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At least 523 records · Page 29

Hybrid Unilamellar Vesicles of Phospholipids and Block Copolymers with Crystalline Domains

Phospholipid (PL) membranes are ubiquitous in nature and their phase behavior has been extensively studied. Lipids assemble in a variety of structures and external stimuli can activate a quick switch between them. Amphiphilic block copolymers (BCPs) can self-organize in analogous structures but are mechanically more robust and transformations are considerably slower. The combination of PL dynamical behavior with BCP chemical richness could lead to new materials for applications in bioinspired separation membranes and drug delivery. It is timely to underpin the phase behavior of these hybrid systems and a few recent studies have revealed that PL–BCP membranes display synergistic structural, phase-separation, and dynamical properties not seen in pure components. One example is phase-separation in the membrane plane, which seems to be strongly affected by the ability of the PL to form lamellar phases with ordered alkyl chains. In this paper we focus on a rather less explored design handle which is the crystalline properties of the BCP component. Using a combination of confocal laser scanning microscopy and X-ray scattering we show that hybrid membranes of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) and methoxy-poly(ethylene glycol)-b-poly(ε-caprolactone) (mPEG-b-PCL) display BCP-rich and PL-rich domains when the BCP comprises crystalline moieties. The packing of the hydrophilic part of the BCP (PEG) favors mixing of DPPC at the molecular level or into nanoscale domains while semi-crystalline and hydrophobic PCL moieties bolster microscopic domain formation in the hybrid membrane plane

phase-separation↗

Brought to Light. I. Quantification of Disk Substructure in Dwarf Early-type Galaxies

Dwarf early-type galaxies (ETGs) display a rich diversity in their photometric, structural, and dynamical properties. In this work, we address their structural complexity by studying with deep imaging a sample of nine dwarf ETGs from the Virgo galaxy cluster, characterized by having faint disk features such as bars and spiral arms, that lie mostly hidden within the bright diffuse light of the galaxies. We present a new, robust method that aims to identify and extract the disk substructure embedded in these dwarf ETGs. The method consists in an iterative procedure that gradually separates a galaxy image into two components: the bright, dominant, diffuse component, and the much fainter, underlying disk component. By applying it to the dwarf ETG sample, we quantify their disk substructure and find that its relative contribution to the total galaxy light ranges between 2.2% and 6.4% within two effective radii. We test the reliability of the method, and prove that it is accurate in recovering the disk substructure we introduce in mock galaxy images, even at low disk-to-total light fractions of a few percent. As a potential application of the method, we perform a Fourier analysis on the extracted disk substructures and measure the orientation, length, and strength of the bars, as well as the pitch angle and strength of the spiral arms. We also briefly discuss a scenario based on the numerical simulations presented in our companion paper, Brought to Light II: Smith et al., in which we investigate the origins of the substructure in such dwarf systems.

79 ASTRONOMY AND ASTROPHYSICS↗

The Influence of Polar Coronal Holes on the Polar ENA Flux Observed by IBEX

Polar coronal holes (PCHs) fill the high-latitude heliosphere with fast solar wind during the minimum phase of the solar cycle. This leads to a hardening of the energy spectrum of the proton plasma in the inner heliosheath (IHS), observed as energetic neutral atoms (ENAs) by the Interstellar Boundary Explorer (IBEX). In particular, the highest-energy channel of the IBEX-Hi instrument (at 4.3 keV) is a very sensitive indicator of pretermination shock fast wind entering the IHS. Herein, we show that the 4.3 keV ENA flux observed from the ecliptic poles is well correlated with the area of the solar surface covered by PCHs throughout the solar cycle, which demonstrates the existence of a direct connection between coronal structure and the dynamic properties of the IHS.

79 ASTRONOMY AND ASTROPHYSICS↗

Disentangling the Distant Stellar Halo Using K Giants in DESI Year 3 Data

We present a sample of 88,959 K giants from Dark Energy Spectroscopic Instrument Milky Way Survey Year 3 data, which we use to characterize the chemo-dynamical properties of the stellar halo at Galactocentric distances of 12 to ∼100 kpc. Using HDBSCAN, we identify five prominent stellar halo substructures: Aleph, the Sagittarius stream, Gaia-Sausage-Enceladus (GSE), Cetus-Palca, and the Orphan–Chenab stream. We present the properties of each of these structures as they appear in our catalog, and examine how uncertainties on distance affect the characterization of substructure with this approach. We also examine regions associated with previously reported overdensities (such as the Virgo Overdensities and the Sagittarius spur) that we do not recover with HDBSCAN. The size and distance range of our catalog allows us to explore in detail the residual stellar halo, comprising stars that we do not associate with any substructure. We find that samples of ∼2000 outer halo stars with both highly prograde and highly retrograde angular momenta have similar metallicity distribution functions (MDFs), which do not resemble the MDFs of either GSE or Sagittarius. Both the prograde and retrograde residual halo MDFs are bimodal, with a metal-poor peak at [Fe/H] ∼ −2 and a metal-rich peak at [Fe/H] ∼ −1.3 (prograde) or −1.5 (retrograde). The MDF for lower-angular-momentum residual halo K giants does not show clear evidence for a metal-poor peak, and broadly resembles the MDF of GSE, even at much lower binding energies than GSE itself. We discuss possible interpretations of these findings for GSE accretion scenarios.

79 ASTRONOMY AND ASTROPHYSICS↗

Nuclear responses with neural-network quantum states

We introduce a variational Monte Carlo framework that combines neural-network quantum states with the Lorentz integral transform technique to compute the dynamical properties of self-bound quantum many-body systems in continuous Hilbert spaces. While broadly applicable to various quantum systems, including atoms and molecules, in this initial application we focus on the photoabsorption cross section of light nuclei, where benchmarks against numerically exact techniques are available. Our accurate theoretical predictions are complemented by robust uncertainty quantification, enabling meaningful comparisons with experiments. We demonstrate that a simple nuclear Hamiltonian, based on a leading-order pionless effective field theory expansion and known to accurately reproduce the ground-state energies of nuclei with $A\leq 20$ nucleons also provides a reliable description of the photoabsorption cross section.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Optimizing radar scan strategies for tracking isolated deep convection using observing system simulation experiments

Abstract. Optimizing radar observation strategies is one of the most important considerations in pre-field campaign periods. This is especially true for isolated convective clouds that typically evolve faster than the observations captured by operational radar networks. This study investigates uncertainties in radar observations of the evolution of the microphysical and dynamical properties of isolated deep convective clouds developing in clean and polluted environments. It aims to optimize the radar observation strategy for deep convection through the use of high-spatiotemporal cloud-resolving model simulations, which resolve the evolution of individual convective cells every 1 min, coupled with a radar simulator and a cell tracking algorithm. The radar simulation settings are based on the Tracking Aerosol Convection Interactions ExpeRiment (TRACER) and Experiment of Sea Breeze Convection, Aerosols, Precipitation and Environment (ESCAPE) field campaigns held in the Houston, TX, area but are generalizable to other field campaigns focusing on isolated deep convection. Our analysis produces the following four outcomes. First, a 5–7 m s−1 median difference in maximum updrafts of tracked cells is shown between the clean and polluted simulations in the early stages of the cloud lifetimes. This demonstrates the importance of obtaining accurate estimates of vertical velocity from observations if aerosol impacts are to be properly resolved. Second, tracking of individual cells and using vertical cross section scanning every minute capture the evolution of precipitation particle number concentration and size represented by polarimetric observables better than the operational radar observations that update the volume scan every 5 min. This approach also improves multi-Doppler radar updraft retrievals above 5 km above ground level for regions with updraft velocities greater than 10 m s−1. Third, we propose an optimized strategy composed of cell tracking by quick (1–2 min) vertical cross section scans from more than one radar in addition to the operational volume scans. We also propose the use of a single-RHI (range height indicator) updraft retrieval technique for cells close to the radars, for which multi-Doppler radar retrievals are still challenging. Finally, increasing the number of deep convective cells sampled by such observations better represents the median maximum updraft evolution with sample sizes of more than 10 deep cells, which decreases the error associated with sampling the true population to less than 3 m s−1.

54 ENVIRONMENTAL SCIENCES↗

Particle inertial effects on radar Doppler spectra simulation

Abstract. Radar Doppler spectra observations provide a wealth of information about cloud and precipitation microphysics and dynamics. The interpretation of these measurements depends on our ability to simulate these observations accurately using a forward model. The effect of small-scale turbulence on the radar Doppler spectra shape has been traditionally treated by implementing the convolution process on the hydrometeor reflectivity spectrum and environmental turbulence. This approach assumes that all the particles in the radar sampling volume respond the same to turbulent-scale velocity fluctuations and neglects the particle inertial effect. Here, we investigate the inertial effects of liquid-phase particles on the forward modeled radar Doppler spectra. A physics-based simulation (PBS) is developed to demonstrate that big droplets, with large inertia, are unable to follow the rapid change of the velocity field in a turbulent environment. These findings are incorporated into a new radar Doppler spectra simulator. Comparison between the traditional and newly formulated radar Doppler spectra simulators indicates that the conventional simulator leads to an unrealistic broadening of the spectrum, especially in a strong turbulent environment. This study provides clear evidence to illustrate the droplet inertial effect on radar Doppler spectrum and develops a physics-based simulator framework to accurately emulate the Doppler spectrum for a given droplet size distribution (DSD) in a turbulence field. The proposed simulator has various potential applications for the cloud and precipitation studies, and it provides a valuable tool to decode the cloud microphysical and dynamical properties from Doppler radar observation.

54 ENVIRONMENTAL SCIENCES↗

Moments of inertia of the lunar globe, and their bearing on chemical differentiation of its outer layers.

It is pointed out that the observed moments of inertia of the moon, disclosed by its librations, are influenced mainly by the distribution of mass in the outer zone in which the lithostatic pressure is less than 10 kb (i.e., in the outer shell not more than 200 km deep); a conspicuous departure of such moments from those expected in hydrostatic equilibrium disclosed that these layers could never have been fluid. In the same way, the actual shape of the lunar surface cannot represent a solidified surface of a fluid, petrified at any distance from the earth. The shape of the moon and differences of its moments of inertia must reflect the way in which the initial process of cold accretion fell short of producing a globe with strictly spherically-symmetrical stratification of material. Such melting or lava flows as may have occurred at the moon's surface from time to time must have remained localized, and without much effect on the dynamical properties of the moon.

Kopal, Z.↗

Response of convectively controlled burning to nonlinear disturbances.

A process where energy release rate is proportional to the square root of the Reynolds number of a burning particle or surface is used to demonstrate some distinctive dynamic properties of a disturbed convectively controlled burning process. The instantaneous energy release rates caused by assumed periodic flow field disturbances are numerically evaluated and examined. Correlation coefficients which express the energy released in-phase with the pressure disturbance are evaluated and analytical solutions for these coefficients are derived. The response of the process is shown to be highly sensitive to the harmonic distortion of the disturbance. For some disturbances the energy released in-phase with the pressure disturbance is an order of magnitude larger than that for linear (sinusoidal) disturbances. The results show that harmonic distortion increases the coupling between the burning process and the flow field. This amplifying effect of harmonic distortion is suppressed when a disturbance becomes steep-fronted; therefore, steepening can act to limit the equilibrium amplitudes in disturbed systems. Amplification is also suppressed when the velocity disturbance is phase shifted with respect to the pressure disturbance or when the process is exposed to a high steady velocity.

Heidmann, M. F.↗

Analysis of the dynamics of thin primary mirrors for large astronomical telescopes

The NASTRAN structural analysis program was used to investigate the dynamic properties of thin primary mirrors suitable for use in large orbiting astronomical telescopes. An analysis is included of the mode shapes and modal frequencies for several thin, homogeneous, isotropic mirrors. Typical cases include two different mirror diameters, two different diameter-to-thickness ratios, and both a mirror without and a mirror with a central hole that is 22 percent of the mirror diameter. The finite-element structural model is evaluated by comparing the NASTRAN generated results with theoretical values for a simply supported, flat, circular mirror. The same model is then used for evaluating the spherical mirrors. The mode shapes and frequencies of a 0.762-meter-diameter mirror with a 60-to-1 diameter-to-thickness ratio and a three-point rigid kinematic (not overconstrained) mount are calculated and plotted for comparison with results obtained previously from the SAMIS structural analysis program for this same mirror. A static analysis is also shown for comparison with experimentally obtained influence coefficients.

Ostroff, A. J.↗

Determinants of Market Structure and the Airline Industry

The general economic determinants of market structure are outlined with special reference to the airline industry. Included are the following facets: absolute size of firms; distributions of firms by size; concentration; entry barriers; product and service differentiation; diversification; degrees of competition; vertical integration; market boundaries; and economies of scale. Also examined are the static and dynamic properties of market structure in terms of mergers, government policies, and economic growth conditions.

Raduchel, W.↗

Note on the semiannual effect in the thermosphere.

There are two external heat sources known that oscillate with a period of half a year: (1) the solar heat input associated with the semiannual migration of the subsolar point between both hemispheres, which peaks at the equator and which is small in comparison with that in the annual component, and (2) the auroral heat input associated with the semiannual component in the occurrence of magnetic storms. An attempt is made to show that a number of apparent conflicts in the description and interpretation of the semiannual effect can be resolved by considering some of the dynamic properties of the thermosphere.

Volland, H.↗