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At least 505 records · Page 28

On the Capabilities of Using AIRSAR Data in Surface Energy/Water Balance Studies

The capabilities of using remote sensing data, and in particular multifrequency/multipolarization SAR data, like AIRSAR, for the retrieval of surface parameters, depend considerably on the specificity of each application. The potentials, and limitations, of SAR data in ecological investigations are well known. Because the chemistry is a major component in such studies and because of the almost lacking chemical information at the wavelengths of SAR data, the capabilities of using SAR-derived information in such studies are considerably limited. However, in the case of surface energy/water balance studies, the determination of the amount of water content, both in the soil and in the plants, is a major component in all modeling approaches. As the information about water content is present in the SAR signal, then the role of SAR data in studies where water content is to be determined becomes clearly predominant. Another situation where the role of SAR data becomes dominant over other remote sensing systems is the case of dense canopies. Because of the penetration capabilities of microwave data, which is especially superior as compared to optical data, information about the canopy as a whole and even the underlying soil is contained in the SAR data, while only the top canopy provides the information content in the case of optical data. In the case of relatively dense canopies, as has been demonstrated in this study, such different penetration capabilities provide very different results in terms of the derived total canopy water content, for instance. However, although all such capabilities are well known, unfortunately there are also well known limitations. Apart from calibration-related aspects (that we will not consider in this study), and apart from other intrinsic problems (like image noise, topographic corrections, etc.) which also significantly affect the derived results, we will concentrate on the problem of extracting information from the data. Even at this level, methods are still not fully well established, especially over vegetation-covered areas. In this paper, an algorithm is described which allows derivation of three fundamental parameters from SAR data: soil moisture, soil roughness and canopy water content, accounting for the effects of vegetation cover by using optical (Landsat) data as auxiliary. Capabilities and limitations of the data and algorithms are discussed, as well as possibilities to use these data in energy/water balance modeling studies. All the data used in this study were acquired as part of the Intensive Observation Period in June-July 1991 (European Multisensor Aircraft Campaign-91), as part of the European Field Experiment in a Desertification- threatened Area (EFEDA), a European contribution to the global-change research sponsored by the IGBP program (Bolle et al., 1993).

Moreno, Jose F.↗

Alpha Spectrometry Results for Groundwater Samples Collected in Northern Iraq and a Summary of the Environmental Setting of the Adaya Burial Site

The Radiation Protection Center (RPC) of the Iraqi Ministry of Environment continues to evaluate the potential health impacts associated with the Adaya Burial Site, which is located 33 kilometers (20.5 miles) southwest of Mosul. This report documents the radiological analyses of 16 groundwater samples collected from wells located in the vicinity of the Adaya Burial Site and at other sites in northern Iraq. The Adaya Burial Site is a high-risk dump site because a large volume of radioactive material and contaminated soil is located on an unsecure hillside above the village of Tall ar Ragrag. The uranium activities for the 16 water samples in northern Iraq are considered to be naturally occurring and do not indicate artificial (man-made) contamination. With one exception, the alpha spectrometry results for the 16 wells that were sampled in 2019 indicate that the water quality concerning the three uranium isotopes (Uranium-233/234, Uranium-235/236, and Uranium-238) was acceptable for potable purposes (drinking and cooking). However, Well 7 in Mosul had a Uranium-233/234 activity concentration that slightly exceeded the World Health Organization guidance level. Eight of the 16 wells are located in the villages of Tall ar Ragrag and Adaya and had naturally occurring uranium concentrations. Wells in the villages of Tall ar Ragrag and Adaya are located near the Adaya Burial Site and should be sampled on an annual schedule. The list of groundwater analytes should include metals, total uranium, isotopic uranium, gross alpha/beta, gamma spectroscopy, organic compounds, and standard water quality parameters. Our current understanding of the hydrogeologic setting in the vicinity of the Adaya Burial Site is solely based on villager's domestic wells, topographic maps, and satellite imagery. To better understand the hydrogeologic setting, a Groundwater Monitoring Program needs to be developed and should include the installation of twelve groundwater monitoring wells in the vicinity of Tall ar Ragrag and the Adaya Burial Site. Characterization of the limestone aquifer and overlying alluvium is needed. RPC should continue to support health assessments for the villagers in Tall ar Ragrag and Adaya. Collecting samples for surface water (storm water), airborne dust, vegetation, and washway sediment should be conducted on a routine basis. Human access to the Adaya Burial Site needs to be strictly limited. Livestock access on or near the burial site needs to be eliminated. The surface-water exposure pathway is likely a greater threat than the groundwater exposure pathway. Installation of a surface-water diversion or collection system is recommended in order to reduce the potential for humans and livestock to come in contact with contaminated water and sediment. To reduce exposure to villagers, groundwater treatment should be considered if elevated uranium or other contaminants are detected in drinking water. Installing water-treatment systems would likely be quicker to accomplish than remediation and excavation of the Adaya Burial Site. The known potential for human exposure to uranium and metals (such as arsenic, chromium, selenium, and strontium) at the Adaya Burial Site is serious. Additional characterization , mitigation, and remediation efforts should be given a high priority.

54 ENVIRONMENTAL SCIENCES↗

Vadose zone flushing of fertilizer tracked by isotopes of water and nitrate

Abstract A substantial fraction of nitrogen (N) fertilizer applied in agricultural systems is not incorporated into crops and moves below the rooting zone as nitrate (NO 3 − ). Understanding mechanisms for soil N retention below the rooting zone and leaching to groundwater is essential for our ability to track the fate of added N. We used dual stable isotopes of nitrate (δ 15 N–NO 3 − and δ 18 O–NO 3 − ) and water (δ 18 O–H 2 O and δ 2 H–H 2 O) to understand the mechanisms driving nitrate leaching at three depths (0.8, 1.5, and 3.0 m) of an irrigated corn field sampled every 2 weeks from 2016 to 2020 in the southern Willamette Valley, Oregon, USA. Distinct periods of high nitrate concentrations with lower δ 15 N–NO 3 − values indicated that a portion of that nitrate was from recent fertilizer applications. We used a mixing model to quantify nitrate fluxes associated with recently added fertilizer N versus older, legacy soil N during these “fertilizer signal periods.” Nitrate leached below 3.0 m in these periods made up a larger proportion of the total N leached at that depth (∼52%) versus the two shallower depths (∼13%–16%), indicating preferential movement of recently applied fertilizer N through the deep soil into groundwater. Further, N associated with recent fertilizer additions leached more easily when compared to remobilized legacy N. A high volume of fall and winter precipitation may push residual fertilizer N to depth, potentially posing a larger threat to groundwater than legacy N. Optimizing fertilizer N additions could minimize fertilizer losses and reduce nitrate leaching to groundwater.

Agriculture↗

Could the 2012 Drought in Central U.S. Have Been Anticipated? A Review of NASA Working Group Research

This paper summarizes research related to the 2012 record drought in the central United States conducted by members of the NASA Energy and Water cycle Study (NEWS) Working Group. Past drought patterns were analyzed for signal coherency with latest drought and the contribution of long-term trends in the Great Plains low-level jet, an important regional circulation feature of the spring rainy season in the Great Palins. Long-term changes in the seasonal transition from rainy spring into dry summer were also examined. Potential external forcing from radiative processes, soil-air interactions, and ocean teleconnections were assessed as contributors to the intensity of the drought. The atmospheric Rossby wave activity was found to be a potential source of predictability for the onset of drought. A probabilistic model was introduced and evaluated for its performance in predicting drought recovery in the Great Plains.

Drought 2012↗

Miscanthus: An Environmental Choice for Marginal Lands

Miscanthus x giganteus, or Giant Miscanthus, is a tall, perennial grass originally from Asia. It is considered a sterile hybrid that has been bred to not produce viable seeds. Instead, rhizomes are planted to establish the crop. Here, the rhizome is an underground modified stem mass that puts out shoots and roots supporting new growth each year. This perennial crop takes two to three years to reach maturity, but established stands can reach upwards of 12 ft. tall with a very thick canopy (Pyter, 2007). Miscanthus has shown potential for high dry matter yields compared to other biomass crops, which could in turn lead to more efficient land use especially when applied to a bioenergy and bioproduct supply chain. In one study, switchgrass (Panicum virgatum) yielded 10.3 Mg/ha of biomass on average, while miscanthus yielded 22.4 Mg/ha (Heaton et al., 2004). Additionally, miscanthus production has been associated with many environmental benefits, including benefits to water quality, nutrient load removal, soil stabilization, and soil health (Bhardwaj et al., 2011; Hussain et al., 2019). Many of the possible practical and environmental benefits that are associated with miscanthus production may be attractive to stakeholders who are interested in alternative land use options, particularly in areas considered to be marginal in productivity.

54 ENVIRONMENTAL SCIENCES↗

Contaminant Transport Modeling for Technology Evaluation and Long-Term Monitoring in the Tims Branch Testbed, SC - 20343

Studies conducted at U.S. DOE sites have shown the presence of heavy metals, radionuclides, and volatile organic compounds in surface water, groundwater, and soil as a result of nuclear activity in the Cold War era. Since the 1990's, innovative cleanup methods have been implemented in the Tims Branch watershed at Savannah River Site (SRS) to limit the contaminant flux to the stream that have reduced the contaminant concentrations to acceptable regulatory levels in the dissolved phase. A tin-based treatment which effectively eliminated all local anthropogenic mercury inputs to this ecosystem resulted in a known step function addition of inert tin oxide particles which now serve as a potential tracer for sedimentation and particle transport processes in the stream. The long-term effectiveness of this and other remediation techniques and the potential for remobilization of adsorbed contaminant in sediment during extreme hydrologic conditions however remains unclear. It is therefore important to understand not only the fate and transport of dissolved contaminants, but also the movement of sediment and the relevant interactions with dissolved contaminant. To narrow this knowledge gap, a study is being conducted using the Tims Branch watershed as a stream-scale ecosystem test-bed to identify the primary transport processes of major contaminants of concern (such as mercury, nickel and uranium) with an emphasis on interactions with sediment transport. This involves the development of a fully distributed hydrologic watershed model of the Tims Branch watershed to predict streamflow under extreme weather conditions, as well as the development of a comprehensive contaminant transport model that can properly account for coupled contaminant and sediment transport. Review of relevant research reports and peer-reviewed journals revealed that aside from advection-dispersion transport of dissolved contaminants, adsorption and desorption with suspended solids and bed sediment also play an important role in the transport of those contaminants of concern. To develop the fully distributed hydrologic watershed model, the MIKE SHE 2-dimensional (2D) land surface/3D groundwater model that simulates surface/subsurface hydrologic processes (such as overland flow, evapotranspiration, and infiltration) was coupled with a 1D streamflow model that accounts for stream water hydraulics (such as hydraulic structures, cross-sections, and network). To model contaminant transport, the MIKE 11 streamflow component was coupled with the MIKE 11 AD module that simulates solute transport through advection and dispersion, and MIKE ECO Lab module that accounts for both sediment transport and interactions with dissolved contaminant. At this stage, the development and optimization of the fully distributed hydrologic model has been completed, achieving satisfactory statistical results between observed and predicted discharge as indicated by a root mean square error (RMSE) of 0.039 cms and a Nash-Sutcliffe efficiency coefficient (NSE) of 0.764. The ongoing development of the contaminant transport model has also yielded realistic results from preliminary tests. Results from this study are a key to evaluating the effectiveness of tin (II)-based mercury treatment of wetlands at the SRS site, and are also relevant to evaluating the potential of using this type of novel remediation technology in other mercury-contaminated stream systems. Knowledge acquired from this research will also support interpretation of historical data on the trends of contaminant concentration distribution in Tims Branch, particularly considering the effect of extreme hydrological events on the stream flow and pollutant transport. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Climate Warming Alters Nutrient Storage in Seasonally Dry Forests: Insights From a 2,300 m Elevation Gradient

Understanding potential response of forest carbon (C) and nutrient storage to warming is important for climate mitigation policies. Unfortunately, those responses are difficult to predict in seasonally dry forests, in part, because ecosystem processes are highly sensitive to both changes in temperature and precipitation. We investigated how warming might alter stocks of C, nitrogen (N), and phosphorus (P) in vegetation and the entire regolith (soil + weathered bedrock or “saprock”) using a space-for-time substitution along a bioclimatic gradient in the Sierra Nevada, California. The pine-oak and mixed-conifer forests between 1,160–2,015 m elevation have more optimal climates (not too dry or hot) for ecosystem productivity, soil weathering, and cycling of essential elements than the oak savannah (405 m) and subalpine forest (2,700 m). We found decreases in overstory vegetation nutrient stocks with decreasing elevation because of enhanced water limitation and greater occurrence of disturbances. Stocks of C, N, and P in the entire regolith peaked at the pine-oak and mixed-conifer forests across the bioclimatic gradient, driven by thicker regolith profiles and greater nutrient input rates. These observations suggest long-term warming will decrease ecosystem nutrient storage at the warmer, transitional pine-oak zone, but will increase nutrient storage at the colder, subalpine zone. Assuming steady-state conditions, we found the mean residence time of ecosystem C decreased with projected rising air temperatures and increased following a major drought event across the bioclimatic gradient. Our study emphasizes potentially elevation-dependent changes in nutrient storage and C persistence with warming in seasonally dry forests.

54 ENVIRONMENTAL SCIENCES↗

Impact of UV-light and pH on the Fate of Tc, I, and U in Wetlands at Savannah River Site - 20230

The Savannah River Site (SRS) is one of the major nuclear facilities owned by the U.S Department of Energy. During the Cold War, these facilities produced large amounts of radioactive and hazardous waste. On site, three unlined seepage basins in the F-Area received approximately 1.8 billion gallons of low-level waste containing nitric acid, radionuclides, and dissolved metals due to plutonium and tritium production operations. The acidic nature of the waste created a source of relatively mobile radionuclides below the basins. Radionuclides previously disposed of within the F-Area, including uranium isotopes (U), technetium-99 (Tc-99), and iodine-129 (I-129), are moving with groundwater towards Four Mile Branch Wetland, where they are subsequently upwelling and interacting with natural organic matter (NOM). Many environmental factors including redox conditions, porewater composition, pH, light, and temperature affect the degradation of organic matter as well as interactions with Tc-99, U, and I-129. In particular, the high concentrations of nitrate from the acidic waste may increase the formation of reactive oxygen species (ROS) that impact both degradation of NOM and behavior of contaminants. In the presence of sunlight, I-129, Tc-99, and U speciation and complexation behavior may be affected by ROS and NOM degradation products in addition to the factors generally considered in subsurface systems in the absence of light. This research aims to determine whether the interactions between radionuclides, NOM, and nitrate affect the fate of I-129, Tc-99, and U and which processes are controlling their behavior. Experiments were conducted at variable pH in the presence of NaNO{sub 3} in order to determine the impact of light and pH on NOM degradation and to evaluate the impact on the fate of contaminants of concern. Soil samples high in NOM collected from two sites in the Southeastern United States (Savannah River Site and the Everglades) were studied. Batch experiments were conducted with NOM and the following aqueous contaminants, U, I-129, Tc-99 with exposure to ultraviolet (UV) light in an environmental chamber. This study was conducted in a sterile environment in order to exclude the potential for microbial degradation of organic matter. Results indicated photodegradation of NOM and significant interaction of radionuclides with NOM. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Niche Partitioning of Microbial Communities at an Ancient Vitrified Hillfort: Implications for Vitrified Radioactive Waste Disposal

A pre-Viking era vitrified hillfort, Broborg, provides a habitat analogue for disposed radioactive waste glass and shows strong niche partitioning among the organisms involved in glass alteration. Microbes cannot be eliminated from radioactive waste disposal facilities and the consequences of bio-colonization must be understood. We use Broborg as a model system to inform what microbial processes might influence long-term radioactive waste glass durability by examining anthropogenic glass that has been subjected to bio-colonization for over 1,500 years. Scanning electron microscopy (SEM) images reveal the surficial biofilm structure, and chemical/mineralogy analysis in combination with deoxyribonucleic acid (DNA) sequencing of samples from the vitrified substrate, the adjacent soil, and the general topsoil provide insight into niche partitioning. The ancient glass niche supports a unique microbial community of bacteria, fungi, and protists that manifests the species response to local geochemical and mineralogical conditions. Communities from the geochemical niche associated with the glass are distinct and less diverse than soil communities. The microbiome of the glass and adjacent soil are dominated by lichens, lichen-associated microorganisms, and other epilithic, endolithic, and epigeic organisms. Pseudomonads dominate the prokaryotic communities on the vitrified material, but not the adjacent soil. In contrast, the general topsoil communities are enriched in plant rhizosphere organisms. Taxa associated with vitrification have bio-corrosive properties that could be detrimental to glass durability, including silicate mineral dissolution, extraction of essential elements, secretion of geochemically reactive organic acids, and dissolution induced by improved water retention. However, these stable long-term biofilms also possess a homeostatic function that could limit glass alteration. Overall, this study demonstrates the potential impacts that microbial colonization and niche partitioning can have on glass alteration and subsequent release of radionuclides from a disposal facility for vitrified radioactive waste.

59 BASIC BIOLOGICAL SCIENCES↗

Soil oxygen dynamics: a key mediator of tile drainage impacts on coupled hydrological, biogeochemical, and crop systems

Tile drainage removes excess water and is an essential, widely adopted management practice to enhance crop productivity in the US Midwest and throughout the world. Tile drainage has been shown to significantly change hydrological and biogeochemical cycles by lowering the water table and reducing the residence time of soil water, although examining the complex interactions and feedbacks in an integrated hydrology–biogeochemistry–crop system remains elusive. Oxygen dynamics are critical to unraveling these interactions and have been ignored or oversimplified in existing models. Understanding these impacts is essential, particularly so because tile drainage has been highlighted as an adaptation under projected wetter springs and drier summers in the changing climate in the US Midwest. We used the ecosys model that uniquely incorporates first-principle soil oxygen dynamics and crop oxygen uptake mechanisms to quantify the impacts of tile drainage on hydrological and biogeochemical cycles and crop growth in corn–soybean rotation fields. The model was validated with data from a multi-treatment, multi-year experiment in Washington, IA. The relative root mean square error (rRMSE) for the corn and soybean yield in validation is 5.66 % and 12.57 %, respectively. The Pearson coefficient (r) of the monthly tile flow during the growing season is 0.78. Plant oxygen stress turns out as an emergent property of the equilibrium between the soil oxygen supply and biological demand. The impact of tile drainage on the system is achieved through a series of coupled feedback mechanisms. The model results show that tile drainage reduces the soil water content and enhances soil oxygenation. It additionally increases the subsurface discharge and elevates inorganic nitrogen leaching, with seasonal variations influenced by climate and crop phenology. The improved aerobic condition alleviates crop oxygen stress during wet springs, thereby promoting crop root growth during the early growth stage. The development of greater root density, in turn, mitigates water stress during dry summers, leading to an overall increase in the crop yield by ∼6 %. These functions indicate the potential of tile drainage in bolstering crop resilience to climate change and the use of this modeling tool for large-scale assessments of tile drainage. The model reveals the underlying causal mechanisms that drive the agroecosystem response to drainage on the coupled hydrology, biogeochemistry, and crop system dynamics.

60 APPLIED LIFE SCIENCES↗

Modeled Impacts of LULC and Climate Change Predictions on Water Quality in Belize

Land use and land cover (LULC) change can have detrimental effects on water quality. In Belize, agricultural expansion creates the risk of increased sediment load and excess nutrients in runoff water, while deforestation removes potential infiltration sites for this outflow. Climate change and evolving precipitation rates can intensify the quantity of runoff, further enabling the flow of sediments and excess nutrients out to the lagoon surrounding the Belize Barrier Reef Reserve System (BBRRS). This study estimated future water quality in Belize by projecting LULC change through 2090 across Belize’s major watersheds based on observed trends from 2008-2018. Those LULC projections were subsequently combined with soil type data, elevation, and precipitation rates into a hydrologic model to produce runoff estimates as a proxy for water quality. The two Coupled Model Intercomparison Project phase 6 (CMIP-6) scenarios employed in the study represented bookend climate change scenarios, and both predicted lower precipitation rates in Belize over the next century due to climate change. When holding LULC change constant, these climate scenarios projected a decrease in runoff, suggesting a positive relationship between precipitation and runoff. The southern watersheds in particular are projected to experience greater decreases in annual rainfall and runoff by 2090. When holding climate constant, runoff increased by approximately 2.8% in the Conservation-focused LULC scenario by 2090, which was 28% lower than the Business as Usual scenario and 42% lower than the Development scenario.

water resources↗

HCMM energy budget data as a model input for assessing regions of high potential groundwater pollution

The author has identified the following significant results. Day thermal data were analyzed to assess depth to groundwater in the test site. HCMM apparent temperature was corrected for atmospheric effects using lake temperature of the Oahe Reservoir in central South Dakota. Soil surface temperatures were estimated using an equation developed for ground studies. A significant relationship was found between surface soil temperature and depth to groundwater, as well as between the surface soil-maximum air temperature differential and soil water content (% of field capacity) in the 0 cm and 4 cm layer of the profile. Land use for the data points consisted of row crops, small grains, stubble, and pasture.

Moore, D. G.↗

High temperatures and low soil moisture synergistically reduce switchgrass yields from marginal field sites and inhibit fermentation

‘Marginal lands’ are low productivity sites abandoned from agriculture for reasons such as low or high soil water content, challenging topography, or nutrient deficiency. To avoid competition with crop production, cellulosic bioenergy crops have been proposed for cultivation on marginal lands, however on these sites they may be more strongly affected by environmental stresses such as low soil water content. In this study we used rainout shelters to induce low soil moisture on marginal lands and determine the effect of soil water stress on switchgrass growth and the subsequent production of bioethanol. Five marginal land sites that span a latitudinal gradient in Michigan and Wisconsin were planted to switchgrass in 2013 and during the 2018–2021 growing seasons were exposed to reduced precipitation under rainout shelters in comparison to ambient precipitation. The effect of reduced precipitation was related to the environmental conditions at each site and biofuel production metrics (switchgrass biomass yields and composition and ethanol production). During the first year (2018), the rainout shelters were designed with 60% rain exclusion, which did not affect biomass yields compared to ambient conditions at any of the field sites, but decreased switchgrass fermentability at the Wisconsin Central–Hancock site. In subsequent years, the shelters were redesigned to fully exclude rainfall, which led to reduced biomass yields and inhibited fermentation for three sites. When switchgrass was grown in soils with large reductions in moisture and increases in temperature, the potential for biofuel production was significantly reduced, exposing some of the challenges associated with producing biofuels from lignocellulosic biomass grown under drought conditions.

09 BIOMASS FUELS↗

Mangala Valles as a Potential Landing Site for the Mars Surveyor 2001 Lander

Mangala Valles is an outflow channel in the Memnonia region of Mars. Although its origin is still under debate, most researchers believe they represent some form of catastrophic flood system which occurred early in the evolutionary history of Mars. The scientific objective of the Mars Surveyor Program 2001 (MSP 01) landed mission is to examine the ancient climatic and geologic history of Mars; to characterized surface materials with respect to elemental and mineral composition of rock and soils; to identify the role water may have played with respect to evolutionary history of the surface; to look for samples which may contain possible evidence of ancient life; and to collect and store unaltered samples which may be eventually returned to Earth during a later mission (MSP 05 - 2005). As with the Mars Pathfinder lander, the landing site will depend on several engineering constraints. Preliminary engineering constraints for MSP 01 landing site is that the landing site lies with 30 N and -15 S of the equator (due to solar power limitations) and below 2 km elevation. Both the scientific objectives and the engineering constraints can be accommodated with a Mangala Valles landing site.

Anderson, R.↗

Weekly Gridded Aquarius L-band Radiometer-Scatterometer Observations and Salinity Retrievals over the Polar Regions - Part 2: Initial Product Analysis

Following the development and availability of Aquarius weekly polar-gridded products, this study presents the spatial and temporal radiometer and scatterometer observations at L band (frequency1.4 GHz) over the cryosphere including the Greenland and Antarctic ice sheets, sea ice in both hemispheres, and over sub-Arctic land for monitoring the soil freeze-thaw state. We provide multiple examples of scientific applications for the L-band data over the cryosphere. For example, we show that over the Greenland Ice Sheet, the unusual 2012 melt event lead to an L-band brightness temperature (TB) sustained decrease of 5 K at horizontal polarization. Over the Antarctic ice sheet, normalized radar cross section (NRCS) observations recorded during ascending and descending orbits are significantly different, highlighting the anisotropy of the ice cover. Over sub-Arctic land, both passive and active observations show distinct values depending on the soil physical state (freeze-thaw). Aquarius sea surface salinity (SSS) retrievals in the polar waters are also presented. SSS variations could serve as an indicator of fresh water input to the ocean from the cryosphere, however the presence of sea ice often contaminates the SSS retrievals, hindering the analysis. The weekly grided Aquarius L-band products used a redistributed by the US Snow and Ice Data Center at http:nsidc.orgdataaquariusindex.html, and show potential for cryospheric studies.

Aquarius↗

The 2008 Mars Phoenix Lander Thermal and Evolved Gas Analyzer (TEGA) Dataset: Placing Easily Interpretable Evolved Gas Data on the Planetary Data System (PDS)

The Phoenix Scout Lander mission investigated the north polar region of Mars in 2008 with the goal to study the history of water, assess the past/present Martian climate, search for organics, and evaluate the potential for past/present microbial habit-ability on Mars. To accomplish this goal, the Phoenix Lander’s Thermal and Evolved-Gas Analyzer (TEGA) instrument assessed the gas composition of the Martian atmosphere and evaluated the mineralogy of the Martian regolith. The TEGA instrument consisted of eight small ovens connected to a 4 channel magnetic sector mass spectrometer. The ovens heated soil samples from ambient to 1000°C where the gases (e.g., H2O, CO2, etc.) evolved from thermal decomposition of mineral phases were analyzed by the mass spectrometer. Minerals thermally decomposed at characteristic temperatures and the evolving gases indicated the presence of perchlorate, carbonate, and hydrated phases in the Phoenix landing site soils.

Garcia, A. H.↗

Towards Soil Moisture Profile Estimation in the Root Zone Using L- and P-Band Radiometer Observations: A Coherent Modelling Approach

Precision irrigation management and crop water stress assessment rely on accurate estimation of root zone soil moisture. However, only the top 5cm soil moisture can be estimated using the two current passive microwave satellite missions, Soil Moisture and Ocean Salinity (SMOS) and Soil Moisture Active Passive (SMAP), which operate at L-band (wavelength of ~21cm). Since the contributing depth of the soil to brightness temperature increases with observation wavelength, it is expected that a P-band (wavelength of ~40cm) radiometer could potentially provide soil moisture information from deeper layers of the soil profile. Moreover, by combining both L- and P- bands, it is hypothesized that the soil moisture profile can be estimated even beyond their individual observation depths. The aim of this study was to demonstrate the potential of combined L-band and P-band radiometer observations to estimate the soil moisture profile under flat bare soil using a stratified coherent forward model. Brightness temperature observations at L-band and P-band from a tower based experimental site across a dry (April 2019) and a wet (March 2020) period, covering different soil moisture profile shapes, were used in this study. Results from an initial synthetic study showed that the performance of a combined L-band and P-band approach was better than the performance of using either band individually, with an average depth over which reliable soil moisture profile information could be estimated (i.e. with a target root mean square error (RMSE) of less than 0.04 m3/m3) being 20cm for linear and 15cm for second-order polynomial functions. Other functions were also tested but found to have a poorer performance. Applying the method to the tower-based brightness temperature achieved an average estimation depth of 28cm (20cm) and 5cm (5cm) during the dry and wet periods respectively when using a second-order polynomial (linear) function. These findings highlight the opportunity of a satellite mission with L-band and P-band observations to accurately estimate the soil moisture profile to as deep as 30cm globally.

Foad Brakhasi↗

Meteorological, reference evapotranspiration and estimated transpiration data, July 2020-Dec 2021, Slate River Floodplain, Crested Butte, Colorado

This data package includes a time series of meteorological data (air temperature, relative humidity, barometric pressure, precipitation, wind speed, soil heat flux, incoming shortwave radiation, incoming longwave radiation, outgoing shortwave radiation and outgoing longwave radiation) from the Slate River floodplain outside Crested Butte, Colorado, a focus field site for the SLAC Floodplain Hydro-Biogeochemistry SFA. The data was generated as part of the work targeting the overarching research question for the SLAC SFA: How do ubiquitous subsurface interfaces mediate molecular-scale biogeochemical processes and groundwater quality in floodplains and watersheds? The package also includes reference evapotranspiration calculated via the Penman-Monteith equation and an estimate of willow (Salix spp.) evapotranspiration using the method of Irmak et al., J. Hydrology, 2013. Due to two malfunctioning sensors (incoming shortwave radiation from Oct 2020-May 2021 and incoming longwave radiation from May 2021-March 2022), observed net radiation and calculated evapotranspiration are only included from July-October 2020. However, users may be able to extend calculated evapotranspiration using estimates of these two parameters from other sources. Both sensors have been replaced and data beyond 2021 be uploaded to this repository when it is available.Within the data package, "FLMD.csv" describes file-level metadata and "dd.csv" defines column headers and universal terms across the dataset. The data package includes 3 "*data.csv" files, two for meteorological data for 2020 and 2021 and one for reference evapotranspiration and transpiration data from 2020 ("SLT_OBJ2_PenmanMonteith_2020_data.csv"). Each "*data.csv" file of meteorological data has a corresponding "*_InstallationMethods.csv" file that describes the location, sensor model, sensor serial number and other metadata corresponding to each measured parameter. We also include a Jupyter notebook ("PenmanMonteithET_Calculations.ipynb") that details the assumptions and equations used to calculate daily and hourly reference evapotranspiration and daily willow transpiration from raw meteorological data.

54 ENVIRONMENTAL SCIENCES↗