Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “CO2 emission”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 523 records · Page 29
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

Correction to "Energy Transport in the Thermosphere During the Solar Storms of April 2002"

We present corrected computations of the infrared power and energy radiated by nitric oxide (NO) and carbon dioxide (CO2) during the solar storm event of April 2002. The computations in our previous paper underestimated the radiated power due to improper weighting of the radiated power and energy with respect to area as a function of latitude. We now find that the radiation by NO during the April 2002 storm period accounts for 50% of the estimated energy input to the atmosphere from the solar storm. The prior estimate was 28.5%. Emission computed for CO2 is also correspondingly increased, but the relative roles of CO2 and NO remain unchanged. NO emission enhancement is still, far and away, the dominant infrared response to the solar storms of April 2002.

Mlynczak, Martin G.↗
DOE OSTI2024

Hydroxide Exchange Membrane Carbon Capture (HEMCC) Using Nickel Hydroxide Batteries and Flow-through Membranes

Proposed is an electrochemical nickel hydroxide based hydroxide exchange membrane carbon capture (HEMCC) device for Direct Air Capture (DAC) of CO2. DAC has been identified as one of the key net negative carbon technologies to achieve net zero carbon emissions. Net negative carbon technologies are required to offset continued emissions from dilute CO2 sources such as agriculture and construction. The majority of current DAC technologies at scale (>1 KT∙yr-1) are adsorbent based technologies with significant energy cost. The traditional DAC energy cost is primarily driven by the temperature swing required to regenerate the sorbent and has been shown to be 1.8 MWh·ton-1 at the system level. Electrochemical pH swing devices are a growing research area for carbon capture devices with the goal of lowering the energy cost required for DAC. A pH gradient is built by generating OH- at the cathode and consuming OH- at the anode. An acid-base equilibrium with CO2 allows for the capture of CO2 at the cathode and release at the anode. This extends from other electrochemical CO2 capture devices based on pKa shifts of an electrochemically active organic species allowing for the capture and release of CO2. Electrochemical CO2 capture is considered promising based on potentially low energy costs to capture CO2 in comparison with current temperature swing adsorption technologies. This work explores Ni(OH)2 electrodes to produce the pH gradient for CO2 capture and release. At the cathode NiOOH is reduced to Ni(OH)2 while at the anode Ni(OH)2 is oxidized to NiOOH. The symmetrical electrodes allow for a low voltage requirement; the thermodynamic potential difference of standard electrochemical reactions is zero. Most of the voltage observed is to produce the pH gradient with the remainder driving the polarization of the electrodes. There is a resistance component as well, but this is small in comparison due to the low current densities used in the device, nominally 2 mA·cm-1. Two similar devices are presented, a traditional MEA (membrane electrode assembly) and a flow-through MEA. The traditional MEA separates the two Ni(OH)2 electrodes with an 80μm Piperion® membrane. While the flow-through membrane separates the electrodes with a three piece membrane consisting of two 80μm Piperion® membranes with a porous membrane between them. In the traditional MEA system air is passed over the cathode for capture, while the flow-through MEA the air is passed through the porous membrane isolated from the electrodes. The traditional MEA has been used to establish a baseline performance of the device and has been shown to capture CO2 at an energy cost of 1 MWh·ton-1 at the device level. An understanding has been built around the components of that energy cost including the relationship of flux to current density, effect of a regeneration process, transient battery behavior, and gas losses coinciding with changing the polarization of the batteries. The flow-through MEA looks to address of transient battery behavior and gas losses. It allows for denser, higher capacity electrodes, which can lean on traditional Ni-MH battery technology used in alkaline batteries used today. The higher capacities, limit the transient battery effect on flux in the device. Gas losses are addressed by having a continuous inlet air stream to the device and continuous outlet product.

Buchen, James↗
NASA NTRS2021

Quantifying the Hypervolatile Abundances in Jupiter-family Comet 46P/Wirtanen

We present analysis of IR and optical spectroscopy of Jupiter-family comet (JFC) 46P/Wirtanen obtained in 2019 January, when the comet had sufficient geocentric velocity to enable studies of the hypervolatiles CO and CH4, as well as [OI] emission. These species could not be studied near closest approach in mid-December because there was insufficient Doppler shift to separate the cometary emission from their corresponding telluric absorption lines. We employed the [OI] observations as a proxy for the CO2/H2O ratio, as CO2 cannot be observed directly from the ground, and space-based assets sensitive to CO2 were not able to observe 46P during this apparition. We focused our analysis on H2O, CO, CH4, C2H6, CH3OH, and CO2 (via [OI] emission). We detected strong emissions from H2O, C2H6, and CH3OH. Over the 3 nights, we found evidence for changing mixing ratios, mostly due to a variable H2O production rate. In 46P, C2H6 and CH3OH are enriched compared to cometary averages, with mixing ratios relative to H2O of ∼1% and ∼3%, respectively. Measurements of CH4 and CO have been especially rare in JFCs. We report significant 3σ upper limits on CH4/H2O<0.97% and CO/H2O<0.54%. They place CH4 being near-average or depleted, and CO being strongly depleted in 46P compared with Oort cloud comets. 46P has comparable CO/H2O to the few other measurements in JFCs, but enriched in C2H6 and CH3OH. Our inferred CO2/H2O mixing ratio is∼15%, though accounting for systematic uncertainties from the lack of knowledge of [OI] photochemistry means a value between 10% and 20% is likely. The compositional profile of46P is similar to another small, hyperactive comet: 103P/Hartley 2. The mechanism of CO2-driven water-rich ice grain production proposed for 103P/Hartley 2 may be operating on 46P as well.

Comets↗
DOE OSTI2026

Integrating CO2 Electrolysis with Gas Fermentation to Produce Valuable Fuels and Chemicals

Many industrial activities squander CO2, decreasing process yield. We envision a future where this waste carbon is instead captured, upgraded, and valorized directly at the point of emission. Within the CO2 Reduction and Upgrading Consortium (a collaboration of seven US national laboratories and industrial partners), we are pursuing this goal by developing and de-risking new technologies for low temperature CO2 electrolysis, coupled with biological upgrading of intermediates into more valuable compounds. One such process involves electrocatalytic reduction of CO2 to generate carbon monoxide (CO). As both a carbon and energy source, CO represents an attractive feedstock for microbial upgrading by certain syngas-fermenting species, such as the autotrophic bacterium Clostridium autoethanogenum. Our team has developed new genetic tools and optimized cultivation techniques to enhance C. autoethanogenum as a platform host for the biological conversion of syngas into value-added products. For example, we have created novel CRISPR-based genetic engineering techniques to build new, genome-reduced, platform strains of C. autoethanogenum with improved growth rates. Further, we ve introduced heterologous biochemical pathways into C. autoethanogenum to enable the production of high-value compounds from syngas, such as the isoprenoid precursor mevalonic acid. With the tools of electrochemistry and synthetic biology, there is virtually no limit to the spectrum of products that could be sustainably manufactured from CO2.

09 BIOMASS FUELS↗
NASA NTRS1990

The effects of clouds on CO2 forcing

The cloud radiative forcing (CRF) is the difference between the radiative flux (at the top of the atmosphere) which actually occurs in the presence of clouds, and that which would occur if the clouds were removed but the atmospheric state were otherwise unchanged. The CO2 forcing is defined, in analogy with the cloud forcing, as the difference in fluxes and/or infrared heating rates obtained by instantaneously changing CO2 concentration (doubling it) without changing anything else, i.e., without allowing any feedback. An increased CO2 concentration leads to a reduced net upward longwave flux at the Earth's surface. This induced net upward flux is due to an increased downward emission by the CO2 in the atmosphere above. The negative increment to the net upward flux becomes more intense at higher levels in the troposphere, reaching a peak intensity roughly at the tropopause. It then weakens with height in the stratosphere. This profile implies a warming of the troposphere and cooling of the stratosphere. The CSU GCM was recently used to make some preliminary CO2 forcing calculations, for a single simulated, for July conditions. The longwave radiation routine was called twice, to determine the radiative fluxes and heating rates for both 2 x CO2 and 1 x CO2. As diagnostics, the 2-D distributions of the longwave fluxes at the surface and the top of atmosphere, as well as the 3-D distribution of the longwave cooling in the interior was saved. In addition, the pressure was saved (near the tropopause) where the difference in the longwave flux due to CO2 doubling has its largest magnitude. For convenience, this level is referred to as the CO2 tropopause. The actual difference in the flux at that level was also saved. Finally, all of these fields were duplicated for the hypothetical case of no cloudiness (clear sky), so that the effects of the clouds can be isolated.

Randall, David A.↗
DOE OSTI2024

Recovery of Natural Gas Equipment Emissions into Gas Compression Engines for the Reduction of Potential Greenhouse Gas Emissions

Since the turn of the millennium, the United States (U.S.) oil and natural gas (ONG) industry has nearly doubled its natural gas production rate. As a result, the ONG industry has recently come under increasing scrutiny for its contributions to greenhouse gas (GHG) emissions. Consequently, various solutions to this problem have been proposed and formulated to reduce the impacts of GHG emissions on the environment. West Virginia University (WVU) have found it important to research the impacts of recovering vented gas streams into prime-mover engines. The U.S. Department of Energy (DOE) and National Energy Technology Laboratory (NETL) have granted WVU funding to research and develop a “Methane Mitigator” (M2) - a “Scalable Vent Mitigation Strategy to Simultaneously Reduce Methane Emissions and Fuel Consumption from the Compression Industry.” One of the main areas of interest for this research was the collection of emissions from natural gas equipment into a Caterpillar G3508J natural gas compression engine. The parameters being analyzed from the engine were brake-specific emissions and power output. The emissions sources considered for this research were pneumatic controllers (PCs), reciprocating compressor vents, and the engine’s open crankcase breather. The compressor vent and PC emissions were simulated using a mass flow controller (MFC) and flowed into the engine using two separate methods: (1) directly into the air intake, and (2) through a retrofitted closed crankcase ventilation system (CCV), serving as a buffer volume. The crankcase emissions were quantified without the CCV, and the impact on exhaust emissions from circulating the crankcase gases into the intake was measured. The simulated compressor vent and PC flows from the MFC had limited effect on the steady state operation of the engine and resulting performance. When the simulated flows were fed directly into the engine’s air intake, the changes within the engine’s continuous performance and emission parameters were larger but lasted for shorter durations. Conversely, when the simulated flows were fed into the CCV before entering the air intake, the changes in the engine’s performance and emission parameters were less pronounced for continuous analysis but lasted for longer durations. In either case, the continuous emission changes in both emissions and performance varied in size depending on the test scenario being run, but the cycle average changes in emissions and performance showed little impact overall compared to the engine’s baseline operation. As a result, the inclusion of a CCV shows a decrease in baseline carbon dioxide equivalent (CO2-eq.) engine emissions (from combined exhaust and open crankcase) of almost 4%. Likewise, the CCV inclusion reduced baseline total methane (CH4) from combined exhaust and open crankcase by upwards of 16%. These atmospheric emissions only decreased further with the inclusions of collected PC and compressor vent flows. The resulting changes in time-averaged rated exhaust behavior (or lack thereof) prove that the proposed M2 system could likely be deployed at sites with modern lean-burn natural gas engines as a viable option for reducing and eliminating potential GHG sources that would have otherwise been unutilized as energy sources.

03 NATURAL GAS↗
NASA NTRS1990

The effect of polar clouds and dust on the radiative budget of the Martian polar cap

How ozone, clouds, and airborne dust affect CO2 ice formation and sublimation is examined to determine if they help explain the asymmetry in the residual polar caps. The radiative flux striking the surface is calculated for 57 solar and 10 IR wavelength intervals from 0 to 100 microns including the scatering, absorption, and emission by O3, CO2, clouds, and dust. UV absorption by H2O, O2, HO2, and H2O2 is also included, as is Rayleigh scattering. The discrete ordinate method of Stamnes et al. (1988) treats the emission, scattering, and absorption of monochromatic radiation.

Lindner, Bernhard L.↗
DOE OSTI2023

Idaho National Laboratory’s FY 22 Greenhouse Gas Report

A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2022 by Idaho National Laboratory (INL)—a Department of Energy (DOE) sponsored entity located in southeastern Idaho. In recent years, concern has grown about the environmental impact of GHGs. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of an inventory of the total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 14057 requires that federal agencies and institutions track and report GHG emissions where required. INL’s GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occurring outside INL’s organizational boundaries, but are a consequence of INL’s activities). This inventory found that INL generated 75,572.42 metric tons (MT) of CO2 equivalent (CO2e) emissions during FY 2022. The following conclusions were made from looking at the results of the individual contributors to INL’s FY 2022 GHG inventory: • Electricity (including the associated transmission and distribution losses) is the largest contributor to INL’s GHG inventory, with over 50% of the CO2e emissions. • Other sources with high emissions were mobile combustion (fleet fuels), employee commuting, stationary combustion (facility fuels), and waste disposal (fugitive emissions from the onsite landfill). • Sources with low emissions were waste disposal (contracted disposal), fugitive emissions from refrigerants, wastewater treatment (onsite and contracted), and business ground travel (in personal and rental vehicles). This report details the methods behind quantifying INL’s GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by Battelle Energy Alliance, LLC (BEA) and those managed by other contractors, it includes only INL’s activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Life cycle assessment of a novel gas switching reforming for sustainable hydrogen production with CO2 capture

Gas switching reforming for hydrogen production (GSR-H2) presents an efficient, low-carbon hydrogen production method that incorporates integrated carbon capture, offering efficiency gains over traditional methods such as proton exchange membrane (PEM) electrolysis, steam methane reforming (SMR) and the newer method of chemical looping reforming (CLR). GSR-H2 has been demonstrated in lab scale which operates as an exothermic process that eliminates the need for additional natural gas combustion, using its own waste heat to generate process steam and partially offset energy usage through electricity production. Beyond its thermal self-sufficiency, GSR-H2 advances upon CLR by integrating all reaction stages within a single reactor cluster, eliminating the complexities of solid circulation, reducing capital costs, and enhancing overall process efficiency. This streamlined design simplifies scale-up and enables inherent CO2 separation with minimal energy penalty, making GSR-H2 a highly competitive pathway for low-carbon hydrogen production. This study presents the first life cycle assessment (LCA) of GSR-H2, offering a novel evaluation of this new process’s environmental impacts across diverse energy scenarios. Key findings reveal that in the renewables-powered scenario, GSR-H2 achieves a GWP of 2.77 kg CO2 eq per kg H2, a substantial improvement over SMR’s 10.4 kg CO2 eq and close to the low emissions of CLR (1.84 kg CO2 eq) and PEM electrolysis (1.85 kg CO2 eq). These results demonstrate GSR-H2’s competitive advantage as a lower-emission alternative, combining design simplicity and efficiency gains, especially in renewable-integrated systems. These results establish GSR-H2 as a competitive, scalable option for hydrogen production, particularly in decarbonization efforts.

03 NATURAL GAS↗
NASA NTRS1993

Altitude profile of aerosols on Mars from measurements of its thermal radiation on limb

Measurements of the thermal (range 7 - 13 micrometers) radiation of Mars with the high space resolution (approximately 2 km) were made by the TERMOSKAN experiment of the Phobos mission. Some of the results were published earlier but only the surface radiation was analyzed in detail. However some part of these measurements was made near the limb of the planet. The atmosphere gives an important input here in the planetary thermal radiation. Beyond the limb the atmosphere is the only source. The task of this work is to estimate some characteristics of the atmosphere using brightness profiles of the thermal radiation near the limb. An appropriate model of the temperature profile T(h) is necessary for such an analysis. A set of T(h) models (nominal, maximal and minimal) was defined using various sources including MARSGRAM, Viking-1 lander data, its theoretical considerations and boundary layer models. On the next step the possible input of the atmospheric gaseous emissions (wing of CO2 15 micrometer band) was estimated. It was found that even for the maximal T(h) this input is no more than a few percents of the measured radiation beyond the limb. Consequently the aerosols are responsible for almost all measured emission. The analysis of the observed profile showed that these aerosols have two components: (1) exponential with the scale height about 10 km and (2) some layered structure (two layers with maxima about 23 and 33 km consisted probably of ice).

Moroz, V. I.↗
NASA NTRS2012

Global CO2 Distributions over Land from the Greenhouse Gases Observing Satellite (GOSAT)

January 2009 saw the successful launch of the first space-based mission specifically designed for measuring greenhouse gases, the Japanese Greenhouse gases Observing SATellite (GOSAT). We present global land maps (Level 3 data) of column-averaged CO2 concentrations (X(sub CO2)) derived using observations from the GOSAT ACOS retrieval algorithm, for July through December 2009. The applied geostatistical mapping approach makes it possible to generate maps at high spatial and temporal resolutions that include uncertainty measures and that are derived directly from the Level 2 observations, without invoking an atmospheric transport model or estimates of CO2 uptake and emissions. As such, they are particularly well suited for comparison studies. Results show that the Level 3 maps for July to December 2009 on a lO x 1.250 grid, at six-day resolution capture much of the synoptic scale and regional variability of X(sub CO2), in addition to its overall seasonality. The uncertainty estimates, which reflect local data coverage, X(sub CO2) variability, and retrieval errors, indicate that the Southern latitudes are relatively well-constrained, while the Sahara Desert and the high Northern latitudes are weakly-constrained. A probabilistic comparison to the PCTM/GEOS-5/CASA-GFED model reveals that the most statistically significant discrepancies occur in South America in July and August, and central Asia in September to December. While still preliminary, these results illustrate the usefulness of a high spatiotemporal resolution, data-driven Level 3 data product for direct interpretation and comparison of satellite observations of highly dynamic parameters such as atmospheric CO2.

Hammerling, Dorit M.↗
NASA NTRS1995

Impulse-response functions and anthropogenic CO2

Non-linearities in the carbon cycle make the response to atmospheric CO2 perturbations dependent on emission history. We show that even when linear representations of the carbon cycle are used, the calculation of time scales characterizing the removal of excess CO2 depends on past emissions.

Tubiello, Francesco N.↗
NASA NTRSDate not supplied

Comparison of Recent Solar Minima Using SABER Data and the Thermosphere Climate Index

The solar minimum at the end of Solar Cycle (SC) 23 was surprisingly long and deep, and it is predicted that the SC 24 minimum will be similar. We present results from analysis of the two most recent solar minima in terms of their duration in time and the degree of cooling that occurs, along with comparisons to the minima of five preceding solar cycles. Measurements of infrared emissions from NO and CO2 made by the Sounding of the Atmosphere Using Broadband Emission Radiometry (SABER) instrument on the NASA Thermosphere-Ionosphere-Mesosphere Energetics and Dynamics (TIMED) satellite for nearly 19 years allow us to see the effects of solar minima in the thermosphere. These data,and products derived from them, including the Thermosphere Climate Index (TCI), provide direct, quantitative information on the state of the upper atmosphere and enable comparisons of different SCs. The TCI extends the SABER record of nitric oxide infrared emission at 5.3 ìm using a linear multiple regression fit of solar and geomagnetic indices to the daily cooling power derived from SABER NO. Thus the TCI provides a 73-year measure of solar variability in Earth’s atmosphere and permits determination of the relative contribution of solar irradiance and geomagnetic processes at solar minimum and throughout the solar cycle. Results of these calculations will be presented to compare solar minima for the six solar cycles included in the TCI time series.

thermosphere↗
DOE OSTI2025

Limited effects of tannin supplementation on the dairy cattle fecal microbiome with modulation of metabolites

Tannins are plant secondary metabolites that bind organic carbon (C) and nitrogen (N), potentially altering substrate bioavailability for enteric fermentation in ruminants. This interaction may reduce greenhouse gas (GHG) emissions and influence nitrogen partitioning. Given tannins' resistance to ruminal degradation and persistence through the gastrointestinal tract, this study investigated the effects of a tannin-based feed additive on fecal microbial diversity, fecal chemical composition, and GHG emissions. Twenty-four early- to mid-lactation dairy cows were randomized to receive either a tannin-based feed additive (TRT; containing condensed and hydrolyzable tannins from Schinopsis quebracho-colorado [Schltdl.]) or a control diet (CON) for 64 days. Cows were blocked by parity, dry matter intake, milk yield, body weight, and days in milk. Fecal samples were collected on days 0, 16, 32, and 64 and analyzed using 16S rRNA gene amplicon sequencing. Fecal C, N, and indole-3-lactate were measured, and GHG emissions (N2O, CH4, CO2) were assessed via 14-day laboratory incubation. A total of 1,538 amplicon sequence variants were identified, with Firmicutes as the dominant phylum. Fecal phylogenetic diversity showed a significant treatment × day interaction (p < 0.01), with TRT cows exhibiting reduced microbial diversity from day 16 to 64. Fecal C and N concentrations were significantly lower (p < 0.01) in TRT cows on day 16, while indole-3-lactate levels were higher on day 64 (p = 0.02). GHG emissions did not differ significantly between treatments. The tannin-based feed additive influenced fecal microbial community structure and select chemical parameters but did not significantly affect GHG emissions from feces. These findings suggest that dietary tannins may modulate gut microbial ecology with minimal impact on downstream manure-related emissions.

Klein, Matthew L↗
NASA NTRS1994

Martian atmospheric radiation budget

A computer model is used to study the radiative transfer of the martian winter-polar atmosphere. Solar heating at winter-polar latitudes is provided predominately by dust. For normal, low-dust conditions, CO2 provides almost as much heating as dust. Most heating by CO2 in the winter polar atmosphere is provided by the 2.7 micron band between 10 km and 30 km altitude, and by the 2.0 micron band below 10 km. The weak 1.3 micron band provides some significant heating near the surface. The minor CO2 bands at 1.4, 1.6, 4.8 and 5.2 micron are all optically thin, and produce negligible heating. O3 provides less than 10 percent of the total heating. Atmospheric cooling is predominantly thermal emission by dust, although CO2 15 micron band emission is important above 20 km altitude.

Lindner, Bernhard Lee↗
DOE OSTI2024

Investigation of Scale Deposition and Wellbore Corrosion in Carbonated Brine Injection: A Simulation Study

Carbonated brine injection (CBI), which involves dissolving CO2 in produced water to be injected into deep geologic reservoirs, is a method to manage produced brine, carbon dioxide (CO2) sequestration, and reduce anthropogenic greenhouse gas emissions. This low-risk CO2 storage strategy can leverage the existing saltwater disposal infrastructure and well resources. However, the potential for corrosion and scale deposition are a major challenge for carbonated brine which may result in subsidence, wellbore failure, casing failure, and cement failure. The main objective of this research was to evaluate the wellbore materials compatibility with carbonated brine water during the injection process, for repurposing Class II saltwater disposal wells for CBI.

Belarbi, Zineb↗