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At least 523 records · Page 29

2021 Hagan Container Surveillance Plan

Prior to 2021, Hagan containers were examined on an ad hoc basis as part of the SAVY-4000 surveillance plan. Given the size, aging horizon, and unique potential failure mechanisms of the Hagan population, the authors identified the need for Hagan-specific surveillance (Kelly, et al., 2020) and have developed this surveillance plan to meet that need.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Los Alamos National Laboratory SAVY-4000 Field Surveillance Plan (Update for 2021)

The Packaging Surveillance Program section of the Department of Energy (DOE) Manual 441.1- 1, Nuclear Material Packaging Manual (DOE 2008), requires DOE contractors to “ensure that a surveillance program is established and implemented to ensure the nuclear material storage package continues to meet its design criteria.” The Los Alamos National Laboratory (LANL) SAVY-4000 Field Surveillance Plan was first issued in fiscal year (FY) 2013. The surveillance plan is reviewed annually and updated as necessary based on SAVY-4000 surveillance findings, as well as results of the lifetime extension studies. Six surveillance plan updates have been issued, one in 2014, one in 2016, one in 2017, one in 2018 one in 2019 and one in 2020. This 2021 update documents what was actually done in 2020 and what is planned for 2021. Deviations from the 2020 surveillance plan were necessary because some of the planned surveillance containers were not available for examination.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Rules of Use Report Engineering evaluations of nuclear material storage containers against the packaging requirements at TA-55

A set of obligations in the yearly storage container surveillance program, ensures that a retrospective approach is applied with loaded containers in inventory to confirm compliance with all “users” to ensure nuclear material storage container requirements are being followed. Validation that packaged containers are properly used, within a specific set of container types prescribed “bounding conditions of use,” is based on meeting requirements as identified in operating procedures associated with TA55-DOP-091, TA-55 Nuclear Material Packaging, and PA-RD-01022, Nuclear Material Packaging Requirements. The surveillance plan obligation requires the application of local area nuclear material accountability software or (LANMAS) to produce queries. The data queries are used to assess attributes of containers in storage these investigations are conducted on a bi-annual basis. This rules of use (ROU) compliance process ensures proper usage of storage containers as containment systems and therefore provides effective worker protection. It is structured as a supporting effort by implementing aspects of PA-AP-01207, Nuclear Material Container Safety Management at TA-55.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Empirical Estimates of Transmission Value using Locational Marginal Prices [Slides]

This study focuses on one potential benefit of transmission infrastructure—congestion relief. It explores historical grid conditions from 2012 through the first half of 2022, and evaluates the marginal value of transmission in facilitating trade within and across regional boundaries by calculating differences in observed nodal wholesale power prices. The study finds that wholesale power prices exhibit stark geographic differences that, in many cases, are stable over time. Many regional and interregional transmission links have significant potential economic value from reducing congestion and expanding opportunities for trade. In fact, many links have hourly average pricing differences in 2021 that exceeded $\$15$/MWh—equivalent to $130 million per year for a 1000 MW link. The value of transmission is correlated with overall energy prices and varies by region and year. Critically, extreme conditions and high-value periods play an outsized role in the value of transmission, with 50% of transmission’s congestion value coming from only 5% of hours. Transmission planners run the risk of understating the benefits of regional and interregional transmission if extreme conditions and high-value periods are not adequately considered. These periods are natural features of actual market operations. As such, the study highlights the need for planners to more-comprehensively assess the value of transmission under both normal and extreme conditions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Water-Resistant Container Testing CNUT INGB Container Design (Rev. 1)

The purpose of this report is to detail the results of water ingress testing conducted on the 5Qt Castle Nut In-Glovebox (5QtCNUT INGB) container design and discuss these results against the water-resistant container requirements of TA55-AP- 522 and PA-RD-01009. The CNUT is a general-purpose container option for material storage inside of a glovebox and/or as an approved non-hermetically sealed inner of an approved packaging configuration inside of an approved outer container as listed in PA-RD-01022. The CNUT containment boundary consists of a filtered lid and deep drawn body with welded collar all made of 316L stainless steel, an aluminum bronze spin down ring to provide compression of a to Viton® O-ring to create a seal for closure and containment.

36 MATERIALS SCIENCE↗

Lifetime extension drop-test of real-world corroded 5 Quart Hagan nuclear material storage container

A 5Qt Hagan container with a 20-year history of nuclear material storage was challenged with three successive drop tests at a height of 3.7 meters. The total mass of the test package was 12.1 kg. The 1st and 2nd drop tests (center of gravity over the container bottom corner but 180 degrees apart on the container bottom face) passed the pre- and post- impact helium leak criterion at less than 1.00E-6 atm-cc/sec (ambient cubic centimeters per second). The 3rd and final test (center of gravity over top corner) failed with a post-impact gross leak of 1.1E-1 atmcc/sec. The RRFMC (Respirable Release Fraction Measurement Chamber) is a drop tower test system that is critical for the sustainability of the SAVY-4000™ series and Hagan-type (NFT Inc. Golden CO) nuclear material storage containers. These are the primary in-use nuclear material storage container types at the Los Alamos National Laboratory TA-55 facility. Results are presented to expand the technical knowledge basis for container lifetime, regarding actual exposure to corrosive gas species on the container inner surfaces. The primary source of general corrosion throughout the container is gaseous hydrogen chloride (HCl). This gas is generated by the degradation of the polyvinylchloride (PVC) bag-out bag. Additionally, in most cases, the nuclear material itself also releases HCl gas (due to residual chemical components associated with the material formation). The RRFMC drop tower gives the end-user the ability record and analyze high-speed video and photography and if needed aerosol mass release measurements. In this report the principal issue is the physical deformation of the 5Qt Hagan container. There were no mass release experiments of test aerosol mass in the present study.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Corrosion Analysis of 121103072 (SAVY-4000)

A surveillance feedlist for fiscal year (FY) 2022 was developed with the intent to target containers with contents known to generate corrosive gasses. One SAVY-4000 (hereafter “SAVY”) container with a serial number 121103072 was selected due to the reasonable wattage and known molten salt extraction (MSE) material corrosive behavior. The material was measured at 3.08 W with approximately 200 g of material placed inside of the SAVY for 6.07 years. The inner packaging configuration included a ¼ Qt stainless steel slip top inner container and a sPVC bag-out bag enclosing the inner container. Visual observations of the container during retrieval revealed several concerning features on the exterior of the container, notably on the lid. Fig. 1 shows the container lid along with an inset image further magnifying the features of interest. The corroded tamper indicating device (TID) wire and the corroded radioactive material tag wire indicated that corrosive gas species for steel were produced during storage. Although the TID wire and rad tag wire are not the same composition as the SAVY body and lid, these are often used as an indicator of potential corrosion inside of the SAVY container. The oxide residing inside of the filter holes and significant buildup around one hole provided further evidence supporting the presence of corrosive species inside of the container.

36 MATERIALS SCIENCE↗

Overview of SAVY-4000 Lifetime Extension Activities in Fiscal Year 2024

This report provides an overview of activities engaged in during the 2024 fiscal year in support of the SAVY-4000 (hereafter “SAVY”) lifetime extension. As the final full year prior to the submittal of the technical basis, efforts were made to assess the current understanding regarding SAVY degradation in service as well as any knowledge that provided a more substantive view of the challenges that SAVYs face in storage. Close coordination with the stakeholders (i.e. LANL program office) ensured alignment with expectations regarding timelines for the remainder of the activities supporting the technical basis document for the lifetime extension request.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

SAVY O-ring characterization for lifetime extension

Los Alamos National Laboratory and Nuclear Filter Technology, Inc. developed the SAVY-4000 nuclear material storage container, named after the designers Stone, Anderson, Viers, and Yarbro. The SAVY 4000 meets the requirements of Department of Energy (DOE) M 441.1-1,2 Nuclear Material Packaging Manual, to protect workers who handle nuclear materials against radiation exposures resulting from the leakage of stored materials. The SAVY-4000 is an innovative and creative design: it can be opened and closed in a few seconds without using torque wrenches and instead only a tire iron or equivalent prying tool; has a built-in, fire-rated filter that prevents the build-up of hydrogen gas yet retains 99.97% of plutonium particulates at 200 ACCM rated flow; and prevents the release of stored materials upon a 12- foot drop.

42 ENGINEERING↗

Technical Basis Update for the Design Life Extension of the SAVY-4000® Series of Containers

This technical basis update focuses on the design life of the SAVY-4000® (hereafter “SAVY”) series of nuclear material storage container (e.g., used to store, transport, and handle special nuclear material outside of a glovebox), previously approved under DOE Manual 441.1-1, Nuclear Material Packaging Manual. The SAVY is approved for storing all authorized contents for a period of 15 years. The lifetime extension technical basis is established on the compiled technical data from the on-going SAVY and Hagan surveillance programs, destructive analysis results, accelerated aging studies, and performance testing, in line with the regulatory rigor of DOE M441.1-1.

42 ENGINEERING↗

Technical Basis SAVY-4000® Series, 5.5G Container (Rev. 1)

The 5.5 Gallon (5.5G) SAVY-4000® nuclear material storage container is the latest in the SAVY-4000® series. The 5.5G is similar to that of a 1or 2Qt container in functionality with the exception of a larger volume deep drawn and spun form body achieved through increases in the depth and diameter of the container. Here, a technical basis using engineering equivalency analysis, calculation, and test data is presented to establish that the 5.5G SAVY-4000® Container is a DOE Manual 441.1-1 compliant container at a drop height of 9 feet (rather than the typical 12 ft of the other SAVY-4000® containers) and that a twenty-five year design life (as with the currently approved SAVY-4000® series) is justified.

99 GENERAL AND MISCELLANEOUS↗

Development and Implementation of a Bag Degradation Predictive Tool at Los Alamos National Laboratory

Nuclear material packaging involves many complex variables derived from the stored material's properties, the storage environment, and the synergistic interaction of said material and its environment on the containment boundary. In the Plutonium Facility (PF-4) at Los Alamos National Laboratory (LANL) the typical containment boundary found, starting from the stored material itself to the outermost containment layer, consists of the material contained within a stainless steel (typically 304) slip-lid (or other equivalent stainless steel packaging layer) wrapped in an sPVC bag-out bag contained within a facility approved outer container stored within the boundaries of an approved facility (i.e., a building designed and approved to store nuclear material). This packaging configuration, though occasionally deviated from in the past, represents the current procedurally enforced, expected containment structure for all interim nuclear material containment outside of an engineered control barrier (e.g., a glovebox). Over the life of containerization research at LANL, packaging engineers have become increasingly concerned with the degradation of the sPVC bag-out bag, which can cause corrosion to the outermost packaging layer as well as possible exposure to alpha contamination if the bag-out bag layer is degraded to the point of containment failure. A bag-out bag degradation predictive tool (BDT) is therefore needed to assess the current and future nuclear material inventory for possible bag degradation in order to continue to ensure safe operations for the facility and its workers to deliver on the vital national security mission of 30 PPY.

42 ENGINEERING↗

Corral Summit Pumped Storage Hydropower Hybrid Site Suitability Assessment (Rev.1)

In 2024, Idaho National Laboratory (INL) and Pacific Northwest National Laboratory (PNNL) initiated a technical-assistance project to support Cat Creek Energy, LLC, (CCE) in evaluating site suitability for the proposed Corral Summit Pumped Storage Hydropower (PSH) project in south-central Idaho near Mackay Reservoir. The Corral Summit facility incorporates battery storage and photovoltaic (PV) solar arrays in a Trybrid configuration to deliver large-volume long-duration (LVLD) storage solutions for rural electric cooperatives in eastern Idaho. The evaluation process focused on determining the most-suitable location for the upper reservoir of the PSH system, guided by a comprehensive assessment framework spanning multiple categories, including physical characteristics, environmental constraints, building infrastructure, regulatory constraints, cultural resources and sensitivity, social factors, and power market and grid integration. Each site was analyzed based on a ranking scale (0–1), which scores ranging from “severely disfavored” to “highly favored,” allowing detailed comparisons of site-specific conditions. Categories such as hydraulic head, utilities corridor, land ownership, and transmission-grid limitations emerged as key contributors to the overall assessment. Site 2 (Idaho Trust) demonstrated a slight advantage over Site 1 (Bureau of Land Management) primarily due to favorable outcomes in regulatory constraints, building infrastructure, and power-market integration. However, Site 1 outperformed Site 2 in factors related to physical characteristics and social factors. The report emphasizes the need for further evaluation of both sites before clear determination of which site is preferred, due to the limited information available on either site at the time of this report. Key areas of evaluation to clearly define the preferred site are ecological impacts, cultural-resource surveys, and economic-feasibility assessments. For successful project execution, recommended follow-up actions include seismic and geotechnical surveys, groundwater and habitat monitoring, regulatory reviews of water rights and right-of-way agreements, cultural engagement with local tribal governments, and enhanced stakeholder strategies. These efforts will ensure the Corral Summit Trybrid facility meets local energy needs while balancing environmental, social, and regulatory responsibilities.

13 - HYDRO ENERGY↗

The DREAM Endstation at the Linac Coherent Light Source

Free-electron lasers (FEL), with their ultrashort pulses, ultrahigh intensities, and high repetition rates at short wavelength, have provided new approaches to Atomic and Molecular Optical Science. One such approach is following the birth of a photo electron to observe ion dynamics on an ultrafast timescale. Such an approach presents the opportunity to decipher the photon-initiated structural dynamics of an isolated atomic and molecular species. It is a fundamental step towards understanding single- and non-linear multi-photon processes and coherent electron dynamics in atoms and molecules, ultimately leading to coherent control following FEL research breakthroughs in pulse shaping and polarization control. A key aspect for exploring photoinduced quantum phenomena is visualizing the collective motion of electrons and nuclei in a single reaction process, as dynamics in atoms/ions proceed at femtosecond (10 –15 s) timescales while electronic dynamics take place in the attosecond timescale (10 –18 s). Here, we report on the design of a Dynamic Reaction Microscope (DREAM) endstation located at the second interaction point of the Time-Resolved Molecular and Optical (TMO) instrument at the Linac Coherent Light Source (LCLS) capable of following the photon–matter interactions by detecting ions and electrons in coincidence. The DREAM endstation takes advantage of the pulse properties and high repetition rate of LCLS-II to perform gas-phase soft X-ray experiments in a wide spectrum of scientific domains. With its design ability to detect multi-ions and electrons in coincidence while operating in step with the high repetition rate of LCLS-II, the DREAM endstation takes advantage of the inherent momentum conservation of reaction product ions with participating electrons to reconstruct the original X-ray photon–matter interactions. In this report, we outline in detail the design of the DREAM endstation and its functionality, with scientific opportunities enabled by this state-of-the-art instrument.

47 OTHER INSTRUMENTATION↗

Validation of Streaklines as Recorders of Synoptic Flow Direction in a Deltaic Setting

Knowledge of the flow patterns within distributary systems is key for understanding deltaic hydro- and morpho-dynamics, yet synoptic measurements of flow fields remain virtually nonexistent. As a means of overcoming this problem, a small number of studies have used biogenic surface films as synoptic flow tracers, under the assumption that biofilm streaklines are tangent to the local flow direction. Here we rigorously test this assumption and show that, despite flow patterns that change severely in space and time (over a range >270°), streaklines are relatively accurate synoptic flow tracers for the Wax Lake Delta, in Louisiana. When the incoming discharge was greater than 2400 m3/s with stable or falling tides, the streakline-derived flow direction departed from near bed flow direction measurements of 22.8° (root mean square). When the discharge was greater than 2400 m3/s and the tides were rising greater than 0.03 m/hr, they were accurate within 28.0°. Under conditions of discharge less than 2400 m3/s and tidal change less than a positive 0.03 m/hr, they were accurate within 33.3°, while during low discharge and rising tides they were accurate within 58.9°. Accuracy varied with distance from the delta, with proximal sites having greater precision. Our results demonstrate that a streakline-derived flow direction can characterize the spatiotemporal variability in the flow directions, but that the accuracy is significantly influenced by the hydrodynamic conditions and location within the network.

58 GEOSCIENCES↗