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At least 505 records · Page 28

NH4-Smectite, a Potential Source of N Compounds (NO) in SAM Analyses

Recent detection of nitrate by Curiosity's Sample Analysis at Mars (SAM) instrument suite in Gale Crater sediments on Mars at abundances up to ~600 mg/kg indicates that nitrogen fixation processes occurred in early Martian history. But little is known about other possible N reservoirs on Mars, including those that may contain reduced forms of fixed N (i.e., NH3, NH4+) in the mantle, crust and sediments. Specifically, fixed nitrogen (i.e. NH3, NH4+, NOx or N that is chemically bound to either inorganic or organic molecules and can be released by hydrolysis to form NH3 or NH4+) is useful to terrestrial living organisms Therefore, understanding whether reduced N compounds such as NH4+ are present in surface materials is important to assess habitability in the Martian environment. While these species generally have short photochemical lifetimes, nitrogen in this form may be sequestered and stabilized in the soil by inclusion of NH4+ in certain phyllosilicates.

Andrejkovičová, S.↗

Importance of Quantifying the Full-depth Carbon Reservoir of Jamaica Bay Salt Marshes, New York

Constraining uncertainty in the global carbon cycle requires valid assessment of both surface and stored carbon in marine and coastal ecosystems (Blue Carbon) as well as terrestrial carbon (forests, peatlands, and soils) [Pendleton et al., 2012]. Quantifying the global carbon stock of coastal salt marshes, potentially the most efficient carbon-burying ecosystems in the world per area, is a key area of further research in both of these fields Pendleton et al., 2012. One of the largest challenges is that despite the fact that salt marshes often sequester carbon several meters deep, nearly all estimates of salt marsh carbon stocks consider only the upper 1 m of sediment (Windham-Myers et al., 2015) [54]. This is particularly concerning because coastal wetlands are increasingly at risk due to climate change, sea level rise, and anthropogenic disturbance and destruction (Deegan et al., 2012) [15]. Using full-depth measurements from marsh cores, we estimate the carbon stock of five salt marshes in the highly urbanized estuary of Jamaica Bay, New York and argue that partial-depth measurements can underestimate carbon stocks. These estimates use calculated carbon content and probe depth data of these marshes collected between 2000 and 2019, applying this data across the full area of the marsh obtained from satellite imagery. Carbon density measurements are then multiplied by the full-depth volume of the marshes to create an estimate of total carbon stock. In addition to calculating present-day estimates, we compare our carbon stock estimates to historical Jamaica Bay imagery to calculate historical carbon stocks and carbon loss. The carbon stock estimates presented here show a 95% carbon stock loss between 1885 and 2019 in Jamaica Bay and highlight the severe underestimation of carbon stocks without full-depth calculations. These findings have important implications for disappearing salt marshes with regard to the global carbon cycle and the incorporation of belowground carbon into global climate models. The findings are increasingly relevant for advocacy efforts aiming to conserve these marshes with sea level rise.

Tidal wetlands↗

Wyoming CarbonSAFE: Advancing Commercialization of Low-Carbon Energy Technologies in Fossil-Rich Wyoming

Wyoming’s Powder River Basin (PRB) is the most prolific coal producer and exporter in the United States and the State of Wyoming’s largest oil-producing basin. In addition to being a leading energy producer, the PRB is the site of research programs whose aim is to develop and integrate low-carbon technologies into existing fossil fuel energy industries. Much of the PRB’s low-carbon research is focused around Dry Fork Station (DFS), which is the newest coal-fired power station in the western US. Currently, DFS hosts five carbon capture projects, including pilot-scale capture projects that utilize different capture technologies and a full front-end engineering and design (FEED) study, a commercial CO 2 pipeline for nearby CO 2 -enhanced oil recovery industry, and is also co-located with the Wyoming Integrated Test Center, which is a host facility for unconventional carbon utilization research (i.e. flue gas carbon-to-products innovations). DFS is also the host site for the Wyoming CarbonSAFE project. Wyoming CarbonSAFE, funded by the Department of Energy/National Energy Technology Laboratory, is a multi-phased program (currently in Phase II) whose core objective is developing and validating storage sites within a complex capable of storing 50 million metric tonnes of CO 2 over a 30 year project period using carbon capture, utilization and storage (CCUS). This paper will provide an overview of the project to-date, showing that CarbonSAFE goals are achievable with respect to geologic, environmental, regulatory, CO 2 source and economic conditions, and why the State of Wyoming offers one of the more favorable environments to advance the commercialization studies. In 2019, the project team designed and completed a ~10,000 foot stratigraphic test well just south of DFS. From this well, the team collected over 600 feet of core, fluid samples from target injection zones, and a full petrophysical log suite. In addition, legacy 2D seismic lines were acquired and a 3D seismic survey was acquired in the fall of 2020. The objective of these field activities has been to identify and characterize target storage reservoirs and associated caprock. This complex has several reservoirs that could meet commercial injection goals, and over 4000 feet of associated caprock. Simulations of site performance suggest that stacked injection provides the most effective storage strategy, and would necessitate several sites within the greater complex to meet final project injection goals. Other work within this project includes the development of a business-case around proximal fields with CO 2 -enhanced oil recovery potential and existing tax credits, assessment of regulatory conditions, including pore space ownership and Class VI injection well permitting requirements, implementation of a robust public outreach Electronic copy available at: https://ssrn.com/abstract=3821220 GHGT-15 McLaughlin 2 program, and surface site characterization activities that have focused on environmental factors. In the PRB and at DFS, the State of Wyoming and other entities have made carbon management a priority of its future energy industry by providing a regulatory and business framework that is favorable to advancing these technologies. These endeavors will become more realistic with the successful implementation of Wyoming CarbonSAFE, and its ability to secure and validate commercial-scale CCUS at the center of Wyoming’s premier low-carbon research efforts.

McLaughlin, Fred↗

Evaluating genetic and environmental controls on silicon accumulation in Populus trichocarpa leaves

Background and aims: Silicon (Si) accumulation and formation of non-crystalline silica particles (phytoliths) inside plant cells contribute to plant function, soil carbon storage, and Si reservoirs in soils. A better understanding of how genetic and environmental factors control Si accumulation may improve understanding of Si cycling between plants and soil and its impacts on other ecosystem processes. Methods: This study examined how genetic potential for Si uptake and silicification translated to Si concentrations and phytolith formation in Populus trichocarpa leaves. Leaves were collected from four different genotypes of cultivated poplar trees that were grown in a common garden and possess established differences in leaf-level gene expression related to Si transport and silicification. Scanning electron microscopy and subsequent image analysis were used to quantify Si concentrations and phytolith abundance and features. Results: Phytoliths were identified in nearly all leaves but were often absent at very low (< 0.5 wt.%) Si concentrations at the leaf surface. The proportion of leaf area occupied by phytoliths increased as Si content increased. Silicon content and phytolith abundance at the leaf surface did not vary across genotypes, but surface Si was weakly correlated with plant available Si in soil. Conclusion: Phytoliths were prevalent in P. trichocarpa leaves; however, the genetic potential for Si uptake and silicification at the leaf-level poorly predicted foliar Si and phytolith abundance. Uniformly low expression of Si uptake genes in the roots may have reduced differences across genotypes. Consequently, Si accumulation in leaves was likely more strongly influenced by soil Si bioavailability, phenology, or additional environmental factors.

Image analysis↗

Innovations in underground hydrogen storage with multiphysics simulations, optimization, and monitoring: A review

Underground Hydrogen Storage (UHS) is a promising solution for large-scale energy storage and a critical component in advancing low-carbon energy system. Ensuring the safety and efficiency of UHS necessitates a comprehensive understanding of multiphysical interactions driven by cyclic pore fluid pressure fluctuations and coupled physicochemical processes. Here, this review examines the key geomechanical responses in UHS, including rock property variations under cyclic loading, fracture evolution and propagation, reservoir stress sensitivity, and fault stability. It also explores the impact of geochemical and microbial reactions on geomechanical characteristics. We provide an in-depth analysis of Thermal-Hydraulic-Mechanical-Chemical (THMC) coupled numerical simulations, highlighting their potential for future multi-scale modeling. Limitations of current machine learning (ML) approaches in addressing UHS challenges are highlighted, emphasizing the need for innovative ML-based methodologies. Operational strategies for hydrogen injection and production are reviewed, focusing on safety, efficiency, and economic viability. The necessity for multi-objective optimization (MOO) to balance storage efficiency, risk mitigation, and cost-effectiveness is also discussed. Current monitoring technologies are evaluated to ensure safe and efficient UHS operations. Finally, this review identifies critical knowledge gaps and underscores the importance of advancing geomechanical understanding under multiphysics-coupling. We highlight the need for ML-driven multiphysics theories, enhanced modeling techniques, and robust optimization strategies to improve UHS performance. This study serves as a comprehensive reference for future research and the large-scale implementation of UHS systems.

25 ENERGY STORAGE↗

Lithium and boron isotopic compositions of olivine in chondrules from carbonaceous and ordinary chondrite meteorites: Implications for the origin of solar 11 B/ 10 B ratio

We report the origin of solar 11 B/ 10 B ratio ~4 remains an open question. It has been thought that a significant portion of boron in the Solar System was derived from continuous spallation nucleosynthesis during interactions between Galactic Cosmic Rays and C—N—O nuclei in the interstellar medium. However, because GCR-produced boron is characterized by 11 B/ 10 B ~2.5, an endmember with 11 B/ 10 B > 4 is required to account for the solar 11 B/ 10 B ratio. Two leading hypotheses for the sources of 11 B-rich components include low energy spallation in the Sun’s parental molecular cloud and the neutrino process during the supernova explosions. In this study, lithium and boron elemental and isotopic compositions of seven porphyritic olivine chondrules and one isolated olivine crystal from four meteorites (Allende, Yamato 81020, Asuka 12236, and QUE 97008) were determined in-situ to help constrain which of the two nucleosynthetic mechanisms has most likely supplied the forming Solar System with extra 11 B. Apparent isotopic variations in Li/Si, B/Si, δ 7 Li and δ 11 B were found in chondrule olivine crystals, but only three chondrules exhibit statistically resolved δ 11 B heterogeneities. Using these three chondrules as a basis for discussion, we evaluated the processes that could potentially cause elemental and isotopic variations of Li and B. We argue that the data can be best understood in the context of condensation of lithium-boron-rich material onto chondrule precursors in (an) initially heterogeneous gaseous reservoir(s), which could be realized if the Solar System derived 11 B-rich components from a supernova or supernovae.

58 GEOSCIENCES↗

Water and Climate Impacts on ERCOT Long-Term Systems Assessment

Water and climate change pose many potential challenges to the electric power system. Substantial water is withdrawn every day to support thermoelectric power generating unit operations, and changes to water supply have the potential to affect generation dispatch. Climate change can accelerate growing demand for electricity, which can necessitate additional generating capacity, often in locations with limited water supply. Drought conditions also threaten thermoelectric power plant operations due to streamflow and reservoir levels dropping below intake structures, or water temperatures exceeding a power plants' permitted operating conditions. Here we explore how future climate change might influence decisions related to electricity capacity expansion planning in Electric Reliability Council of Texas (ERCOT) using a multi-model framework. Specifically, water resource modeling is used to simulate climate impacts on the future water supply for thermoelectric and hydropower generation for four future climate projections. Separately, temperature impacts on electricity load are evaluated for these scenarios. These climate impacts are applied to five alternative electricity futures in an electricity capacity expansion model that projects future generation and transmission capacity additions in ERCOT. Results indicate that climate has a measurable influence on future generation and transmission capacity needs, with temperature-driven increases in peak and average load resulting in 5-15 GW additional generating capacity and up to 1 GW additional transmission capacity. Additional capacity is a diverse mix of PV, natural gas, and wind, depending on the makeup of economic, policy and technology assumptions. Climate impacts increase total system costs 2-5%, while the marginal cost of energy and emissions are not affected substantially by climate change effects.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The cesium bombardment engine north-south stationkeeping experiment on ATS-6

Two one millipound-thrust cesium bombardment ion thrusters have been developed and integrated on the ATS-F spacecraft for the purpose of demonstrating compatible north-south stationkeeping of a synchronous communication satellite. Preliminary operation of the two thrusters on ATS-6 was completely successful on the first run of each. In addition to verifying operation, the principal accomplishments were the demonstration of a total absence of interference with the communications systems, verification of the predicted spacecraft operating potential, demonstration of compatibility with the star tracker, and demonstration of spacecraft attitude by thrust vectoring. Subsequent attempts to operate the thrusters have not been successful. Analysis indicates that the problem is associated with operation of the propellant reservoirs in zero-g.

Worlock, R. M.↗

Electromagnetic Pumps for Conductive-Propellant Feed Systems

There has been a recent, renewed interest in high-power electric thrusters for application in nuclear-electric propulsion systems. Two of the most promising thrusters utilize liquid metal propellants: the lithium-fed magnetoplasmadynamic thruster and the bismuth-fed Hall thruster. An important element of part of the maturation of these thrusters will be the development of compact, reliable conductive-propellant feed system components. In the present paper we provide design considerations and experimental calibration data for electromagnetic (EM) pumps. The role of an electromagnetic pump in a liquid metal feed system is to establish a pressure gradient between the propellant reservoir and the thruster - to establish the requisite mass flow rate. While EM pumps have previously been used to a limited extent in nuclear reactor cooling loops, they have never been implemented in electric propulsion (EP) systems. The potential benefit of using EM pumps for EP are reliability (no moving parts) and the ability to precisely meter the propellant flow rate. We have constructed and tested EM pumps that use gallium, lithium, and bismuth propellants. Design details, test results (pressure developed versus current), and material compatibility issues are reported. It is concluded that EM pumps are a viable technology for application in both laboratory and flight EP conductive-propellant feed systems.

Markusic, T. E.↗

Assessing the Value of Seismic Amplitude Versus Offset (AVO) Attributes for CO2 Storage Project Using a Bayesian Network Model for Decision Support

Attributes versus offset (AVO) are a set of measurements to analyze how the characteristics of reflected seismic waves change as a function of the offset. It can be useful for monitoring CO2 storage sites because the presence of leaked CO2 into the overlying aquifer can change the properties of the rocks and pore fluids composition that can alter the way seismic waves reflect and their amplitudes. The time-lapse changes in AVO attributes derived from repeat seismic surveys can help identify anomalies or shifts in the subsurface that could potentially be used as an indicator for CO2 leak detection. Our study leverages multiple seismic attributes derived from synthetic seismic data and Bayesian network model to quantify the probability of leak detection in the overlying aquifer above the storage reservoir. It helps to quantify the value of individual seismic attributes at multiple monitoring periods based upon their sensitivities.

Kumar, Abhash↗

Evaluate ERTS imagery for mapping and detection of changes of snowcover on land and on glaciers

The author has identified the following significant results. Snowlines on a small drainage basin were accurately identified on bulk ERTS-1 images without use of digital processing, and results checked with high altitude and ground-based photography. The area and approximate shape of snow patches as small as 20,000 sq m could be correctly identified with a magnifying scanning densitometer. The resolution of ERTS is more than ample for most snow mapping needs. Mount Baker, Washington, has a large crater south of the summit and an area north of the summit which emit considerable geothermal heat in the form of fumaroles and hot ground. Temperatures are being monitored using an ERTS DCS. Debris flows are occassionally released from the crater due to water saturation at the base of a heavy snowpack lying on hydrothermally altered hot ground. These debris flows present a possible hazard to life and property, as they are discharged down the Boulder Glacier toward Baker Lake, the upper of two major hydroelectric power reservoirs which are situated above the populated Skagit River Valley. ERTS-1 images show that the most recent debris flow (20-21 August 1973) can be clearly discerned and mapped. ERTS images provide another important tool for monitoring this potential hazard.

Meier, M. F.↗

Endogenous Lunar Volatiles

The chapter will begin with an introduction that defines magmatic volatiles (e.g., H, F, Cl, S) versus geochemical volatiles (e.g., K, Rb, Zn). We will discuss our approach of understanding both types of volatiles in lunar samples and lay the ground work for how we will determine the overall volatile budget of the Moon. We will then discuss the importance of endogenous volatiles in shaping the "Newer Views of the Moon", specifically how endogenous volatiles feed forward into processes such as the origin of the Moon, magmatic differentiation, volcanism, and secondary processes during surface and crustal interactions. After the introduction, we will include a re-view/synthesis on the current state of 1) apatite compositions (volatile abundances and isotopic compositions); 2) nominally anhydrous mineral phases (moderately to highly volatile); 3) volatile (moderately to highly volatile) abundances in and isotopic compositions of lunar pyroclastic glass beads; 4) volatile (moderately to highly volatile) abundances in and isotopic compositions of lunar basalts; 5) volatile (moderately to highly volatile) abundances in and isotopic compositions of melt inclusions; and finally 6) experimental constraints on mineral-melt partitioning of moderately to highly volatile elements under lunar conditions. We anticipate that each section will summarize results since 2007 and focus on new results published since the 2015 Am Min review paper on lunar volatiles [9]. The next section will discuss how to use sample abundances of volatiles to understand the source region and potential caveats in estimating source abundances of volatiles. The following section will include our best estimates of volatile abundances and isotopic compositions (where permitted by available data) for each volatile element of interest in a number of important lunar reservoirs, including the crust, mantle, KREEP, and bulk Moon. The final section of the chapter will focus upon future work, outstanding questions, and any in-sights on the types of samples or experimental studies that will be needed to answer these questions.

McCubbin, F. M.↗

Regional Assessment for the CO2 Storage Potential in Northern Niagaran Pinnacle Reef Trend

The goal of Task 1-11 was to perform an initial assessment of the geologic storage capacity and injectivity of the Northern Fairway of Michigan’s Niagaran Reef Trend. This task included a regional assessment and mapping effort to understand the variability in the reef geology, fluid content, and reservoir parameters across the trend consisting of several hundred reefs.

cross section↗

Impact of aquifer properties on the extent and timeline of CO 2 trapping

Abstract Geologic CO 2 sequestration in porous saline aquifers is a promising approach to reducing atmospheric concentrations of CO 2 . Reactive transport simulations provide the opportunity to analyze which factors influence geochemical reactivity in the reservoir, understand those most important for promoting CO 2 trapping, and assess individual sites. Field‐scale aquifer characterization is time and resource intensive such that here, reactive transport simulations are leveraged to enhance understanding of selected aquifer properties including porosity, permeability, depth of storage, and carbonate mineralogy on the overall CO 2 trapping potential to better select sites promoting geochemical reactivity for CO 2 trapping. There are different mechanisms for sequestrating CO 2 . Once injected, CO 2 will dissolve into the brine to create an acidic environment, resulting in the dissolution of pre‐injection formation minerals. Released ions can reprecipitate as secondary minerals. The dissolved CO 2 and mineralized CO 2 are considered as a more secure form of CO 2 trapping in this study compared to the free supercritical CO 2 . Here, a framework leveraging a controlled set of field scale simulations is developed to facilitate rapid, optimized site selection. Simulations vary aquifer properties to understand the impact of each unique property on CO 2 trapping, tracking, and comparing the amount of supercritical, aqueous, and mineralized CO 2 . The rate at which the CO 2 injected into the aquifer is converted to aqueous or mineralized CO 2 is newly defined here as the sequestration efficiency and used to compare simulation results. The reservoir depth and fraction of carbonate minerals in the formation are shown to be more important factors than reservoir porosity and permeability in affecting CO 2 trapping. However, the impact of aquifer properties on the evolution of injected CO 2 depends on the stage of the sequestration project. © 2023 Society of Chemical Industry and John Wiley & Sons, Ltd.

Energy & Fuels↗

Potential for monitoring soil erosion features and soil erosion modeling components from remotely sensed data

Accurate estimates of soil erosion and its effects on soil productivity are essential in agricultural decision making and planning from the field scale to the national level. Erosion models have been primarily developed for designing erosion control systems, predicting sediment yield for reservoir design, predicting sediment transport, and simulating water quality. New models proposed are more comprehensive in that the necessary components (hydrology, erosion-sedimentation, nutrient cycling, tillage, etc.) are linked in a model appropriate for studying the erosion-productivity problem. Recent developments in remote sensing systems, such as Landsat Thematic Mapper, Shuttle Imaging Radar (SIR-B), etc., can contribute significantly to the future development and operational use of these models.

Langran, K. J.↗

De-risking fault leakage risk and containment integrity for subsurface storage applications

The subsurface is pivotal in the energy transition, for the sequestration of CO 2 and energy storage. It is crucial to understand to what extent geological faults may form leakage pathways that threaten the containment integrity of these projects. Fault flow behavior has been studied in the context of hydrocarbon development, supported by observations from wells drilled through faults, but such observations are rare in geoenergy projects. Focusing on mechanical behavior as early indicator of potential leakage risks, a probabilistic Coulomb Failure Stress workflow is developed and demonstrated using data from the Decatur CO 2 sequestration project to rank faults based on their containment risk. The analysis emphasizes the importance of fault throw relative to reservoir thickness and pore pressure change in assessing reactivation risks. Integrating this mechanical assessment with geological and dynamic fault analyses contributes to derisking fault containment for geoenergy applications, providing valuable insights for the successful development of subsurface storage projects.

58 GEOSCIENCES↗

The Santorini Volcanic Complex as a Valuable Source of Enzymes for Bioenergy

Marine microbial communities are an untapped reservoir of genetic and metabolic diversity and a valuable source for the discovery of new natural products of biotechnological interest. The newly discovered hydrothermal vent field of Santorini volcanic complex located in the Aegean Sea is gaining increasing interest for potential biotechnological exploitation. The conditions in these environments, i.e., high temperatures, low pH values and high concentration of heavy metals, often resemble harsh industrial settings. Thus, these environments may serve as pools of enzymes of enhanced catalytic properties that may provide benefits to biotechnology. Here, we screened 11 metagenomic libraries previously constructed from microbial mat samples covering the seafloor and the polymetallic chimneys of Kolumbo volcano as well as mat samples from Santorini caldera, to mine, in silico, genes associated with bioenergy applications. We particularly focused on genes encoding biomass hydrolysis enzymes such as cellulases, hemicellulases and lignin-degrading enzymes. A total of 10,417 genes were found for three specific groups of enzymes—i.e., the endoglucanases, the three different beta-glucosidases BGL, bglX and bglB, and the alpha-galactosidases melA, and rafA. Overall, we concluded that the Santorini–Kolumbo volcanic ecosystems constitute a significant resource of novel genes with potential applications in bioenergy that deserve further investigation.

59 BASIC BIOLOGICAL SCIENCES↗

How Does Water Delivery System Design Impact the Microbial Load of Salad Crops?

In a microgravity setting, such as the environment aboard the International Space Station (ISS), an ideal plant water delivery system is one that can grow edible crops with minimal resource consumption and minimal risk to crew members. There are also concerns associated with the ability to control fluid escape and biofilm formation resulting in potential dangers to systems, crops, or crewmembers. To identify an appropriate system, candidate systems were assembled and operated under simulated ISS environmental conditions (T,CO2,and RH) with red romaine lettuce (Lactuca sativa cultivar 'Outredgeous') as a model crop. Fluid reservoirs and randomly selected planting sites were sampled every seven days until maturity at which point edible plant biomass and root samples were also taken. Heterotrophic bacteria and fungi growth patterns throughout each planting cycle were determined by plate counts on appropriate agar media. The candidate systems were compared to a classic hydroponics system as a control and harvested crops were compared to controls as well as Veggie-grown and market produce. Plants harvested from candidate systems yielded lower average heterotrophic bacteria and fungi per gram of plant mass levels when compared to market and Veggie samples as well as those from the control system. Additional studies to evaluate the system sanitation regimen as well as testing additional crops should be considered to aid in the selection of an ideal system.

Curry, Aaron B.↗