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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28

The cosmic ray abundances of the platinum-lead elements as measured on HEAO-3

The relative abundances of elements in the charge ranges of Z = 75-79 (platinum) and Z = 80-83 (lead) should be a sensitive indication of the contributions of the r- and s-processes in nucleosynthesis. Data from the HEAO 3 Heavy Nuclei Experiment are used to establish abundances, relative to iron, of these elements in the cosmic radiation, as well as the ratio of 'secondary' elements, in the Z = 62-74 range, to the primary lead-platinum elements. These results appear to suggest that either the source abundances are deficient in s-process elements or that they are not organized solely by first ionization potential. In addition, present propagation models can adequately represent the relative abundances of primary and secondary elements.

Fixsen, D. J.↗

Image contrast of diffraction-limited telescopes for circular incoherent sources of uniform radiance

A simple approximate formula is derived for the background intensity beyond the edge of the image of uniform incoherent circular light source relative to the irradiance near the center of the image. The analysis applies to diffraction-limited telescopes with or without central beam obscuration due to a secondary mirror. Scattering off optical surfaces is neglected. The analysis is expected to be most applicable to spaceborne IR telescopes, for which diffraction can be the major source of off-axis response.

Shackleford, W. L.↗

Irradiance calibration with solar diffuser

The sun's energy is used in combination of movable and fixed diffuser plates, windows and apertures which are positioned in a series of test sequences (modes) for reflectance monitoring and calibration without the use of man-made sources. There are three embodiments, or implementations, of the invention--one embodiment uses two diffusers--a working diffuser and a secondary diffuser--the second embodiment uses three diffusers, a working diffuser, a secondary diffuser and a reference diffuser--and the third embodiment uses two diffusers--a working diffuser and a secondary diffuser, the latter also functioning as a cover for the working diffuser. The movable diffusers are mounted on rotatable cones and, in all embodiments, the sun is blocked from reaching the diffusers when not in use. Thus, the sun is used as a stable source for calibration and monitoring and the sun/diffuser combination is used in such a way that the response of all elements of the optical subsystem of the TOMS can be unambiguously and efficiently characterized with high accuracy and precision.

Haring, Robert E.↗

Biosensor and machine learning-aided engineering of an amaryllidaceae enzyme

A major challenge to achieving industry-scale biomanufacturing of therapeutic alkaloids is the slow process of biocatalyst engineering. Amaryllidaceae alkaloids, such as the Alzheimer’s medication galantamine, are complex plant secondary metabolites with recognized therapeutic value. Due to their difficult synthesis they are regularly sourced by extraction and purification from the low-yielding daffodil Narcissus pseudonarcissus. Here, we propose an efficient biosensor-machine learning technology stack for biocatalyst development, which we apply to engineer an Amaryllidaceae enzyme in Escherichia coli. Directed evolution is used to develop a highly sensitive (EC 50 = 20 μM) and specific biosensor for the key Amaryllidaceae alkaloid branchpoint 4’-O-methylnorbelladine. A structure-based residual neural network (MutComputeX) is subsequently developed and used to generate activity-enriched variants of a plant methyltransferase, which are rapidly screened with the biosensor. Functional enzyme variants are identified that yield a 60% improvement in product titer, 2-fold higher catalytic activity, and 3-fold lower off-product regioisomer formation. A solved crystal structure elucidates the mechanism behind key beneficial mutations.

60 APPLIED LIFE SCIENCES↗

Secondary neutron production from thick target deuteron breakup

Thick target deuteron breakup is a variable-energy accelerator-based source of high-energy neutrons, with applications in fundamental and applied nuclear science and engineering. However, the breakup mechanism remains poorly understood, and data on neutron yields from thick target breakup remain relatively scarce. In this work, the double-differential neutron yields from deuteron breakup have been measured on a thick beryllium target at ϵ d = 33 and 40 MeV, using both time-of-flight and activation techniques. We have also introduced a simple hybrid model for the double-differential deuteron breakup cross section, applicable in the ϵ d = 10-100 MeV energy range on light (Z ≤ 6) targets. This model features four empirical parameters that have been fit to reproduce experimental breakup measurements on beryllium targets, using the method of least squares. It was shown that these parameters extrapolate well to higher energies, and to other low-Z target materials. Here, we also include optimization of the parameters that modify the Kalbach systematics for compound and preequilibrium reactions, in order to better reproduce the experimental data for beryllium targets at large angles.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Advancing Molecular Level Understanding of Aerosol Processes in the Amazon and Integration with Modeling (Final Report)

The Amazon forest is being converted to urban and agricultural uses through land clearing including large scale burning. It is also the dominant source of biogenic hydrocarbons globally, which can chemically transform in the atmosphere to form secondary organic aerosol (SOA). Most aerosols (solid or liquid particles suspended in air) are organic and formed through secondary chemical processes. This means that SOA chemical composition and their physical properties can impact cloud formation, the hydrologic cycle, and radiative balance in this region. The 2014 GoAmazon field campaign at the DOE/ARM facility at T3 afforded study of chemical transformations in the region downwind of Manaus. Local biogenic hydrocarbons emissions are high, and their chemical oxidation can be studied with varying degrees of influence by the urban plume. We collected aerosol filter samples and made time-resolved molecular level measurements by deploying a sequential filter sampler and a Semi-Volatile Thermal desorption Aerosol Gas Chromatograph (SV-TAG) during Jan-Mar 2014 (wet season) and Aug-Oct 2014 (dry season).

54 ENVIRONMENTAL SCIENCES↗

PPI DataHub Project Data Package: S. elongatus PCC 7942 Circadian Control Bioproduction Metabolomics (PB-DP5)

The purpose of this experiment was to evaluate how circadian clock regulation impacts carbon partitioning between storage, growth, and product synthesis in Synechococcus elongatus PCC 7942 in providing insights to strategies for enhanced bioproduction. Culture samples were collected at 0, 0.5, 1, 2, 4, 6, and 8 hours for extracellular sucrose analysis. Circadian metabolomics data was acquired using a Agilent single quadrupole gas chromatography-mass spectrometer and processed using Agilent Mass Hunter for targeted sucrose quantification. Metabolomic analysis of PCC 7942 light-dark cycle cultures transitioned to constant light revealed distinct temporal patterns in sucrose production. Processed metabolomic datasets are openly accessible from the PNNL DataHub project dataset download page and contain secondary processed GC-MS results files and supporting metadata materials linked to relevant source code information supporting data transparency and reuse.

59 BASIC BIOLOGICAL SCIENCES↗

PPI DataHub Project Data Package: S. elongatus PCC 7942 Circadian Control Bioproduction Transcriptomics (PB-DP3)

The purpose of this experiment was to evaluate how circadian clock regulation impacts carbon partitioning between storage, growth, and product synthesis in Synechococcus elongatus PCC 7942 in providing insights to strategies for enhanced bioproduction. Sample data was acquired using a Illumina HiSeq sequencer system and processed for RNA sequencing (RNA-Seq) expression analysis. Transcriptomic differential expression analysis revealed coordinated circadian clock-driven adjustment of the cell cycle and rewiring of energy and carbon metabolism. Processed RNA-Seq datasets are openly accessible from the PNNL DataHub project dataset download page and contain secondary processed RNA-seq results files and supporting metadata materials linked to relevant source code information supporting data transparency and reuse.

59 BASIC BIOLOGICAL SCIENCES↗

Spinoff, 1984

A pictorial resume that underlines the challenging nature of NASA programs and their extraordinary demands for technological input, is presented. Also, NASA's current mainline programs, which require development of new technology, are given. A representative sampling of spinoff products and processes resulting from technology utiliization, or secondary application, and the mechanisms NASA employs to stimulate technology utilization are provided. Contact sources for further information are presented.

Haggerty, J. J.↗

Ultraviolet, optical, and infrared observations of the intermediate polar TV Columbae

Forty-three IUE spectra of the X-ray discovered, triply periodic cataclysmic variable, TV Col are examined. The results show that the UV flux varies with the four-day period discovered by Motch in 1981. By fitting continuum models to the UV and optical fluxes, it is inferred that this modulation corresponds to the periodic heating of a normally 9000 K source within the binary system due to reprocessing of beamed X-ray and (possibly) EUV radiation from the vicinity of the degenerate star. The observed flux from this heated source is consistent with its origin at either the disk hot spot or the secondary star. Phasing arguments, however, favor the identification of the latter as the primary reprocessing site in the system. The infrared observations are not consistent with the model proposed by Watts et al. in 1982 and imply that the four-day period does not correspond to the orbital period of the binary.

Mateo, M.↗

Energy deposition of corpuscular radiation in the middle atmosphere

Main components of corpuscular radiation contributing to energy deposition (ED in eV/cu cm/s) in the atmosphere (10 to 100 km) are cosmic ray nuclei (CR - galactic and solar) and high energy electrons (HEE), mainly of magnetospheric origin. Galactic CR depending on solar cycle phase and latitude are dominant source of ED by corpuscular radiation below 50 to 60 km. Below 20 km secondaries must be assumed. More accurate treatment need assuming of individual HE solar flare particles, cut off rigidities in geomagnetic field and their changes during magnetospheric disturbances. Electrons E sub e greater than 30 keV of magnetospheric origin penetrating to atmosphere contribute to production rate below 100 km especially on night side. High temporal variability, local time dependence and complicated energy spectra lead to complicated structure of electron ED rate. Electrons of MeV energy found at geostationary orbit, pronouncing relation to solar and geomagnetic activity, cause maximum ED at 40 to 60 km. Monitoring the global distribution of ED by corpuscular radiation in middle atmosphere need continuing low altitude satellite measurements of both HEE and x ray BS from atmosphere as well as measurements of energy spectra and charge composition of HE solar flare particles.

Kudela, K.↗

Ionizing radiation exposure of LDEF (pre-recovery estimates)

The long duration exposure facility (LDEF), launched into a 258 nautical mile orbit with an inclination of 28.5 degrees, remained in space for nearly 6 yr. The 21,500 lb NASA satellite was one of the largest payloads ever deployed by the Space Shuttle. LDEF completed 32,422 orbits and carried 57 major experiments representing more than 200 investigators from 33 private companies, 21 universities and nine countries. The experiments covered a wide range of disciplines including basic science, electronics, optics, materials, structures and power and propulsion. A number of the experiments were specifically designed to measure the radiation environment. These experiments are of specific interest, since the LDEF orbit is essentially the same as that of the Space Station Freedom. Consequently, the radiation measurements on LDEF will play a significant role in the design of radiation shielding of the space station. The contributions of the various authors presented here attempt to predict the major aspects of the radiation exposure received by the various LDEF experiments and therefore should be helpful to investigators who are in the process of analyzing experiments which may have been affected by exposure to ionizing radiation. The paper discusses the various types and sources of ionizing radiation including cosmic rays, trapped particles (both protons and electrons) and secondary particles (including neutrons, spallation products and high-LET recoils), as well as doses and LET spectra as a function of shielding. Projections of the induced radioactivity of LDEF are also discussed.

Flight Experiment↗

Event Driven Messaging with Role-Based Subscriptions

Event Driven Messaging with Role-Based Subscriptions (EDM-RBS) is a framework integrated into the Service Management Database (SMDB) to allow for role-based and subscription-based delivery of synchronous and asynchronous messages over JMS (Java Messaging Service), SMTP (Simple Mail Transfer Protocol), or SMS (Short Messaging Service). This allows for 24/7 operation with users in all parts of the world. The software classifies messages by triggering data type, application source, owner of data triggering event (mission), classification, sub-classification and various other secondary classifying tags. Messages are routed to applications or users based on subscription rules using a combination of the above message attributes. This program provides a framework for identifying connected users and their applications for targeted delivery of messages over JMS to the client applications the user is logged into. EDMRBS provides the ability to send notifications over e-mail or pager rather than having to rely on a live human to do it. It is implemented as an Oracle application that uses Oracle relational database management system intrinsic functions. It is configurable to use Oracle AQ JMS API or an external JMS provider for messaging. It fully integrates into the event-logging framework of SMDB (Subnet Management Database).

Bui, Tung↗

Evidence of a Plasmoid-Looptop Interaction and Magnetic Inflows During a Solar Flare/Coronal Mass Ejection Eruptive Event

Observational evidence is presented for the merging of a downward-propagating plasmoid with a looptop kernel during an occulted limb event on 2007 January 25. RHESSI light curves in the 9-18 keV energy range, as well as that of the 245 MHz channel of the Learmonth Solar Observatory, show enhanced nonthermal emission in the corona at the time of the merging suggesting that additional particle acceleration took place. This was attributed to a secondary episode of reconnection in the current sheet that formed between the two merging sources. RHESSI images were used to establish a mean downward velocity of the plasmoid of 12 km/s. Complementary observations from the SECCHI suite of instruments on board STEREO-B showed that this process occurred during the acceleration phase of the associated coronal mass ejection (CME). From wavelet-enhanced EUV Imager, image evidence of inflowing magnetic field lines prior to the CME eruption is also presented. The derived inflow velocity was found to be 1.5 km/s. This combination of observations supports a recent numerical simulation of plasmoid formation, propagation, and subsequent particle acceleration due to the tearing mode instability during current sheet formation.

Milligan, Ryan O.↗

Corona, Jet, and Relativistic Line Models for Suzaku/RXTE/Chandra-HETG Observations of the Cygnus X-1 Hard State

Using Suzaku and the Rossi X-ray Timing Explorer (RXTE), we have conducted a series of four simultaneous observations of the galactic black hole candidate Cyg X-1 in what were historically faint and spectrally hard "low states". Additionally, all of these observations occurred near superior conjunction with our line of sight to the X-ray source passing through the dense phases of the "focused wind" from the mass donating secondary. One of our observations was also simultaneous with observations by the Chandra-High Energy Transmission Grating (HETG). These latter spectra are crucial for revealing the ionized absorption due to the secondary s focused wind. Such absorption is present and must be accounted for in all four spectra. These simultaneous data give an unprecedented view of the 0.8-300 keV spectrum of Cyg X-1, and hence bear upon both corona and X-ray emitting jet models of black hole hard states. Three models fit the spectra well: coronae with thermal or mixed thermal/non-thermal electron populations, and jets. All three models require a soft component that we fit with a low temperature disk spectrum with an inner radius of only a few tens of GM/c2. All three models also agree that the known spectral break at 10 keV is not solely due to the presence of reflection, but each gives a different underlying explanation for the augmentation of this break. Thus whereas all three models require that there is a relativistically broadened Fe line, the strength and inner radius of such a line is dependent upon the specific model, thus making premature line-based estimates of the black hole spin in the Cyg X-1 system. We look at the relativistic line in detail, accounting for the narrow Fe emission and ionized absorption detected by HETG. Although the specific relativistic parameters of the line are continuum-dependent, none of the broad line fits allow for an inner disk radius that is > 40 GM/c(sup 2).

Nowak, Michael A.↗

Discrepancies Between MODIS and ISCCP Land Surface Temperature Products Analyzed with Microwave Measurements

This paper compares land surface temperature (LST) products from the Moderate Resolution Imaging Spectroradiometer (MODIS) and the International Satellite Cloud Climatology Project (ISCCP). With both sources, the LST data are derived from infrared measurements. For ISCCP, LST is a secondary product in support of the primary cloud analyses, but the LST data have been used for several other purposes. The MODIS measurements from the Aqua spacecraft are taken at about 01:30 and 13:30 local time, and the ISCCP three-hourly data, based on several geostationary and polar orbiting satellites. were interpolated to the MODIS measurement times. For July 2003 monthly averages over all clear-sky locations, the ISCCP-MODIS differences were +5.0 K and +2.5 K for day and night, respectively, and there were areas with differences as large as 25 K. The day-night differences were as much as approximately 10 K higher for ISCCP than for MODIS. The MODIS measurements were more consistent with independent microwave measurements from AMSR-E, by several measures, with respect to day-night differences and day-to-day variations.

Moncet, Jean-Luc↗

Electroactive materials for rechargeable batteries

A secondary battery including a cathode having a primary cathode active material and an alkaline source material selected from the group consisting of Na2O, Na2O2, Na2S, NaF, NaCl, NaBr, Li2O, Li2O2, Li2S, LiF, LiCl, LiBr, Na2O, Na2O2, Na2S, NaF, NaCl, and a mixture of any two or more thereof; an anode having an anode active material; an electrolyte; and a separator.

Amine, Khalil↗

Missing Peroxy Radical Sources Within a Rural Forest Canopy

Organic peroxy (RO2) and hydroperoxy (HO2) radicals are key intermediates in the photochemical processes that generate ozone, secondary organic aerosol and reactive nitrogen reservoirs throughout the troposphere. In regions with ample biogenic hydrocarbons, the richness and complexity of peroxy radical chemistry presents a significant challenge to current-generation models, especially given the scarcity of measurements in such environments. We present peroxy radical observations acquired within a Ponderosa pine forest during the summer 2010 Bio-hydro-atmosphere interactions of Energy, Aerosols, Carbon, H2O, Organics and Nitrogen - Rocky Mountain Organic Carbon Study (BEACHON-ROCS). Total peroxy radical mixing ratios reach as high as 180 pptv and are among the highest yet recorded. Using the comprehensive measurement suite to constrain a near-explicit 0-D box model, we investigate the sources, sinks and distribution of peroxy radicals below the forest canopy. The base chemical mechanism underestimates total peroxy radicals by as much as a factor of 3. Since primary reaction partners for peroxy radicals are either measured (NO) or under-predicted (HO2 and RO2, i.e. self-reaction), missing sources are the most likely explanation for this result. A close comparison of model output with observations reveals at least two distinct source signatures. The first missing source, characterized by a sharp midday maximum and a strong dependence on solar radiation, is consistent with photolytic production of HO2. The diel profile of the second missing source peaks in the afternoon and suggests a process that generates RO2 independently of sun-driven photochemistry, such as ozonolysis of reactive hydrocarbons. The maximum magnitudes of these missing sources (approximately 120 and 50 pptv min−1, respectively) are consistent with previous observations alluding to unexpectedly intense oxidation within forests. We conclude that a similar mechanism may underlie many such observations.

atmosphere↗