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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Hydrogen Passivation of Interstitial Zn Defects in Heteroepitaxial InP Cell Structures and Influence on Device Characteristics

Hydrogen passivation of heteroepitaxial InP solar cells is of recent interest for deactivation of dislocations and other defects caused by the cell/substrate lattice mismatch that currently limit the photovoltaic performance of these devices. In this paper we present strong evidence that, in addition to direct hydrogen-dislocation interactions, hydrogen forms complexes with the high concentration of interstitial Zn defects present within the p(+) Zn-doped emitter of MOCVD-grown heteroepitaxial InP devices, resulting in a dramatic increase of the forward bias turn-on voltage by as much as 280 mV, from ~680 mV to ~960 mV. This shift is reproducible and thermally reversible and no such effect is observed for either n(+)p structures or homoepitaxial p(+)n structures grown under identical conditions. A combination of photoluminescence (PL), electrochemical C-V dopant profiling, SIMS and I-V measurements were performed on a set of samples having undergone a matrix of hydrogenation and post-hydrogenation annealing conditions to investigate the source of this voltage enhancement and confirm the expected role of interstitial Zn and hydrogen. A precise correlation between all measurements is demonstrated which indicates that Zn interstitials within the p(+) emitter and their interaction with hydrogen are indeed responsible for this device behavior.

Ringel, S. A.↗
DOE OSTI2023

Thermally Responsive Hydrogels for Passive Temperature Regulation under Direct Sunlight

By spontaneously emitting midinfrared radiation to outer space through the atmospheric window and reflecting sunlight, daytime radiative coolers achieve notable passive cooling performance. However, existing daytime radiative cooling systems generally lack the ability to adaptively switch between heating and cooling states based on ambient conditions. Herein a passive thermal regulation system that features a temperature‐dependent switchable solar reflectance from 0.05 (low temperature) to 0.8 (high temperature) is presented. This, along with a ≈0.95 midinfrared emittance, it enables automatic switching between radiative cooling and solar heating. Switchablity is enabled using a poly( N ‐isopropylacrylamide) (PNIPAM) hydrogel which exhibits high solar scattering above its tunable lower critical solution temperature (LCST) and transparency below its LCST. The lower part of the hydrogel is loaded with graphite to absorb solar energy in the heating state. In testing under sunny and partly cloudy outside conditions, this system maintains a temperature close to the set LCST.

Xie, Dajie↗
NASA NTRS1972

Apollo 12 thermal radiation properties.

The spectral and total thermal radiation properties are presented as a function of bulk density for lunar fines from the Apollo 12 mission collected on the Ocean of Storms. The total emittance is presented as a function of temperature from 90 to 400 K and the solar reflectance (albedo) for near normal incidence.

Birkebak, R. C.↗
NASA NTRS1977

The multiple applications of electrons in space

An electron source such as a simple cathode is a cheap and light device which can serve several technological and scientific purposes in space: (1) electrostatic charging of a spacecraft can be limited by releasing electrons accumulated on the conductive elements of their surface; (2) the erosion of conductive coatings and the ability of conductive paints to withstand the space environment can be evaluated by monitoring the flow of charged particles impinging on their surface; (3) measuring the current collected by the spacecraft surface as a function of its potential with respect to an emitter is a very sensitive diagnostic technique which can yield a number of plasma parameters, such as density and temperature; (4) it is possible to convert the thermal motion of space plasmas into electrical energy by collecting energetic electrons and returning them to the medium as cold particles; (5) a wave in a plasma is characterized by a conduction current density which gives rise to fluctuations of the current flowing to the surface.

Grard, R. J. L.↗
NASA NTRS1990

An evaluation of two flat-black silicone paints for space application

Tests were conducted on two flat-black silicone paints suggested for space applications to determine their optical, electrical, and mechanical properties. Three different types of substrate materials were chosen for these paint tests; the application of the paints onto the primed substrates was carried out by spray coating. The adhesion properties were verified by thermal shock and sudden immersion into liquid nitrogen. A controlled thermal vacuum tests was also carried out by varying the temperature of the paint from -100 to 225 C. The measured optical properties included normal and hemispherical emittance, and solar absorption/reflectance. A simultaneous exposure to low-energy proton/UV irradiation in vacuum, and high-energy proton/electron irradiation was carried out. Additional tests of the paints are described.

Clatterbuck, Carroll H.↗
NASA NTRS2008

Templates for Deposition of Microscopic Pointed Structures

Templates for fabricating sharply pointed microscopic peaks arranged in nearly regular planar arrays can be fabricated by a relatively inexpensive technique that has recently been demonstrated. Depending on the intended application, a semiconducting, insulating, or metallic film could be deposited on such a template by sputtering, thermal evaporation, pulsed laser deposition, or any other suitable conventional deposition technique. Pointed structures fabricated by use of these techniques may prove useful as photocathodes or field emitters in plasma television screens. Selected peaks could be removed from such structures and used individually as scanning tips in atomic force microscopy or mechanical surface profiling.

Pugel, Diane E.↗
NASA NTRS2011

Hemispherical Reflectance and Emittance Properties of Carbon Nanotubes Coatings at Far-Infrared Wavelengths

Recent visible wavelength observations of Multiwalled Carbon Nanotubes (MWCNT) coatings have revealed that they represent the blackest materials known in nature with a Total Hemispherical Reflectance (THR) less than .25%. This makes them as exceptionally good absorbers, with the potential to provide order-of-magnitude improvement in stray-light suppression over current black surface treatments when used in an optical system. Here we extend the characterization of this class of materials into the infrared spectral region to further evaluate their potential for use on instrument baffles for stray-light suppression and to manage spacecraft thermal properties to dissipate heat through radiant heat transfer process. These characterizations will include the wavelength-dependent Total Hemispherical Reflectance properties in the mid-IR and far-infrared spectral regions (2-100 micrometers). Determination of the temperature-dependent emittance will be investigated in the temperature range of 20 to 300 K. These results will be compared against other more conventional black coatings such as Acktar Fractal Black or Z-306 coatings among others.

Quijada, Manuel A.↗
NASA NTRS1980

Tailored emitter, low-resistivity, ion-implanted silicon solar cells

Open-circuit voltages as high as 0.645 V (AM0, 25 C) have been obtained by a new process developed for low-resistivity silicon. The process utilizes high-dose phosphorus implantation followed by furnace annealing and simultaneous oxide growth. The effect of the thermally grown oxide is a reduction of surface recombination velocity; the oxide also acts as a moderately efficient antireflection (AR) coating. Boron-doped, float-zone silicon with resistivities from 0.1 to 1.0 (omega)(cm) has been processed according to this sequence; results show that the highest open-circuit voltage is obtained with 0.1(omega)(cm) starting material. The effects of Auger recombination and bandgap narrowing caused by high doping concentrations in the n(+)junction region have been investigated by implanting phosphorus over a wide range of dose levels. The effects of emitter-phosphorus concentrations tailored to optimize electric fields in the emitter have also been investigated.

Minnucci, J. A.↗
NASA NTRS1988

Carbon doping in molecular beam epitaxy of GaAs from a heated graphite filament

Carbon doping of GaAs grown by molecular beam epitaxy has been obtained for the first time by use of a heated graphite filament. Controlled carbon acceptor concentrations over the range of 10 to the 17th-10 to the 20th/cu cm were achieved by resistively heating a graphite filament with a direct current power supply. Capacitance-voltage, p/n junction and secondary-ion mass spectrometry measurements indicate that there is negligible diffusion of carbon during growth and with postgrowth rapid thermal annealing. Carbon was used for p-type doping in the base of Npn AlGaAs/GaAs heterojunction bipolar transistors. Current gains greater than 100 and near-ideal emitter heterojunctions were obtained in transistors with a carbon base doping of 1 x 10 to the 19th/cu cm. These preliminary results indicate that carbon doping from a solid graphite source may be an attractive substitute for beryllium, which is known to have a relatively high diffusion coefficient in GaAs.

Malik, R. J.↗
DOE OSTI2022

Semiconductor-dielectric-metal solar absorbers with high spectral selectivity

An ideal solar thermal absorber has a sharp transition between high and low absorptance at the wavelength where the blackbody emissive power begins to exceed the solar irradiance. However, most real selective absorbers have a fairly broad transition, leading to both solar absorption and thermal emission losses. Here, we model, fabricate, and characterize a highly selective semiconductor-dielectric-metal (Ga0.46In0.54As - MgF2 - Ag) solar absorber with an extremely sharp transition from high to low absorptance. The thin semiconductor serves as a selective filter, absorbing photons with wavelengths shorter than the bandgap and transmitting those with longer wavelengths. The highly reflective dielectric-metal rear mirror allows the structure to have very low emittance for longer wavelengths. These characteristics provide the absorber with a measured solar absorptance >91% below the bandgap wavelength and infrared emittance <5% at 100 degrees C above the bandgap wavelength. This transition wavelength can be tuned by modifying the semiconductor composition, and modeling indicates that the absorber's optical properties should be stable at high temperatures, making the structure a good candidate for unconcentrated to highly concentrated solar thermal energy conversion.

14 SOLAR ENERGY↗
NASA NTRS1974

Evaluation of commercially supplied silver coated Teflon for spacecraft temperature control usage

A series of tests are described which were performed to evaluate the acceptability of a commercially supplied silver backed teflon thermal control coating relative to teflon previously coated at GSFC. Optical measurements made on numerous samples indicate that the commercial material possesses an average solar absorptance of 0.085, an emittance of 0.76 and an average alpha/epsilon equal to 0.112, all of which are equivalent to the GSFC coated teflon. The emittance of the protective inconel backing was found to be 0.037. The coating is shown to have good adhesion at the Ag-teflon interface and exposure to UV irradiation uncovered no coating irregularities. Temperature cycling over the range -135 C to +200 C produced crazing in the evaporated Ag layer as expected but no delamination was observed. The suitability of Mystik no. 7366 and 3M no. 467 adhesives as bonding agents for the metallized polymer is demonstrated. Various problems associated with production reproducibility and selection of a proper bonding process are discussed.

Heaney, J. B.↗
NASA NTRS1974

High-efficiency, low-temperature cesium diodes with lanthanum-hexaboride electrodes

Lanthanum hexaboride electrodes in 1700 K cesium diodes may triple power outputs compared with those demonstrated for nuclear thermionic space applications. Still greater relative gains seem possible for emitters below 1700 K. Further improvements in cesium diode performance should result from the lower collector temperatures allowed for earth and low power space duties. Decreased temperatures will lessen thermal transport losses that attend thermionic conversion mechanisms. Such advantages will add to those from collector Carnot and electrode effects. If plasma ignition difficulties impede diode temperature reductions, recycling small fractions of the output power could provide ionization. So high efficiency, low temperature cesium diodes with lanthanum hexaboride electrodes appear feasible.

Morris, J. F.↗
NASA NTRS1984

Ion-beam-textured and coated surfaces experiment (S1003)

The objective of this LDEF experiment is to measure the effects of exposure to the shuttle launch and near Earth space environments on the optical properties of ion beam textured high absorptance solar thermal control surfaces, the optical and electrical properties of ion beam sputtered conductive solar thermal control surfaces, and the weight loss of ion beam deposited oxide polymer films. The various types of surfaces to be tested include six major categories: (1) ion beam textured surfaces suitable for space solar thermal (solar concentration) application; (2) painted and/or state of the art solar thermal surfaces; (3) ion beam sputtered conductive coatings for thermal and space charge control (e.g., indium-oxide coated metalized FEP Teflon); (4) ion beam sputtered conductive coated solar sail materials for space charge control and cooling through emittance; (5) micrometeoroid sensitive samples whose optical properties change only as a result of micrometeoroid impact; and (6) Kapton coated with oxide polymer films to minimize oxygen degradation at near Earth orbit altitudes.

Mirtich, M. J., Jr.↗
NASA NTRS1985

Emission, absorption and group delay of microwaves in the atmosphere in relation to water vapour content over the Indian subcontinent

The advent of satellite communication for global coverage has apparently indicated a renewed interest in the studies of radio wave propagation through the atmosphere, in the VHF, UHF and microwave bands. The extensive measurements of atmosphere constituents, dynamics and radio meterological parameters during the Middle Atmosphere Program (MAP) have opened up further the possibilities of studying tropospheric radio wave propagation parameters, relevant to Earth/space link design. The three basic parameters of significance to radio propagation are thermal emission, absorption and group delay of the atmosphere, all of which are controlled largely by the water vapor content in the atmosphere, particular at microwave bands. As good emitters are also good absorbers, the atmospheric emission as well as the absorption attains a maximum at the frequency of 22.235 GHz, which is the peak of the water vapor line. The group delay is practically independent of frequency in the VHF, UHF and microwave bands. However, all three parameters exhibit a similar seasonal dependence originating presumably from the seasonal dependence of the water vapor content. Some of the interesting results obtained from analyses of radiosonde data over the Indian subcontinent collected by the India Meteorological Department is presented.

Sen, A. K.↗
NASA NTRS1986

Effect of low-energy hydrogen ion implantation on dendritic web silicon solar cells

The effect of a low-energy (0.4 keV), short-time (2-min), heavy-dose (10 to the 18th/sq cm) hydrogen ion implant on dendritic web silicon solar cells and material was investigated. Such an implant was observed to improve the cell open-circuit voltage and short-circuit current appreciably for a number of cells. In spite of the low implant energy, measurements of internal quantum efficiency indicate that it is the base of the cell, rather than the emitter, which benefits from the hydrogen implant. This is supported by the observation that the measured minority-carrier diffusion length in the base did not change when the emitter was removed. In some cases, a threefold increase of the base diffusion length was observed after implantation. The effects of the hydrogen implantation were not changed by a thermal stress test at 250 C for 111 h in nitrogen. It is speculated that hydrogen enters the bulk by traveling along dislocations, as proposed recently for edge-defined film-fed growth silicon ribbon.

Rohatgi, A.↗
NASA NTRS2007

Weathering of Thermal Control Coatings

Spacecraft radiators reject heat to their surroundings. Radiators can be deployable or mounted on the body of the spacecraft. NASA's Crew Exploration Vehicle is to use body mounted radiators. Coatings play an important role in heat rejection. The coatings provide the radiator surface with the desired optical properties of low solar absorptance and high infrared emittance. These specialized surfaces are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an applique. Not specifically designed for a weathering environment, little is known about the durability of conventional paints, coatings, and appliques upon exposure to weathering and subsequent exposure to solar wind and ultraviolet radiation exposure. In addition to maintaining their desired optical properties, the coatings must also continue to adhere to the underlying radiator panel. This is a challenge, as new composite radiator panels are being considered as replacements for the aluminum panels used previously. Various thermal control paints, coatings, and appliques were applied to aluminum and isocyanate ester composite coupons and were exposed for 30 days at the Atmospheric Exposure Site of the Kennedy Space Center s Beach Corrosion Facility for the purpose of identifying their durability to weathering. Selected coupons were subsequently exposed to simulated solar wind and vacuum ultraviolet radiation to identify the effect of a simulated space environment on the as-weathered surfaces. Optical properties and adhesion testing were used to document the durability of the paints and coatings. The purpose of this paper is to present the results of the weathering testing and to summarize the durability of several thermal control paints, coatings, and appliques to weathering and postweathering environments.

Jaworske, Donald A.↗