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All sources NASA NTRS DOE OSTI

DOE OSTI2023

Hierarchical Cellulose Superinsulation Membrane

The environment-friendly components coupled with the ability to mimic the simplicity and originality of nature necessitate advanced sustainable materials with structural capabilities for energy-efficient applications. The use of feedstock deriving from plant-based, renewable organic material to produce nanofibril that embodies enhanced insulating properties and high mechanical strength constitutes an efficient development strategy. In this work, a free-standing, hierarchical superinsulation membrane by leveraging the principle of the bottom-up method is reported. The electrospun cellulose nanofibrils/aerogel-based core layer provides exceptional thermal properties with its thermal conductivity of 10.2 mW m –1 K –1 . The lightweight, flexible, and durable paper-like membrane features a tensile strength of 11.3 MPa and a bending rigidity in the order of 4.6 cN mm –1 . The hydrophobic superinsulation membrane material also exhibits a ΔT of ≈25 °C under continuous sunlight illumination and allows thermal runaway mitigation of rechargeable lithium-ion batteries. All the aforementioned properties position this hybrid superinsulation membrane as a promising material for energy-saving thermal management applications.

36 MATERIALS SCIENCE↗

NASA NTRS1982

Thermally Insulated Glove With Good Tactility

Thermally insulated glove contains short, closely-spaced elastomeric pins that insulate without impairing flexibility. By confining pins to the inter-joint areas of palm, fingers and back of the hand, joint mobility is retained. Glove thermal-insulation requirements dictate the relationships among pin length, pin diameter, and number of pins per unit surface length.

Balinskas, R.↗

DOE OSTI2024

Research Highlight - Dispatch Optimization, System Design and Cost Benefit Analysis of a Nuclear Reactor with Molten Salt Thermal Storage

We highlight our work from our previous publication titled "Dispatch Optimization, System Design, and Cost Benefit Analysis of a Nuclear Reactor with Molten Salt Thermal Storage" published in MDPI Energies 2022 (doi.org/10.3390/en15103599). Variable renewable energy availability has increased the volatility in energy prices in most markets. Nuclear power plants, with a large ratio of capital to variable costs, have historically operated as base load energy suppliers but the need for more flexible operation is increasing. We simulate the techno-economic performance of a 950 MWt nuclear power plant, based on the Westinghouse lead-cooled fast reactor, coupled with molten salt thermal storage as a method for flexible energy dispatch. We use the System Advisor Model to model the nuclear reactor thermal power input and power cycle operating modes. We combine this robust engineering model with a mixed-integer linear program model for optimized dispatch scheduling. We then simulate the coupled nuclear and thermal storage system under different market scenarios with varying price volatility. We find that the coupled plant outperforms the base plant under markets where energy price peaks fluctuate by a factor of two or more about the mean price. We show that a calculated power purchase agreement price for the plant improves by up to 10% when operating under California energy market conditions. Sensitivity analysis on the thermal storage cost shows that the optimal design remains unchanged even when doubling costs.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2021

Dynamic Human-in-the-Loop Simulated Nuclear Power Plant Thermal Dispatch System Demonstration and Evaluation Study

An Idaho National Laboratory research team performed a human-in-the-loop study with two formerly licensed retired operators to evaluate thermal power dispatch operations supported by the modified GSE Systems GPWR plant simulator. Virtual representations of the analog control panels were presented on touch-screen bays configured to mimic the control room layout in the newly renovated Human Systems Simulation Laboratory. The operators performed 15 scenarios covering normal evolutions to transition the plant from full turbine operation to joint turbine and thermal power dispatch operations in addition to transient response scenarios induced with simulated faults to evaluate the impact of thermal power dispatch system on operator and plant responses. A prototype human-system interface (HSI) was developed and displayed in tandem with the virtual analog panels to support the operators executing the procedurally drive evolutions and transient responses. An interdisciplinary team of operations experts, nuclear engineers, and human factors experts observed the operators performing the scenarios to evaluate the operations. Only a preliminary analysis of the results has been performed. The full analysis will be shared in a milestone report scheduled for release at the end of September; however, some high-level conclusions were readily available. Two high level findings for the system design were captured in the study. The manual control supported by the HSI to transition from standard operations to thermal power dispatch operation imposed a considerable amount of workload on the operators due to tedious manual valve manipulations and system monitoring required to verify their intended effect. An additional operator would be required in the control room to support the daily evolution. Automatic control for the transition was deemed a requirement for plant adoption without imposing additional staffing costs. The second finding was the necessity for an automatic thermal power dispatch system trip isolation function linked to a turbine and reactor trip signal. The operators completed scenarios with automatic isolation functionality and manually required actuation of the thermal power dispatch system. The operator response was sufficiently slower in the manual trip condition, such that operators were unable to manually actuate key post trip safety functions an indicate a degraded control capability that should be avoided. With an automatic trip signal little to no impact of the thermal power dispatch system was identified on the primary plant response and therefore the system could be readily and safely adopted. Together these two findings represent the need to support the adoption of thermal power dispatch capability into existing operations by leveraging automation to augment any additional operator tasking required to control and monitor an additional system beyond existing operations.

99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2025

Extraction of high-purity medium-chain-length polyhydroxyalkanoates via combined mechanical treatment and mild oxidation

Polyhydroxyalkanoates (PHAs) are a class of polyester polymers of microbial origin and considered biodegradable alternatives to conventional plastics. To make PHAs cost-competitive with synthetic plastics, their production cost, including extraction cost, should be significantly reduced. Herein, this study aimed to develop an effective extraction method based on combined mechanical disruption and chemical treatment for the recovery of high-purity medium-chain-length PHAs (mcl-PHAs) at a lower cost. mcl-PHAs-accumulating Pseudomonas strains were used for PHA extraction via high-pressure homogenization (HPH) coupled with surfactant treatment and mild alkaline hydrogen peroxide oxidation. The mechanical-chemical method was found to have strong synergy for PHA extraction while minimizing PHA depolymerization. The optimized condition resulted in nearly 90 % mcl-PHA recovery with high purity (>91 %). The extracted high-purity PHAs exhibited thermal and mechanical properties suitable for downstream applications entailing flexible and elastomeric materials.

42 ENGINEERING↗

DOE OSTI2025

Exploring diversion-pathway analysis of a generic molten-salt fast reactor using multiphysics informed signatures

Molten salt reactors are being explored by multiple commercial ventures due to their inherent safety features, flexibility in fuel sources, and high fuel utilization and thermal efficiency. The continual flow of fuel salt, large fissile quantities present, and ability to add or divert material due to the liquid nature introduces new challenges for international safeguards. To understand how international safeguards should be applied, it is important to capture the inherent multi-physics nature of a molten salt reactor. This work examines a generic molten salt fast reactor to understand how potential diversion scenarios would affect the concentration of radionuclides in the primary and auxiliary systems. Three types of diversion were examined: a slow drip of fuel salt, gaseous plutonium extraction, and uranium metal plating. The analysis determined that several key isotopes become statistically significant once diversion begins, indicating that detection of such diversion cases would be possible through measuring specific signatures such as gamma spectra.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2024

Thermally unstable roosts influence winter torpor patterns in a threatened bat species

Abstract Many hibernating bats in thermally stable, subterranean roosts have experienced precipitous declines from white-nose syndrome (WNS). However, some WNS-affected species also use thermally unstable roosts during winter that may impact their torpor patterns and WNS susceptibility. From November to March 2017–19, we used temperature-sensitive transmitters to document winter torpor patterns of tricolored bats (Perimyotis subflavus) using thermally unstable roosts in the upper Coastal Plain of South Carolina. Daily mean roost temperature was 12.9 ± 4.9°C SD in bridges and 11.0 ± 4.6°C in accessible cavities with daily fluctuations of 4.8 ± 2°C in bridges and 4.0 ± 1.9°C in accessible cavities and maximum fluctuations of 13.8 and 10.5°C, respectively. Mean torpor bout duration was 2.7 ± 2.8 days and was negatively related to ambient temperature and positively related to precipitation. Bats maintained non-random arousal patterns focused near dusk and were active on 33.6% of tracked days. Fifty-one percent of arousals contained passive rewarming. Normothermic bout duration, general activity and activity away from the roost were positively related to ambient temperature, and activity away from the roost was negatively related to barometric pressure. Our results suggest ambient weather conditions influence winter torpor patterns of tricolored bats using thermally unstable roosts. Short torpor bout durations and potential nighttime foraging during winter by tricolored bats in thermally unstable roosts contrasts with behaviors of tricolored bats in thermally stable roosts. Therefore, tricolored bat using thermally unstable roosts may be less susceptible to WNS. More broadly, these results highlight the importance of understanding the effect of roost thermal stability on winter torpor patterns and the physiological flexibility of broadly distributed hibernating species.

Biodiversity & Conservation↗

DOE OSTI2021

Advanced Energy Approaches for Mixed-Use Developments in the Front Range Urban Corridor

The primary objective of the document is to present example technical approaches and strategies that planners and developers can reference for all-electric mixed-use developments in the Rocky Mountain Front Range urban corridor that are considering advanced energy performance goals such as high levels of energy efficiency and renewable integration. The strategies are tailored toward the vision for a zero energy, all-electric, district thermal system-connected starter district. In this example, on-site solar generation is emphasized as a strategy that can be combined with electrical and thermal energy storage for enhanced community resilience and demand flexibility. Opportunities for utilizing or adapting these strategies include: sharing with vertical developers for potential integration of strategies into vertical design guidelines; incorporation into Owner Project Requirements (OPRs); providing example strategies to design teams as a starting point for design; informing structure of agenda for a building design charrette; comparing building designs to example strategies at various points in the design process to evaluate design progression. While the technical strategies outlined in this document can help inform the development of guidelines for projects in the Front Range urban corridor, this document does not set requirements for any rating, certification, program, or policy.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

NASA NTRS1975

Demonstration of a sterilizable solid rocket motor system

A solid propellant rocket motor containing 60.9 Kg (134-lb) of propellant was successfully static fired after being subjected to eight heat sterilization cycles (three 54-hour cycles plus five 40-hour cycles) at 125 C (257 F). The test motor, a modified SVM-3 chamber, incorporated a flexible grain retention system of EPR rubber to relieve thermal shrinkage stresses. The propellant used in the motor was ANB-3438, and 84 wt% solids system (18 wt% aluminum) containing 66 wt% stabilized ammonium perchlorate oxidizer and a saturated hydroxylterminated polybutadiene binder. Bonding of the propellant to the EPR insulation (GenGard V-4030) was provided by the use of SD-886, an epoxy urethane restriction.

Mastrolia, E. J.↗

NASA NTRS1978

Temperature control analysis and flight results for the Viking Orbiter 1975 Mars atmospheric water detection instrument

The Mars atmospheric water detector (MAWD) instrument required a temperature of -70 C at the detector. The monochromator housing required +20 C + or - 1 C. This instrument was located on the scan platform, and slewed across two solar panels. The thermal design for the detector was an open flat plate radiator thermally isolated on four 1-in. tubes, with a flexible strap to the detector. MAWD radiator view factors and heat loads from the spacecraft were determined for the Lander on and off, for all angular positions of the scan platform. Subsystem and system tests were performed using the 25-ft diameter solar simulator. In-flight results have shown no anomalies, and no degradation has been observed. Servo-controlled heaters are used to control the temperature.

Kavanagh, H. M.↗

NASA NTRS1984

Demonstration of transparent solar array module design

This report discusses the design, development, fabrication and testing of IR transparent solar array modules. Three modules, consisting of a baseline design using back surface reflector cells, and two modules using gridded back contact, IR transparent cells, were subjected to vacuum thermal balance testing to verify analytical predictions of lower operating emperature and increased efficiency. As a result of this test program, LMSC has verified that a significant degree of IR transparency can be designed into a flexible solar array. Test data correlates with both steady state and transient thermal analysis.

Pack, G. J.↗

NASA NTRS1985

Phthalocyanine polymers

A method of forming 4,4',4'',4''' -tetraamino phthalocyanines involves reducing 4,4',4'',4''' -tetranitro phthalocyanines, polymerizing the metal tetraamino phthalocyanines with a tetracarboxylic dianhydride (preferably aromatic) or copolymerizing with a tetracarboxylic dianhydride and a diamine (preferably also aromatic) to produce amic acids which are then dehydrocyclized to imides. Thermally and oxidatively stable polymers result which form tough, flexible films, varnishes, adhesives, and fibers.

Achar, B. N.↗

NASA NTRS1994

Aromatic Polyimides With Low Dielectric Constants

Linear aromatic polyimides developed containing dimethylsilane linkages in dianhydride portions of molecules and at least one trifluoromethyl group in each of diamine portions. Polyimides offer advantages of thermal stability, low density, resistance to ionizing radiation, toughness, flexibility, and exhibit lower dielectric constants. Also polyimides nearly transparent and colorless; an advantage in protective coating of solar photovoltaic cells, optical components, and antennas.

St. Clair, Anne K.↗

NASA NTRS1999

The New Millennium Program: Validating Advanced Technologies for Future Space Missions

This presentation reviews the activities of the New Millennium Program (NMP) in validating advanced technologies for space missions. The focus of these breakthrough technologies are to enable new capabilities to fulfill the science needs, while reducing costs of future missions. There is a broad spectrum of NMP partners, including government agencies, universities and private industry. The DS-1 was launched on October 24, 1998. Amongst the technologies validated by the NMP on DS-1 are: a Low Power Electronics Experiment, the Power Activation and Switching Module, Multi-Functional Structures. The first two of these technologies are operational and the data analysis is still ongoing. The third program is also operational, and its performance parameters have been verified. The second program, DS-2, was launched January 3 1999. It is expected to impact near Mars southern polar region on 3 December 1999. The technologies used on this mission awaiting validation are an advanced microcontroller, a power microelectronics unit, an evolved water experiment and soil thermal conductivity experiment, Lithium-Thionyl Chloride batteries, the flexible cable interconnect, aeroshell/entry system, and a compact telecom system. EO-1 on schedule for launch in December 1999 carries several technologies to be validated. Amongst these are: a Carbon-Carbon Radiator, an X-band Phased Array Antenna, a pulsed plasma thruster, a wideband advanced recorder processor, an atmospheric corrector, lightweight flexible solar arrays, Advanced Land Imager and the Hyperion instrument

Minning, Charles P.↗

NASA NTRS2002

Single Source Precursors for Thin Film Solar Cells

The development of thin film solar cells on flexible, lightweight, space-qualified substrates provides an attractive cost solution to fabricating solar arrays with high specific power, (W/kg). The use of a polycrystalline chalcopyrite absorber layer for thin film solar cells is considered as the next generation photovoltaic devices. At NASA GRC we have focused on the development of new single source precursors (SSP) and their utility to deposit the chalcopyrite semi-conducting layer (CIS) onto flexible substrates for solar cell fabrication. The syntheses and thermal modulation of SSPs via molecular engineering is described. Thin-film fabrication studies demonstrate the SSPs can be used in a spray CVD (chemical vapor deposition) process, for depositing CIS at reduced temperatures, which display good electrical properties, suitable for PV (photovoltaic) devices.

Banger, Kulbinder K.↗

NASA NTRS2002

Chemical Vapor Deposition for Ultra-lightweight Thin-film Solar Arrays for Space

The development of thin-film solar cells on flexible, lightweight, space-qualified substrates provides an attractive cost solution to fabricating solar arrays with high specific power, (W/kg). The use of a polycrystalline chalcopyrite absorber layer for thin film solar cells is considered as the next generation photovoltaic devices. A key technical issues outlined in the 2001 U.S. Photovoltaic Roadmap, is the need to develop low cost, high throughput manufacturing for high-efficiency thin film solar cells. At NASA GRC we have focused on the development of new single-source-precursors (SSPs) and their utility to deposit the chalcopyrite semi-conducting layer (CIS) onto flexible substrates for solar cell fabrication. The syntheses and thermal modulation of SSPs via molecular engineering is described. Thin-film fabrication studies demonstrate the SSPs can be used in a spray CVD process, for depositing CIS at reduced temperatures, which display good electrical properties, suitable for PV devices.

Hepp, Aloysius F.↗

NASA NTRS2003

Geoscience Laser Altimetry System (GLAS) On-Orbit Flight Report on the Propylene Loop Heat Pipes (LHPs)

The Geoscience Laser Altimetry System (GLAS) instrument which is the sole instrument on ICESat was launched on January 12, 2003. GLAS utilizes two actively controlled propylene Loop Heat Pipes (LHPs) as the core of its thermal system. The LHPs started quickly when the Dale Ohm starter heaters were powered and have as designed. The low control heater power and on-orbit tight temperature control appear independent of gravity effects when comparing ground testing to flight data. The use of coupling blocks was also unique to these LHPs. Their application reduced control heater power by reducing the subcooling from the radiator. The effectiveness in reducing subcooling of the coupler blocks decreased during flight from ground testing, but internal thermal isolation in the compensation chamber between the subcooled returning liquid increased in flight resulting in no net increase in control heater power versus ground measurements. Overall the application of LHPs in the thermal system for GLAS met instrument requirements and provided flexibility for the overall system as last minute requirements became known.

Baker, Charles L.↗

NASA NTRS2010

Aerogel/polymer composite materials

The invention provides new composite materials containing aerogels blended with thermoplastic polymer materials at a weight ratio of aerogel to thermoplastic polymer of less than 20:100. The composite materials have improved thermal insulation ability. The composite materials also have better flexibility and less brittleness at low temperatures than the parent thermoplastic polymer materials.

Williams, Martha K.↗