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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

Reversing the Irreversible: Thermodynamic Stabilization of LiAlH 4 Nanoconfined Within a Nitrogen-Doped Carbon Host

A general problem when designing functional nanomaterials for energy storage is the lack of control over the stability and reactivity of metastable phases. Using the high-capacity hydrogen storage candidate LiAlH4 as an exemplar, we demonstrate an alternative approach to the thermodynamic stabilization of metastable metal hydrides by coordination to nitrogen binding sites within the nanopores of N-doped CMK-3 carbon (NCMK-3). The resulting LiAlH 4 @NCMK-3 material releases H 2 at temperatures as low as 126 °C with full decomposition below 240 °C, bypassing the usual Li 3 AlH 6 intermediate observed in bulk. Moreover, >80% of LiAlH 4 can be regenerated under 100 MPa H 2 , a feat previously thought to be impossible. Nitrogen sites are critical to these improvements, as no reversibility is observed with undoped CMK-3. Density functional theory predicts a drastically reduced Al–H bond dissociation energy and supports the observed change in the reaction pathway. Finally, the calculations also provide a rationale for the solid-state reversibility, which derives from the combined effects of nanoconfinement, Li adatom formation, and charge redistribution between the metal hydride and the host.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Electrical Validation Testing for ORPC MHK Generator, Modification 6: ORPC SBV for MHK Generator System (CRADA Final Report)

For the U.S. Department of Energy’s (DOE) 2016 Small Business Voucher for Marine and Hydrokinetic (MHK) System, Second Round 2016, ORPC intends to work with the National Renewable Energy Laboratory (NREL) to perform dynamometer testing of the MHK generator systems and its associated controls and inverters. ORPC will provide the generator, variable frequency drives (VFD), controls, and inverter for this testing. NREL will utilize the NREL Energy Systems Integration Facility (ESIF) and dynamometer facilities at the National Wind Technology Center (NWTC) for this work. Modification 6: Additionally, NREL will conduct a feasibility study for implementing passive DC rectification at the turbine.

17 WIND ENERGY↗

Active cooling requirements for propellant storage

Recent NASA and DOD mission models have indicated future needs for orbital cryogenic storage and supply systems. Two thermal control systems which show the greatest promise for improving propellant storage life were evaluated. One system was an open cycle thermodynamic vent type with a refrigeration system for partial hydrogen reliquefaction located at the LH2 tank and a vapor cooled shield for integrated and non-integrated tank designs to reduce boiloff. The other was a closed system with direct refrigeration at the LH2 tank. A reversed Brayton cycle unit was baselined for the propellant processor. It is concluded that: (1) reliquefaction systems are not attractive for minimizing propellant boiloff; (2) open cycle systems may not be economically attractive for long term storage; (3) a number of refrigeration systems are available to assist in the long term storage of cryogenic propellants; and (4) shields can significantly improve the performance of mechanical coolers.

Klein, G. A.↗

Filtering and Control of High Speed Motor Current in a Flywheel Energy Storage System

The NASA Glenn Research Center has been developing technology to enable the use of high speed flywheel energy storage units in future spacecraft for the last several years. An integral part of the flywheel unit is the three phase motor/generator that is used to accelerate and decelerate the flywheel. The motor/generator voltage is supplied from a pulse width modulated (PWM) inverter operating from a fixed DC voltage supply. The motor current is regulated through a closed loop current control that commands the necessary voltage from the inverter to achieve the desired current. The current regulation loop is the innermost control loop of the overall flywheel system and, as a result, must be fast and accurate over the entire operating speed range (20,000 to 60,000 rpm) of the flywheel. The voltage applied to the motor is a high frequency PWM version of the DC bus voltage that results in the commanded fundamental value plus higher order harmonics. Most of the harmonic content is at the switching frequency and above. The higher order harmonics cause a rapid change in voltage to be applied to the motor that can result in large voltage stresses across the motor windings. In addition, the high frequency content in the motor causes sensor noise in the magnetic bearings that leads to disturbances for the bearing control. To alleviate these problems, a filter is used to present a more sinusoidal voltage to the motor/generator. However, the filter adds additional dynamics and phase lag to the motor system that can interfere with the performance of the current regulator. This paper will discuss the tuning methodology and results for the motor/generator current regulator and the impact of the filter on the control. Results at speeds up to 50,000 rpm are presented.

Kenny, Barbara H.↗

Interoperable, Inverter-Based Distributed Energy Resources (DERs) Enable 100% Renewable and Resilient Utility Microgrids

Project overcomes frequency stability and system control issues when operating distribution microgrids in a low inertia, high PV penetration environment without fossil fuel generators. The team implemented a grid-forming inverter and advanced control features at SDG&E's Borrego Springs Microgrid to demonstrate islanding and blackstart using renewable resources. Simulation and emulation in advance of deployment de-risks field operations.

battery energy storage systems↗

Pumped Thermal Energy Storage With Liquid Storage

Pumped Thermal Energy Storage (PTES) uses electricity to power a heat pump; transferring heat from a cold space to a hot space forms a hot and a cold thermal reservoir, thereby storing energy. To discharge, the temperature difference between the two stores is used to drive a heat engine which generates electricity. In this chapter, PTES systems which store energy in liquids will be described. The chapter will concentrate on Joule-Brayton power cycles with molten salt storage. Part-load operation of Joule-Brayton PTES with liquid storage can be managed with "inventory control," and it is demonstrated that this control method leads to relatively good performance over a range of operating points.

Carnot batteries↗

Software defined grid energy storage

Today, consumer battery installations are isolated, physical devices. Virtual power plants (VPPs) allow consumer devices to aggregate for grid services, but they are are vertically integrated, vendor controlled systems (e.g., Tesla’s VPP). Consumer batteries are therefore unable to participate in energy markets or other grid services outside what their vendor provides. We describe a software system that provides software control of multiple, networked battery energy storage systems in the electric grid. The system introduces two new ideas that enable flexible and dependable management of energy storage. The first is a virtual battery, which can either partition a battery or aggregate multiple batteries. The second is a reservation-based API which allows asynchronous control of batteries to meet contractual guarantees in a safe and dependable manner. Virtual batteries and a reservation-based API address the unique challenges of achieving high and efficient utilization of energy storage systems, including heterogeneity of battery systems such as varying C-rates, participation in energy markets, utility bill management systems, community resource sharing, and reliability. Using a testbed comprised of sonnen Inc. storage units installed in several homes and a lab, we demonstrate that virtualized batteries can seamlessly replace physical batteries, flexibly manage energy storage resources, isolate multiple clients using a shared battery, and create new energy storage applications.

25 ENERGY STORAGE↗

CFD Modeling of the Multipurpose Hydrogen Test Bed (MHTB) Self-Pressurization and Spray Bar Mixing Experiments in Normal Gravity: Effect of Accommodation Coefficient on the Tank Pressure

In this paper, a computational model that describes pressure control phase of a typical MHTB experiment will be presented. The fidelity of the model will be assessed by comparing the models predictions with MHTB experimental data. In this paper CFD results for MHTB spray bar cooling case with 50 tank fill ratio will be presented and analyzed. Effect of accommodation coefficient for calculating droplet-ullage mass transfer will be evaluated.

cryogenic fluid storage↗

Cryogenic Fluid Management Technology Development Roadmaps

Advancement in Cryogenic Fluid Management (CFM) Technologies is essential for achieving NASA's future long duration missions. Propulsion systems utilizing cryogens are necessary to achieve mission success. Current State Of the Art (SOA) CFM technologies enable cryogenic propellants to be stored for several hours. However, some envisioned mission architectures require cryogens to be stored for two years or longer. The fundamental roles of CFM technologies are long term storage of cryogens, propellant tank pressure control and propellant delivery. In the presence of heat, the cryogens will "boil-off" over time resulting in excessive pressure buildup, off-nominal propellant conditions, and propellant loss. To achieve long term storage and tank pressure control, the CFM elements will intercept and/or remove any heat from the propulsion system. All functions are required to perform both with and without the presence of a gravitational field. Which CFM technologies are required is a function of the cryogens used, mission architecture, vehicle design and propellant tank size. To enable NASA's crewed mission to the Martian surface, a total of seventeen CFM technologies have been identified to support an In-Space Stage and a Lander/Ascent Vehicle. Recognizing that FY2020 includes a Decision Point regarding the In-Space Stage Architecture, a set of CFM Technology Development Roadmaps have been created identifying the current Technology Readiness Level (TRL) of each element, current technology "gaps", and existing technology development efforts. The roadmaps include a methodical approach and schedule to achieve a flight demonstration in FY2023, hence maturing CFM technologies to TRL 7 for infusion into the In-Space Stage Preliminary Design.

Stephens, J. R.↗

Singular perturbation techniques for on-line optimal flight path control

This paper presents a partial evaluation on the use of singular perturbation methods for developing computer algorithms for on-line optimal control of aircraft. The evaluation is based on a study of the minimum time intercept problem using F-4 aerodynamic and propulsion data as a base line. The extensions over previous work on this subject are that aircraft turning dynamics (in addition to position and energy dynamics) are included in the analysis, the algorithm is developed for a moving end point and is adaptive to unpredictable target maneuvers, and short range maneuvers that do not have a cruise leg are included. Particular attention is given to identifying those quantities that can be precomputed and stored (as a function of aircraft total energy), thus greatly reducing the onboard computational load. Numerical results are given that illustrate the nature of the optimal intercept flight paths, and an estimate is given for the execution time and storage requirements of the control algorithm.

Calise, A. J.↗

Control System Development for A Zero Boil-Off Hydrogen Storage Demonstration With Two-Stage Active Cooling

A NASA team is designing and building a test article to demonstrate the long duration storage of liquid hydrogen via active cooling (cryocoolers) while implementing a two-stage cooling approach. This activity is one of a large portfolio of NASA’s Space Technology Mission Directorate funded activities which focuses on the technology maturation needed for long duration storage of cryogenic liquid in-space. The current state-of-the-art for liquid hydrogen storage on-orbit is on the order of hours while NASA’s planned missions require storage for months, or even years. To enable such a long duration, Zero Boil-Off conditions must be achieved which requires passive technologies to minimize environmental heat loads, but also active cooling to intercept and reject the remaining heat to deep space. The implementation of active cooling results in a significant amount of dry mass added to the vehicle. Utilizing a Two-Stage Cooling approach, analysis and testing to date indicates the Zero Boil-Off of liquid hydrogen can be achieved with less mass and electrical power relative to a single-stage cooling approach where only one cryocooler is used. This activity will demonstrate the fully integrated suite of technologies needed to enable the Two-Stage Cooling approach which includes Multi-Layer Insulation blankets, Low Conductivity Structures, a Tube-On-Tank Heat Exchanger, Tube-On-Shield Heat Exchanger and a Two-Stage Cryogenerator (both 90 Kelvin and 20 Kelvin) with each stage having an independently controlled circulation loop. The bulk of the heat load is intercepted by the 90 Kelvin loop via a thin foil heat exchanger internal to the insulation blankets (also known as a Broad Area Cooling Shield), with the remainder removed at cryofluid temperature (20 Kelvin) by tubes directly welded to the outer tank surface. In this paper, we examine the challenges of controlling the system, and describe the development of control algorithms and software for future testing with liquid hydrogen. The interactions between the cryofans which control circulation loop mass flow rates, electrical heaters which vary the cryocooler lift to simulate the operation of variable-lift flight units, tank heaters which can vary the overall heat load, and the effects of changes in circulation loop pressure as temperatures change, can be complex and must be well understood to maintain steady-state propellant conditions and achieve Zero Boil-Off. Parallel PID loops and watchdog programs implemented on the user interface system will help bring the systems to steady state operation and keep them at selected operating points within acceptable error, while avoiding runaway feedback loops.

cryogenics↗

NASA's Cryogenic Fluid Management Technology Development Roadmaps

The maturation of Cryogenic Fluid Management (CFM) Technologies is essential for achieving NASA's future long duration missions. Propulsion systems utilizing cryogens are necessary to achieve NASA's exploration missions to the moon, Mars, and beyond. Current State Of the Art (SOA) CFM technologies enable cryogenic propellants to be stored for several hours prior to their use. However, some envisioned mission architectures require that cryogens to be stored for two years or longer. The fundamental roles of CFM technologies are long term storage of cryogens, propellant tank pressure control and propellant delivery. In the presence of heat, the cryogens will "boil-off" over time resulting in excessive pressure buildup, off-nominal propellant conditions for engine consumption, and propellant loss. To achieve long term storage and tank pressure control, the CFM elements will intercept and/or remove any heat from the propulsion system. All functions are required to be performed both with and without the presence of a gravitational field. Which CFM technologies are required is a function of the cryogens used, mission architecture, vehicle design and propellant tank size. To enable NASA's crewed missions beyond Low Earth Orbit, a total of twenty-seven CFM technologies have been identified to support various In-Space Stages and Lander/Ascent Vehicles. A set of CFM Technology Development Roadmaps have been created identifying the current Technology Readiness Level (TRL) of each element, current technology "gaps", and existing technology development efforts. The roadmaps include a methodical approach and schedule to achieve a flight demonstration, hence maturing CFM technologies to TRL 6/7 for infusion into the NASA's exploration elements. Additionally, a survey of the aerospace industry was completed to understand their views on the various technologies and how they would be infused. This does not cover all possible technologies, but rather those that are of interest to NASA specifically.

Cryogenic fluid management↗

ATS-6 - Flight performance of the Advanced Thermal Control Flight Experiment

The Advanced Thermal Control Flight Experiment on ATS-6 was designed to demonstrate the thermal control capability of a thermal diode (one-way) heat pipe, a phase-change material for thermal storage, and a feedback-controlled heat pipe. Flight data for the different operational modes are compared to ground test data, and the performance of the components is evaluated on an individual basis and as an integrated temperature-control system.

Kirkpatrick, J. P.↗

Use of Power Hardware-in-the-Loop and Controller Hardware-in-the-Loop to De-Risk the Use Of Grid-Forming Fuel Cell Inverters in Microgrids

Microgrids continue to proliferate, particularly those that rely on inverter-based resources as the microgrid's voltage and frequency leader. Hardware-in-the-loop simulations can de-risk microgrid deployments, and therefore we need power-hardware-in-the-loop (PHIL) interfaces for grid-forming (GFM) inverters to enable simulations of seamless transitions between islanded and grid-connected operation. Such interfaces are particularly challenging when the inverters need to switch modes, i.e., between grid-following (GFL) and GFM as the microgrid transitions between grid-connected and islanded operation. This presentation shows the use of PHIL interfaces for such microgrids and the preliminary experimental results.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Dynamics and controls working group summary

The technology status of the dynamics and controls discipline as it applies to energy storage wheel systems was evaluated. No problems were identified for which an adequate solution could not be proposed. Design issues that influence control were addressed. The dynamics and control aspects associated with the energy storage system concept and its various constituent parts, and the control tasks attendant to large, manned spacecraft are discussed.

Oglevie, R. E.↗

Energy performance of an operational government building retrofitted with ceiling phase change material tiles in a mixed-humid climate

The aging U.S. building stock requires various retrofit measures to enhance their energy efficiency. Here, this study explores the integration of thermal energy storage and advanced building controls as viable retrofit solutions for load flexibility and peak demand response while maintaining the occupants' comfort. A detailed assessment is conducted on the energy use of an administrative building in Sumner County, Kansas, focusing on the implementation of phase change materials (PCMs) in the ceiling of occupied zones. First, a time-resolved, whole-building energy model is developed in EnergyPlus, incorporating complex thermal behaviors such as air exchange between the plenum space and occupied zones, envelope leakage, and operational schedules. The model is then validated using experimental field test data, and subsequently a parametric assessment of key PCM properties and application strategies is performed to evaluate cooling electricity demand benefits. The parametric study shows that the optimal retrofit strategy, comprising a PCM with 23°C peak melting temperature, 0.125 in. (3.17 mm) thickness, and 150 kJ/kg latent heat, combined with active controls that include 8 h of precooling, forced convection under the ceiling, and a 2°C thermostat setback during peak hours, can result in a maximum load shift during the peak period of 99.6 % and the total electricity savings during the peak period of 98.9 % for the optimum case and thus provide significant cost savings under time-of-use pricing scenarios.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Electro-mechanical Modeling of Wind Turbine and Energy Storage Systems with Enhanced Inertial Response

In this paper, a coordinated control scheme for wind turbine generator (WTG) and supercapacitor energy storage system (ESS) is proposed for temporary frequency supports. Inertial control is designed by using generator torque limit considering the security of WTG system, while ESS releases its energy to compensate the sudden active power deficit during the recovery process of turbine rotor. WTG is modeled using the fatigue, aerodynamic, structure, turbulence (FAST) code, which identifies the mechanical loadings of the turbine and addresses electro-mechanical interactions in the wind energy system. A damping controller is augmented to the inertial control to suppress severe mechanical oscillations in the shaft and tower of the turbine during frequency supports. Furthermore, the result of small-signal stability analysis shows that the WTG-ESS tends to improve the stability of the whole multi-energy power grid. The major contributions of this paper will be validated by utilizing the proposed control method that combines the grid support capability and maintaining the integrity of structural design of the turbine for normal operations.

17 WIND ENERGY↗

Resolving dynamic mineral-organic interactions in the rhizosphere by combining in-situ microsensors with plant-soil reactive transport modeling

Associations between minerals and organic matter represent one of the most important carbon storage mechanisms in soils. Plant roots are major sources of soil carbon, and resolving the dynamics and dominance of microbial consumption versus mineral sorption of root-derived carbon is critical to understanding soil carbon storage. Here we integrate in-situ rhizosphere microsensor and plant physiological measurements with a 3-D plant-soil reactive transport model to explore the fate of dissolved organic carbon (DOC) in the rhizosphere, particularly its microbial consumption and interaction with Fe oxide minerals. Over several days, a microdialysis probe sampling pore water at the root-soil interface of growing Vicia faba roots in live soil, revealed clear diel patterns of DOC concentration. Daytime DOC spikes coincided with peaks in leaf-level photosynthesis rates and were accompanied by declining redox potential and dissolved oxygen as well as increasing pH in the rhizosphere. Incorporating microsensor data into our modeling framework showed that the measured rapid loss of DOC after each mid-day spike could not be explained by consumption via aerobic respiration, nor via anaerobic respiration dominated by Fe oxide reduction. Rather, in the model, a large fraction of rhizosphere DOC was rapidly immobilized each day by adsorption to Fe oxides. Further, modeled microbial Fe reduction (fueled by DOC) did not mobilize significant organic carbon from Fe oxides during the day. Instead, the model predicted equilibrium desorption of organic carbon from Fe oxides at night. This new mechanistic modeling framework, which couples aboveground plant physiological measurements with non-destructive high-resolution monitoring of rhizosphere processes, has great potential for exploring the dynamics and balance of the various microbial reactions and mineral interactions controlling carbon transformations and storage in soils.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗