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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Geologic Characterization for CO 2 Storage with Enhanced Oil Recovery in Northern Michigan

The Midwest Regional Carbon Sequestration Partnership (MRCSP) was founded in 2003 as part of the U.S. Department of Energy’s (DOE’s) Regional Carbon Sequestration Partnership initiative. Since its founding, MRCSP has made significant strides toward making CCUS a viable option for states in the region. The public/private consortium, funded through the DOE Regional Carbon Sequestration Initiative, brings together nearly 40 industry partners and 10 states. Battelle, as the project lead, oversees research, development and operations and coordinates activities among the partners. The incremental, phased approach has built a valuable knowledge base for the industry and paved the way for commercial-scale adoption of CCUS technologies. From 2008 to 2020, MRCSP Phase III focused on the development of large-scale injection projects. This report is part of a series of reports prepared under the Midwestern Regional Carbon Sequestration Partnership (MRCSP) Phase III (Development Phase). These reports summarize and detail the findings of the work conducted under the Phase III project. This report compiles the results of geologic characterization of late-stage reefs, active EOR reefs, and new EOR reefs in the Northern Niagaran Pinnacle Reef Trend (NNPRT) in Michigan to demonstrate developed methodologies, geologic variability, and reservoir potential for CO 2 storage. Conducting CO 2 injection and monitoring in these settings provide significant insights for addressing the project objectives: assessment of injectivity in complex carbonate reef deposits; assessing CO 2 trapping mechanisms in a closed reservoir system; assessing any final oil recovery from transitional or residual oil zones in a field where CO 2 flooding is nearing completion; evaluating the transition from EOR to storage of CO 2 ; assessing regional commercialization; assessing new technologies for tracking CO 2 , brine, and oil movements underground; and monitoring options in a closed reservoir with oil, residual oil, and water zones.

01 COAL, LIGNITE, AND PEAT↗

Estimation of surface heat and moisture fluxes over a prairie grassland. IV - Impact of satellite remote sensing of slow canopy variables on performance of a hybrid biosphere model

Numerical experiments are conducted using the Ex-BATS model of Crosson and Weng (1993), which is an adaptation the Dickinson (1983, 1984) and Dickinson et al. (1986) biosphere model BATS. The purpose of these experiments is the assessment of the Ex-BATS performance when using remotely sensed data for the estimation of three key canopy variables retrieved from NOAA-AVHRR measurements: the total surface albedo, the leaf area index (LAI), and the nondiurnally varying component of stomatal resistance, r(s). The results of the simulations, which cover the entire FIFE 1987 time period, show that the satellite retrievals of r(s) are only 20 to 30 percent less accurate than the idealized results of the control experiment. The performance of the model which used satellite retrieval of the surface albedo and LAI was essentially equivalent to the hypothetical version.

Crosson, William L.↗

Wind tunnel test evaluation of a Shuttle derived launch system

The Shuttle Derived Vehicle (SDV) is a proposed unmanned launch system configured using Shuttle elements. The SDV incorporates two solid rocket boosters, an external tank and three Space Shuttle main engines identical to those used in the present Space Transportation System. Two new elements, a recoverable propulsion/avionics module housing the main engines and an expendable payload module, complete the SDV configuration. This paper describes the activities and results of wind tunnel tests conducted to validate the aerodynamic and controllability characteristics of SDV configurations. The configuration variables consisted of the payload module diameter, length and nose shape. The tests were conducted in the NASA/Marshall Space Flight Center 14 inch trisonic wind tunnel. Aerodynamic force and moment data were obtained over a Mach number range of 0.6 to 4.96. The attack and sideslip angles were varied + or - 8.0 deg. Forces and moments were measured by a sting-supported six component strain gage balance.

Tewell, J. R.↗

In situ synchrotron diffraction of pressure-induced phase transition in DyPO 4 under variable hydrostaticity

In situ synchrotron x-ray diffraction was conducted on polycrystalline DyPO 4 to elucidate the details of the pressure-induced transition from the xenotime polymorph to the monazite polymorph. We used three different pressure-transmitting media (neon, a 16:3:1 methanol-ethanol-water mixture, and potassium chloride) to investigate the effect of hydrostaticity on the phase behavior. Specifically, our data clearly show a hydrostatic onset pressure of the xenotime-monazite transition of 9.1 GPa, considerably lower than the 15.3 GPa previously determined by Raman spectroscopy. Based on (quasi)hydrostatic data taken in a neon environment, third-order Birch-Murnaghan equation-of-state fits give a xenotime bulk modulus of 144 GPa and a monazite bulk modulus of 180 GPa (both with pressure derivatives of 4.0). Structural data and axial compressibilities show that DyPO 4 is sensitive to shear and has an anisotropic response to pressure. More highly deviatoric conditions cause the onset of the transition to shift to pressures at least as low as 7.0 GPa. We attribute early transition to shear-induced distortion of the PO4 tetrahedra. Finally, our characterization of the high-pressure behavior of DyPO 4 under variable hydrostaticity is critical for advancing rare earth orthophosphate fiber coating applications in ceramic matrix composites and may inform future tailoring of phase composition for controlled shear and pressure applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Lunar magnetic field measurements, electrical conductivity calculations and thermal profile inferences

Steady magnetic field measurements of magnitude 30 to 100 gamma on the lunar surface impose problems of interpretation when coupled with the nondetectability of a lunar field at 0.4 lunar radius altitude and the limb induced perturbations of the solar wind at the Explorer orbit. The lunar time-varying magnetic field clearly indicates the presence of eddy currents in the lunar interior and permits calculation of an electrical conductivity profile. The problem is complicated by the day-night asymmetry of the moon's electromagnetic environment, the possible presence of the transverse magnetic mode, and the variable wave directions of the driving function. The electrical conductivity is calculated to be low near the surface, rising to a peak of .006/ohm meter at 250 km, dropping steeply inwards to a value of about .00005/ohm meter, and then rising toward the interior. A transition at 250 km depth from a high conductivity to a low conductivity material is inferred, suggesting an olivine-like core at approximately 800 C, although other models are possible.

Colburn, D. S.↗

A reconstructed discontinuous Galerkin method for compressible flows in Lagrangian formulation

In this work, a high-order accurate reconstructed discontinuous Galerkin (rDG) method is developed for solving two-dimensional hydrodynamic problems in cell-centered updated Lagrangian formulation. This method is the Lagrangian limit of the unsplit rDG-ALE formulation, and is obtained by assuming the equality of the grid velocity to the fluid velocity only at cell boundaries. The conservative variables and the Taylor basis defined on the time-dependent moving mesh, provide the piece-wise polynomial expansion in the updated Lagrangian formulation. A multi-directional nodal Riemann solver is implemented for computing the grid velocity at the vertices and the numerical flux at the cell boundaries. A characteristic limiting procedure is extended from the primitive variable version to the conservative variable version, and its performance is compared with the limiter on physical variables. A number of benchmark test cases are conducted to assess the accuracy, robustness, and non-oscillatory property of the DG(P0), DG(P1) and rDG(P1P2) methods. The numerical experiments demonstrate that the developed rDG method is able to attain the designed order of accuracy and the characteristic limiting procedure outperforms the limiter on physical variables in terms of the monotonicity and symmetry preservation for shock problems.

42 ENGINEERING↗

A Systematic Search for Short-term Variability of EGRET Sources

The 3rd EGRET Catalog contains 170 unidentified high-energy (E>100 MeV) gamma-ray sources, and there is great interest in the nature of these sources. One means of determining sources class is the study of flux variability on time scales of days; pulsars are believed to be stable on these scales while blazars are known to be highly variable. In addition, previous work has led to the discovery of 2CG 135+01 and GRO J1838-04, candidates for a new high-energy gamma-ray source class. These sources display transient behavior but cannot be associated with any known blazars. These considerations have led us to conduct a systematic search for short-term variability in EGRET data, covering all viewing periods through cycle 4. Three unidentified sources show some evidence of variability on short time scales; the source displaying the most convincing variability, 3EG J2006-2321, is not easily identified as a blazar.

Wallace, P. M.↗

Impact of grassland fire dynamics on particulate emission factors

Understanding particulate emission factors in grassland fires is critical for improving air quality assessments and refining emissions inventories. This study explores the dynamic and heterogeneous nature of fire processes and their influence on particulate emissions. Traditional emission factor inventories often rely on static values, overlooking the spatially and temporally variable dynamics of fire behavior. Through field experiments conducted at Konza Prairie Biological Station measuring emissions with uncrewed aerial vehicles, and computational modeling using HIGRAD/FIRETEC, this research highlights the dependency of emission production on localized fire dynamics, including ignition patterns, fuel properties, and atmospheric conditions. The results demonstrate a need for fire dynamic considerations to accurately capture emissions variability.

09 BIOMASS FUELS↗

Aerodynamic performance of a fan stage utilizing Variable Inlet Guide Vanes (VIGVs) for thrust modulation

An experimental research program was conducted in the Lewis Research Center's 9x15-foot (2.74x4.57 m) low speed wind tunnel to evaluate the aerodynamic performance of an inlet and fan system with variable inlet guide vanes (VIGVs) for use on a subsonic V/STOL aircraft. At high VIGV blade angles (lower weight flow and thrust levels), the fan stage was stalled over a major portion of its radius. In spite of the stall, fan blade stresses only exceeded the limits at the most extreme flow conditions. It was found that inlet flow separation does not necessarily lead to poor inlet performance or adverse fan operating conditions. Generally speaking, separated inlet flow did not adversely affect the fan blade stress levels. There were some cases, however, at high VIGV angles and high inlet angles-of-attack where excessive blade stress levels were encountered. An evaluation term made up of the product of the distortion parameter, K alpha, the weight flow and the fan pressure ratio minus one, was found to correlate quite well with the observed blade stress results.

Woollett, R. R.↗

Performance of an isolated two-dimensional variable-geometry wedge nozzle with translating shroud and collapsing wedge at speeds up to Mach 2.01

A wind-tunnel investigation was conducted to determine the aeropropulsion performance (thrust-minus-drag) of a single-engine, variable-geometry, two-dimensional (2-D) wedge nozzle with simulated translating-shroud and collapsing-wedge mechanisms. The investigation was conducted statically and at Mach numbers from 0.60 to 2.01 at an angle of attack of 0 deg and at varied jet total-pressure ratios up to 21, depending on the Mach number. The results indicate that the isolated aeropropulsion performance of a variable-geometry two-dimensional wedge nozzle is competitive with axisymmetric nozzles at transonic and supersonic speeds, but the isolated performance is slightly inferior for static take-off and low subsonic speeds. With the use of a simple tertiary-air ejector, the static take-off performance was increased.

Maiden, D. L.↗

Variable pitch fan system for NASA/Navy research and technology aircraft

Preliminary design of a shaft driven, variable-pitch lift fan and lift-cruise fan was conducted for a V/STOL Research and Technology Aircraft. The lift fan and lift-cruise fan employed a common rotor of 157.5 cm diameter, 1.18 pressure ratio variable-pitch fan designed to operate at a rotor-tip speed of 284 mps. Fan performance maps were prepared and detailed aerodynamic characteristics were established. Cost/weight/risk trade studies were conducted for the blade and fan case. Structural sizing was conducted for major components and weights determined for both the lift and lift-cruise fans.

Ryan, W. P.↗

Terahertz Nano-Imaging of Electronic Strip Heterogeneity in a Dirac Semimetal

Emerging topological semimetals offer promise of realizing topological electronics enabled by terahertz (THz) current persistent against impurity scattering. Yet most fundamental issues remain on how to image nanoscale conductivity inhomogeneity. Here in this paper we show noninvasive and contactless conductivity mapping at THz-nm limit of electronic heterogeneity and nanostrip junctions in a Dirac material ZrTe 5 . A clear Dirac Fermion density transition, manifested as the exclusive THz conductivity contrast, is quantitatively analyzed and profiled on both sides of the junction. This also allows the determination of variable junction width of ~25–220 nm, depending on the THz conductivity contrast of adjacent strips. The unique THz-nm contrast is absent in mid-infrared nano-imaging measurements since topological semimetals with small Fermi pockets exhibit a better matching of their plasma frequency and scattering rate to the THz spectral region. The first-principles calculations provide two compelling implications: the conductivity nanocontrast can be induced by a small anisotropic strain, even less than 0.5%, due to an extreme strain sensitivity in ZrTe 5 ; A nanoscale topological phase transition is realized across some junctions induced by the strain, between strong topological insulators (TIs) and weak TIs/Dirac semimetals (DSMs).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mechanical Characteristics of Additively Manufactured ODS 316L and 316H Alloys with and Without Post-build Processing

This research aims to explore an accelerated development path for oxide dispersion-strengthened (ODS) alloys by integrating additive manufacturing (AM) technologies with recent advances in ODS materials and traditional manufacturing methods. Novel AM and post-build processing routes have been developed for ODS austenitic alloys, specifically Fe-Cr-Ni alloys like 316L and 316H. Electron microscopy and mechanical characterizations were conducted to evaluate the effects of process variables on microstructure and properties, aiming for an economically feasible route property optimization. Traditionally, ODS alloy production involves multi-day high-energy mechanical milling of alloy powder with yttria (Y 2 O 3 ) followed by powder consolidation via extrusion or other methods and additional thermomechanical processing (TMP) for property control. Here, to address these challenges associated with this complex and costly approach, we propose exploring alternative, cost-effective processing routes focusing on AM and traditional TMP methods. The new ODS alloy processing routes have achieved up to a 400% increase in yield strength and a 60% increase in ultimate tensile strength compared to wrought stainless steels while still maintaining significant ductility and fracture toughness. This paper details the novel and economical AM-based processing routes for ODS austenitic alloys, combined with post-build TMPs, and discusses the mechanical and microstructural characteristics of the developed materials.

Byun, Thak Sang [Oak Ridge National Laboratory (OR↗

Effect of thickness on metal-to-semiconductor transition in 2-dimensional TiN thin films

Titanium nitride thin films have been grown on c-plane sapphire substrates using a pulsed laser deposition technique in the thickness range of 6–45 nm. X-ray diffraction (XRD) analysis has demonstrated TiN (111) as the preferred orientation of growth on the sapphire substrates. The XRD measurements have also indicated that orientational alignment between the TiN and the sapphire improved with an increase in the TiN film thickness. A change in the resistivity behavior of the TiN thin films from metallic to semiconducting has been observed as the TiN film thickness is reduced below 15 nm. Analyzing and fitting of TiN films’ conductivity data have shown that while the Arrhenius law governs their conductivity in the temperature range of 300–350 K, conductivity values of the films follow the variable range hopping mechanism below 300 K.

36 MATERIALS SCIENCE↗

Development of a pulsed, variable-energy positron beam for atomic scale defect studies

Positron annihilation spectroscopy provides a sensitive means of non-destructive characterization of materials, capable of probing single atom vacancies in solids with 10 –7 sensitivity. Here, in this work, we detail the development of a magnetically guided, variable energy, pulsed positron beam designed to conduct depth-dependent defect studies in metals, semiconductors, and dielectrics, which will be the first of its kind in the United States. The design of the target stage provides capabilities for measurements during in situ annealing up to 800 °C and incorporates a new approach to minimize the background due to energetic backscattered positrons. The developed beam at Bowling Green State University provides a powerful tool for characterization of thin films, devices, and ion irradiated materials.

47 OTHER INSTRUMENTATION↗

A comprehensive framework to assess elemental mercury in the Department of Energy: A time series analysis

Objective: This study investigated whether seasonal categories affect airborne mercury concentrations in the U.S. Department of Energy operations. Methods: We conducted an initial assessment of the general variability of airborne elemental mercury time-weighted average (TWA) samples. Then, we performed a two-component time series analysis to determine whether long-term, cyclical temperature change patterns affect mercury concentrations. Results: Both ARIMA time series models demonstrated stationary, non-random means (χ² = 83.8, p < 0.001) and standard deviation (χ² = 55.8, p < 0.001) of mercury concentrations. Here, our results indicate that the seasonal factors did not influence mercury concentration. Conclusions: Our results demonstrate that mercury concentrations primarily emanate from operational activities, work practices, and/or transient environmental conditions rather than seasonal fluctuations.

Cannady, Ryan T. [Oak Ridge National Laboratory (O↗

CCM vs. CRM Design Optimization of a Boost-derived Parallel Active Power Decoupler for Microinverter Applications

Single-phase inverter or rectifier systems often make use of an auxiliary active power decoupler (APD) to balance the mismatch between steady DC power and fluctuating AC power. This paper deals with efficiency and size optimization of a parallel boost-type APD circuit for PV microinverter applications. Specifically, design of an eGaNFET-based, 400 W APD circuit, employing planar inductor and operating in either continuous conduction mode (CCM) or critical conduction mode (CRM) is considered. Available design variables including inductance value, inductor core geometry, capacitor voltage, switching frequency, and modulation scheme (CCM vs. CRM) are explored to identify Pareto-optimal configurations, which can achieve low California Energy Commission (CEC) efficiency drop while also reducing the footprint area of the inductor. The theoretical study predicts that the optimal CRM design can achieve 37% reduced inductor size, while operating with similar efficiency drop, compared to the optimal CCM design. Experimental results, obtained using two separate 40 V, 400 W hardware prototypes for CCM and CRM, are presented to verify the analyses.

14 SOLAR ENERGY↗

Mechanical Performance of Additively Manufactured ODS 316L and 316H Stainless Steels

This work package within the Advanced Materials and Manufacturing Technologies (AMMT) program focused on the mechanical and microstructural characterization of oxide dispersion strengthened (ODS) stainless steels produced using advanced manufacturing techniques. The research aimed to identify an accelerated development path for ODS alloys by integrating additive manufacturing (AM) technologies with recent advancements in ODS materials and traditional manufacturing methods. For FY 24, the research specifically targeted exploring an accelerated development path for ODS alloys by combining AM technologies with these advancements. Novel AM and post-build processing routes were developed for ODS austenitic alloys, including Fe-Cr-Ni alloys such as 316L and 316H. Electron microscopy and mechanical characterizations were conducted to evaluate the impact of process variables on microstructure and properties, with the goal of optimizing these properties economically. Traditionally, producing ODS alloys involves multi-day, high-energy mechanical milling of alloy powder with yttria powder, followed by milled-powder consolidation through extrusion or other methods, and additional thermomechanical processing (TMP) for property control. To overcome the challenges associated with this complex and costly approach, we propose exploring alternative, cost-effective processing routes that emphasize AM and traditional TMP methods. The new processing routes for ODS alloys have achieved significantly higher strengths—several times greater than those of wrought stainless steels—while maintaining substantial ductility and fracture toughness. This report outlines the novel and economical AM-based processing routes for ODS austenitic alloys, combined with post-build TMPs, and discusses the mechanical and microstructural characteristics of the developed materials.

36 MATERIALS SCIENCE↗