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All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Spectra of cosmic X-ray sources

X-ray measurements provide the most direct probes of astrophysical environments with temperatures exceeding one million K. Progress in experimental research utilizing dispersive techniques (e.g., Bragg and grating spectroscopy) is considerably slower than that in areas utilizing photometric techniques, because of the relative inefficiency of the former for the weak X-ray signals from celestial sources. As a result, the term "spectroscopy" as applied to X-ray astronomy has traditionally satisfied a much less restrictive definition (in terms of resolving power) than it has in other wavebands. Until quite recently, resolving powers of order unity were perfectly respectable, and still provide (in most cases) the most useful spectroscopic data. In the broadest sense, X-ray photometric measurements are spectroscopic, insofar as they represent samples of the overall electromagnetic continua of celestial objects.

Holt, S. S.↗
NASA NTRS2001

Deuterium and Oxygen Toward Feige 110: Results from the Far Ultraviolet Spectroscopic Explorer (FUSE) Mission

We present measurements of the column densities of interstellar D I and O I made with the Far Ultraviolet Spectroscopic Explorer (FUSE), and of H I made with the International Ultraviolet Explorer (IUE) toward the sdOB star Feige 110 [(l,b) = (74.09 deg., - 59.07 deg.); d = 179(sup +265, sub -67) pc; Z = -154(sup +57, Sub -227 pc). Our determination of the D I column density made use of curve of growth fitting and profile fitting analyses, while our O I column density determination used only curve of growth techniques. The H I column density was estimated by fitting the damping wings of the interstellar Ly(lpha) profile. We find log N(D I) = 15.47 +/- 0.06, log N(O I) = 16.73 +/- 0.10, and log N(H I) = 20.14(sup +0.13, sub -0.20) (all errors 2(sigma)). This implies D/H = (2.14 +/- 0.82) x 10(esp -5), D/O = (5.50(sup + 1.64, sub -133)) x 10(exp -2), and O/H = (3.89 +/- 1.67) x 10(exp -4). Taken with the FUSE results reported in companion papers and previous measurements of the local interstellar medium, this suggests the possibility of spatial variability in D/H for sight lines exceeding approx. 100 pc. This result may constrain models which characterize the mixing time and length scales of material in the local interstellar medium.

Friedman, S. D.↗
NASA NTRS2003

Impact of low-temperature plasmas on Deinococcus radiodurans and biomolecules

The effects of cold plasma on Deinococcus radiodurans, plasmid DNA, and model proteins were assessed using microbiological, spectrometric, and biochemical techniques. In low power O(2) plasma (approximately 25 W, approximately 45 mTorr, 90 min), D. radiodurans, a radiation-resistant bacterium, showed a 99.999% reduction in bioburden. In higher power O(2) plasma (100 W and 500 mTorr), the reduction rate increased about 10-fold and observation by atomic force microscopy showed significant damage to the cell. Damage to cellular lipids, proteins, and chromosome was indicated by losses of infrared spectroscopic peaks at 2930, 1651, 1538, and 1245 cm(-1), respectively. In vitro experiments show that O(2) plasmas induce DNA strand scissions and cross-linking as well as reduction of enzyme activity. The observed degradation and removal of biomolecules was power-dependent. Exposures to 200 W at 500 mTorr removed biomolecules to below detection limits in 60 s. Emission spectroscopy indicated that D. radiodurans cells were volatilized into CO(2), CO, N(2), and H(2)O, confirming that these plasmas were removing complex biological matter from surfaces. A CO(2) plasma was not as effective as the O(2) plasma, indicating the importance of plasma composition and the dominant role of chemical degradation. Together, these findings have implications for NASA planetary protection schemes and for the contamination of Mars.

Evaluation Studies↗
NASA NTRS2004

A Rigorous Attempt to Verify Interstellar Glycine

In 2003, Kuan, Charnley, and co-workers reported the detection of interstellar glycine (NH2CH2COOH) based on observations of 27 lines in 19 different spectral bands in one or more of the sources Sgr BP(N-LMH), Orion KL, and W51 e1/e2. They supported their detection report with rotational temperature diagrams for all three sources. In this paper, we present essential criteria which can be used in a straightforward analysis technique to confirm the identity of an interstellar asymmetric rotor such as glycine. We use new laboratory measurements of glycine as a basis for applying this analysis technique, both to our previously unpublished 12 m telescope data and to the previously published SEST data of Nummelin and colleagues. We conclude that key lines necessary for an interstellar glycine identification have not yet been found. We identify several common molecular candidates that should be examined further as more likely carriers of the lines reported as glycine. Finally, we illustrate that rotational temperature diagrams used without the support of correct spectroscopic assignments are not a reliable tool for the identification of interstellar molecules. Subject headings: ISM: abundances - ISM: clouds - ISM: individual (Sagittarius B2[N-

Snyder, L. E.↗
NASA NTRS1980

Resonant Doppler velocimeter

A technique is presented for visualizing and quantitatively measuring velocity, temperature, and pressure by shining a single frequency laser beam into a gaseous flow which is seeded with an atomic species. The laser is tuned through the absorption frequencies of the seeded species and the absorption profile is detected by observing fluorescence as the atoms relax back to the ground state. The flow velocity is determined by observing the Doppler shift in the absorption frequency. Spectroscopic absorption line broadening mechanisms furnish information regarding the static temperature and pressure of the moving gas. Results of experiments conducted in the free stream and in the bow shock of a conical model mounted in a hypersonic wind tunnel indicate that the experimental uncertainties in the measurement of average values for the velocity, temperature and pressure of the flow are 0.1, 5 and 10 percent respectively.

Zimmermann, M.↗
NASA NTRS1985

EBIC spectroscopy - A new approach to microscale characterization of deep levels in semi-insulating GaAs

The microscale characterization of electronic defects in (SI) GaAs has been a challenging issue in connection with materials problems encountered in GaAs IC technology. The main obstacle which limits the applicability of high resolution electron beam methods such as Electron Beam-Induced Current (EBIC) and cathodoluminescence (CL) is the low concentration of free carriers in semiinsulating (SI) GaAs. The present paper provides a new photo-EBIC characterization approach which combines the spectroscopic advantages of optical methods with the high spatial resolution and scanning capability of EBIC. A scanning electron microscope modified for electronic characterization studies is shown schematically. The instrument can operate in the standard SEM mode, in the EBIC modes (including photo-EBIC and thermally stimulated EBIC /TS-EBIC/), and in the cathodo-luminescence (CL) and scanning modes. Attention is given to the use of CL, Photo-EBIC, and TS-EBIC techniques.

Li, C.-J.↗
NASA NTRS1985

Magnetic canopies and models of the solar chromosphere

Magnetic canopies are the topologies formed by magnetic field lines as they spread from compact, nearly vertical concentrations of flux in the low photosphere into the large-scale organization of the corona and heliosphere. Analytical techniques for inferring the base-heights of canopies from magnetographic data are reviewed together with observational evidence that much of the sun is covered by canopies which lie two or more pressure scale heights below the level which is traditionally inferred from thin flux tube models. Implications of these results for modeling the structure and energetics of the chromosphere are discussed, and it is argued that future models should be based upon both spectroscopic and polarimetric data. Recent improvements in magnetostatic model atmospheres are reviewed, and new observational data, including C IV Doppler-grams from the Ultraviolet Spectrometer and Polarimeter on the Solar Maximum Mission, are considered. Directions for future research in MHD modeling of canopies, in simulating spectrographic and polarimetric data from such models, and in observational programs are discussed.

Jones, H. P.↗
NASA NTRS1990

Probing the tides in interacting galaxy pairs

Detailed spectroscopic and imaging observations of colliding elliptical galaxies revealed unmistakable diagnostic signatures of the tidal interactions. It is possible to compare both the distorted luminosity distributions and the disturbed internal rotation profiles with numerical simulations in order to model the strength of the tidal gravitational field acting within a given pair of galaxies. Using the best-fit numerical model, one can then measure directly the mass of a specific interacting binary system. This technique applies to individual pairs and therefore complements the classical methods of measuring the masses of galaxy pairs in well-defined statistical samples. The 'personalized' modeling of galaxy pairs also permits the derivation of each binary's orbit, spatial orientation, and interaction timescale. Similarly, one can probe the tides in less-detailed observations of disturbed galaxies in order to estimate some of the physical parameters for larger samples of interacting galaxy pairs. These parameters are useful inputs to the more universal problems of (1) the galaxy merger rate, (2) the strength and duration of the driving forces behind tidally stimulated phenomena (e.g., starbursts and maybe quasi steller objects), and (3) the identification of long-lived signatures of interaction/merger events.

Borne, Kirk D.↗
NASA NTRS1973

Laser radar studies: A study of the feasibility of remote measurement of atmospheric density and turbidity by means of rotational Raman scattering of laser light

A remote sensing technique is described which utilizes elastic scattering and rotational Raman scattering of laser light in the atmosphere to obtain soundings of turbidity, transmissivity and density. A scheme is devised whereby, through selective weighting of the rotational Raman lines, the effect of atmospheric temperature structure may be eliminated. The close spectral proximity of the elastic and Raman-scattered signals, combined with the fact that the Raman scattering is quite weak, produces special requirements for the spectroscopic and light-gathering components of a rotational Raman laser radar system. These requirements are investigated. A computation of typical signal-to-noise ratios is made. It is shown that daytime signal-to-noise ratios greater than 10 db are to be expected for observation heights of 5 km and below. For nighttime work, 10 db signal-to-noise ratios are achievable to altitudes as high as 15 km.

Reiss, N.↗
NASA NTRS1994

A deep imaging survey of the Pleiades with ROSAT

We have obtained deep ROSAT images of three regions within the Pleiades open cluster. We have detected 317 X-ray sources in these ROSAT Position Sensitive Proportional Counter (PSPC) images, 171 of which we associate with certain or probable members of the Pleiades cluster. We detect nearly all Pleiades members with spectral types later than G0 and within 25 arcminutes of our three field centers where our sensitivity is highest. This has allowed us to derive for the first time the luminosity function for the G, K, amd M dwarfs of an open cluster without the need to use statistical techniques to account for the presence of upper limits in the data sample. Because of our high X-ray detection frequency down to the faint limit of the optical catalog, we suspect that some of our unidentified X-ray sources are previously unknown, very low-mass members of Pleiades. A large fraction of the Pleiades members detected with ROSAT have published rotational velocities. Plots of L(sub X)/L(sub Bol) versus spectroscopic rotational velocity show tightly correlated `saturation' type relations for stars with ((B - V)(sub 0)) greater than or equal to 0.60. For each of several color ranges, X-ray luminosities rise rapidly with increasing rotation rate until c sin i approximately equal to 15 km/sec, and then remains essentially flat for rotation rates up to at least v sin i approximately equal to 100 km/sec. The dispersion in rotation among low-mass stars in the Pleiades is by far the dominant contributor to the dispersion in L(sub X) at a given mass. Only about 35% of the B, A, and early F stars in the Pleiades are detected as X-ray sources in our survey. There is no correlation between X-ray flux and rotation for these stars. The X-ray luminosity function for the early-type Pleiades stars appears to be bimodal -- with only a few exceptions, we either detect these stars at fluxes in the range found for low-mass stars or we derive X-ray limits below the level found for most Pleiades dwarfs. The X-ray spectra for the early-type Pleiades stars detected by ROSAT are indistinguishable from the spectra of the low-mass Pleiades members. We believe that the simplest explanation for this behavior is that the early-type Pleiades stars are not themselves intrinsic X-ray sources and that the X-ray emission actually arises from low-mass companions to these stars.

Stauffer, J. R.↗
NASA NTRS1959

Global Aspects of the Exploration of Space

The interest of man in outer space began long ago among uncivilized peoples to whom the face of the sky was clock and almanac; the celestial bodies, objects of worship. Exploration was at first by visual observation, later aided by armillary spheres and quadrants, and still later by more precise measuring instruments, telescopes, and spectroscopes. The information obtained was that borne by the light that was transmitted from the distant celestial object through the atmosphere to the observing instrument on the ground. In recent years the light waves have been supplemented by radio waves as carriers of information from the stars and planets. Men of many nations have contributed through the centuries to the exploration of space by the methods of astronomy. The history of advances in astronomical knowledge and technique includes the records of Chinese, Babylonians, Greeks, Arabians, and of nearly every nation of the modern world. International cooperation was early recognized as essential and beneficial; the countless number of the stars and the vastness of space present mankind with a truly global task. The picture of the universe obtained by the astronomers early stirred the imagination of men to speculate about the existence of life elsewhere in the universe, about means of communication with distant stars, and in the last centuries about the possibility of the travel of man to the moon and planets. Some sought to apply the science and engineering of their day to describe the vehicles to be used. For example, Jules Verne published in 1865 in "From the Earth to the Moon" a description of a gun-launched projectile carrying passengers to orbit the moon. Today we have taken the first steps to bring this inspired vision to reality. The exploration of space by unmanned vehicles carrying scientific apparatus began on October 4, 1957; exploration by man will follow in due course.

Dryden, Hugh L.↗
NASA NTRS1990

Methane overtone absorption by intracavity laser spectroscopy

Interpretation of planetary methane (CH4) visible-near IR spectra, used to develop models of planetary atmospheres, has been hampered by a lack of suitable laboratory spectroscopic data. The particular CH4 spectral bands are due to intrinsically weak, high overtone-combination transitions too complex for classical spectroscopic analysis. The traditional multipass cell approach to measuring spectra of weakly absorbing species is insufficiently sensitive to yield reliable results for some of the weakest CH4 absorption features and is difficult to apply at the temperatures of the planetary environments. A time modulated form of intracavity laser spectroscopy (ILS), has been shown to provide effective absorption pathlengths of 100 to 200 km with sample cells less than 1 m long. The optical physics governing this technique and the experimental parameters important for obtaining reliable, quantitative results are now well understood. Quantitative data for CH4 absorption obtained by ILS have been reported recently. Illustrative ILS data for CH4 absorption in the 619.7 nm and 681.9 nm bands are presented. New ILS facilities at UM-St. Louis will be used to measure CH4 absorption in the 700 to 1000 nm region under conditions appropriate to the planetary atmospheres.

Obrien, James J.↗
NASA NTRS1993

A deep x-ray survey of the Pleiades cluster and the B6-A3 main sequence stars in Orion

We have obtained deep ROSAT images of three regions within the Pleiades open cluster. We have detected 317 X-ray sources in these ROSAT PSPC images, 171 of which we associate with certain probable members of the Pleiades cluster. We detect nearly all Pleiades members with spectral types later than G0 and within 25 arcminutes of our three field centers where our sensitivity is highest. This has allowed us to derive for the first time the luminosity function for the G, K, and M dwarfs of an open cluster without the need to use statistical techniques to account for the presence of upper limits in the data sample. Because of our high X-ray detection frequency down to the faint limit of the optical catalog, we suspect that some of our unidentified X-ray sources are previously unknown, very low-mass members of the Pleiades. A large fraction of the Pleiades members detected with ROSAT have published rotational velocities. Plots of L(sub x)/L(sub bol) versus spectroscopic rotational velocity show tightly correlated 'saturation' type relations for stars with (B - V)(sub O) greater than 0.60. For each of several color ranges, X-ray luminosities rise rapidly with increasing rotation rate until v sin i approximately equals 15 km/s, and then remain essentially flat for rotation rates up to at least v sin i approximately equal to 100 km/s. The dispersion in rotation among low-mass stars in the Pleiades is by far the dominant contributor to the dispersion in L(subx) at a given mass. Only about 35 percent of the B.A. and early F stars in the Pleiades are detected as X-ray sources in our survey. There is no correlation between X-ray flux and rotation for these stars. The X-ray luminosity function for the early-type Pleiades stars appears to be bimodal, with only a few exceptions. We either detect these stars at fluxes in the range found for low-mass stars or we derive X-ray limits below the level found for most Pleiades dwarfs. The X-ray spectra for the early-type Pleiades stars detected by ROSAT are indistinguishable from the spectra of the low-mass Pleiades members. We believe that the simple explanation for this behavior is that the early-type Pleiades stars are not themselves intrinsic X-ray sources and that the X-ray sources and that the X-ray emission actually arises from low-mass companions to these stars.

Caillault, Jean-Pierre↗
NASA NTRS2020

Thermal Decomposition of the Murchison CM2 Carbonaceous Chondrite: Implications of Space Weathering Processes for Sample Return Missions

Primitive carbonaceous asteroids are the target bodies for the JAXA Hayabusa2 mission to Ryugu and the NASA OSIRIS-REx mission to Bennu. Both asteroids share spectral characteristics of CI/CM type carbonaceous chondrites. Ryugu, in particular, appears to have undergone thermal processing that has modified its spectral properties. The nature and extent of space weathering processes on the surfaces of Bennu and Ryugu are under active investigation using remote sensing data from the missions [4] and through laboratory studies on analog materials. The analog studies are needed in order to understand the mineralogical and chemical changes that occur in space weathered samples that give rise to the observed optical effects measured by remote-sensing and to prepare for the analysis of returned samples. The space weathering effects of micrometeorite impact and solar wind irradiation on primitive carbonaceous chondrites have been simulated by analog studies on the Murchison CM2 chondrite. We performed a coordinated mineralogical, chemical and spectroscopic study to examine in detail the effects of thermal metamorphism on Murchison samples as an analog to processes that may have occurred on Ryugu. The bulk measurements including X-ray diffraction (XRD), Mössbauer spectroscopy, UV-VIS-NIR spectroscopy, thermogravimetric analysis, and evolved gas analysis are reported in a companion paper. Here we report on our preliminary nanoscale mineralogical and chemical analyses of pre- and post-heated Murchison samples using multiple electron beam techniques to understand how the mineralogical, chemical, and physical characteristics of carbonaceous chondrites change with increasing thermal effects.

Lee, S.↗
NASA NTRS1991

FTIR Spectroscopic Characterization Of II-VI Semiconductors

Combination of commercial Fourier-transform infrared (FTIR) spectrometer with computer and special-purpose software constitutes highly automated facility for acquisition and processing of infrared transmission or reflection spectral image data. Intended principally to acquire transmission spectra of some compounds of elements in groups II and VI of periodic table. System used to characterize specimens of II/VI alloy semiconductors grown by directional solidification and quenching. Transmission-edge maps helpful in studies of flows, gradients of temperature, and coefficients of diffusion in solidifying melts. Data acquired by system include optical characteristics, and they both verify and complement data obtained by such other techniques as measurements of density and x-ray-dispersion analysis.

Perry, G. L. E.↗
NASA NTRS2002

Interstellar Deuterium, Nitrogen and Oxygen Abundances Toward BD+28(deg) 4211: Results from the Far Ultraviolet Spectroscopic Explorer

High resolution far-ultraviolet spectra of the O-type subdwarf BD+28(deg)4211 were obtained with the Far Ultraviolet Spectroscopic Explorer to measure the interstellar deuterium, nitrogen, and oxygen abundances in this direction. The interstellar D(I) transitions are analyzed down to Ly(ioat) at 920.7 A. The star was observed several times at different target offsets in the direction of spectral dispersion. The aligned and coedited spectra have high signal-to-noise ratios (S/N=50-100). D(I), N(I), and O(I) transitions were analyzed with curve-of-growth and profile fitting techniques. A model of interstellar molecular hydrogen on the line of sight was derived from H(II) lines in the FUSE spectra and used to help analyze some features where blending with H(II) was significant. The H(I) column density was determined from high resolution HST/STIS spectra of Ly(alpha) to be log N(H(I))= 19.846+/-0.035(2sigma), which is higher than is typical for sight lines in the local ISM studied for D/H. We found that D/H=(1.39+/-0.21)x 10(exp -5)(2sigma) and O/H=(2.37+/-0.55)x10(exp -4)(2sigma). O/H toward BD+28(deg)4211 appears to be significantly below the mean O/H ratio for the ISM and the Local Bubble.

Sonneborn, George↗
NASA NTRS2007

Decontamination of Genesis Array Materials by UV Ozone Cleaning

Shortly after the NASA Genesis Mission sample return capsule returned to earth on September 8, 2004, the science team discovered that all nine ultra-pure semiconductor materials were contaminated with a thin molecular organic film approximately 0 to 100 angstroms thick. The organic contaminate layer, possibly a silicone, situated on the surface of the materials is speculated to have formed by condensation of organic matter from spacecraft off-gassing at the Lagrange 1 halo orbit during times of solar exposure. While the valuable solar wind atoms are safely secured directly below this organic contamination and/or native oxide layer in approximately the first 1000 angstroms of the ultra-pure material substrate, some analytical techniques that precisely measure solar wind elemental abundances require the removal of this organic contaminate. In 2005, Genesis science team laboratories began to develop various methods for removing the organic thin film without removing the precious material substrate that contained the solar wind atoms. Stephen Sestak and colleagues at Open University first experimented with ultraviolet radiation ozone (UV/O3) cleaning of several non-flight and flown Genesis silicon wafer fragments under a pure flowing oxygen environment. The UV/O3 technique was able to successfully remove organic contamination without etching into the bulk material substrate. At NASA Johnson Space Center Genesis Curation Laboratory, we have installed an UV/O3 cleaning devise in an ambient air environment to further experimentally test the removal of the organic contamination on Genesis wafer materials. Preliminary results from XPS analysis show that the UV/O3 cleaning instrument is a good non-destructive method for removing carbon contamination from flown Genesis array samples. However, spectroscopic ellipsometry results show little change in the thickness of the surface film. All experiments to date have shown UV/O3 cleaning method to be the best non-destructive method for removing organic contamination from the surface of the Genesis materials. The UV/O3 cleaning process can also clean carbon contamination to levels below non-flight standards. This can be seen by comparing sample 60260's carbon 10667 cps with non-flight Si carbon 21675 cps. Therefore, surface carbon contamination should not hinder the analysis of solar wind.

Calaway, Michael J.↗
NASA NTRS2012

Near-Infrared (NIR) Raman Spectroscopy of Precambrian Carbonate Stromatolites with Post-Depositional Organic Inclusions

Raman spectroscopy has promising potential for future Mars missions as a non-contact detection technique for characterizing organic material and mineralogy. Such a capability will be useful for selecting samples for detailed analysis on a rover and for selecting samples for return to Earth. Stromatolites are important evidence for the earliest life on Earth and are promising targets for Mars investigations. Although constructed by microorganisms, stromatolites are organo-sedimentary structures that can be large enough to be discovered and investigated by a Mars rover. In this paper, we report the Raman spectroscopic investigations of the carbonate mineralogy and organic layering in a Precambrian (;1.5 Gyr old) stromatolite from the Crystal Spring Formation of Southern California. Ultraviolet (UV: 266 nm), visible (514 nm, 633 nm), and near-infrared (NIR: 785 nm, 1064 nm) Raman spectra are presented. We conclude that 1064 nm excitation is the optimal excitation wavelength for avoiding intrinsic fluorescence and detecting organic carbon within the carbonate matrix. Our results confirm that NIR Raman spectroscopy has important applications for future Mars missions.

Tanaka, Zuki↗