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At least 523 records · Page 29

Bio-fuel effects and seasonal fuel property variations related to abnormal combustion occurrences observed in the field

Since 2015, the automotive industry has regularly observed sharp increases in customer complaints of poor driveability and increased warranty claims during the months of September and October. These persistent seasonal complaint increases have been tracked to occur from increased abnormal combustion events that coincide with the seasonal transition from summer to winter fuel volatility, beginning on September 15th annually. The Reid Vapor Pressure (RVP) of gasoline during this seasonal transition has been found to be the primary property attributed to this annual issue. It’s hypothesized that an increase in volatile butanes and pentanes from advanced petroleum recovery techniques and hydrofracking production has hastened the transition from summer to winter fuel volatility in the marketplace, rather than the gradual increase of the RVP over time as historically intended. At worst, mid-winter fuel, with an RVP ranging from 12 to 16 psi, depending on location in the U.S., enters the market while ambient temperatures can still be above average for the winter season. This combination of high volatility fuel with unseasonably warm weather will increase fuel system flash boiling, injector spray cavitation, and spray collapse inside the engine’s combustion chamber, ultimately linking fuel property variations to abnormal engine combustion processes. This CRADA program will investigate these known knowledge gaps by coupling with two national laboratories, Oak Ridge National Laboratory, and the National Renewable Energy Laboratory to employ both unique tools and expertise throughout the industry to provide the insight, knowledge, and data critical to understand the observed interactions. Overall findings of this work are that fuel wall retention increased SPI proportionally, and fuels with an increased distillation (i.e. energy fraction) above the wall temperature increased fuel retention. Likewise fuels with increased enthalpy of vaporization (HoV) increased fuel retention proportional to the temperature reduction from the HoV (~13K reduction in this work). Thus, fuel with increased HoV and increased fuel distillation above the linear temperature also exhibited increased SPI rates. Fuel with high RVP did exhibit increased fuel spray collapse form spray imaging measurements, but in SPI testing the high volatility of these fuels at the tested conditions did not necessarily increase SPI rates despite exhibiting increased spray collapse in injector imaging and increased spray-wall impingement measured in fired engine testing. It was also found that spray imaging showed collapse was possible at throttled conditions, but this was not relevant to high boost pressures relevant to SPI conditions, however, under transient load and or speed encountered in real-world operation fuel spray collapse could affect fuel retention and real-world SPI that were not probed in the automated high load test sequence of this work.

09 BIOMASS FUELS↗

Ion bombardment and its effects on the optical properties of metals

An experimental program, to evaluate the change in total hemispherical emittance and solar absorptance of engineering metals used on spacecraft and in spacecraft instrumentation systems, is presented. Three materials, titanium alloy, pure aluminum, and electrolytic copper, were used in the experiment. Results show that emittance, absorptance, and alpha/epsilon ratio of the materials were changed by ion bombardment. The time before the change occurs depends upon the material used, the intensity of bombardment, and the environment assumed.

Anderson, D. L.↗

The influence of environmental effects on the mechanical properties of graphite/epoxy laminates

The time dependent deformational and creep rupture processes in graphite/epoxy laminates are examined as a function of temperature and stress level. The role of accelerated characterization of design materials is discussed, and the use of a nonlinear time-temperature-stress-superposition principle in the determination of compliance master curves as a function of stress and temperature is considered. Creep rupture analytical models are discussed as applied to polymer-matrix composites, and the data is shown to be in general agreement with a logarithmic stress and temperature-dependent delayed fracture model. Comparisons between creep and rupture experiments and phenomenological models are presented.

Brinson, H. F.↗

Spacecraft contamination: Sources and prevention; Thermophysics Conference, 18th, Montreal, Canada, June 1-3, 1983, Selected Papers

Results of current research in the field of spacecraft contamination are presented. An overview of the various sources of contamination is given, showing the many and diverse mechanisms associated with the degradation of thermal and optical performance of spacecraft surfaces and optics. Some of the causes of contamination are discussed, including spallation of foam insulation on cryogenic fuel tanks, dispersion of particle contamination about a spacecraft, particle contamination of optical sensors, and the influence of the location of venting systems. Contamination prevention is addressed. Infrared transmittance and infrared optical properties of contaminants are considered along with the effects and properties of mixtures of exhaust species, of plume boundary layer flow, and of the contamination associated with bipropellant attitude control thrusters proposed for the Galileo spacecraft. Also discussed are: degradation of 'clean' thermal control surfaces over four years in orbit, in-orbit measurement of solar absorptance, and contamination from postfire efflux of a solid-propellant rocket motor.

Roux, J. A.↗

Simulated space environment effects on the optical properties of poly(arylene ethers)

Results are reported from a study of the stability of poly(arylene ethers) formed in a reaction of 1,3 -bis(4-chlorobenzoyl)benzene and various bisphenols after experiencing long-term exposure to space conditions. Transparent poly(arylene ethers) films were subjected to separate electron and UV bombardments, as were polysulfone and Kapton films for comparisons. The order of exposure to the two types of radiation was reversed for two sample populations. The optical properties and glass transition temperatures of the samples were determined after irradiation. The poly(arylene ethers) films exhibited good resistance to the electron radiation but suffered severe degradation in the UV environment. The loss of optical transmissivity was proportional to the UV radiation dose.

Sykes, George F.↗

Thermal effects on the mechanical properties of SiC fiber reinforced reaction bonded silicon nitride matrix (SiC/RBSN) composites

The elevated temperature four-point flexural strength and the room temperature tensile and flexural strength properties after thermal shock were measured for ceramic composites consisting of 30 vol pct uniaxially aligned 142 micron diameter SiC fibers in a reaction bonded Si3N4 matrix. The elevated temperature strengths were measured after 15 min of exposure in air at temperatures to 1400 C. Thermal shock treatment was accomplished by heating the composite in air for 15 min at temperatures to 1200 C and then quenching in water at 25 C. The results indicate no significant loss in strength properties either at temperature or after thermal shock when compared with the strength data for composites in the as-fabricated condition.

Bhatt, R. T.↗

Oxidation effects on the mechanical properties of SiC fiber-reinforced reaction-bonded silicon nitride matrix composites

The room temperature mechanical properties of SiC fiber reinforced reaction bonded silicon nitride composites were measured after 100 hrs exposure at temperatures to 1400 C in nitrogen and oxygen environments. The composites consisted of approx. 30 vol percent uniaxially aligned 142 micron diameter SiC fibers in a reaction bonded Si3N4 matrix. The results indicate that composites heat treated in a nitrogen environment at temperatures to 1400 C showed deformation and fracture behavior equivalent to that of the as-fabricated composites. Also, the composites heat treated in an oxidizing environment beyond 400 C yielded significantly lower tensile strength values. Specifically in the temperature range from 600 to 1000 C, composites retained approx. 40 percent of their as-fabricated strength, and those heat treated in the temperatures from 1200 to 1400 C retained 70 percent. Nonetheless, for all oxygen heat treatment conditions, composite specimens displayed strain capability beyond the matrix fracture stress; a typical behavior of a tough composite.

Bhatt, Ramakrishna T.↗

Stoichiometric effects on the optical properties of LiInSe(2)

The diffuse reflectance of LiInSe(2) between 0.67 and 3.54 eV have been measured and the Kubelka-Munk theory was used to obtain the absorption coefficient from the data. The band gap in the samples is located at approximately 1.6 eV. The In and Se content of the samples was determined from atomic absorption measurements. Absorption peaks at 0.890 and 0.896 eV have been observed which are correlated, respectively, to the selenium and indium deficiencies in the samples.

Smith, Cecily J.↗

Thermal effects on the mechanical properties of SiC fibre reinforced reaction-bonded silicon nitride matrix composites

The elevated temperature four-point flexural strength and the room temperature tensile and flexural strength properties after thermal shock were measured for ceramic composites consisting of 30 vol pct uniaxially aligned 142 micron diameter SiC fibers in a reaction bonded Si3N4 matrix. The elevated temperature strengths were measured after 15 min of exposure in air at temperatures to 1400 C. Thermal shock treatment was accomplished by heating the composite in air for 15 min at temperatures to 1200 C and then quenching in water at 25 C. The results indicate no significant loss in strength properties either at temperature or after thermal shock when compared with the strength data for composites in the as-fabricated condition.

Bhatt, R. T.↗

The effect of matrix mechanical properties on (0)8 unidirectional SiC/Ti composite fatigue resistance

The relationship between constituent and MMC properties in fatigue loading is investigated with low-cycle fatigue-resistance testing of an alloy Ti-15-3 matrix reinforced with SiC SCS-6 fibers. The fabrication of the composite is described, and specimens are generated that are weak and ductile (WD), strong and moderately ductile (SM), or strong and brittle (SB). Strain is measured during MMC fatigue tests at a constant load amplitude with a load-controlled waveform and during matrix-alloy fatigue tests at a constant strain amplitude using a strain-controlled waveform. The fatigue resistance of the (0)8 SiC/Ti-15-3 composite is found to be slightly influenced by matrix mechanical properties, and the composite- and matrix-alloy fatigue lives are not correlated. This finding is suggested to relate to the different crack-initiation and -growth processes in MMCs and matrix alloys.

Gabb, T. P.↗

Oxidation effects on the mechanical properties of a SiC-fiber-reinforced reaction-bonded Si3N4 matrix composite

The room-temperature mechanical properties of SiC fiber reinforced reaction bonded silicon nitride composites were measured after 100 hrs exposure at temperatures to 1400 C in nitrogen and oxygen environments. The composites consisted of approx. 30 vol percent uniaxially aligned 142 micron diameter SiC fibers in a reaction bonded Si3N4 matrix. The results indicate that composites heat treated in a nitrogen environment at temperatures to 1400 C showed deformation and fracture behavior equivalent to that of the as-fabricated composites. Also, the composites heat treated in an oxidizing environment beyond 400 C yielded significantly lower tensile strength values. Specifically in the temperature range from 600 to 1000 C, composites retained approx. 40 percent of their as-fabricated strength, and those heat treated in the temperatures from 1200 to 1400 C retained 70 percent. Nonetheless, for all oxygen heat treatment conditions, composite specimens displayed strain capability beyond the matrix fracture stress; a typical behavior of a tough composite.

Bhatt, Ramakrishna T.↗

Environmental effects on the compressive properties - Thermosetting vs. thermoplastic composites

The influence of moisture and temperature on the compressive properties of graphite/epoxy and APC-2 materials systems was investigated to assess the viability of using APC-2 instead of graphite/epoxy. Data obtained indicate that the moisture absorption rate of T-300/epoxy is higher than that of APC-2. Thick plate with smaller surface area absorbs less moisture than thin plate with larger surface area. The compressive strength and modulus of APC-2 are higher than those of T-300/epoxy composite, and APC-2 sustains higher compressive strength in the presence of moisture. The compressive strength and modulus decrease with the increase of temperature in the range of 23-100 C. The compression failure was in the form of delamination, interlaminar shear, and end brooming.

Haque, A.↗

Heat Treatment Effects on the Tensile Properties and Microstructures of a SiC/RBSN Composite in Nitrogen

The room-temperature tensile properties and constituent microstructures of a unidirectionally reinforced SiC/reaction bonded silicon nitride (RBSN) composite have been investigated after heat treatments at 1400, 1600, or 1800 C in nitrogen for up to 100 hr. The composite consisted of approximately 24 vol% of aligned 140 micron diameter, continuous length, chemically vapor deposited SiC fibers in an approximately 40% porous silicon nitride matrix. The composites heat treated at 1400 C for up to 100 hr showed elastic modulus, first matrix cracking strength, and ultimate tensile strength values similar to those of the as-fabricated composites, but those heat treated for 1 hr beyond this temperature displayed losses in all three properties. Recrystallization of the SiC fibers, reaction between the carbon-rich interface coating on the fibers and the RBSN matrix, and dissociation of the RBSN matrix are the reasons for the loss of mechanical properties.

Bhatt, R. T.↗

Fiber Effects on Minicomposite Mechanical Properties for Several Silicon Carbide Fiber: Chemically Vapor-Infiltrated Silicon Carbide Matrix Systems

Several different types of SiC fiber tows were coated with BN and composited using chemically vapor-infiltrated SiC to form single-tow minicomposites. The types of SiC fiber included Nicalon(sup TM), Hi-Nicalon(sup TM), and the new Sylramic(sup TM) polycrystalline SiC fiber. The interfacial shear stresses were determined from unload-reload tensile hysteresis-loop tests. The ultimate stress and strain properties also were determined for the minicomposites. The ultimate strengths of the newer Hi-Nicalon and Sylramic fibers were superior to that of Nicalon minicomposites with similar fiber volume fractions. The Sylramic minicomposites had the lowest strain to failure and highest interfacial shear strength, respectively, because of the high modulus of the fiber and the rough surface of this fiber type. The apparent interfacial shear strength increased as the stress increased for the Sylramic minicomposites, which also was attributed to the surface roughness of this fiber.

Morscher, Gregory N.↗