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Development and performance evaluation of active insulation systems using solid-state thermal switches

Traditional building envelopes have passive insulation systems that cannot respond to dynamic changes in the environment. An Active Insulation System (AIS) consists of Active Insulation Materials (AIMs) that dynamically vary the thermal conductivity of the insulation system. Several researchers have evaluated the impact of AIS on building thermal and energy performance by using simulation tools. Up to 70% savings in annual heating and cooling energy and significant reductions in peak demand have been predicted for some climates with wall systems employing AIS. However, materials and assembly development still need a cost-effective product that achieves the required performance. Here, in this study, we present the process of developing an AIS that we will install in a test hut for its performance evaluation. Minimum performance criteria of the AIS system are developed based on R-low/R-high ratio, required time and efficiency to switch states, and cost estimates. The following steps during this study are creating the concept to meet the requirements, predicting the performance via simulations, developing the experimental setup for bench-scale testing, and finally, constructing a full-scale wall assembly and monitoring the performance when exposed to environmental chamber tests. The selected approach uses off-the-shelf products to create an AIS that can switch R-value between 0.98 ft 2 ·°F·h/BTU (0.173 m 2 ·K/W) and 5.81 ft 2 ·°F·h/BTU (1.02 m 2 ·K/W) and have a switching time of less than one minute between R-high and R-low.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Mode structure measurements of ion cyclotron emission and sub-cyclotron modes on DIII-D

We report mode structure measurements of coherent ion cyclotron emission (ICE) and sub-cyclotron modes on DIII-D. Through a dedicated experiment, we aimed to characterize a variety of modes via the upgraded ICE diagnostic in both L- and H-mode plasmas. In the L-mode plasmas, autopower spectrum peaks at harmonics of the ion cyclotron frequency fci were observed and are localized in the core of the plasma. Sub-cyclotron modes (f ~ 0.5f ci ) were also observed in L-mode plasmas when the toroidal magnetic field strength was lowered from B T = 2.17 T. In H-mode plasmas, many ICE harmonics localized to the plasma edge were observed, with some exceeding the nominal ICE diagnostic bandwidth of f ϵ [0, 100] MHz. Polarization estimates made using an orthogonal pair of vertical and horizontal magnetic pickup loops on the outer wall of the machine indicate that ICE and sub-cyclotron modes have compressional polarization at the plasma edge, the latter being consistent with simulation efforts for comparable DIII-D plasmas. For all modes, the same harmonics are observed on both the centerpost and outer wall loops, indicating that ICE is poloidally extended. Finally, toroidal mode numbers were calculated using three outer wall loops for both core ICE and sub-cyclotron modes in L-mode plasmas. Furthermore, the sub-cyclotron case served as a benchmark for our calculation method, with measured numbers of n ϵ [–24, –18] roughly agreeing with heuristic estimates of n ϵ [–20, –13]. Core ICE mode numbers were measured to be n ϵ [–10, 5], which is comparable to measurements made on other machines.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Geophysical measurements of a demolition at NRF

On May 31 st , 2025, at approximately 14:40:00 UTC, the former Submarine First Westinghouse (SW1) structure housing a large crane was demolished at the Naval Reactors Facility (NRF) located within the perimeter of the Idaho National Laboratory (INL). Several targeted explosives were used to facilitate this demolition. The INL Seismic Monitoring Program (SMP) installed four temporary seismic instrument suites around the site of the demolition in order to monitor ground motion including measuring peak ground acceleration (PGA), peak ground velocity (PGV), and to calculate peak ground displacement (PGD). The demolition produced three types of waves: body waves, surface waves, and acoustic waves. The acoustic wave represents the largest signal received. The PGA, measured on the eastern component of the instrument located approximately 95m away from the demolition site, was 0.187g. The PGV measured was 0.0004 m/s, and the PGD was approximately 0.000006m. Rayleigh waves incident on an instrument located at the Advanced Test Reactor, about 7.6km away, were used to estimate a magnitude of 0.3 at the ATR, representing a yield of energy equivalent to approximately 3 grams of TNT.

58 - GEOSCIENCES↗

A New Member of the Fast and Furious Family: A Relativistic and Time-variable UV Outflow in a Luminous Quasar

We report the fastest quasar outflow first detected in the ultraviolet, via variable C IV and Si IV absorption at outflow velocities −77,000 km s −1 to at least −90,000 km s −1 , in the radio-quiet quasar SDSS J231854.31+243954.2 (J2318). J2318 is a weak-lined quasar in the rest-frame ultraviolet, but Gemini GNIRS spectroscopy reveals an Hα redshift of z = 2.6781 ± 0.0004. A 20 yr photometric time series shows peak-to-peak variability of 0.5 mag in the g band. The C IV outflow strengthened monotonically over three epochs spanning ∼2.2 rest-frame years. The existence of such a high-velocity outflow implies that models of quasar outflows must be able to either accelerate gas to 0.3c while still preserving C IV and Si IV ions, or enable the formation of C IV and Si IV ions in gas, which has been accelerated to 0.3c. Virial estimates reveal a black-hole mass of 1.65 × 10 9 M ⊙ , which leads to an Eddington luminosity and Eddington ratio of 2.4 × 10 47 erg s −1 and 0.45, respectively. Using very conservative assumptions, the UV-absorbing outflow alone has an estimated mass loss of >0.82 M ⊙ yr −1 and a kinetic luminosity ratio L kin /L bol ≥ 0.75%. The lower limit is just above the threshold usually cited for significant feedback on the host galaxy. Comparison to PDS 456, the only other known quasar with a UV-absorbing outflow at 0.3c, suggests that the true $\dot{M}$ and Lkin/Lbol could be up to 2 orders of magnitude larger.

Seaton, Lucas M. [York University] (ORCID:00090006↗

Efficiency and Demand Flexibility in Large Office Buildings: The Potential for Cost Savings and CO 2 Reductions from Lighting and Cooling Measures

This report presents the estimated impact of lighting and cooling efficiency and demand flexibility measures in large office buildings in each state in the contiguous United States. It provides modeled results for three different metrics: bill savings, regional grid operational costs savings, and carbon dioxide (CO 2 ) emissions reductions. Lighting efficiency and demand flexibility are estimated to reduce load by up to 80 MWh/yr in a single large office building. These load reductions result in customer bill savings of up to $8,800/yr per building, with the highest savings in southern and midwestern states. Grid operating cost savings are estimated at up to $3,240/yr/building, with greatest benefit in southern and northeastern states. CO 2 emissions reduction potential is highest in the Dakotas, Nebraska, across the Midwest, in West Virginia, and in Mississippi (<48,200 kg/yr/building). Comparatively, cooling measures are found to have less load reduction potential (<28.5 MWh/yr/building), with the greatest potential in southern states including Texas, which ranks top of the list across several of the metrics studied. In numerous states, shifting cooling load to off-peak hours is found to increase costs and CO 2 emissions because precooling results in increased load during high-cost or high-CO 2 emissions periods. In general, focusing on cooling efficiency and load shedding has the potential for more savings. In all cases, the specific rate structure is a significant determinant in actual bill savings, which are up to $4,000/yr/building. To realize the full potential for bill savings through an energy measure, building operators must identify how the measure will change the building load pattern and the interaction of this load change with the applicable rate tariff. To realize CO 2 emissions reductions, industry and state coordination is needed to verify which fuel source is on the margin and then to create incentives for end users to reduce load during high-CO 2 emissions hours. Regular updates to data sets and analyses are critical. Regulators and policymakers are well positioned to facilitate the necessary coordination between the electric industry and building energy managers to develop appropriate price signals and incentives.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

The first high-redshift cavity power measurements of cool-core galaxy clusters with the International LOFAR Telescope

Radio-mode feedback associated with the active galactic nuclei (AGNs) at the cores of galaxy clusters injects a large amount of energy into the intracluster medium (ICM), offsetting radiative losses through X-ray emission. This mechanism prevents the ICM from rapidly cooling down and fueling extreme starburst activity as it accretes onto the central galaxies, and it is therefore a key ingredient in the evolution of galaxy clusters. However, the influence and mode of feedback at high redshifts (z ∼ 1) remains largely unknown. Low-frequency sub-arcsecond-resolution radio observations taken with the International LOFAR Telescope have demonstrated their ability to assist X-ray observations with constraining the energy output from the AGNs (or “cavity power”) in galaxy clusters, thereby enabling research at higher redshifts than before. In this pilot project, we tested this hybrid method on a high-redshift (0.6 < z < 1.3) sample of 13 galaxy clusters for the first time with the aim of verifying the performance of this method at these redshifts and providing the first estimates of the cavity power associated with the central AGN for a sample of distant clusters. We were able to detect clear radio lobes in three out of 13 galaxy clusters at redshifts of 0.7 < z < 0.9, and we used these detections in combination with ICM pressures surrounding the radio lobes obtained from standard profiles to calculate the corresponding cavity powers of the AGNs. Combining our results with the literature, the current data appear to suggest that the average cavity power peaked at a redshift ofz ∼ 0.4 and slowly decreases toward higher redshifts. However, we require more and tighter constraints on the cavity volume and a better understanding of our observational systematics to confirm any deviation of the cavity power trend from a constant level.

Astronomy & Astrophysics↗

Effect of Stress on Irradiation Responses of Highly Oriented Pyrolytic Graphite

The effect of stress on irradiation responses of highly oriented pyrolytic graphite (HOPG) was studied by combing molecular dynamics (MD) simulation, proton irradiation, and Raman characterization. MD simulations of carbon knock-on at energies < 60 eV were used to obtain average threshold displacement energies (E¯d) as a function of strain ranging from 0 to 10%. Simulations at a higher irradiation energy of 2–5 keV were used to study the effect of strain on damage cascade evolution. With increasing tensile strain, E¯d was reduced from 35 eV at 0% strain to 31 eV at 10% strain. The strain-reduced E¯d led to a higher damage peak and more surviving defects (up to 1 ps). Furthermore, high strains induced local cleavage around the cavities, as one additional mechanism of damage enhancement. Experimentally, HOPG film was folded, and the folded region with the maximum tensile stress was irradiated by a 2 MeV proton beam. Raman characterization showed significantly enhanced D to G modes in comparison to the stress-free irradiation. Based on the strain dependence of E¯d and the Kinchin–Pease model, a formula for displacement estimation under different tensile strains is proposed. The stress effects need to be considered in graphite applications in a reactor’s harsh environment where both neutron damage and stress are present.

36 MATERIALS SCIENCE↗

Optimization under uncertainty of a hybrid waste tire and natural gas feedstock flexible polygeneration system using a decomposition algorithm

Market uncertainties motivate the development of flexible polygeneration systems that are able to adjust operating conditions to favor production of the most profitable product portfolio. However, this operational flexibility comes at the cost of higher capital expenditure. A scenario-based two-stage stochastic nonconvex Mixed-Integer Nonlinear Programming (MINLP) approach lends itself naturally to optimizing these trade-offs. This work studies the optimal design and operation under uncertainty of a hybrid feedstock flexible polygeneration system producing electricity, methanol, dimethyl ether, olefins or liquefied (synthetic) natural gas. A recently developed C++ based software framework (named GOSSIP) is used for modeling the optimization problem as well as its efficient solution using the Nonconvex Generalized Benders Decomposition (NGBD) algorithm. Two different cases are studied: The first uses estimates of the means and variances of the uncertain parameters from historical data, whereas the second assesses the impact of increased uncertain parameter volatility. The value of implementing flexible designs characterized by the value of the stochastic solution (VSS) is in the range of 260–405 M$ for a scale of approximately 893 MW of thermal input. Increased price volatility around the same mean results in higher expected net present value and VSS as operational flexibility allows for asymmetric exploitation of price peaks.

42 ENGINEERING↗

Sensitivity of Regional WRF‐Chem Air Quality and Weather Simulations to Biomass‐Burning Emission Data Sets: A Case Study of the Impact of Canadian Wildfire on the US°

This study focuses on the period from June 26 to 29, 2023, when record‐breaking Canadian wildfires severely impacted air quality in the Midwest United States. Using the Weather Research and Forecasting Model with Chemistry (WRF‐Chem) and four biomass‐burning data sets (Fire Inventory from NCAR version 1, Fire Inventory from NCAR version 2.5, Quick Fire Emissions Data set [QFED], and Regional ABI‐VIIRS Emission), we analyzed aerosol transport from Canada to the US and assessed the model's accuracy in predicting PM 2.5 , O 3 , CO and aerosol weather feedback. Model simulations were compared with ground‐based and remote sensing observations as well as field measurements from the Community Research on Climate and Urban Science (CROCUS) project. Our findings show that the movement of a low‐pressure system from the Great Lakes to the Atlantic, combined with the high‐pressure system over the Atlantic, caused the transport of aerosols from Canadian wildfires to the US. Results show WRF‐Chem significantly underestimated key atmospheric components: aerosol optical depth (AOD) by over 50%, PM 2.5 by 65%–90% and peak O 3 concentrations by 50%–55% across four biomass burning data sets. Additionally, CO and NO 2 concentrations were underpredicted. The substantial underestimation of PM 2.5 led to an overestimation of temperature by up to 3.6 °C primarily due to excessive downward shortwave radiation, which resulted from the underestimation of direct aerosol effects and an increase in sensible heat flux. Among the biomass‐burning data sets, QFED produced the most accurate AOD and PM 2.5 predictions due to improved wildfire emission estimates, leading to a 1.0 to 1.5 °C reduction in temperature overestimation during the daytime. These findings underscore the need for improving wildfire emission estimates for trace gases and aerosols to enhance air quality and weather feedback predictions.

WRF-chem model↗

Measured and projected beam backgrounds in the Belle II experiment at the SuperKEKB collider

The Belle II experiment at the SuperKEKB electron–positron collider aims to collect an unprecedented data set of 50 ab -1 to study CP -violation in the B -meson system and to search for Physics beyond the Standard Model. SuperKEKB is already the world’s highest-luminosity collider. In order to collect the planned data set within approximately one decade, the target is to reach a peak luminosity of 6 x 10 35 cm −2 s −1 by further increasing the beam currents and reducing the beam size at the interaction point by squeezing the betatron function down to β $^*_y$ = 0.3 mm. To ensure detector longevity and maintain good reconstruction performance, beam backgrounds must remain well controlled. We report on current background rates in Belle II and compare these against simulation. We find that a number of recent refinements have significantly improved the background simulation accuracy. Finally, we estimate the safety margins going forward. We predict that backgrounds should remain high but acceptable until a luminosity of at least 2.8 x 10 35 cm −2 s −1 is reached for β $^*_y$ = 0.6 mm. At this point, the most vulnerable Belle II detectors, the Time-of-Propagation (TOP) particle identification system and the Central Drift Chamber (CDC), have predicted background hit rates from single-beam and luminosity backgrounds that add up to approximately half of the maximum acceptable rates.

Detector background↗

Dynamics of filaments during the edge-localized mode crash on NSTX

Edge localized modes (ELMs) are routinely observed in H-mode plasma regimes of the National Spherical Torus Experiment (NSTX). Due to the explosive nature of the instability, only diagnostics with high temporal and spatial resolution could provide a detailed insight into the dynamics associated with the ELMs. Gas-puff imaging at NSTX provides 2D measurements of the magnetic field aligned fluctuations (e.g., ELM filaments) in the scrape-off layer and at the plasma edge with 2.5 μs temporal and 10 mm optical resolution. A novel analysis technique was developed to estimate the frame-by-frame velocities and the spatial parameters of the dominant structures associated with the ELMs. The analysis was applied to single ELM events to characterize the ELM crash dynamics and then extended to a database of 159 ELM events. Statistical analysis was performed in order to find the characterizing dynamics of the ELM crash. The results show that on average, an ELM crash consists of a filament with a circular cross section, which is propelled outward with a characterizing peak radial velocity of ~3.3 km/s. The radial velocity was found to be linearly dependent on the distance of the filament from the separatrix, which has never been seen before. The ELM filament is characterized by propagation in the ion-diamagnetic direction poloidally with a peak velocity of 11.4 km/s. The ELM crash lasts for approximately 100 μs until the radial propulsion settles back to the pre-ELM level. Furthermore, the experimental findings were compared with analytical theory. Two possible mechanisms were identified for explaining the observations: the curvature interchange model and the current–filament interaction model.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Dynamics of filaments during the edge-localized mode crash on NSTX

Edge localized modes (ELMs) are routinely observed in H-mode plasma regimes of the National Spherical Torus Experiment (NSTX). Due to the explosive nature of the instability, only diagnostics with high temporal and spatial resolution could provide a detailed insight into the dynamics associated with the ELMs. Gas-puff imaging (GPI) at NSTX provides 2D measurements of the magnetic field aligned fluctuations (e.g. ELM filaments) in the scrape-off layer and the at the plasma edge with 2.5 us temporal and 10 mm optical resolution.A novel analysis technique was developed to estimate the frame-by-frame velocities and the spatial parameters of the dominant structures associated with the ELMs. The analysis was applied to single ELM events to characterize the ELM crash dynamics, and then extended to a database of 169 ELM events.Statistical analysis was performed in order to find the characterizing dynamics of the ELM crash. The results show that on average an ELM crash consists of a filament with a circular cross-section which is propelled outwards with a characterizing peak radial velocity of ~3.3 km/s. The radial velocity was found to be linearly dependent on the distance of the filament from the separatrix, which has never been seen before. The ELM filament is characterized by propagation in the ion-diamagnetic direction poloidally with a peak velocity of 11.4 km/s. The ELM crash lasts for approximately 100us until the radial propulsion settles back to the pre-ELM level. The experimental findings were compared with analytical theory. Two possible mechanisms were identified for explaining the observations: the curvature interchange model and the current-filament interaction model.

correlation↗

A System Approach to Deep Heating Savings Through Measurement, Management, and Motivation

Across multi-tenant commercial office and multifamily buildings, centrally metered fuel use represents a substantial fraction of whole-building energy use. Energy audit practitioners understand that improving heating distribution efficiency is typically more of an opportunity than combustion efficiency and that differing thermal comfort preferences between tenants are the bane of operators across these building typologies. There is an unmet market need for retrofit technologies that allow for the delivery of the right amount of heat to the right spaces, at the right time. The Energy Management and Information System (EMIS) package fills this gap through enhanced controls and metering, incorporating low-cost sensors and wireless communication infrastructure to provide a platform for ongoing commissioning and tenant feedback, including heat cost allocation. With support from the US DOE Building Technologies Office, Steven Winter Associates, Inc. (SWA) partnered with Sentient Buildings, E Source, building owners, and utility and policy stakeholders, to demonstrate a market viable EMIS that achieves a reduction in space heating energy use by reducing heating load, improving control, and positively impacting behavior while providing an acceptable financial return. In this study, EMIS packages were implemented in two New York City multifamily rental buildings. Both buildings conducted basic mechanical work (e.g., repairing steam traps) to ensure the heating system was operating well before any tenant feedback was layered in. Heating Energy Use Reports (HEUR) were created to provide tenants with social comparisons and energy savings tips to influence their behavior; these were provided monthly to all tenants in both buildings. Additionally, one building allocated heating costs to a portion of the tenants. Heat cost allocation (HCA) has a long history in the European Union (EU), although it is not common in the US or in steam-heated buildings. SWA leveraged existing EU best practices and stakeholder feedback to develop a Heat Cost Allocation algorithm that was considered equitable and intuitive. Energy use and tenant behavior impacts were tracked throughout the study. The basic mechanical repair work saved between 11-20% of heating energy. Those savings rose to 17-24% with the addition of tenant feedback. While it may not be possible to precisely determine the impact of COVID-19 on research studies like this, there may have been additional savings realized had the study taken place in a period of normal occupancy patterns. These types of central heating systems have been a blind spot for utilities, who have traditionally had little visibility into detailed behind-the-meter gas usage. Heating energy savings stayed consistent during the coldest months, indicating the potential for utilities to utilize EMIS packages for peak gas demand reductions or demand response programs. Tenant comfort was also improved. Post installation, room temperatures more closely matched thermostat set points. Perhaps due to this greater level of control, the vast majority of tenants being billed for heating were accepting of the allocation costs. And tenants receiving heat cost allocations were more likely to reduce their thermostat setpoints than tenants receiving behavioral feedback without financial impacts were. Variation in building specifics makes it difficult to provide precise energy and financial savings estimates. But within the range of expected conditions, the study identified a few key variables that can have the greatest impact on financial returns: the cost of fuel, the ability and willingness to allocate heating costs to tenants, and a well-functioning heating system as a starting point. This study focused on two multifamily buildings, but additional use cases, such as commercial buildings and affordable housing, should be explored to better understand the full market potential. While this type of upgrade has the potential for deep energy reductions and cost savings, future projects should take into account the balance of costs and benefits between owners and tenants, especially in the affordable, regulated, or other low-to-moderate income (LMI) segments of the market. Rent credits, utility allowances, or a shared savings program are possible options to accelerate adoption of this strategy in these market segments.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Lighting and visual comfort performance of commercially available tubular daylight devices

Tubular daylight devices (TDDs) require a much smaller roof opening than conventional skylights and, because of their highly reflective tube, they can deliver daylight farther away from the building envelope. This can provide lighting energy savings, increasing resilience in new and existing buildings. Different types and configurations are available amongst commercially available TDDs, including domes/diffusers with varying optical properties and the diameter of the TDD. This paper presents a comprehensive experimental evaluation of the lighting and visual comfort performance of multiple configurations of commercially available TDDs, varying dome type (prismatic and clear), diffuser type (Fresnel and prismatic), and diameter (53 and 35 cm), under a range of environmental conditions (different times of day/year, sky cover). Based on illuminance measurements, estimated lighting energy use is also presented. Results indicate that, for clear sky, light levels increase and energy use decreases with solar altitude (e.g., 16 Wh/m 2 daily energy use intensity on a high maximum daily solar altitude (MDSA) day and 34 Wh/m 2 on a low MDSA day) and TDD diameter (e.g., 34 Wh/m 2 and 69 Wh/m 2 for 53 cm and 35 cm TDDs, respectively, for low MDSA). The daily illuminance profile is more rounded for prismatic domes and has higher peaks for clear domes; this translates into a somewhat higher average daily useful daylight illuminance (DUDI) for prismatic domes (86 %) when compared to clear domes (80 %). No clear impact of diffuser type was apparent. In conclusion, measurements indicated no discomfort glare for any of the conditions tested.

14 SOLAR ENERGY↗

Characterization of injection and confinement improvement through impurity induced profile modifications on the Wendelstein 7-X stellarator

Pulsed injections of boron carbide granules into Wendelstein 7-X stellarator (W7-X) plasmas transiently increase the plasma stored energy and core ion temperatures above the reference W7-X experimental programs by up to 30%. In a series of 4 MW electron cyclotron resonance heating experiments, the PPPL Probe Mounted Powder Injector provided 50 ms bursts of 100 μm granules every 350 ms at estimated quantities ranging from approximately 1 mg/pulse to over 30 mg/pulse. For each injection, the stored energy was observed to initially drop and the radiated power transiently increased, while the radial electron density profile rose at the edge as material was assimilated. Once the injected boron carbide was fully absorbed, the density rise transitioned to the core while the stored energy increased above the previous baseline level by an amount linearly correlated with the injection quantity. During the injection, the ion temperature gradient steepened with peak core ion temperatures observed to increase from a nominal 1.7 keV to over 2.6 keV for the largest injection amounts. Enhanced performance is accompanied by a reversal of the radial electric field at ρ < 0.3, indicating that the core transport has switched to the ion root. These observations are suggestive of a change in transport and provide further evidence that externally induced profile modifications provide a possible path to enhanced W7-X performance metrics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Na 22 activation level measurements of fused silica rods in the LHC target absorber for neutrals compared to simulations

The Target Absorbers for Neutrals (TANs) are located in a high intensity radiation environment inside the tunnel of the Large Hadron Collider (LHC). TANs are positioned about 140 m downstream from the beam interaction points. Seven 40-cm long fused silica rods with different dopant specifications were irradiated in the TAN by the Beam RAte of Neutrals (BRAN) detector group during p + p data taking from 2016 to 2018 at the LHC. The peak dose delivered to the fused silica rods was 18 MGy. We report measurements of the 22 Na activation of the fused silica rods carried out at the University of Illinois at Urbana-Champaign and Argonne National Laboratory. At the end of the irradiation campaign, the maximum 22 Na activity observed was A = 21 kBq/cm 3 corresponding to a density, ρ = 2.5 x 10 12 /cm 3 , of 22 Na nuclei. FLUKA Monte Carlo simulations have been performed by the CERN FLUKA team to estimate 22 Na activities for the irradiated BRAN rod samples. The simulations reproduce the 22 Na activity profile measured along the rods, with a 35% underestimation of the experimental measurement results.

43 PARTICLE ACCELERATORS↗

AGR-5/6/7 Thermal Model with Non-uniform Gas Gaps

Fuel compact temperatures are a crucial factor in assessing irradiation performance of the Tristructural isotropic fuel particles. In the absence of direct measurement, fuel compact temperatures were calculated using a three-dimensional finite element thermal model, which is subject to simulation uncertainty. The most dominant factor in uncertainty of calculated fuel temperature is the gas gap uncertainty due to the nub-to-shell clearance because of fabrication error. A revision to the thermal model was made to examine the most probable offset position for four different dates of interest. The offset position options varied in magnitude and azimuthal direction of offset of the holder top and bottom position. The best-fit offset of the holder is estimated based on the minimum root mean square error of residuals for all operational thermocouples (TCs). From these results, the following conclusions were made: 1) During earlier cycles (162A – 164A) when numerous TCs were still operational, the best-fit offset distance varied in range [0.002 – 0.0035 in.] for both the top and bottom holder while offset azimuthal direction varied widely, especially for the holder bottom. 2) Holder offset led to slightly lower Capsule 1 average temperature, but wider temperature variation (lower minimum and higher peak fuel temperatures). 3) The maximum offset of 0.006 in. to the northwest direction for both the top and bottom holder yielded a much higher temperature than the original peak fuel temperature, which increased from 1422 to 1557 ? (or 135 ? increase). This could be one of the reasons for massive particle failure near the end of Cycle 165A. 4) Even though, the highest temperature at the TC-1-7 tip reached slightly higher than 1000?, the temperature along the TC wire reached as high as 1335? assuming a holder offset of 0.006 in. to the northwest. Consequently, at this temperature nickel from this TC wire could cause particle failures in Capsule 1.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Complete the Design, Cost Estimate, Assembly Plan, and Operating Instructions for a Bench-Scale Packed-Bed Tubular Methanol Catalyst Testing System

This report details the design of a test stand that converts carbon dioxide and hydrogen into methanol via a two-step process. The first step is a reverse water-gas shift reaction, carried out at 600°C and 25 bar to reduce carbon dioxide to carbon monoxide, and the second is a synthesis reaction that forms methanol at 260°C and 75 bar. The purpose of the system is to test catalysts for each of these steps. The test stand produces approximately 1.5 gallons of crude methanol (methanol mixed with water) per day, and recycles unreacted syngas for increased efficiency. At peak recycle, the stand is expected to consume 0.29 cylinders per day of carbon dioxide and 1.43 cylinders per day of hydrogen. It is planned to be built next to the Blue Star electrolysis unit in the Energy Systems Laboratory (ESL) and includes future plans of acquiring hydrogen from that stand rather than gas cylinders. At this phase of research, three key documents have been produced, as summarized in Table 1. These documents are primarily intended to describe the system and its operation, demonstrate that selected components are appropriate for the intended application, identify potential hazards, safeguards, and mitigation strategies, and ensure that the system is designed to appropriate standards. The body of the report and its appendices provide a narrative of the work completed in FY25. The parts required to build the test stand will be procured and assembled in FY26. Testing will be conducted in the final quarter.

10 - SYNTHETIC FUELS↗