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At least 523 records · Page 29

Final Report on NASA Portable Laser Coating Removal Systems Field Demonstrations and Testing

Processes currently used throughout the National Aeronautics and Space Administration (NASA) to remove corrosion and coatings from structures, ground service equipment, small parts and flight components result in waste streams consisting of toxic chemicals, spent media blast materials, and waste water. When chemicals are used in these processes they are typically high in volatile organic compounds (VOC) and are considered hazardous air pollutants (HAP). When blast media is used, the volume of hazardous waste generated is increased significantly. Many of the coatings historically used within NASA contain toxic metals such as hexavalent chromium, and lead. These materials are highly regulated and restrictions on worker exposure continue to increase. Most recently the Occupational Safety and Health Administration (OSHA) reduced the permissible exposure limit (PEL) for hexavalent chromium (CrVI) from 52 to 5 micrograms per cubic meter of air as an 8-hour time-weighted average. Hexavalent chromium is found in numerous pretreatment and primer coatings used within the Space Shuttle Program. In response to the need to continue to protect assets within the agency and the growing concern over these new regulations, NASA is researching different ways to continue the required maintenance of both facility and flight equipment in a safe, efficient, and environmentally preferable manner. The use of laser energy to prepare surfaces for a variety of processes, such as corrosion and coating removal, weld preparation, and non destructive evaluation (NDE) is a relatively new application of the technology that has been proven to be environmentally preferable and in many cases less labor intensive than currently used removal methods. The novel process eliminates VOCs and blast media and captures the removed coatings with an integrated vacuum system. This means that the only waste generated are the coatings that are removed, resulting in an overall cleaner process. The development of a Portable Laser Coating Removal System (PLCRS) started as the goal of a Joint Group on Pollution Prevention (JG-PP) project, led by the Air Force, where several types of lasers in several configurations were thoroughly evaluated. Following this project, NASA decided to evaluate the best performers on processes and coatings specific to the agency. Laser systems used during this project were all of a similar design, between 40 and 500 Watts, most of which had integrated vacuum systems in order to collect materials removed from substrate surfaces during operation.

Rothgeb, Matthew J↗

Power-Law Template for IR Point Source Clustering

We perform a combined fit to angular power spectra of unresolved infrared (IR) point sources from the Planck satellite (at 217,353,545 and 857 GHz, over angular scales 100 < I < 2200), the Balloonborne Large-Aperture Submillimeter Telescope (BLAST; 250, 350 and 500 microns; 1000 < I < 9000), and from correlating BLAST and Atacama Cosmology Telescope (ACT; 148 and 218 GHz) maps. We find that the clustered power over the range of angular scales and frequencies considered is well fit by a simple power law of the form C_l\propto I(sup -n) with n = 1.25 +/- 0.06. While the IR sources are understood to lie at a range of redshifts, with a variety of dust properties, we find that the frequency dependence of the clustering power can be described by the square of a modified blackbody, nu(sup beta) B(nu,T_eff), with a single emissivity index beta = 2.20 +/- 0.07 and effective temperature T_eff= 9.7 K. Our predictions for the clustering amplitude are consistent with existing ACT and South Pole Telescope results at around 150 and 220 GHz, as is our prediction for the effective dust spectral index, which we find to be alpha_150-220 = 3.68 +/- 0.07 between 150 and 220 GHz. Our constraints on the clustering shape and frequency dependence can be used to model the IR clustering as a contaminant in Cosmic Microwave Background anisotropy measurements. The combined Planck and BLAST data also rule out a linear bias clustering model.

Addison, Graeme E.↗

Swamp Works- Multiple Projects

My Surface Systems internship over the summer 2013 session covered a broad range of projects that ranged multiple aspects and fields of engineering and technology. This internship included a project to create a command center for a 120 ton regolith bin, a design and build for a blast shield to add further protection for the Surface Systems engineers, a design for a portable four monitor hyper wall that can extend as large as needed, research and programming a nano drill for a next generation robot, and social media tasks including the making of videos, posting to social networking websites and implementation of a new weekly outreach program to help spread the word about the Swamp Works laboratory. The objectives for the command center were to create a central computer controlled area for the still in production lunar regolith bin. It needed to be easy to use and the operating systems had to be Linux. The objectives for the hyper wall were to build a mobile transport of monitors that could potentially attach to one another. It needed to be light but sturdy, and have the ability to last. The objectives for the blast shield included a robust design that could withstand a small equipment malfunction, while also being convenient for use. The objectives for the nano-drill included the research and implementation of programming for vertical and horizontal movement. The hyper wall and blasts shield project were designed by me in the Pro/Engineer/Creo2 software. Each project required a meeting with the Swamp Works engineers and was declared successful.

Carelli, Jonathan M.↗

Power-Law Template for Infrared Point-Source Clustering

We perform a combined fit to angular power spectra of unresolved infrared (IR) point sources from the Planck satellite (at 217, 353, 545, and 857 GHz, over angular scales 100 approx < l approx < 2200), the Balloon-borne Large-Aperture Submillimeter Telescope (BLAST; 250, 350, and 500 micron; 1000 approx < l approx < 9000), and from correlating BLAST and Atacama Cosmology Telescope (ACT; 148 and 218 GHz) maps. We find that the clustered power over the range of angular scales and frequencies considered is well fitted by a simple power law of the form C(sup clust)(sub l) varies as l (sub −n) with n = 1.25 +/- 0.06. While the IR sources are understood to lie at a range of redshifts, with a variety of dust properties, we find that the frequency dependence of the clustering power can be described by the square of a modified blackbody, ν(sup Beta)B(ν, T(sub eff) ), with a single emissivity index Beta = 2.20 +/- 0.07 and effective temperature T(sub eff) = 9.7 K. Our predictions for the clustering amplitude are consistent with existing ACT and South Pole Telescope results at around 150 and 220 GHz, as is our prediction for the effective dust spectral index, which we find to be alpha(sub 150-220) = 3.68 +/- 0.07 between 150 and 220 GHz. Our constraints on the clustering shape and frequency dependence can be used to model the IR clustering as a contaminant in cosmic microwave background anisotropy measurements. The combined Planck and BLAST data also rule out a linear bias clustering model.

cosmic background radiation↗

An Experimental Study of Unconfined Hydrogen/Oxygen and Hydrogen/Air Explosions

Development tests are being conducted to characterize unconfined Hydrogen/air and Hydrogen/Oxygen blast characteristics. Most of the existing experiments for these types of explosions address contained explosions, like shock tubes. Therefore, the Hydrogen Unconfined Combustion Test Apparatus (HUCTA) has been developed as a gaseous combustion test device for determining the relationship between overpressure, impulse, and flame speed at various mixture ratios for unconfined reactions of hydrogen/oxygen and hydrogen/air. The system consists of a central platform plumbed to inject and mix component gasses into an attached translucent bag or balloon while monitoring hydrogen concentration. All tests are ignited with a spark with plans to introduce higher energy ignition sources in the future. Surrounding the platform are 9 blast pressure "Pencil" probes. Two high-speed cameras are used to observe flame speed within the combustion zone. The entire system is raised approx. 6 feet off the ground to remove any ground reflection from the measurements. As of this writing greater than 175 tests have been performed and include Design of Experiments test sets. Many of these early tests have used bags or balloons between approx. 340L and approx. 1850L to quantify the effect of gaseous mixture ratio on the properties of interest. All data acquisition is synchronized between the high-speed cameras, the probes, and the ignition system to observe flame and shock propagation. Successful attempts have been made to couple the pressure profile with the progress of the flame front within the combustion zone by placing a probe within the bag. Overpressure and impulse data obtained from these tests are used to anchor engineering analysis tools, CFD models and in the development of blast and fragment acceleration models.

Richardson, Erin↗

Numerical Simulation of Bolide Entry with Ground Footprint Prediction

As they decelerate through the atmosphere, meteors deposit mass, momentum and energy into the surrounding air at tremendous rates. Trauma from the entry of such bolides produces strong blast waves that can propagate hundreds of kilometers and cause substantial terrestrial damage even when no ground impact occurs. We present a new simulation technique for airburst blast prediction using a fully-conservative, Cartesian mesh, finite-volume solver and investigate the ability of this method to model far- field propagation over hundreds of kilometers. The work develops mathematical models for the deposition of mass, momentum and energy into the atmosphere and presents verification and validation through canonical problems and the comparison of surface overpressures, and blast arrival times with actual results in the literature for known bolides. The discussion also examines the effects of various approximations to the physics of bolide entry that can substantially decrease the computational expense of these simulations. We present parametric studies to quantify the influence of entry-angle, burst-height and other parameters on the ground footprint of the airburst, and these values are related to predictions from analytic and handbook-methods.

Simulation↗

Tsunami Generation from Asteroid Airburst and Ocean Impact and Van Dorn Effect

Airburst - In the simulations explored energy from the airburst couples very weakly with the water making tsunami dangerous over a shorter distance than the blast for asteroid sizes up to the maximum expected size that will still airburst (approx.250MT). Future areas of investigation: - Low entry angle airbursts create more cylindrical blasts and might couple more efficiently - Bursts very close to the ground will increase coupling - Inclusion of thermosphere (>80km altitude) may show some plume collapse effects over a large area although with much less pressure center dot Ocean Impact - Asteroid creates large cavity in ocean. Cavity backfills creating central jet. Oscillation between the cavity and jet sends out tsunami wave packet. - For deep ocean impact waves are deep water waves (Phase speed = 2x Group speed) - If the tsunami propagation and inundation calculations are correct for the small (<250MT) asteroids in these simulations where they impact deep ocean basins, the resulting tsunami is not a significant hazard unless particularly close to vulnerable communities. Future work: - Shallow ocean impact. - Effect of continental shelf and beach profiles - Tsunami vs. blast damage radii for impacts close to populated areas - Larger asteroids below presumed threshold of global effects (Ø200 - 800m).

Tsunami↗

Understanding the Impact of Meteorological Spatiotemporal Variability on Distant Focusing Overpressure Risk

Since the 1950s, the amplification of blast energy from explosions has been understood to be a significant hazard to public safety at launch ranges. Historically, the risk assessment of the Distant Focusing Overpressure (DFO) hazard started with a single temperature and wind profile (e.g., a radiosonde launch) as input to acoustic 1-D ray tracing models. By analyzing rays propagation and performing ray tracing, population centers under high DFO risk can be identified. Although this method is useful, less is known about how the blast waves can be focused when the spatiotemporal variability of the input profiles are considered. In summary, this work aims to consider how realistic atmospheric boundary layer variability (e.g., turbulence, land-surface contrasts) may affect blast waves propagation and focusing and, as a result, DFO risk assessment results.

Blumberg, W. Greg↗

Spreadsheet Assessment Tool v. 2.4

The Spreadsheet Assessment Tool (SAT) is an easy to use, blast assessment tool that is intended to estimate the potential risk due to an explosive attack on a blood irradiator. The estimation of risk is based on the methodology, assumptions, and results of a detailed blast effects assessment study that is summarized in Sandia National Laboratories Technical Report SAND2015-6166. Risk as defined in the report and as used in the SAT is: "The potential risk of creating an air blast-induced vent opening at a buildings envelope surface". Vent openings can be created at a buildings envelope through the failure of an exterior building component—like a wall, window, or door—due to an explosive sabotage of an irradiator within the building. To estimate risk, the tool requires that users obtain and input information pertaining to the building's characteristics and the irradiator location. The tool also suggests several prescriptive mitigation strategies that can be considered to reduce risk. Given the variability in civilian building construction practices, the input parameters used by this tool may not apply to all buildings being assessed. The tool should not be used as a substitute for engineering judgment. The tool is intended for assessment purposes only.

Allen, David J.↗

Expectation vs. Reality: The Unexpected Abrasive Nature of Biomass Feedstocks

Early reports coming from stover-fed biorefineries have indicated that the feedstock is damaging equipment due to wear caused by the feedstock. It is suspected that biomass ash, both physiological and introduced ash, is responsible for the accelerated rates of wear being observed. Biomass ash can contain several different types of minerals, some of which are very hard. To simulate biomass wear on material handling equipment, a sandblaster was modified to shoot ground biomass at a metal coupon. The angle of impingement was set at 90°, 65.5°, or 45° by rotating the coupon. The coupon was weighed before and after shooting a known quantity of biomass to determine mass loss, and the surface characteristics of the blasted coupon were analyzed using laser microscopy. Coupon mass loss was positively correlated with ash content. Coupons blasted with loblolly pine (0.58% ash) lost 2.2mg±0.3mg per kg biomass shot, while high-ash stover (12.56% ash) coupons lost 104.7±2.1mg per kg biomass shot. Coupons blasted with NaOH leached low-ash stover (4.01% ash) lost 10.1±2.7mg per kg biomass shot. Decreasing the angle of impingement (90° to 45°) increased mass loss by about 17%. The concentrations of soil elements (silicon, aluminum, iron, titanium, sodium) were positively correlated with coupon mass loss, indicating that introduced ash is likely the primary source of wear to equipment. Future studies will identify mineral forms of ash present in biomass to further characterize biomass wear properties and to identify strategies to improve biomass quality.

09 BIOMASS FUELS↗

Explosion Source Models

Explosive detonations produce shocked transients with highly nonlinear pressure signatures in the near field. Here, this chapter presents the properties and defining characteristics of a suite of theoretical source pressure functions representative of detonations and deflagrations, and constructs criteria for defining reference blast pulses. Both the primary positive overpressure and the negative underpressure phases contribute to the temporal and spectral features of a blast pulse.

Blast Pulse↗

Interactions of Alumina-Based and Magnesia-Based Refractories with Iron Melts and Slags: A Review

A novel flash ironmaking technology (FIT) based on the direct reduction of iron ore concentrate with a reductant gas (such as hydrogen, natural gas, coal gas, or a combination thereof) in a flash furnace is being developed at the University of Utah. This technology which is undergoing large-scale laboratory testing aims at overcoming the limitations of blast furnace ironmaking by bypassing the problematic pelletization/sintering and cokemaking steps.[1–5] Refractory selection is expected to play an important step in the development of FIT and its proposed scale-up. For nominating an appropriate refractory for the FIT, understanding the interactions of candidate refractories with iron/iron oxide and slags under H{sub 2}/CO/CO{sub 2}/H{sub 2}O environments is necessary. This work is undertaken to review the existing literature on the interactions of important refractories with iron melts and relevant slags with an emphasis on two of the most commonly used refractories in ironmaking and steelmaking applications: the alumina-based refractories (used widely in blast furnace operations) and the magnesia-based refractories (used extensively in primary as well as secondary steelmaking). First, a comprehensive review on the interactions of alumina-based refractories with iron melts and slags has been done. Next the existing literature on the interactions of magnesia-based refractories with iron melts and relevant slags has been reviewed. Summaries have been included after each section and sub-section along with comments and critical insights from the authors. Finally, in the concluding remarks the differences in operating conditions between existing iron and steelmaking practices and the novel FIT have been highlighted. On the basis of these differences, it has been argued that the results and conclusions available from previous studies on refractory–metal–slag interactions are of little significance to flash ironmaking. Thus, there exists a need to carry out laboratory experiments for evaluating refractory performance in flash ironmaking under conditions relevant to the current process (FIT).

36 MATERIALS SCIENCE↗

Thermal Properties of Carbon-Containing Iron Ore Composite Prepared by Vapor Deposition of Tar for Limonite

The optimal conditions for preparing composites, in which tar-derived carbonaceous materials completely fill the pores in Indonesian limonite(IL), were investigated using the vapor deposition (VD) method of tar. Characterization of the composites and their reactivity (reduction/combustion/gasification) during heat treatment was examined. The specific surface area and pore volume of the as-received-IL and dehydrated-IL decreased after the VD treatment for different combinations of tar pyrolysis temperature (TPT) and VD temperature (VDT). It was also noted that the carbon content and crushing strength of the samples increased after the VD treatment, and the optimal values for the TPT-VDT are 700 °C and 350 °C. The C content and the crushing strengths of the composites prepared at TPT-VDT = 700 °C to 350 °C increased with an increase of the VD time to 50 pct carbon content and 10 daN at 240 minutes, respectively. The strength was similar to that of commercial metallurgical coke used in blast furnaces. The reduction of the composite prepared at TPT-VDT = 700 °C to 350 °C for 240 minutes started above 400 °C and was almost completed at 1000 °C. This reduction rate was higher than that of commercial cold-bonded pellets or a coke/IL mixture. The combustion and gasification rates of the composites prepared under different conditions depended on the preparation condition of composites, and the rates were higher than those of commercial metallurgical coke used in blast furnaces.

36 MATERIALS SCIENCE↗

The role of alumina on performance of alkali-activated slag paste exposed to 50 °C

The strength and microstructural evolution of two alkali-activated slags, with distinct alumina content, exposed to 50 °C have been investigated. These two slags are ground-granulated blast furnace slag (containing 13% (wt.) alumina) and phosphorous slag (containing 3% (wt.) alumina). They were hydrated in the presence of a combination of sodium hydroxide and sodium silicate solution at different ratios. The microstructure of the resultant slag pastes was assessed by X-ray diffraction, differential thermogravimetric analysis, and scanning electron microscopy. The results obtained from these techniques reveal the presence of hexagonal hydrates: CAH{sub 10} and C{sub 4}AH{sub 13} in all alkali-activated ground-granulated blast-furnace slag pastes (AAGBS). These hydrates are not observed in pastes formed by alkali-activated ground phosphorous slag (AAGPS). Upon exposure to 50 °C, the aforementioned hydration products of AAGBS pastes convert to C{sub 3}AH{sub 6}, leading to a rapid deterioration in the strength of the paste. In contrast, no strength loss was detected in AAGPS pastes following exposure to 50 °C. -- Highlights: •Strength of alkali-activated slag (AAS) pastes after exposure to 50 °C is studied. •AAS pastes with high alumina content lose strength after the exposure. •C{sub 4}AH{sub 13} and CAH{sub 10} form in these AAS pastes. •Conversion of these calcium alumina hydrates is associated with the strength loss. •AAS pastes with low alumina content maintain its strength after the exposure.

36 MATERIALS SCIENCE↗

Modifying the pore size distribution in Fe-rich inorganic polymer mortars: An effective shrinkage mitigation strategy

Highlights: • Inorganic polymer mortar has mainly macropores and a drying shrinkage of 5.1 mm/m. • 2-methyl-2,4-pentanediol acts as air entrainer in inorganic polymer mortars. • Optimal dosage 2 wt% 2-methyl-2,4-pentanediol reduced drying shrinkage to 1.8 mm/m. • Heat curing inorganic polymer mortars reduced drying shrinkage more than 50%. • Blast Furnace slag addition increased drying shrinkage and reduced strength. Inorganic polymer (IP) binder is formed upon alkali-activation of Fe-rich (41 wt%) metallurgical slag leading to materials with mechanical properties comparable to ordinary Portland cement binders. Crack formation is reported in IPs, which can be related to volumetric stability, which is to date not thoroughly understood in IPs. This study determined the autogenous and drying shrinkage of IP mortars. Shrinkage mitigation strategies, such as the addition of 2-methyl-2,4-pentanediol (2MPL), blast furnace slag (GGBFS), and applying heat curing, were used separately or in combination. IP mortars exhibited autogenous expansion and high drying shrinkage. The addition of 2MPL led to a porosity increase, as air was entrained, decreasing the drying shrinkage with 64%. Additional heat curing had no effect on samples with 2MPL. Introducing GGBFS resulted in smaller pores, increasing drying shrinkage. Shrinkage in IP mortars is driven by its pore size distribution and higher shrinkage resulted in lower flexural strength.

36 MATERIALS SCIENCE↗

Fermi at Trinity

Enrico Fermi estimated the yield of the Trinity test to be about 10 kt by dropping small pieces of paper and observing their motion in the blast wave. This is about 40% of the radiochemically derived value of 25±2 kt that necessarily includes thermal and nuclear radiation that do not contribute to the blast. Although this story is classic, there appears to be no account of how he related his observation to the yield. This paper attempts to reconstruct how he might have done so.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Battery State of Health Estimator: Cooperative Research and Development Final Report

NREL has developed a software tool to enable Renewance to estimate the degradation of batteries from basic information such as the type of battery and the application of that battery during its first life, so that used batteries may be evaluated for potential repurposing at low cost. This software tool utilizes NREL's BLAST-Lite battery degradation modeling code, which was updated with additional models for commercially produced lithium-ion batteries as a part of this CRADA. The software tool enables users to input details such as battery type and application so that lifetime estimates can be made without any programming or expert battery knowledge. The application input loads in saved values for parameters such as cycles per year, depth-of-discharge, and other battery operating parameters from a file defined by Renewance. These parameters may be modified to refine simulations for specific batteries. The software tool also incorporates a degradation model optimization tool, whereby existing battery degradation models may be tuned according to measured battery health. This ensures that new models still predict degradation behaviors expected from a certain battery chemistry, but with the overall degradation rate tuned to a specific battery make and model. The new model can then be saved for estimating the degradation of other similar batteries. An additional task was planned to utilize machine-learning to enable battery health diagnosis from rapid EIS measurements to accelerate the screening of used batteries. This task was not completed due to lack of available data for training a machine-learning model. CRADA benefit to DOE, Participant, and US Taxpayer: Further development of open-source software tool BLAST-Lite for predicting the lifetime of commercially produced Lithium-ion batteries (NREL SWR-22-69).

25 ENERGY STORAGE↗

The Application of Quaternions to Strap-Down MEMS Sensor Data

We describe the mathematical transformations required to convert the data recorded using typical 6-axis microelectromechanical systems (MEMS) sensor packages (3-axis rate gyroscopes and 3-axis accelerometers) when attached to an object undergoing a short duration loading event, such as blast loading, where inertial data alone are sufficient to track the object motion. By using the quaternion description, the complex object rotations and displacements that typically occur are translated into the more convenient earth frame of reference. An illustrative example is presented where a large and heavy object was thrown by the action of a very strong air blast in a complex manner. The data conversion process yielded an accurate animation of the object’s subsequent motion.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗