liquid metal reactor, providing data for computer code validation, and demonstrating the inherent and passive safety benefits of its specific design features. The program included thirteen unprotected loss of flow without scram tests. The results of modeling and simulation of LOFWOS Tests #10, #11, and #12 are presented in this report to support validation of Argonne’s SAS4A/SASSYS-1 fast reactor safety analysis code. These three tests did not use the primary loop pony motors and thus transitioned to natural circulation flow rates from varying initial power levels. This validation activity leverages modeling and simulation efforts that originated under an International Atomic Energy Agency Coordinated Research Project (CRP) for benchmark analysis of the FFTF LOFWOS Test #13. The SAS4A/SASSYS-1 model originally developed for the CRP has been extended to include LOFWOS Tests #10-12 and modernized to utilize new code features and modeling practices. Predicted results from SAS4A/SASSYS-1 were compared to measured test data and differences were investigated. Overall, it was concluded that, for LOFWOS Tests #10-12, there was good agreement between the flow, power, and temperature predictions and the measured data.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Characterizing the Impacts of Multi-Scale Heterogeneity on Solute Transport in Fracture Networks

We model flow and transport in fracture networks with varying degrees of fracture-to-fracture aperture heterogeneity and network intensity to show how changes in these properties can cause the emergence of anomalous flow and transport behavior. If fracture-to-fracture aperture heterogeneity is increased in sparse networks, velocity fluctuations inhibit high flow rates and solute transport can be delayed. Surprisingly, transport can be slowed even in cases where hydraulic aperture is monotonically increased. As the intensity of the networks is increased, more connected pathways allow for particles to bypass these effects. There exists transition behavior where with relatively few connected pathways in a network, first arrival times of particles are not heavily affected by fracture-to-fracture aperture heterogeneity, but the scaling behavior of the tails is strongly influenced. These results reinforce the importance of considering multi-scale effects in fractured systems and can inform flow and transport processes in both natural and engineered fractured systems.

58 GEOSCIENCES↗