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Potential for constraining sequence stratigraphy and cycle stratigraphy with U-Pb dating of carbonates

Studies of sequence stratigraphy and cycle stratigraphy in carbonate formations increasingly improve our understanding of depositional systems and basinal to global correlations. However, there is still a scarcity of dated sequences to determine the time length of sequences and cycles. Furthermore, the durations of sequences and cycles provide tests of the processes that produce them. Poor age resolution mostly stems from the lack of recognizable volcanic ash deposits in many sections. Through continuing advances in analytical techniques and approaches to sampling, the current state of Usingle bondPb dating of carbonate sedimentary rocks provides opportunities to fill in age gaps. The approach should build on well-constrained 3-dimensional stratigraphic architectures and diagenetic stratigraphies.

58 GEOSCIENCES↗

Exploring for Superhot Geothermal Targets in Magmatic Settings: 2022 Field Campaign at Newberry Volcano

This paper presents preliminary results from a subset of work carried out as part of a multinational research project entitled DErisking Exploration for multiple geothermal Plays in magmatic ENvironments (DEEPEN), supported by the U.S. Department of Energy (DOE) and Geothermica, a joint effort by EU member states and associated countries. The DEEPEN project will develop a customized approach to exploration for supercritical and superhot geothermal plays in magmatic systems, which will be applied to two demonstration sites. This paper summarizes field activities carried out at the U.S. demonstration site, Newberry Volcano in central Oregon. The objective of this work effort is to refine the subsurface model of Newberry Volcano, with special focus on deeper zones including the magmatic plumbing system and other key geologic elements. New data collection included gravity and wideband magnetotelluric (MT) surveys, as well as reinstallation of a seismic network. The National Renewable Energy Laboratory (NREL) and Enthalpion Energy LLC (Enthalpion) worked with the Deschutes National Forest Fort Rock District to use a low ground disturbance method of MT deployment to collect MT data inside the caldera and other restricted areas inside the National Volcanic Monument. This opened these areas to geophysical exploration for the first time in decades. Sites along and adjacent to the south rim of the volcano constituted the primary survey objectives. A team from Lawrence Berkeley National Laboratory (LBNL), the U.S. Geological Survey (USGS), and AltaRock also began the process of reinstalling the seismic network from the AltaRock enhanced geothermal system (EGS) demonstration in anticipation of further development activities at the site. The data ingestion, reduction, and analysis phase of the project is ongoing. We are currently processing the MT and gravity data and are developing a new, highly GPU-accelerated, 3D joint MT and gravity inversion to better localize the south rim/south flank conductive target and better understand its relationship to deep heat, fluid sources, and surface extrusive features. Joint inversions, which have not yet been undertaken at Newberry, will allow us to obtain constraints on the geologic model that cannot be determined from each method in isolation, improving our ability to image key geologic features at depth.

geophysics↗

Compositionally and density stratified igneous terrain in Jezero crater, Mars

Before Perseverance, Jezero crater’s floor was variably hypothesized to have a lacustrine, lava, volcanic airfall, or aeolian origin. SuperCam observations in the first 286 Mars days on Mars revealed a volcanic and intrusive terrain with compositional and density stratification. The dominant lithology along the traverse is basaltic, with plagioclase enrichment in stratigraphically higher locations. Stratigraphically lower, layered rocks are richer in normative pyroxene. The lowest observed unit has the highest inferred density and is olivine-rich with coarse (1.5 millimeters) euhedral, relatively unweathered grains, suggesting a cumulate origin. This is the first martian cumulate and shows similarities to martian meteorites, which also express olivine disequilibrium. Alteration materials including carbonates, sulfates, perchlorates, hydrated silicates, and iron oxides are pervasive but low in abundance, suggesting relatively brief lacustrine conditions. Orbital observations link the Jezero floor lithology to the broader Nili-Syrtis region, suggesting that density-driven compositional stratification is a regional characteristic.

79 ASTRONOMY AND ASTROPHYSICS↗

Remote sensing and geologic studies of the orientale basin region

Both visual and near-infrared spectral observations are combined with multispectral imaging to study the Orientale interior and exterior, the Cruger region, Grimaldi Region, the Schiller-Schickard Region, and the Humorum Region of the Moon. It was concluded that anorthosites occur in the Inner Rook Mountains of Orientale, the inner ring of Grimaldi, and the main ring of Humorum. Imaging spectroscopy shows that the entire eastern Inner Rook Mountains are composed of anorthosites. Orientale ejecta are strikingly like the surface materials in the region where Apollo 16 landed. This similarity indicates similar mineralogy, i.e., noritic anorthosite. Thus, Orientile ejecta is more mafic than the Inner Rook Mountains. This situation is also true for the Nectaris, Humorum, and Gramaldi basins. Isolated areas of the Orientale region show the presence of gabbroic rocks, but, in general, Orientale ejecta are noritic anorthosites, which contain much more low-Ca pyroxene than high-Ca pyroxene. Ancient (pre-Orientale) mare volcanism apparently occurred in several areas of the western limb.

Hawke, B. Ray↗

Records of our Early Biosphere Illuminate our Origins and Guide our Search for Life Beyond Earth

A scientific "mission of exploration to early Earth" will help us chart the distribution of life elsewhere. We must discriminate between attributes of biospheres that are universal versus those attributes that represent principally the outcomes of long-term survival specifically on Earth. In addition to the basic physics and chemistry of matter, the geologic evolution of rocky habitable planets and their climates might be similar elsewhere in the Universe. Certain key agents that drive long-term environmental change (e.g., stellar evolution, impacts, geothermal heat flow, tectonics, etc.) can help us to reconstruct ancient climates and to compare their evolution among populations of Earth- like planets. Early Earth was tectonically more active than today and therefore it exhaled reduced chemical species into the more oxidized surface environment at greater rates. This tectonic activity thus sustained oxidation-reduction reactions that provided the basis for the development of biochemical pathways that harvest chemical energy ("bioenergetics"). Most examples of bioenergetics today that extract energy by reacting oxidized and reduced chemicals in the environment were likely more pervasive among our microbial ancestors than are the presently known examples of photosynthesis. The geologic rock record indicates that, as early as 3.5 billion years ago (3.5 Ga), microbial biofilms were widespread within the coastal environments of small continents and tectonically unstable volcanic islands. Non oxygen-producing (non-oxygenic) photosynthesis preceded oxygenic photosynthesis, but all types of photosynthesis contributed substantially to the long-term increase in global primary biological productivity. Evidence of photosynthesis is tentative by 3.5 Ga and compelling by 2.7 Ga. Evidence of oxygenic photosynthesis is strong by 2.7 Ga and compelling by 2.3 Ga. These successive innovations transformed life from local communities that survived principally by catalyzing chemical equilibration to a globally dominant agent that created and sustained widespread chemical disequilibria in the environment and shallow crust. Major biogeochemical perturbations ca. 2.3 to 2.0 Ga, 1.3 Ga, and also 0.8 to 0.6 Ga, contributed to the irreversible oxidation of the global environment and perhaps also triggered evolutionary innovations (e.g., the development of multi-cellular biota) that became the foundations of our modern biosphere. Understanding the nature and timing of this ascent of life is crucial for discerning our o m beginnings. This understanding also empowers OUT search for the origins, evolution and distribution of life elsewhere in our solar system and beyond.

DesMarais, David J.↗

Constraining Our Understanding of the Actions and Effects of Martian Volatiles Through the Study of Returned Samples

Volatiles have clearly played a key role in the evolution of Mars' atmosphere, hydrosphere and geosphere, with effects ranging from the geomorphological evidence for outflow channels and valley networks early in Mars' history to formation of alteration products in rocks to the current seasonal changes in the polar caps. It is clear that the absolute and relative abundances of various volatiles have changed through time via volcanic degassing, atmospheric loss, and interactions with the crust.

Source record↗

The geologic evolution of the moon

A synthesis of pre- and post-Apollo 11 studies is presented to produce an outline of the moon's geologic evolution from three lines of evidence: (1) relative ages of lunar landforms and rock types, (2) absolute ages of returned lunar samples, and (3) petrography, chemistry, and isotopic ratios of lunar rocks and soils. It is assumed that the ray craters, circular mare basins, and most intermediate circular landforms are primarily of impact origin, although many other landforms are volcanic or of hybrid origin. The moon's evolution is divided into four main stages, each including several distinct but overlapping events or processes.

Lowman, P. D., Jr.↗

A preliminary evaluation of ERTS-1 images on the volcanic areas of Southern Italy

The test site selected for the investigation covers nearly all the regions of active and quiescent volcanism in southern Italy, i.e. the eastern part of the island of Sicily, the Aeolian Islands and the area of Naples. The three active European volcanoes (Etna, Stromboli and Vesuvius) are included. The investigation is in the frame of a program for the surveillance of active volcanoes by geophysical (including remote sensing thermal methods) and geochemical methods. By the multispectral analysis of ERTS-1 data it is intended to study the spectral behavior of the volcanic materials as well as the major geological lineaments with special reference to those associated with the volcanic region. Secondary objectives are also the determination of the hydrographic network seasonal behavior and the relationship between the vegetation cover and the different type of soils and rocks.

Cassinis, R.↗

Vector diagram of the chemical compositions of tektites and earth lavas

The chemical compositions of tektites and various volcanic glasses, similar in composition to tektites are compared by a petrochemical method. The advantage of the method is that a large number of chemical analyses of igneous rocks can be graphically compared with the help of vectors, plotted in relation to six parameters. These parameters, calculated from ratios of the main oxides given by silicate analysis, reflect the chief characteristics of igneous rock. Material for the study was suppled by data from chemical analysis characterizing tektites of all known locations and data from chemical analyses of obsidians similar in chemical composition to tektites of various petrographical provinces.

Kvasha, L. G.↗

Composition of island arcs and continental growth.

Island arc volcanism has contributed and is still contributing to continental growth, but the composition of island arcs differs from that of the upper continental crust in its lower abundance of Si, K, Rb, Ba, Sr and light rare earth elements. In their advanced stage of evolution, island arcs contain more than 80% of tholeiitic and 15% of ?island arc' calc-alkaline rocks with varied SiO2 contents. The larger proportion of tholeiitic rocks is in the lower crustal levels. The high stratigraphical levels of the island arcs are composed of tholeiitic plus calc-alkaline and/or high potash (shoshonitic) associations with higher abundances of K, Rb, Sr, and Ba. Stratification of the island arc crust is accentuated by another type of calc-alkaline volcanism (Andean type) originating at a late stage of arc evolution, probably by partial melting at the base of the crust. This causes enrichment of the upper crust in K, Rb, Ba and REE and accounts for upper crustal abundances of these elements as well as of SiO2.

Jakes, P.↗

Spectroscopy of Mount Etna Lava Flows as A Proxy for Age: A Potential Analogue to Recent Volcanism on Venus

There is growing evidence of geologically recent volcanism at Venus [1–3], a question that may be resolved by forthcoming missions to our sister planet that will make spectroscopic measurements of the surface. The thick, relatively opaque atmosphere of Venus makes observation difficult, but a few key atmospheric windows in the near-infrared (NIR) around 1 μm make emission from the surface detectable [4]. At these wavelengths, the spectroscopic signature of rocks are due to its primary mineralogy and chemistry, as well as the presence of secondary weathering minerals [2, 5, 6]. If the degree of alteration can be tied to the spectroscopy of Venus analogue materials, then spectroscopy of venusian lava flows can potentially reveal their degree of weathering and thus their age, which in turn gives an estimate of the extent of recent volcanism [2, 7]. A potential Earth analogue to volcanoes on Venus is Mount Etna in Sicily, Italy [8]. This composite volcano is among the most active in the world and features mafic lava flows with definitive ages that exhibit varying degrees of alteration [9]. While Mount Etna is not a perfect analogue due to its different weathering environment, the natural age progression of altered basaltic rock can be a useful comparison. Here, we will investigate how weathering at Mount Etna affects spectroscopic measurements and if this can be used as a proxy for Venus. While planned missions to Venus such as DAVINCI, VERITAS, and EnVision will measure NIR emissivity from the surface, Kirchhoff’s Law states that e = 1 − r, where e is emissivity and r is reflectance, meaning that NIR emissivity can be estimated from reflectance measurements [10]. Given its relative ease, laboratory reflectance spectroscopy is a useful tool to efficiently test potential Venus analogue materials.

Gabriel L Eggers↗

A Radar Survey of Lunar Dome Fields

The near side of the Moon has several areas with a high concentration of volcanic domes. These low relief structures are considerably different in morphology from terrestrial cinder cones, and some of the domes may be similar to some terrestrial shields formed through Hawaiian or Strombolian eruptions from a central pipe vent or small fissure [1]. The domes are evidence that some volcanic lavas were more viscous than the mare flood basalts that make up most of the lunar volcanic flows. It is still not known what types of volcanism lead to the creation of specific domes, or how much dome formation may have varied across the Moon. Prior work has shown that some domes have unusual radar polarization characteristics that may indicate a surface or subsurface structure that is different from that of other domes. Such differences might result from different styles of late-stage volcanism for some of the domes, or possibly from differences in how the erupted materials were altered over time (e.g. by subsequent volcanism or nearby cratering events). For example, many of the domes in the Marius Hills region have high circular polarization ratios (CPRs) in S-band (12.6 cm wavelength) and/or P-band (70 cm wavelength) radar data [2]. The high CPRs are indicative of rough surfaces, and suggest that these domes may have been built from overlapping blocky flows that in some cases have been covered by meters of regolith [2, 3]. In other cases, domes have low circular polarization ratios indicative of smooth, rock-poor surfaces or possibly pyroclastics. The ~12 km diameter dome Manilius 1 in Mare Vaporum [1], has a CPR value of 0.20, which is significantly below values for the surrounding basalts [4]. To better understand the range of surface properties and styles of volcanism associated with the lunar domes, we are currently surveying lunar dome fields including the Marius Hills, Cauchy/Jansen dome field, the Gruithuisen domes, and domes near Hortensius and Vitruvius.

Carter, Lynn M.↗

On the original igneous source of Martian fines

The composition of the silicate portion of Martian regolith fines indicates derivation of the fines from mafic to ultramafic rocks, probably rich in pyroxene. Rock types similar in chemical and mineralogical composition include terrestrial Archean basalts and certain achondrite meteorites. If these igneous rocks weathered nearly isochemically, the nontronitic clays proposed earlier as an analog to Martian fines could be formed. Flood basalts of pyroxenitic lavas may be widespread and characteristic of early volcanism on Mars, analogous to maria flood basalts on the moon and early Precambrian basaltic komatiites on earth. Compositional differences between lunar, terrestrial, and Martian flood basalts may be related to differences in planetary sizes and mantle compositions of the respective planetary objects.

Baird, A. K.↗

Petrogenesis of the Elephant Moraine A79001 meteorite Multiple magma pulses on the shergottite parent body

The EETA 79001 achondrite consists of two distinct igneous lithologies joined along a planar, non-brecciated contact. Both are basaltic rocks composed primarily of pigeonite, augite, and maskelynite, but one contains zoned megacrysts of olivine, orthopyroxene, and chromite that represent disaggregated xenoliths of harzburzite. Both lithologies probably formed from successive volcanic flows or multiple injections of magma into a small, shallow chamber. Many similarities between the two virtually synchronous magmas suggest that they are related. Possible mechanisms to explain their differences involve varying degrees of assimilation, fractionation from similar parental magmas, or partial melting of a similar source peridotite; of these, assimilation of the observed megacryst assemblage seems most plausible. However, some isotopic contamination may be required in any of these petrogenetic models. The meteorite has suffered extensive shock metamorphism and localized melting during a large impact event that probably excavated and liberated it from its parent body.

Mcsween, H. Y., Jr.↗

Hellas Planitia, Mars - Site of net dust erosion and implications for the nature of basin floor deposits

Hellas Planitia, located within an enclosed basin which includes the lowest topography on Mars, appears to be undergoing net erosion. Dust is removed from the basin. It probably contributes to global dust storms and should leave behind a coarse lag. The particle size distributions and particularly the rock or boulder populations in this lag might be useful for distinguishing between processes which formed the lithologic units that comprise Hellas Planitia. This report concludes that the abundance of rock particles larger than coarse sand is very low. Although this hypothesis awaits confirmation from forthcoming spacecraft data, the origins for Hellas floor deposits favored by this study are indurated volcanic airfall or ancient loess, lacustrine deposits, and some types of volcanic mud flows. The conclusions of this study tend to disfavor such geologic processes as blocky lava flows, glacial deposits (e,g., moraines), or boulder-laden catastrophic flood outwash.

Moore, Jeffrey M.↗

Global Assessment of Volcanic Debris Hazards from Space

Hazard (slope stability) assessment for different sectors of volcano edifices was successfully obtained from volcanoes in North and South America. The assessment entailed Hyperion images to locate portions of the volcano that were hydrothermally altered to clay rich rocks with zones that were also rich in alunite and other minerals. The identified altered rock zones were field checked and sampled. The rock strength of these zones was calculated from the field and laboratory measurements. Volcano modeling utilizing the distinct element method and limit equilibrium technique, with the calculated strength data was used to assess stability and deformation of the edifice. Modeling results give indications of possible failure volumes, velocities and direction. The models show the crucial role hydrothermally weak rock plays in reducing the strength o the volcano edifice and the rapid identification of weak rock through remote sensing techniques. Volcanoes were assessed in the Cascade Range (USA), Mexico, and Chile (ongoing).

Watters, Robert J.↗

Scientific investigations at a lunar base

Scientific investigations to be carried out at a lunar base can have significant impact on the location, extent, and complexity of lunar surface facilities. Among the potential research activities to be carried out are: (1) Lunar Science: Studies of the origin and history of the Moon and early solar system, based on lunar field investigations, operation of networks of seismic and other instruments, and collection and analysis of materials; (2) Space Plasma Physics: Studies of the time variation of the charged particles of the solar wind, solar flares and cosmic rays that impact the Moon as it moves in and out of the magnetotail of the Earth; (3) Astronomy: Utilizing the lunar environment and stability of the surface to emplace arrays of astronomical instruments across the electromagnetic spectrum to improve spectral and spatial resolution by several orders of magnitude beyond the Hubble Space Telescope and other space observatories; (4) Fundamental physics and chemistry: Research that takes advantage of the lunar environment, such as high vacuum, low magnetic field, and thermal properties to carry out new investigations in chemistry and physics. This includes material sciences and applications; (5) Life Sciences: Experiments, such as those that require extreme isolation, highly sterile conditions, or very low natural background of organic materials may be possible; and (6) Lunar environmental science: Because many of the experiments proposed for the lunar surface depend on the special environment of the Moon, it will be necessary to understand the mechanisms that are active and which determine the major aspects of that environment, particularly the maintenance of high-vacuum conditions. From a large range of experiments, investigations and facilities that have been suggested, three specific classes of investigations are described in greater detail to show how site selection and base complexity may be affected: (1) Extended geological investigation of a complex region up to 250 kilometers from the base requires long range mobility, with transportable life support systems and laboratory facilities for the analysis of rocks and soil. Selection of an optimum base site would depend heavily on an evaluation of the degree to which science objectives could be met. These objectives could include lunar cratering, volcanism, resource surveys or other investigations; (2) An astronomical observatory initially instrumented with a VLF radio telescope, but later expanding to include other instruments, requires site preparation capability, "line shack" life support systems, instrument maintenance and storage facilities, and sortie mode transportation. A site perpetually shielded from Earth is optimum for the advanced stages of a lunar observatory; (3) an experimental physics laboratory conducting studies requiring high vacuum facilities and heavily instrumented experiments, is not highly dependent on lunar location, but will require much more flexibility in experiment operation and EVA capability, and more sophisticated instrument maintenance and fabrication facilities.

Extraterrestrial Environment↗

A TEM Investigation of the Fine-Grained Matrix of the Martian Basaltic Breccia NWA 7034

The martian basaltic breccia NWA 7034 is characterized by fine-grained groundmass containing several different types of mineral grains and lithologic clasts. The matrix composition closely resembles Martian crustal rock and soil composition measured by recent rover and orbiter missions. The first results of NWA 7034 suggest that the brecciation of this martian meteorite may have formed due to eruptive volcanic processes; however, impact related brecciation processes have been proposed for paired meteorites NWA 7533 and NWA 7475]. Due to the very fine grain size of matrix, its textural details are difficult to resolve by optical and microprobe observations. In order to examine the potential nature of brecciation, transmission electron microscopy (TEM) studies combined with focused ion-beam technique (FIB) has been undertaken. Here we present the preliminary observations of fine-grained groundmass of NWA 7034 from different matrix areas by describing its textural and mineralogical variations and micro-structural characteristics.

Muttik, N.↗