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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Genetic and epigenetic signatures of Populus trichocarpa in response to abiotic stresses

Plants respond to abiotic stresses such as drought, heat, and salinity through both shared and stress-specific regulatory pathways. However, the role of epigenetic mechanisms, particularly DNA methylation, in modulating these responses is still underexplored. Here, we integrated transcriptome profiling with whole-genome bisulfite sequencing (WGBS) to investigate the dynamic relationship between gene expression and DNA methylation in Populus trichocarpa during brief early-stage exposure to abiotic stress. Each stress elicited distinct transcriptional and methylation signatures; however, a subset of conserved stress-responsive genes was commonly regulated across treatments. We found that ∼5-6% of differentially expressed genes also displayed differential methylation patterns, suggesting a coordinated role for DNA methylation in regulating gene expression. Motif enrichment analysis of differentially methylated regions revealed binding sites of key transcription factor families, including ERF, bHLH, and ABF, highlighting potential role for methylation in modulating transcription factor targeting. Furthermore, we identified stress-inducible molecular markers with potential applications in early stress detection and functional dissection of gene regulatory pathways. Together, these findings provide new insights into the coordinated genetic and epigenetic responses to abiotic stress and provide a foundation for developing biosensors and breeding strategies to enhance stress resilience woody plants.

DNA methylation↗
DOE OSTI2023

How to detect lensing rotation

Gravitational lensing rotation of images is predicted to be negligible at linear order in density perturbations, but can be produced by the post-Born lens-lens coupling at second order. This rotation is somewhat enhanced for Cosmic Microwave Background (CMB) lensing due to the large source path length, but remains small and very challenging to detect directly by CMB lensing reconstruction alone. We show the rotation may be detectable at high significance as a cross-correlation signal between the curl reconstructed with Simons Observatory (SO) or CMB-S4 data, and a template constructed from quadratic combinations of large-scale structure (LSS) tracers. Equivalently, the lensing rotation-tracer-tracer bispectrum can also be detected, where LSS tracers considered include the CMB lensing convergence, galaxy density, and the Cosmic Infrared Background (CIB), or optimal combinations thereof. We forecast that an optimal combination of these tracers can probe post-Born rotation at the level of 5.7σ–6.1σ with SO and 13.6σ–14.7σ for CMB-S4, depending on whether standard quadratic estimators or maximum a posteriori iterative methods are deployed. We also show possible improvement up to 21.3σ using a CMB-S4 deep patch observation with polarization-only iterative lensing reconstruction. However, these cross-correlation signals have non-zero bias because the rotation template is quadratic in the tracers, and exists even if the lensing is rotation free. We estimate this bias analytically, and test it using simple null-hypothesis simulations to confirm that the bias remains subdominant to the rotation signal of interest. Detection and then measurement of the lensing rotation cross-spectrum is therefore a realistic target for future observations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Characterization of Humoral Responses to Nipah Virus Infection in the Syrian Hamster Model of Disease

Abstract Nipah virus (NiV) is a highly pathogenic paramyxovirus. The Syrian hamster model recapitulates key features of human NiV disease and is a critical tool for evaluating antivirals and vaccines. Here we describe longitudinal humoral immune responses in NiV-infected Syrian hamsters. Samples were obtained 1–28 days after infection and analyzed by ELISA, neutralization, and Fc-mediated effector function assays. NiV infection elicited robust antibody responses against the nucleoprotein and attachment glycoprotein. Levels of neutralizing antibodies were modest and only detectable in surviving animals. Fc-mediated effector functions were mostly observed in nucleoprotein-targeting antibodies. Antibody levels and activities positively correlated with challenge dose.

Immunology↗
DOE OSTI2022

Search for extended Lyman-α emission around 9k quasars at z = 2–3

ABSTRACT Enormous Lyα nebulae (ELANe) around quasars have provided unique insights into the formation of massive galaxies and their associations with super-massive black holes since their discovery. However, their detection remains highly limited. This paper introduces a systematic search for extended Lyα emission around 8683 quasars at z = 2.34–3.00 using a simple but very effective broad-band gri selection based on the Third Public Data Release of the Hyper Suprime-Cam Subaru Strategic Program. Although the broad-band selection detects only bright Lyα emission (≳ 1 × 10−17 erg s−1cm−2 arcsec−2) compared with narrow-band imaging and integral field spectroscopy, we can apply this method to far more sources than such common approaches. We first generated continuum g-band images without contributions from Lyα emission for host and satellite galaxies using r- and i-bands. Then, we established Lyα maps by subtracting them from observed g-band images with Lyα emissions. Consequently, we discovered extended Lyα emission (with masked area >40 arcsec2) for 7 and 32 out of 366 and 8317 quasars in the Deep and Ultra-deep (35 deg2) and Wide (890 deg2) layers, parts of which may be potential candidates of ELANe. However, none of them seem to be equivalent to the largest ELANe ever found. We detected higher fractions of quasars with large nebulae around more luminous or radio-loud quasars, supporting previous results. Future applications to the forthcoming big data from the Vera C. Rubin Observatory will help us detect more promising candidates. The source catalogue and obtained Lyα properties for all the quasar targets are accessible as online material.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Lifetime measurements in the even-even Cd 102 – 108 isotopes

The heaviest T z = 0 doubly-magic nucleus, Sn 100 , and the neighboring nuclei offer unique opportunities to investigate the properties of nuclear interaction. For instance, the structure of light-Sn nuclei has been shown to be affected by the delicate balance between nuclear-interaction components, such as pairing and quadrupole correlations. From Cd to Te, many common features and phenomena have been observed experimentally along the isotopic chains, leading to theoretical studies devoted to a more general and comprehensive study of the region. In this context, having only two proton holes in the Z = 50 shell, the Cd isotopes are expected to present properties similar to those found in the Sn isotopic chain. The aim of this work was to measure lifetimes of excited states in neutron-deficient nuclei in the vicinity of Sn 100 . Here, the neutron-deficient nuclei in the N ≈ Z ≈ 50 region were populated using a multinucleon transfer reaction with a Cd 106 beam and a Mo 92 target. The beamlike products were identified by the VAMOS + + spectrometer, while the γ rays were detected using the AGATA array. Lifetimes of excited states were determined using the recoil distance Doppler-shift method, employing the Cologne differential plunger. Lifetimes of low-lying states were measured in the even-mass Cd 102 – 108 isotopes. In particular, multiple states with excitation energy up to ≈ 3 MeV, belonging to various bands, were populated in Cd 106 via inelastic scattering. The transition strengths corresponding to the measured lifetimes were compared with those resulting from state-of-the-art beyond-mean-field calculations using the symmetry-conserving configuration-mixing approach. Conclusions: Despite the similarities in the electromagnetic properties of the low-lying states, there is a fundamental structural difference between the ground-state bands in the Z = 48 and Z = 50 isotopes. The comparison between experimental and theoretical results revealed a rotational character of the Cd nuclei, which have prolate-deformed ground states with β 2 ≈ 0.2 . At this deformation Z = 48 becomes a closed-shell configuration, which is favored with respect to the spherical one.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Search by the SENSEI Experiment for Millicharged Particles Produced in the NuMI Beam

Millicharged particles appear in several extensions of the standard model, but have not yet been detected. These hypothetical particles could be produced by an intense proton beam striking a fixed target. We use data collected in 2020 by the SENSEI experiment in the MINOS cavern at the Fermi National Accelerator Laboratory to search for ultrarelativistic millicharged particles produced in collisions of protons in the NuMI beam with a fixed graphite target. The absence of any ionization events with 3 to 6 electrons in the SENSEI data allow us to place world-leading constraints on millicharged particles for masses between 30 to 380 MeV. This work also demonstrates the potential of utilizing low-threshold detectors to investigate new particles in beam-dump experiments, and motivates a future experiment designed specifically for this purpose. Published by the American Physical Society 2024

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Additional Analysis of the 2H-Evaporator Wall Scale Sample HTF-17-57

Savannah River National Laboratory previously analyzed scale samples from both the wall and cone sections of the 242-16H Evaporator prior to chemical cleaning. The samples were analyzed for uranium and plutonium isotopes required for a Nuclear Criticality Safety Assessment of the scale removal process. The analysis of the scale samples found the material to contain crystalline nitrated cancrinite and clarkeite and significant amounts of mercury. Savannah River Remediation subsequently requested additional analyses on the samples. Inspection of the sample bottles revealed that no sample remained of the cone scale (HTF-17-56) while approximately 4 g of the wall scale sample (HTF-17-57) remained. The wall sample was subsequently ground with a mortar and pestle, at which time it was discovered that the sample contained a significant amount of liquid, metallic mercury. The portion of the sample that was not mercury was approximately 3 g. This portion of the sample was analyzed to determine the concentrations of selected radionuclides. The following radionuclide concentrations were measured: <9.6E+02 dpm/g H-3, 2.9E+02 dpm/g C-14, 5.6E+03 dpm/g Tc-99, and 1.6E+02 dpm/g I-129. Blank samples were also analyzed to evaluate sample contamination from the Shielded Cells environment. All blank sample results were below detectable limits. Due to the limited sample size and the anticipated low levels of the target radionuclides, no replicate sample analysis was conducted.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Deep Deception: Exemplars of Adversarial Machine Learning and Countermeasures Applicable to International Safeguards

As a follow-up to our more comprehensive report on Adversarial Machine Learning (AML), here we provide demonstrations of AML attacks against the Limbo image database of UF6 cylinders in a variety of orientations and amongst a variety of distractor images. We demonstrate the Carlini & Wagner AML attack against a subset of Limbo images, with 100% attack success rate; meaning all attacked images were misclassified by a highly accurate trained model, yet the image changes were imperceptible to the human eye. We also demonstrate successful attacks against segmented images (images with more than one targeted object). Finally, we demonstrated the Fast Fourier Transform countermeasure that can be used to detect AML attacks on images. The intent of this and our previous report is to inform the IAEA and stakeholders of both the promise of machine learning, which could greatly improve the efficiency of surveillance monitoring, but also of the real threat of AML and potential defenses.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2024

Qubit-Based Detector For Dark Matter Search And Radiation Studies

One of the challenges in exploring promising novel materials for dark matter searches is the detection of sub-eV energy excitations from light-dark matter interaction with a target material. Dark matter interaction can excite sub-eV optical phonon modes in polar materials like sapphire. We plan to utilize superconducting qubits on a sapphire substrate to study their response to energy deposition into the superconducting film and the substrate by irradiating them with photons and particles and also generating phonons in the chip. A fraction of the incident energy is expected to break Cooper pairs in the superconductor, releasing quasiparticles. As the quasiparticles tunnel across the Josephson junction, the charge parity of the qubit changes. The parity switching rate is proportional to the quasiparticle density in the qubit superconductor film and can be measured using standard qubit readout protocol. This presentation describes our ongoing attempt to build such a prototype detector.

Khatiwada, Rakshya↗
DOE OSTI2025

Genetic_and_epigenetic_signatures_of_Populus_Trichocarpa_in_response_to_abiotic_stress

Plants respond to abiotic stresses such as drought, heat, and salinity through both shared and stress-specific regulatory pathways. However, the role of epigenetic mechanisms, particularly DNA methylation, in modulating these responses is still underexplored. Here, we integrated transcriptome profiling with whole-genome bisulfite sequencing (WGBS) to investigate the dynamic relationship between gene expression and DNA methylation in Populus trichocarpa during brief early-stage exposure to abiotic stress. Each stress elicited distinct transcriptional and methylation signatures; however, a subset of conserved stress-responsive genes was commonly regulated across treatments. Approximately 5% of differentially expressed genes also displayed differential methylation patterns, suggesting a coordinated role for DNA methylation in regulating gene expression. Motif enrichment analysis of differentially methylated regions revealed binding sites of key transcription factor families, including ERF, bHLH, and ABF, highlighting potential role for methylation in modulating transcription factor targeting. Furthermore, we identified stress-inducible molecular markers with potential applications in early stress detection and functional dissection of gene regulatory pathways. Together, these findings provide new insights into the coordinated genetic and epigenetic responses to abiotic stress and provide a foundation for developing biosensors and breeding strategies to enhance stress resilience woody plants.

CBI↗
DOE OSTI2020

Size and Shape Constraints of (486958) Arrokoth from Stellar Occultations

We present the results from four stellar occultations by (486958) Arrokoth, the flyby target of the New Horizons extended mission. Three of the four efforts led to positive detections of the body, and all constrained the presence of rings and other debris, finding none. Twenty-five mobile stations were deployed for 2017 June 3 and augmented by fixed telescopes. There were no positive detections from this effort. The event on 2017 July 10 was observed by the Stratospheric Observatory for Infrared Astronomy with one very short chord. Twenty-four deployed stations on 2017 July 17 resulted in five chords that clearly showed a complicated shape consistent with a contact binary with rough dimensions of 20 by 30 km for the overall outline. A visible albedo of 10% was derived from these data. Twenty-two systems were deployed for the fourth event on 2018 August 4 and resulted in two chords. The combination of the occultation data and the flyby results provides a significant refinement of the rotation period, now estimated to be 15.9380 ± 0.0005 hr. The occultation data also provided high-precision astrometric constraints on the position of the object that were crucial for supporting the navigation for the New Horizons flyby. This work demonstrates an effective method for obtaining detailed size and shape information and probing for rings and dust on distant Kuiper Belt objects as well as being an important source of positional data that can aid in spacecraft navigation that is particularly useful for small and distant bodies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Controlled and Selective Photo-oxidation of Amyloid-β Fibrils by Oligomeric p-Phenylene Ethynylenes

Photodynamic therapy (PDT) has been explored as a therapeutic strategy to clear toxic amyloid aggregates involved in neurodegenerative disorders such as Alzheimer’s disease. A major limitation of PDT is off-target oxidation, which can be lethal for the surrounding cells. In this work, we have shown that a novel class of oligo-p-phenylene ethynylenes (OPEs) exhibit selective binding and fluorescence turn-on in the presence of prefibrillar and fibrillar aggregates of disease-relevant proteins such as amyloid-β (Aβ) and α-synuclein. Concomitant with fluorescence turn-on, OPE also photosensitizes singlet oxygen under illumination through the generation of a triplet state, pointing to the potential application of OPEs as photosensitizers in PDT. Herein, we investigated the photosensitizing activity of an anionic OPE for the photo-oxidation of Aβ fibrils and compared its efficacy to the well-known but nonselective photosensitizer methylene blue (MB). Our results show that, while MB photo-oxidized both monomeric and fibrillar conformers of Aβ40, OPE oxidized only Aβ40 fibrils, targeting two histidine residues on the fibril surface and a methionine residue located in the fibril core. Oxidized fibrils were shorter and more dispersed but retained the characteristic β-sheet rich fibrillar structure and the ability to seed further fibril growth. Importantly, the oxidized fibrils displayed low toxicity. We have thus discovered a class of novel theranostics for the simultaneous detection and oxidization of amyloid aggregates. Importantly, the selectivity of OPE’s photosensitizing activity overcomes the limitation of off-target oxidation of traditional photosensitizers and represents an advancement of PDT as a viable strategy to treat neurodegenerative disorders.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

SDSS-IV MaNGA: a catalogue of spectroscopically detected strong galaxy–galaxy lens candidates

ABSTRACT We spectroscopically detected candidate emission-lines of 8 likely, 17 probable, and 69 possible strong galaxy–galaxy gravitational lens candidates found within the spectra of $\approx 10\, 000$ galaxy targets contained within the completed Mapping of Nearby Galaxies at Apache Point Observatory survey. This search is based upon the methodology of the Spectroscopic Identification of Lensing Objects project, which extends the spectroscopic detection methods of the BOSS Emission-Line Lensing Survey and the Sloan Lens ACS Survey. We scanned the co-added residuals that we constructed from stacks of foreground subtracted row-stacked-spectra so a sigma-clipping method can be used to reject cosmic rays and other forms of transients that impact only a small fraction of the combined exposures. We also constructed narrow-band images from the signal to noise of the co-added residuals to observe signs of lensed source images. We also use several methods to compute the probable strong lensing regime for each candidate lens to determine which candidate background galaxies may reside sufficiently near the galaxy centre for strong lensing to occur. We present the spectroscopic redshifts within a value-added catalogue (VAC) for data release 17 (DR17) of SDSS-IV. We also present the lens candidates, spectroscopic data, and narrow-band images within a VAC for DR17. High resolution follow-up imaging of these lens candidates are expected to yield a sample of confirmed grade-A lenses with sufficient angular size to probe possible discrepancies between the mass derived from a best-fitting lens model, and the dynamical mass derived from the observed stellar velocities.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Integrating Machine-learning-assisted Computer Vision with RICH System

Developments in artificial intelligence have vastly expanded the capabilities of robots. Currently, the Spallation Neutron Source (SNS) beamlines at Oak Ridge National Lab (ORNL) have robotic sample loaders to increase the efficiency of running experiments. However, they require retraining if anything about the situation changes, e.g., where the samples are, and cannot notice if errors occur. So, the viability of using computer vision and machine learning to enhance these sample loaders’ functionality was investigated. In this project, the RICH system with a Dobot CR3 6-axis robot present at the VULCAN beamline assisted by an Intel Realsense D435i camera, a unique camera that enables convenient translation of 2D pixel coordinates to 3D world points, was programmed to load ceramic crucibles into a thermogravimetric analyzer (TGA) furnace. An algorithm was constructed in Python with three major phases planned: (1) obtaining a sample, (2) moving it to the target location, and then (3) bringing the sample back to its original location once the experiment finished. In the first phase, the algorithm would dynamically detect sample locations using ArUco markers to recognize the samples’ general location and a custom-trained yolov5 object detection model to locate the crucibles’ centers. Afterward, the robot would be directed to pick up samples based on the crucibles’ calculated positions. In the second phase, the robot would move the sample to a secondary point, reorient its grip, and place the sample at the target location. In the final phase, the robot would determine whether the sample was intact and would bring it back to its original place if it was or raise an alarm. Using this algorithm, the robot was able to pick up different types of crucibles at varying positions. These results indicate that integrating machine-learning-assisted computer vision with robotic sample loaders can result in effective autonomous detection of samples.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2022

Snowmass Instrumentation Frontier IF08 Topical Group Report: Noble Element Detectors

Particle detectors making use of noble elements in gaseous, liquid, or solid phases are prevalent in neutrino and dark matter experiments and are also used to a lesser extent in collider-based particle physics experiments. These experiments take advantage of both the very large, ultra-pure target volumes achievable and the multiple observable signal pathways possible in noble-element based particle detectors. As these experiments seek to increase their sensitivity, novel and improved technologies will be needed to enhance the precision of their measurements and to broaden the reach of their physics programs. The areas of R&D in noble element instrumentation that have been identified by the HEP community in the Snowmass process are highlighted by five key messages: IF08-1) Enhance and combine existing modalities (scintillation and electron drift) to increase signal-to-noise and reconstruction fidelity; IF08-2) Develop new modalities for signal detection in noble elements, including methods based on ion drift, metastable fluids, solid-phase detectors and dissolved targets. Collaborative and blue-sky R&D should also be supported to enable advances in this area; IF08-3) Improve the understanding of detector microphysics and calibrate detector response in new signal regimes; IF08-4) Address challenges in scaling technologies, including material purification, background mitigation, large-area readout, and magnetization; and IF08-5) Train the next generation of researchers, using fast-turnaround instrumentation projects to provide the design-through-result training no longer possible in very-large-scale experiments. This topical group report identifies and documents recent developments and future needs for noble element detector technologies. In addition, we highlight the opportunity that this area of research provides for continued training of the next generation of scientists.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Measurements of $\overline{\nu}_{\mu}$ and $\overline{\nu}_{\mu} + \nu_{\mu}$ charged-current cross-sections without detected pions or protons on water and hydrocarbon at a mean anti-neutrino energy of 0.86 GeV

We report measurements of the flux-integrated $\overline{\nu}_\mu$ and $\overline{\nu}_\mu+\nu_\mu$ charged-current cross-sections on water and hydrocarbon targets using the T2K anti-neutrino beam with a mean beam energy of 0.86 GeV. The signal is defined as the (anti-)neutrino charged-current interaction with one induced $\mu^\pm$ and no detected charged pion or proton. These measurements are performed using a new WAGASCI module recently added to the T2K setup in combination with the INGRID Proton Module. The phase space of muons is restricted to the high-detection efficiency region, $p_{\mu}>400~{\rm MeV}/c$ and $\theta_{\mu}<30^{\circ}$, in the laboratory frame. An absence of pions and protons in the detectable phase spaces of $p_{\pi}>200~{\rm MeV}/c$, $\theta_{\pi}<70^{\circ}$ and $p_{\rm p}>600~{\rm MeV}/c$, $\theta_{\rm p}<70^{\circ}$ is required. In this paper, both the $\overline{\nu}_\mu$ cross-sections and $\overline{\nu}_\mu+\nu_\mu$ cross-sections on water and hydrocarbon targets and their ratios are provided by using the D’Agostini unfolding method. The results of the integrated $\overline{\nu}_\mu$ cross-section measurements over this phase space are $\sigma_{\rm H_{2}O}=(1.082\pm0.068(\rm stat.)^{+0.145}_{-0.128}(\rm syst.)) \times 10^{-39}\,{\rm cm^{2} / nucleon}$, $\sigma_{\rm CH}=(1.096\pm0.054(\rm stat.)^{+0.132}_{-0.117}(\rm syst.)) \times 10^{-39}\,{\rm cm^{2} / nucleon}$, and $\sigma_{\rm H_{2}O}/\sigma_{\rm CH} = 0.987\pm0.078(\rm stat.)^{+0.093}_{-0.090}(\rm syst.)$. The $\overline{\nu}_\mu+\nu_\mu$ cross-section is $\sigma_{\rm H_{2}O} = (1.155\pm0.064(\rm stat.)^{+0.148}_{-0.129}(\rm syst.)) \times 10^{-39}\,{\rm cm^{2} / nucleon}$, $\sigma_{\rm CH}=(1.159\pm0.049(\rm stat.)^{+0.129}_{-0.115}(\rm syst.)) \times 10^{-39}\,{\rm cm^{2} / nucleon}$, and $\sigma_{\rm H_{2}O}/\sigma_{\rm CH}=0.996\pm0.069(\rm stat.)^{+0.083}_{-0.078}(\rm syst.)$.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Heartbeat: Detecting Malware by Periodic Power Signal Injection and Monitoring

Rootkits and other stealthy malware attempt to conceal their presence on a computer by making changes to the host computer’s operating environment. ORNL’s Heartbeat technology detects these changes, and thus the malware itself. Heartbeat operates by directly monitoring the DC power consumption of the computer while a set of operations, the “heartbeat,” is executed periodically. These operations exercise parts of the operating system that are common targets of malware tampering. The power consumption during these heartbeat events is monitored and then compared to a previously learned baseline, with any significant deviation detected and analyzed. This technology has been tested and validated in a laboratory environment, and ORNL is currently seeking a deployment partner to allow for further in-context development and testing of this technology.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2022

Trace Compound Analysis in TATB by Liquid Chromatography coupled with Spectroscopic and Spectrometric Detection

Accurate quantitation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) is important because of its strategic use as an energetic material. A purity determination is also needed for the proper assessment of performance. A fast and sensitive method has been developed to measure the purity of TATB in polymer-bonded materials. The target material is extracted with DMSO, and the extract is separated on a reversed-phase chromatography column. The column effluent is monitored by diode array detection (DAD) at 354 nm. The characteristic UV-Vis response and retention time identify the individual components when compared to pure compound standards. The chemical structures of compounds with no pure standards available have been determined by high-resolution mass spectrometry (MS) and MS/MS. The major component, TATB, along with 1-chloro-3,5-dinitro-2,4,6-triaminobenzene (T4A) and mono-benzofuroxan (FX1) were quantitated directly from pure compound standards. Several trace concentration components, mono-benzofurazan (F1), 1-bromo-3,5-dinitro-2,4,6-triaminobenzene (Br-T4A), 2,4,6-triamino-1-nitroso-3,5-dinitrobenzene (MN-TATB), 2,4,6-triamino-1-hydroxyl-3,5-dinitrobenzene (HO-TATB), and 2,4,6-triamino-1-nitrile-3,5-dinitrobenzene (Nitrile-TATB) were also detected and structures verified via MS/MS. Approximate concentrations were determined using calibrations from standards of similar structures. Additional trace components were also detected by MS. Contained herein are the results of analyses of TATB-based materials characterized for polymer-bonded formulations compared to different preparations of TATB. The accuracy, details, and process of developing this method are reported here.

36 MATERIALS SCIENCE↗