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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Application of a coupled aerosol formation: Radiative transfer model to climatic studies of aerosols

A sophisticated one dimensional physical-chemical model of the formation and evolution of stratospheric aerosols was used to predict the size and number concentration of the stratospheric aerosols as functions of time and altitude following: a large volcanic eruption; increased addition of carbonyl sulfide (OCS) or sulfur dioxide (SO2) to the troposphere; increased supersonic aircraft (SST) flights in the stratosphere; and, large numbers of space shuttle (SS) flights through the stratosphere. A radiative-convective one dimensional climate sensitivity study, using the results of the aerosol formation model, was performed to assess the ground level climatic significance of these perturbations to the stratospheric aerosol layer. Volcanic eruptions and large OCS or SO2 increases could cause significant climatic changes. Currently projected SS launches and moderate fleets of SST's are unlikely to upset the stratospheric aerosol layer enough to significantly impact climate.

Toon, O. B.↗
NASA NTRS1977

Lithium cell test results

Three lithium SO2 cells, two lithium CF cells, and a vinyl chloride cell, all with crimped seals, and all strictly experimental, were independently discharged on resistors. Three temperatures were used and several different storage temperatures. Discharge rate generally on the nominal discharges were 0.1 amp, 0.5 amp, and 1 amp. Tests results show that the crimp seals are inadequate, especially for the SO2 cells. Normal discharges present no hazards. All cells discharge to zero. The problem of lithium cell explosions, such as occurred during off-limits testing, is discussed.

Bragg, B. J.↗
NASA NTRS1979

Chemistry and thermodynamics of sulfur on Venus

Sulfur reactions on Venus are discussed. It is suggested that photochemical reactions convert SO2 to H2SO4 and remove O2 from the Venus stratosphere, while thermochemical reactions near the surface probably make the SO2, regenerate CO2 from photolytic CO, and produce free sulfur. Optical evidence for liquid sulfur on Venus is examined; the Venera data suggest a light drizzle of liquid sulfur above 18 km and the existence of several per cent of sulfur vapor below that height.

Young, A. T.↗
NASA NTRS1979

Burn coal cleanly in a fluidized bed - The key is in the controls

The fluidized-bed combustion (FBC) process produces few sulfur emissions, and can burn wood, municipal solid waste as well as every kind of coal available in the U.S. The presurized, coal-burning fluidized-bed reactor at NASA's Lewis Research Center is described, together with a discussion of the operating results. The FBC system at Lewis, having a completely instrumented reactor, is used to test turbine blade alloys for future power plant applications. With the same type of coal and limestone used in the first testing phase covering 136 hours, it was found that all NOx values were below the EPA standard of 0.7 lb/MBtu, whereas the maximum observed level of SO2 was above the EPA standard of 1.3 lb/MBtu, but with the average SO2 level, however, only 0.63 lb/MBtu. Unburned hydrocarbon and CO levels were very low, indicating combustion efficiencies of close to 99% in almost all tests. Testing is now underway using high temperature cyclones and gas turbine to eliminate erosion and corrosion effects which were observed after the initial tests on the turbine and blades.

Kobak, J. A.↗
NASA NTRS1978

The chemistry of Venus' atmosphere

A model for the Venus atmosphere involving photochemistry of oxygen, hydrogen, chlorine and sulfur species is presented. Sulfur reaction schemes and hydrogen and chlorine reaction schemes were included. The impact of sulfur on the oxygen budget and the subsequent production of H2SO4 molecules for the Venus cloud deck were explored. A major new reaction scheme for production of H2SO4 molecules involving sulfur and oxygen chemistry was established shown to dominate over the odd hydrogen scheme proposed earlier. The efficiency of the scheme in formation of H2SO4 is only about 50%, with the remaining sulfur residing in SO2 molecules. The calculated downward flux of H2SO4 may be sufficient to maintain a steady state sulfuric acid cloud if the resident time of H2SO4 droplets in the cloud is as long as a few years. If however, the resident time is half a year or shorter, additional chemistry capable of more efficient conversion of SO2 to SO3 is required.

Sze, N. D.↗
NASA NTRS1980

High temperature storage characteristics of lithium sulfur dioxide cells

Hermetically sealed SO2 cells were developed to eliminate SO2 diffusion and its adverse effects on shelf life. A two part barrier coating material was applied to the internal surface of the glass seal and cured under a predetermined thermal profile in order to prevent the self discharge associated with glass seal corrosion.

Watson, T.↗
NASA NTRS1980

Studies of thermochemical water-splitting cycles

Higher temperatures and more isothermal heat profiles of solar heat sources are developed. The metal oxide metal sulfate class of cycles were suited for solar heat sources. Electrochemical oxidation of SO2 and thermochemical reactions are presented. Electrolytic oxidation of sulfur dioxide in dilute sulfuric acid solutions were appropriate for metal oxide metal sulfate cycles. The cell voltage at workable current densities required for the oxidation of SO2 was critical to the efficient operation of any metal oxide metal sulfate cycle. A sulfur dioxide depolarized electrolysis cell for the splitting of water via optimization of the anode reaction is discussed. Sulfuric acid concentrations of 30 to 35 weight percent are preferred. Platinized platinum or smooth platinum gave the best anode kinetics at a given potential of the five materials examined.

Remick, R. J.↗
NASA NTRS1979

High resolution absorption coefficients for Freon-12

The ultra high resolution absorption coefficients of the Q-branch of Freon-12 obtained with tunable diode laser spectroscopy are presented. Continuous spectra are presented from 1155/cm to 1163/cm, and absolute wavelength calibration was obtained using SO2 spectra as a standard and a 5 cm Ge etalon for relative calibration between SO2 lines. The Freon-12 data obtained at a pressure of 0.05 torr showed a rich and highly structured spectra, but with the exception of three isolated features, collisional broadening reduces the spectra to a structureless continuum for nitrogen pressures greater than 20 torr. The spectra at 1161/cm continue to exhibit structure at atmospheric pressure.

Hoell, J. M.↗
NASA NTRS1980

Infrared spectrum of Io, 2.8-5.2 microns

The reflectance spectrum of Io is presented from 2.8 to 5.2 microns demonstrating the full extent of the broad and deep spectral absorption between 3.5 and 4.8 microns. Laboratory spectra of nitrates and carbonates diluted with sulfur do not satisfactorily reproduce the Io spectrum, but new information based on recently discovered volcanic activity on the satellite lead to consideration of other classes of compounds reported by Fanale et al. (1979). It is concluded that the variability of the supply of condensible SO2 gas to the surface of Io, its removal by sublimination, and the temporal variations in the strength of the SO2 band may provide an index of volcanic activity on Io that can be monitored from the earth.

Cruikshank, D. P.↗
NASA NTRS1981

Design, fabrication, and bench testing of a solar chemical receiver

Solar thermal energy can be effectively collected, transported, stored, and utilized by means of a chemical storage and transport system employing the reversible SO2 oxidation reaction. A solar chemical receiver for SO3 thermal decomposition to SO2 and oxygen was analyzed. Bench tests of a ten foot section of a receiver module were conducted with dissociated sulfuric acid (SO3 and H2O) in an electrical furnace. Measured percent conversion of SO3 was 85% of the equilibrium value. Methods were developed to fabricate and assemble a complete receiver module. These methods included applying an aluminide coating to certain exposed surfaces, assembling concentric tubes with a wire spacer, applying a platinum catalyst to the tubing wall, and coiling the entire assembly into the desired configuration.

Summers, W. A.↗
NASA NTRS1980

Greenhouse models of Venus' high surface temperature, as constrained by Pioneer Venus measurements

Recent measurements conducted from the Pioneer Venus probes and orbiter have provided a significantly improved definition of the solar net flux profile, the gaseous composition, temperature structure, and cloud properties of Venus' lower atmosphere. Using these data, we have carried out a series of one-dimensional radiative-convective equilibrium calculations to determine the viability of the greenhouse model of Venus' high surface temperature and to assess the chief contributors to the greenhouse effect. New sources of infrared opacity include the permitted transitions of SO2, CO, and HCl as well as opacity due to several pressure-induced transitions of CO2. We find that the observed surface temperature and lapse rate structure of the lower atmosphere can be reproduced quite closely with a greenhouse model that contains the water vapor abundance reported by the Venera spectrophotometer experiment. Thus the greenhouse effect can account for essentially all of Venus' high surface temperature. The prime sources of infrared opacity are, in order of importance, CO2, H2O, cloud particles, and SO2, with CO and HCl playing very minor roles.

Pollack, J. B.↗
NASA NTRS1980

Evolution of Io's volatile inventory

Voyager data are used to make crude estimates of the rate at which Io loses volatiles, by a variety of processes, to the surrounding magnetosphere, for the case of both the current, SO2-dominated atmosphere and hypothetical paleoatmospheres in which such other gases as N2 may have been the dominant constituent. Among the mechanisms making significant contributions to the prodigious rate at which Io is losing volatiles are: the interaction of the magnetospheric plasma with volcanic plume particles and the background atmosphere; the sputtering of ices on the surface, if the nightside atmospheric pressure is low enough; and Jeans' escape of O as a dissociation product of SO2 gas. It is also argued that in the case of paleoatmospheres only the first two alternatives would have been possible and, nevertheless, insufficient to account for N2 loss over the life of the satellite.

Pollack, J. B.↗
NASA NTRS1981

Absorbers seen near the Venus cloud tops from Pioneer Venus

Pioneer Venus Orbiter measurements of planetary contrast at the Venus cloud tops are discussed. Images of the cloud tops at wavelengths between 1990 and 3400 A were obtained by the Pioneer UV Spectrometer together with broadband imagery and polarimetry at 2700 and 3650 A from the Orbiter Cloud Photopolarimeter at Venus phase angles of 33 to 130 deg. The planet is found to be darkest at the point where the UV Spectrometer line of sight penetrates perpendicular to the cloud tops, indicating that the absorbing material must be deep in the atmosphere. The contrast observed at wavelengths shortward of 3200 A is explained by SO2 absorption in the dark regions, while the persistence of the contrast at longer wavelengths requires the presence of an additional absorber or absorbers closely associated with the SO2, and a haze of submicron particles overlying the cloud tops in the bright regions. The correlations found between contrast and polarization indicate that no single constituent or change in vertical structure can account for the UV contrast. The origin of the markings is instead explained by a model in which absorbers subject to photochemical destruction are mixed upward into the cloud top region.

Esposito, L. W.↗
NASA NTRS1981

Investigation into the role of NaCl deposited on oxide and metal substrates in the initiation of hot corrosion

Morphological aspects of the conversion to Na2SO4 of NaCl deposits over the temperature range 500-700 C, in air with added SO2 and H2O. Progress of the reaction was observed by withdrawing samples at various times and examining them under the scanning electron microscope using EDAX to assess the extent of chloride to sulfate conversion. These initial results show that the conversion to Na2SO4 proceeds directly on the sodium chloride surface as well as on the surrounding substrate due to evaporation of NaCl from the solid particle. The mechanism of this reaction could involve reaction in the vapor to produce Na2SO4 which then deposits, alternatively Na2SO4 could form directly on the substrate surface due to direct reaction there between the vapors NaCl, SO2 and O2.

Birks, N.↗
NASA NTRS1982

Exchange of sulfur between the free troposphere, marine boundary layer, and the sea surface

A steady state analysis has been made of the sources and sinks of sulfur in the remote marine atmosphere and of the steady state exhanges of SO2 and sulfate between the sea, boundary layer, and free troposphere. Two situations were examined: an area of high biological productivity (Gulf of Guinea) and an area of low productivity (tropical Atlantic). The results of the analysis suggest that about one-third of the background concentrations of SO2 and excess sulfate observed in the remote marine atmosphere mixes in from the free troposphere, with the balance, about 100 micrograms S/sq m per day, attributed to the local oxidation of reduced sulfur-bearing precursors in the boundary layer.

Kritz, M. A.↗
NASA NTRS1982

The infrared spectral properties of frozen volatiles

Since Whipple's dirty snowball model of comet nuclei, it has been generally accepted that volatile ices help to explain cometary phenomena. The infrared spectral properties of many substances that are potential candidates for frozen volatiles in the solar system are being pursued; indeed some of these frozen materials have been found in the solar system: H2O, CO2, and SO2. A review of laboratory spectra in the range 1 to 20 microns of H2O, CO2, SO2, CH4, NH3, H2S, CO, NH4HS and NH3.H2O is presented. Both reflection spectra of thick frosts and transmission spectra of thin films are shown, and their main characteristics are described. Hydrates, clathrates, and composite spectra are discussed. When it is possible to observe the nuclei of comets at close range, it may be possible to identify frozen volatiles by their infrared spectra.

Fink, U.↗
NASA NTRS1982

Thermal- and plasma-induced molecular redistribution on the icy satellites

The molecular transport of condensed gas species across the surfaces of the icy satellites of Jupiter and Saturn is examined with the view of describing, in part, certain gross visual features associated with these bodies. Molecular redistribution induced by thermal sublimation and magnetospheric plasma-ion impact on satellites with negligible atmospheres is calculated by assuming that the molecules follow ballistic trajectories and by statistically selecting initial molecular velocities and points of origin. Erosion/deposition profiles so calculated are compared for a variety of satellite sizes and environments in order to understand the relative importance of sublimation and cold corotating plasma-ion- and fast plasma-ion-induced transport. The erosion/deposition profiles are used to discuss the appearance of a polar frost on Ganymede. A balance of magnetospheric-ion implantation and ion-induced molecular redistribution is used to discuss the observation of embedded SO2 and the darkening of the trailing side on Europa. Ion-induced molecular transport may also limit the deposition of SO2 frost in the polar regions of Io and may be a source of heavy particles in the Jovian and Saturnian magnetospheres.

Sieveka, E. M.↗
NASA NTRS1983

The clouds of Venus - Sulfuric acid by the lead chamber process

The Pioneer Venus atmospheric probe provided new data on the clouds of Venus. A model consistent with this data involves SO2 being oxidized to H2SO4 by NO(x) in the presence of H2O. NO(x) also forms nitrosylsulfuric acid (NOHSO4) dissolved in the H2SO4 droplets. This acid solution, along with SO2 and perhaps NO2, can explain the UV and visible reflection spectrum of Venus. In the middle and lower clouds, NOHSO4 forms solid particles.

Sill, G. T.↗