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DOE OSTI2025

Controlled electrochemical nutrient delivery to enhance marine primary productivity

Oceanic photosynthesis contributes to approximately half of the Earth’s net annual primary productivity. Marine photosynthetic productivity has a high degree of heterogeneity due to spatial and temporal co-limitations of light, temperature, and/or nutrients. Across coastal, near-shore, and open ocean regions, insufficient concentrations of key nutrients (e.g., N, P, Fe) can limit primary productivity. Although studies have shown a significant increase in primary productivity with the addition of low doses of trace nutrients, a sustainable approach to reliably deliver and maintain low doses of nutrients and ensure their bioavailability, remains a challenge. Chemical nutrient addition has relied on the use of chelating agents to ensure nutrient bioavailability, but synthetic chelators are persistent environmental pollutants. In this study, we demonstrate for the first time the use of a controlled electrochemical nutrient delivery (CEND) approach to accelerate the growth of phytoplankton without the need for such chelators. Our study uses commercial stainless-steel electrodes to deliver low concentrations of iron to enhance growth rates in the microalga Picochlorum celeri TG2. To demonstrate the process control offered by the CEND method, we evaluate iron delivery as a function of pulse time, pulse frequency, and rest time between pulses. Our data show that at the same total Fe dose of 163 ppb, electrochemical iron delivery can achieve 9.54 ± 0.58 mg biomass/µg Fe, which is comparable to 9.14 ± 0.17 mg biomass/µg Fe achieved with chemical iron additions that include the synthetic chelating agent ethylenediaminetetraacetic acid (EDTA). Further, when different total iron doses (163 ppb, 325 ppb, and 650 ppb) were delivered over 72 h using CEND, biomass yield per iron dose was higher at lower doses: 9.54 ± 0.58 mg biomass/µg Fe at 163 ppb vs. 4.32 ± 0.32 mg biomass/µg Fe at 650 ppb. This highlights the benefits of CEND in delivering frequent and low doses of nutrients for improved process efficiency. Preliminary assessments show both lower cost and reduced greenhouse gas emissions from electrochemical over chemical iron additions with EDTA. The CEND approach opens new pathways to enhance marine primary productivity, without the unintended environmental impacts of synthetic chelators.

analytical chemistry↗

DOE OSTI2020

A comparative study of thermal- and electrocatalytic conversion of furfural: methylfuran as a primary and major product

Controlling reaction selectivity represents a fundamental challenge in heterogeneous catalysis. Here, we compare the selectivity in aqueous-phase thermal catalytic and electrocatalytic conversion of furfural and report the fundamental difference in elementary steps in the two reaction systems. Specifically, we observed that furfural alcohol and 2-methylfuran, which is the hydrogenation and hydrogenolysis product of furfural, respectively, are both primary products in electrocatalysis over a Cu electrode, with 2-methylfuran dominating the product distribution under electrode potentials between -0.55 and -0.75 V versus RHE. By contrast, in an aqueous-phase thermal reaction using a SiO 2 -supported Cu catalyst, furfural alcohol and its derivatives from the ring-rearrangement reaction are the major products, without production of 2-methylfuran, at the reaction temperature between 140 and 200 °C. Here, we propose that the distinct selectivity trends for oxygenate conversion via thermal and electrocatalytic reduction result from the distinct sequence of proton attack to the aldehyde group and may be generally true for reduction reactions of other biomass-derived oxygenates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1983

The IRAS project organisation and mission operations

The project organisation of IRAS is described, showing the tasks assigned to each project group during post-launch operations. The satellite is described, emphasizing the detectors. In the task division, the role of the U.S. is to construct the telescope and survey instrument, launch the satellite, process final science data for the survey instrument, and provide certain standard satellite items. The Netherlands construct the spacecraft and three additional instruments, integrates and tests the overall satellite, and designs and participates in the development of the operational system. The U.K. provides the operational control center and primary tracking station, generates a system for preliminary science analysis of the survey data, provides housekeeping analysis software and science data distribution software, and staffs the control center operations. The teams involved in mission planning and operations, and their roles, are identified, and a block diagram of the operations organisation is presented.

Van Holtz, R. C.↗

NASA NTRS1992

A mathematical model of a tilt-wing aircraft for piloted simulation

A mathematical model of a tilt-wing aircraft that was used in a piloted, six-degree-of-freedom flight simulation application is described. Two types of control systems developed for the math model are discussed: a conventional, programmed-flap wing-tilt control system and a geared-flap wing-tilt control system. The primary objective was to develop the capability to study tilt-wing aircraft. Experienced Tilt-wing pilots subjectively evaluated the model using programmed-flap control to assess the quality of the simulation. The math model was then applied to study geared-flap control to investigate the possibility of eliminating the need for auxilary pitch-control devices (such as the horizontal tail rotor or tail jet used in earlier tilt-wing designs). This investigation was performed in the moving-base simulation environment, and the vehicle responses with programmed-flap and geared-flap control were compared. The results of the evaluation of the math model are discussed.

Totah, Joseph J.↗

NASA NTRS1982

The B-747 flight control system maintenance and reliability data base for cost effectiveness tradeoff studies

Primary and automatic flight controls are combined for a total flight control reliability and maintenance cost data base using information from two previous reports and additional cost data gathered from a major airline. A comparison of the current B-747 flight control system effects on reliability and operating cost with that of a B-747 designed for an active control wing load alleviation system is provided.

Source record↗

NASA NTRS1990

Wavefront control of large optical systems

Several levels of wavefront control are necessary for the optimum performance of very large telescopes, especially segmented ones like the Large Deployable Reflector. In general, the major contributors to wavefront error are the segments of the large primary mirror. Wavefront control at the largest optical surface may not be the optimum choice because of the mass and inaccessibility of the elements of this surface that require upgrading. The concept of two-stage optics was developed to permit a poor wavefront from the large optics to be upgraded by means of a wavefront corrector at a small exit pupil of the system.

Meinel, Aden B.↗

NASA NTRS1992

NASA TSRV essential flight control system requirements via object oriented analysis

The objective was to analyze the baseline flight control system of the Transport Systems Research Vehicle (TSRV) and to develop a system specification that offers high visibility of the essential system requirements in order to facilitate the future development of alternate, more advanced software architectures. The flight control system is defined to be the baseline software for the TSRV research flight deck, including all navigation, guidance, and control functions, and primary pilot displays. The Object Oriented Analysis (OOA) methodology developed is used to develop a system requirement definition. The scope of the requirements definition contained herein is limited to a portion of the Flight Management/Flight Control computer functionality. The development of a partial system requirements definition is documented, and includes a discussion of the tasks required to increase the scope of the requirements definition and recommendations for follow-on research.

Duffy, Keith S.↗

NASA NTRS1958

Stability-Derivative Determination from Flight Data

A comprehensive discussion of the various factors affecting the determination of stability and control derivatives from flight data is presented based on the experience of the NASA High-Speed Flight Station. Factors relating to test techniques, determination of mass characteristics, instrumentation, and methods of analysis are discussed. For most longitudinal-stability-derivative analyses simple equations utilizing period and damping have been found to be as satisfactory as more comprehensive methods. The graphical time-vector method has been the basis of lateral-derivative analysis, although simple approximate methods can be useful If applied with caution. Control effectiveness has been generally obtained by relating the peak acceleration to the rapid control input, and consideration must be given to aerodynamic contributions if reasonable accuracy is to be realized.. Because of the many factors involved In the determination of stability derivatives, It is believed that the primary stability and control derivatives are probably accurate to within 10 to 25 percent, depending upon the specific derivative. Static-stability derivatives at low angle of attack show the greatest accuracy.

Holowicz, Chester H.↗

NASA NTRS1972

Phase A reaction control system design for the Large Space Telescope (LST)

The design of a reaction control system (RCS) for the Large Space Telescope is discussed. The primary requirement for the RCS is to serve as an emergency backup control system to the primary attitude control system. A regulated gaseous nitrogen RCS was selected. The operation of the system and its individual components is described. The principal design goals of the RCS were to minimize contamination effects, make use of existing components, and modularize the system to provide ease in manned orbital maintenance.

Price, W. B.↗

NASA NTRS1980

Aliasing filter for multirate systems

Rolloff filter is inexpensive way of reducing aliasing in digital control systems. Rolloff filter operating at faster sample rate (or rates) of system with 2:1 rate ratio gives infinite attenuation at half-sample rate of fast-rate loop. Tested successfully on Space Shuttle primary flight-control systems, filter technique could be applied to other multirate sampled-data systems.

Lee, J. F. L.↗

NASA NTRS1989

Periodic-disturbance accommodating control of the space station for asymptotic momentum management

Periodic maneuvering control is developed for asymptotic momentum management of control gyros used as primary actuating devices for the Space Station. The proposed controller utilizes the concepts of quaternion feedback control and periodic-disturbance accommodation to achieve oscillations about the constant torque equilibrium attitude, while minimizing the control effort required. Three-axis coupled equations of motion, written in terms of quaternions, are derived for roll/yaw controller design and stability analysis. It is shown that the quaternion feedback controller is very robust for a wide range of pitch angles. It is also shown that the proposed controller tunes the open-loop unstable vehicle to a stable oscillatory motion which minimizes the control effort needed for steady-state operations.

Warren, Wayne↗

NASA NTRS1991

Adaptive Cartesian coordinate control of space based robot manipulators

A Cartesian coordinate robot controller is presented for use when the mass properties of a load are unknown. The mass, center of mass, and moments of inertia of the end-effector are assumed unknown. All other inertial properties of the robot are assumed known. This knowledge of the parameters allows the control of the end-effector in a way similar to the use of reaction wheels to control the orientation of a satellite. This is the primary result of the controller. The basic method of the controller is similar to that used for terrestrial-based robot manipulators. The controller is demonstrated using a new simulation algorithm which is based on Hamilton's form of the equations of motion.

Walker, Michael W.↗

NASA NTRS1973

Mariner 9 control net Mars, June 1973

The latitude and longitude are reported for 1645 primary points in the control net of Mars. The points were derived from Mariner 9 photographs as of June 1973. The new Mariner 9 aerographic coordinates system used in performing the computations is discussed.

Davies, M. E.↗

NASA NTRS1976

Summary of studies for a solar optical telescope in space: 1968-1976

The primary objective of this review is to tabulate the basic recommendations of several solar telescope studies. A primary matrix, listing some of the basic optical parameters, was compiled and forms the basis for a table. From this table it is apparent that a strong consensus exists on the configuration of the telescope and on its fundamental dimensionless parameters. Other tables presented in this document address the basic approach of each study to the telescope design as well as to the design of critical subsystems. These subsystem problems include the material, coating, configuration, mounting, launch locks, and thermal control of the primary mirror, the structure of the main telescope and the instrument bay, the mechanisms for radiation rejection, thermal control, and meteoroid shielding, and methods of maintaining image quality by proper alignment and by image motion compensation.

Bremer, J.↗

NASA NTRS1974

Dynamics of multirate sampled data control systems

The effect was investigated of the synthesis approach (single or multirate) on the machine requirements for a digital control system for the space shuttle boost vehicle. The study encompassed four major work areas: synthesis approach trades, machine requirements trades, design analysis requirements and multirate adaptive control techniques. The primary results are two multirate autopilot designs for the low Q and maximum Q flight conditions that exhibits equal or better performance than the analog and single rate system designs. Also, a preferred technique for analyzing and synthesizing multirate digital control systems is included.

Naylor, J. R.↗

NASA NTRS1976

An overview of NASA's digital fly-by-wire technology development program

The feasibility of using digital fly by wire systems to control aircraft was demonstrated by developing and flight testing a single channel system, which used Apollo hardware, in an F-8C test airplane. This is the first airplane to fly with a digital fly by wire system as its primary means of control and with no mechanical reversion capability. The development and flight test of a triplex digital fly by wire system, which will serve as an experimental prototype for future operational digital fly by wire systems, are underway.

Jarvis, C. R.↗

NASA NTRS1975

An overview of NASA's digital fly-by-wire technology development program

The feasibility of using digital fly-by-wire systems to control aircraft was demonstrated by developing and flight testing a single channel system, which used Apollo hardware, in an F-8C test airplane. This is the first airplane to fly with a digital fly-by-wire system as its primary means of control and with no mechanical reversion capability. The development and flight test of a triplex digital fly-by-wire system, which will serve as an experimental prototype for future operational digital fly-by-wire systems, is underway.

Jarvis, C. R.↗

NASA NTRS1978

Summary of system state-of-health measurements STRATCOM 8: A balloon experiment

Various measurements were made to determine the temperature and attitude of the gondola and the status of primary power and control equipment. Bead thermistors were used to measure temperatures at selected points throughout the gondola. A two-axis magnetometer and a two-axis pendulum were used to measure gondola attitude. Voltage and current measurements indicated the status of the primary power sources and associated power converters.

Herrington, P. B.↗