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At least 523 records · Page 29

Corrosion Control during Closure Activities at the Savannah River Site - 13514

Liquid radioactive wastes from the Savannah River Site (SRS) separation process are stored in large underground carbon steel tanks. Until the waste is removed from storage, transferred, and processed, the materials and structures of the tanks must maintain a confinement function by providing a barrier to the environment and by maintaining acceptable structural stability during normal service and design basis events (e.g., earthquake conditions). A corrosion control program is in place to ensure that degradation of the steel does not impact the structural and leak integrity functions of these waste tanks. The SRS is currently retrieving waste from older waste tanks and processing the waste through the vitrification for long term stabilization. The retrieval processes prepare the tanks for ultimate closure (i.e., grouting) by removing sludge by mechanical and/or sluicing methods, dissolving salt cake by adding water, and chemical cleaning of the residual sludge with oxalic acid. Each of these retrieval methods will result in waste chemistry that does not meet the requirements of the current corrosion control program. Given the short-term exposure and limited remaining service life for the tanks in which retrievals are being performed, an assessment of the need for corrosion controls in these tanks was performed. The assessment reviewed the corrosion rates in the more aggressive environments and the postulated loads on the structure during the closure activities. The assessment concluded that the current corrosion control program may be suspended for a short period of time while final retrieval of the waste is performed. (authors)

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Monitoring Developments for Safe Repository Operation and staged Closure - The International MoDeRn Project - 12040

The main goal of the collaborative, European Commission 7. Framework MoDeRn project is to take the state-of-the-art of broadly accepted, main monitoring objectives and to develop these to a level of description that is closer to the actual implementation of monitoring during the staged approach of the disposal process. To achieve this goal, 18 partners representing 12 countries and including 8 Waste Management Organizations joined their efforts since 2009, and aim at developing a reference framework for repository monitoring by 2013. Achieving this goal includes analysis of whether the implementation of a realistic monitoring programme is likely to address expert and lay stakeholder expectations (objectives), to provide an understanding of monitoring activities and available technologies that can be implemented in a repository context (feasibility), and to provide recommendations for related, future stakeholder engagement activities (social acceptance). Monitoring programs should describe activities likely to verify - with the aim of confirming and possibly enhancing the prior license basis for safety and pre-closure management options - expected repository system evolutions (i.e. natural environment and engineered system evolutions) during a progressive construction, operation and closure phase that may last on the order of a century. (authors)

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The 'People Plan' Concept for Contract Closure - 12432

The U.S. Department of Energy's (DOE) first-of-a-kind closure project at the Hanford Site in Richland, Washington, still has more than 3 years to run, but its contractor, Washington Closure Hanford (WCH), has already started its plans for going out of business. It will be the first contract that closes in increments and, paramount to its success, will be its ability to provide a disciplined and positive approach to release personnel while at the same time retaining personnel critical to timely and safe completion of the work scope. In May 2011, WCH produced the people plan, a program that maximizes communication and support for employees being released, provides an incentivization strategy to retain personnel to the end of their assignments, and reflects a sensitivity to the long-term goals of the contract and WCH's parent companies. The combination of all of these efforts equal one thing: treating employees with respect by providing specific information in a timely manner; respecting employees by sharing as much information as possible, as soon as possible, with as much detail as possible; and respecting each individual's ability to be in control of their next step in their life or career. The project is only in the second ORW and has 13 more before the end of the contract. That time remaining will continue to bring new challenges and unknowns, but the confidence and trust of the employees is proving to be solid. This is largely as a result of the stability provided by the people plan program. A success that can only truly be measured by the continued positive response it has already received from WCH's employees. (authors)

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Implementing an Alternative Modeling Strategy for Closure of the Rainier Mesa Corrective Action Unit at the Nevada National Security Site - 17481

The strategy to close the Rainier Mesa/Shoshone Mountain (RMSM) Corrective Action Unit (CAU) of the Underground Test Area (UGTA) Project at the Nevada National Security Site (NNSS) is defined under a joint agreement between the State of Nevada, the U.S. Department of Energy (DOE) and the Department of Defense (DoD). That strategy required a corrective action investigation (CAI) to define the evolution of contaminated volumes of groundwater under uncertainty as a means to define a surface-projected contaminant boundary and serve as a basis for longer term monitoring. As the initial phase of the CAI was nearing completion in 2012, concerns were raised as to whether the original Federal Facility Agreement and Consent Order (FFACO) strategy was achievable. This was evident when the complexity of the system and the additional costs required to sufficiently characterize it were judged to be out of balance with the overall perceived risks (low) associated with this particular CAU. As a result, an Alternative Modeling Strategy (AMS) and New FFACO Strategy Decision Process for UGTA RM/SM CAU were approved in November 2013. The AMS removes the requirement for developing ensembles of 3D contaminant transport simulations and replaces it with a simpler one requiring the generation of multiple 1D streamline models. These are meant to encompass a range of alternative, yet plausible release and transport scenarios as a means to bound the overall lateral extent of contaminant transport. The new Decision Process is streamlined and progresses from the revised CAI stage, to an external peer review, and then, upon favorable evaluation, directly to a closure stage. Although the project has suffered some delays from implementation of the new strategy, the new process of achieving closure is expected to save several years in time and several million dollars over the original process while still protecting human health and the environment over the 1,000-year compliance period stipulated in the FFACO. (authors)

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A performance and closure evaluation approach for Pump-and-Treat systems - 15132

Pump-and-Treat (P and T) technology has been widely applied for groundwater remediation across many types of sites and for multiple types of contaminants. Decisions regarding major changes in the remediation approach are an important element of environmental remediation management for a site using P and T. An evaluation approach that includes an assessment of P and T system performance is under development to facilitate remediation decisions for P and T systems. The approach provides information on technical data and analyses that can be used to support remediation decisions. The document is organized to help decision makers distinguish between several categories of decision outcomes. These outcomes include 1) Initiate Remedy Closure, 2) Transition P and T to Monitored Natural Attenuation, 3) Continue P and T, 4) Supplement P and T with Another Treatment Technology, 5) Transition from P and T to Another Treatment Remedy, and 6) Transition P and T to an Alternative Closure or Contamination Management Approach. Key triggers that support selection of the appropriate outcome are provided, along with a description of suitable supporting data needed to formulate the technical basis for a remediation decision. (authors)

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The cementitious barriers partnership experimental programs and software advancing DOE's waste disposal/tank closure efforts - 15436

The U.S. Department of Energy Environmental Management (DOE-EM) Office of Tank Waste Management sponsored Cementitious Barriers Partnership (CBP) is chartered with providing the technical basis for implementing cement-based waste forms and radioactive waste containment structures for long-term disposal. DOE needs in this area include the following to support progress in final treatment and disposal of legacy waste and closure of High-Level Waste (HLW) tanks in the DOE complex: - Long-term performance predictions and - Flow sheet development and flow sheet enhancements - Conceptual designs for new disposal facilities The DOE-EM Cementitious Barriers Partnership is producing software and experimental programs resulting in new methods and data needed for end-users involved with environmental cleanup and waste disposal. Both the modeling tools and the experimental data have already benefited the DOE sites in the areas of performance assessments by increasing confidence backed up with modeling support, leaching methods, and transport properties developed for actual DOE materials. In 2014, the CBP Partnership released the CBP Software Toolbox - 'Version 2.0' which provides concrete degradation models for: 1) sulfate attack, 2) carbonation, 3) chloride initiated rebar corrosion, and includes constituent leaching. These models are applicable and can be used by both DOE and the Nuclear Regulatory Commission (NRC) for service life and long-term performance evaluations and predictions of nuclear and radioactive waste containment structures across the DOE complex (Figure 1) including Future SRS salt-stone and HLW tank performance assessments and special analyses - Hanford site HLW tank closure projects and other projects in which cementitious barriers are required - The Advanced Simulation Capability for Environmental Management (ASCEM) project which requires source terms from cementitious containment structures as input to their flow simulations - Regulatory reviews of DOE performance assessments - Nuclear Regulatory Commission reviews of commercial nuclear power plant (NPP) structures which are part of the overall US Energy Security program to extend the service life of NPPs In addition, the CBP experimental programs have had a significant impact on the DOE complex by providing specific data unique to DOE sodium salt wastes at Hanford and SRS which are not readily available in the literature. Two recent experimental programs on cementitious phase characterization and on technetium (Tc) mobility have provided significant conclusions as summarized below: Recent mineralogy characterization discussed in this paper illustrates that sodium salt waste form matrices are somewhat similar to but not the same as those found in blended cement matrices which to date have been used in long-term thermodynamic modeling and contaminant sequestration as a first approximation. Utilizing the CBP generated data in long-term performance predictions provides for a more defensible technical basis in performance evaluations. - In addition, recent experimental studies related to technetium mobility indicate that conventional leaching protocols may not be conservative for direct disposal of Tc- containing waste forms in vadose zone environments. These results have the potential to influence the current Hanford supplemental waste treatment flow sheet and disposal conceptual design. (authors)

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The Success of the River Corridor Closure Project - A Look at the Last 10 Years - 16105

Washington Closure Hanford (WCH) was selected by the U.S. Department of Energy, Richland Operations Office (DOE-RL) to manage the River Corridor Closure Project (RCCP), a 10-year contract in which WCH will clean up 572 km{sup 2} (220 mi{sup 2}) of contaminated land at the Hanford Site in Richland, Washington. Since 2005, WCH has safely and efficiently performed field remediation and building demolition activities along the Columbia River corridor. To date, 99% of the buildings have been demolished and field remediation is 88% complete. These numbers represent work on 323 buildings and 571 waste sites, respectively. From a safety perspective, WCH has experienced an outstanding safety record with a total of 230 first aid cases, 47 recordable only cases, 2 restricted work day cases, and 7 lost work day cases. WCH exceeded 6 million hours worked without a lost time injury on September 30, 2015, for the second time in the contract period. The project has worked a total of 23,217,840 hours. WCH has experienced extensive successes over the last 10 years. These successes include, but are not limited to, explosive demolition, technological applications, and creative land restoration techniques. Efficiencies in work planning, execution, and subcontracting will also be shared. The photographs showing how the landscape has changed are impressive, as is some of the video captured during explosive demolition of a reactor stack in the 100-N Area of the Hanford Site. (authors)

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Performance Assessment for Closure of the Calcined Solids Storage Facility at the INL Site - 19289

The Calcined Solids Storage Facility is composed of six discrete stainless steel 'bin sets' at the Idaho Nuclear Technology and Engineering Center at the INL Site. Approximately 4,440 m{sup 3} of the dry, granular calcine waste is stored in the facility. Closure of the facility will entail removal of the calcine waste followed by grouting. A 5-cm thick residual amount of calcine was assumed to remain at the bottom of the bins. Important radionuclides in the residual layer for the groundwater pathway were identified as the fission and activation products Tc-99, Se-79, I-129, Cs-135, H-3, and actinides Pu-239, and Pu-240. The stainless-steel bins prevent near-term release of grouted residual calcine waste to the environment. Future releases were conservatively based on the corrosion rate of the weld seams on the stainless-steel bins, which site-specific studies measured mean tunnel corrosion rates of 0.0132 mm/yr with a coefficient of variation of 0.333. Based on tunnel corrosion rates, mean bin hydrologic containment times were estimated to be between 238 years and 1,191 years, depending on the thickness of the bin. Any breach in the weld seam was assumed to result in water flow and radionuclide leaching through the bin. The structural integrity of the bin was assumed to be controlled by the general stainless-steel corrosion rate, which was much slower (3.5 x 10{sup -5} mm/yr), resulting in structural integrity times between 24,000 years to over 100,000 years. A mixing-cell model was used to compute water flow and transport through the hydrologically failed bins and the vadose zone. Credit was taken for the geochemical properties of the grout used to fill the bins at closure, which significantly slows the releases from the bins for key radionuclides like Tc-99. A semi-analytical model for three-dimensional dissolved-phase transport in an aquifer of constant unidirectional flow, infinite length and width, and finite thickness was used to compute concentrations in the aquifer across the model domain for a time varying source. Cumulative impacts from all bin sets were calculated by summation across the bin set sources that were superimposed on a uniform Cartesian grid. Effective doses were calculated for direct groundwater ingestion from wells located 100-m downgradient from each of the bin sets and ingestion of meat, milk, and vegetables irrigated with water derived from the well. Intruder doses were based on a well drilled through the grouted waste and cuttings spread around a home site after a 500-year institutional control period. Peak doses during the 1,000-year compliance period were less than 5% of the 250 μSv/yr (25 mrem/yr) performance objective and intruder doses were generally less 5% of the of the 5000 μSv/yr (500 mrem) and 1000 μSv/yr (100 mrem) performance objective for acute and chronic intruder exposure, respectively. Groundwater concentrations were all less than the maximum contaminant limits. In all cases, doses were highest for the oldest bin set because, compared to the other bin sets, it had the highest radionuclide concentrations in the calcine waste. The performance assessment results indicate that performance objectives can be met leaving considerably more than 5-cm of residual calcine waste in the bin sets. (authors)

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Path to Subsurface Closure: When Real and Predicted Data Don't Match, Central Nevada Test Area (CNTA) - 19560

The Central Nevada Test Area, Nevada, was the site of an underground nuclear test in 1968, which resulted in residual contamination at and near the detonation depth of 975 meters (3200 feet). The environmental corrective action strategy for the site was conducted in accordance with the Federal Facility Agreement and Consent Order and all applicable Nevada Division of Environmental Protection (NDEP) policies and regulations. The corrective action strategy initiated in 1999 included developing a conceptual site model, preparing a numerical flow and transport model, calculating contaminant boundaries, negotiating compliance boundaries with NDEP, performing model validation, and monitoring groundwater. This strategy was executed through the Corrective Action Decision Document/Corrective Action Plan phase, when it was determined that the flow and transport model could not be validated because it failed to adequately predict groundwater elevations in the monitoring/validation (MV) wells (MV-1, MV-2, and MV-3) drilled subsequent to the modeling effort. This led to a change in the corrective action strategy that is now designed to validate the compliance boundary through monitoring and institutional controls, rather than relying predominantly on a numerical flow and transport model. This new approach included enhancements to the monitoring well network and additional monitoring to confirm that data were sufficient to proceed to closure. The corrective action activities were completed in 2015, and the Closure Report, which established the long-term postclosure monitoring program, was approved in 2016. The postclosure monitoring program is designed to (1) assess the effectiveness of the compliance boundary by monitoring for the radionuclides of interest and (2) evaluate the effectiveness of monitoring locations within the groundwater flow system by monitoring water elevations to ensure that monitoring wells are located along the potential migration pathways. (authors)

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The Incorporation of Pump-and-Treat Data in the New Tracking Restoration and Closure (TRAC)Web-Based Mapping Tool - 20339

Groundwater pump-and-treat (P and T) systems are a common remediation strategy for sites with contaminated groundwater within the U.S. Department of Energy (DOE) Office of Environmental Management (EM). Currently, there are six DOE-EM sites with active P and T systems, but integrated information on individual systems is only primarily available in separate annual reports. To provide a broad view of both current and historical P and T operations, data has been collected on all of the P and T systems. This summary information not only includes capital and average annual costs, but also identifies contaminants treated and forecasted P and T closure dates. Principal contaminants of concern treated with P and T systems include trichloroethylene, chromium (VI), strontium-90, technetium-99, and uranium. DOE-EM is continuing to create a web-based mapping tool that compiles information on groundwater contaminants, remediation strategies and, current data related to plumes and cleanup progress within all DOE-EM sites. The information collected on P and T systems will be added to the TRAC (Tracking Restoration and Closure) tool using interactive maps to quickly access and share information. This information sharing supports the transition from active to passive remediation methods and long-term monitoring approaches. TRAC can ensure that managers, stakeholders, regulators, and contractors remain up to date on cleanup progress for all sites within the complex. The information on P and T systems expands the use of TRAC and can assist in project monitoring and budget planning and support potential shifts in management plans based on plume data. (authors)

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Analysis of the likelihood of post-closure criticality in a geological disposal facility - 14349

Radioactive Waste Management (RWM) is responsible for implementing geological disposal of the UK's higher activity radioactive wastes. These wastes include significant quantities of fissile nuclides and, therefore, demonstration of the criticality safety of the wastes under disposal conditions forms an important component of RWM's disposal system safety case. At the time of disposal, controls will ensure that all waste packages are sub-critical, and the containment provided by the engineered barrier system of a geological disposal facility (GDF) will ensure that criticality is prevented for some time after disposal. However, as waste packages begin to degrade, fissile and other materials may be mobilised, which could affect the potential for criticality. Therefore, the possibility for the evolution of conditions in a GDF to result in criticality requires assessment. RWM established the 'Likelihood of Criticality' research project to develop qualitative and quantitative arguments to demonstrate that criticality after closure of a GDF is unlikely. The project included consideration of the criticality safety of disposal concepts for intermediate and high level waste, spent fuel, separated plutonium and highly-enriched uranium in different generic geological settings. The results are underpinned by the construction of post-closure criticality scenarios that have been evaluated using high-level judgments about scenario credibility as well as modelling of evolving conditions in a GDF. In the latter case, a probabilistic modelling approach has been undertaken to address uncertainty in the calculation of concentrations and masses of fissile material that could occur at potential accumulation sites. The potential for criticality has been judged based on comparisons of the calculated fissile masses with minimum values required for criticality at different locations in the barrier system. This paper explains the novel approach taken to evaluating the likelihood of criticality in a GDF based on the probabilistic modelling of waste package evolution and plutonium and uranium migration. The role of this research in RWM's work to demonstrate the criticality safety of a GDF in the UK is presented in a companion paper, which also draws on the results of a parallel research project that demonstrates that, even if a criticality were to occur, then its consequences would be insignificant to GDF performance. (authors)

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Closure Devices for Iatrogenic Thoraco-Cervical Vascular Injuries

IntroductionThe unintentional arterial placement of a central venous line can have catastrophic complications. The purpose of this systematic review is to assess and analyse the available evidence regarding the use of the various vascular closure devices (VCDs) for the management of iatrogenic thoraco-cervical arterial injuries (ITCAI).MethodsA systematic review was performed according to PRISMA guidelines.ResultsThirty-two relevant case series and case reports were identified with a total of 69 patients having being studied. In the majority of the studies, plug-based VCDs were used (81%) followed by suture-based devices (19%). The majority of studies reported successful outcomes from the use of VCDs in terms of achieving immediate haemostasis without any acute complications. Long-term follow-up data were only available in nine studies with only one case of carotid pseudoaneurysm being reported after 1-month post-procedure. All other cases had no reported long-term complications. Five studies performed direct or indirect comparisons between VCDs and other treatments (open surgery or stent grafting) suggesting no significant differences in safety or effectiveness.ConclusionAlthough there is limited evidence, VCDs appear to be safe and effective for the management of ITCAIs. Further research is warranted regarding the effectiveness of this approach in comparison to surgery and in order to identify those patients who are more likely to benefit from this minimally invasive approach.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Successful Retrieval of an Embolized Vascular Closure Device (Angio-Seal{sup ®}) After Peripheral Angioplasty

A 55-year-old male with peripheral arterial disease underwent angioplasty of the right lower limb arteries via antegrade femoral access. Angio-Seal{sup ®} closure device was used to treat the puncture site, whereby the intravascular sealing anchor accidentally embolized into the malleolar region of the right posterior tibial artery. Successful retrieval of the anchor was accomplished by a SpiderFX embolic protection device. This technique may be a useful approach to retrieve embolized foreign bodies via endovascular access.

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An Enhanced Virtual Crack Closure Technique for Stress Intensity Factor Calculation along Arbitrary Crack Fronts and the Application in Hydraulic Fracturing Simulation

The virtual crack closure technique (VCCT) is widely used for calculating energy release rates along crack fronts and modeling the propagation of cracks in solid materials. Although the VCCT formulation for smooth crack fronts has been sufficiently addressed in the literature, the application of VCCT to a nonsmoothed crack front with sharp corners warrants further investigation. In this study, we describe an enhanced VCCT to calculate energy release rates and stress intensity factors for cracks with arbitrary shapes in 3D domains discretized on structured grids. The formulations of the enhanced VCCT were developed and implemented into a multiphysics simulation environment capable of simulating crack propagation in the framework of linear elastic fracture mechanics. Comparisons with existing analytical/numerical solutions and other VCCT approaches were performed to verify the enhanced VCCT in terms of SIF calculation along nonsmoothed crack fronts. We then applied the enhanced VCCT to a hydraulically driven penny-shaped fracture problem to further demonstrate its capability to simulate nonsmoothed fracture propagation.

02 PETROLEUM↗

τ-SIMPLE Algorithm for the closure problem in homogenization of stokes flows

Estimation of the permeability tensor is crucial for many natural and industrial porous media applications. Homogenization provides a rigorous framework to calculate effective parameters from pore-scale images of a representative unit cell of the porous medium by solving a boundary value problem, also known as closure problem, subject to global constraints. However, the latter are hard to satisfy for arbitrarily complex geometries. We have developed a novel computational algorithm to calculate rigorously the permeability tensor. The approach, here referred to as τ-SIMPLE, is based on introducing an artificial time scale τ to satisfy the global constraint within the SIMPLE iteration. Here, we show that the proposed algorithm has high accuracy for both two-dimensional and three-dimensional periodically arranged geometries.

54 ENVIRONMENTAL SCIENCES↗

3D Cell-centered hydrodynamics with subscale closure model and multi-material remap

We extend a higher-order finite volume cell-centered hydrodynamic (CCH) formulation to include an interface-aware subscale closure model and a multi-material remap for simulating 3D compressible hydrodynamic problems within an arbitrary Lagrangian-Eulerian (ALE) framework. This CCH formulation involves a multidirectional approximate Riemann solution using quadratic polynomial reconstructions of the stress tensor and the velocity. At the subscale level, we determine pair-wise material interactions by solving a distinct approximate Riemann problem at the common interface, using the volume of fluids (VOF) method to find the interface. Material interactions are constrained to ensure smooth pressure equilibration among materials. The accuracy and robustness of the ALE method is demonstrated by simulating a suite of 3D Cartesian multi-material problems covering both gas and solid dynamics, where each test case has two or more materials.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Autonomous Multistate Nanoencoding Using Combinatorial Ferroelectric Closure Domains in BiFeO 3

Recent advances in ferroic materials have identified topological defects as promising candidates for enabling additional functionalities in future electronic systems. The generation of stable and customizable polar topologies is needed to achieve multistates that enable beyond-binary device architectures. Here, in this study, we show how to autonomously pattern on-demand highly tunable striped closure domains in pristine rhombohedral-phase BiFeO 3 thin films through precise scanning of a biased atomic force microscopy tip along carefully designed paths. By employing this strategy, we generate and manipulate closed-loop structures with high spatial resolution in an automated manner, allowing the creation of highly tunable and intricate topological domain structures that exhibit distinct polarization configurations without the need for electrode deposition or complex heterostructure growth. As a proof-of-concept for ferroelectric beyond-binary memory devices, we use such topological domains as multistates, engineering an alphabet and automating the symbolic writing/reading process using autonomous microscopy. The resulting information density is compared with that of current commercially available memory devices, demonstrating the potential of ferroelectric topological domains for multistate information storage applications.

BiFeO3↗

Closure measures for coarse-graining of the tent map

We quantify the relationship between the dynamics of a time-discrete dynamical system, the tent map T and its iterations T{sup m}, and the induced dynamics at a symbolical level in information theoretical terms. The symbol dynamics, given by a binary string s of length m, is obtained by choosing a partition point α∈[0,1] and lumping together the points x∈[0,1] s.t. T{sup i}(x) concurs with the i − 1th digit of s—i.e., we apply a so called threshold crossing technique. Interpreting the original dynamics and the symbolic one as different levels, this allows us to quantitatively evaluate and compare various closure measures that have been proposed for identifying emergent macro-levels of a dynamical system. In particular, we can see how these measures depend on the choice of the partition point α. As main benefit of this new information theoretical approach, we get all Markov partitions with full support of the time-discrete dynamical system induced by the tent map. Furthermore, we could derive an example of a Markovian symbol dynamics whose underlying partition is not Markovian at all, and even a whole hierarchy of Markovian symbol dynamics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗