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At least 505 records · Page 28

Synthesis of amino acyl adenylates using the tert-butoxycarbonyl protecting group

The synthesis of amino acyl adenylates using N-tert-butoxycarbonyl-protected amino acids is reported. Anhydrous solutions containing N-tert-butoxycarbonyl alanine, phenylalanine, and methionine were combined with the anhydrous mono (tri-n-octylammonium) salt of adenosine 5'-phosphate and the resultant amino acyl adenylates were characterized by means of elemental analysis, and infrared and proton NMR spectroscopy. Amino acyl adenylate yields of up to 60% were obtained with high purity at room temperatures. The reported synthesis is considered to represent a large improvement over previous methods due to the purity of the products, normal temperature requirements, and the stability of the starting compounds, which suggests its use in investigations of prebiotic oligo- and polypeptide synthesis.

Armstrong, D. W.↗

Coordinates of features on the Galilean satellites

The coordinate systems of each of the Galilean satellites are defined and coordinates of features seen in the Voyager pictures of these satellites are presented. The control nets of the satellites were computed by means of single block analytical triangulations. The normal equations were solved by the conjugate iterative method which is convenient and which converges rapidly as the initial estimates of the parameters are very good.

Davies, M. E.↗

Image processing in remote sensing data analysis - The state of the art

Image analysis techniques applicable to remote sensing data and covering image models, feature detection, segmentation and classification, texture analysis, and matching are studied. Model types for characterizing images examined include random-field, mosaic, and facet models. Edge and corner detection as well as global extraction of linear features are discussed. Pixel clustering and classification are covered in addition to the regional approach to segmentation. Autocorrelation, second-order gray level probability density, and the use of primitive element statistics are discussed in relation to texture analysis. Finally, reducing the cost of (sub)imaging matching methods (e.g., pixelwise comparison of gray levels and normalized cross-correlation between two images) as well as improving match sharpness is considered.

Rosenfeld, A.↗

Error detection process - Model, design, and its impact on computer performance

An analytical model is developed for computer error detection processes and applied to estimate their influence on system performance. Faults in the hardware, not in the design, are assumed to be the potential cause of transition to erroneous states during normal operations. The classification properties and associated recovery methods of error detection are discussed. The probability of obtaining an unreliable result is evaluated, along with the resulting computational loss. Error detection during design is considered and a feasible design space is outlined. Extension of the methods to account for the effects of extant multiple faults is indicated.

Shin, K. G.↗

Long range downwind propagation of low-frequency sound

The propagation of low-frequency noise outdoors was studied using as the source a large (80-m diameter) 4-megawatt horizontal axis wind turbine. Acoustic measurements were made with low-frequency microphone systems placed on the ground at five downwind sites ranging from 300 m to 10,000 m (6.3 mile) away from the wind turbine. The wind turbine fundamental was 1 Hz and the wind speed was generally 12 - 15 m/s at the hub height (80 m). The harmonic levels, when plotted versus propagation distance, exhibit a 3 dB per doubling of distance divergence. Two plausible explanations identified for this cylindrical spreading behavior were propagation of the low frequency wind turbine noise via a surface wave and downwind refraction. Surface was amplitude predictions were found to be more than 20 dB smaller than the measured levels. Ray-tracing results were used to qualitatively explain measured trends. A normal mode approach was identified as a candidate method for low-frequency acoustic refraction prediction.

Willshire, W. L., Jr.↗

Electrocatalytic reduction of oxygen on modified oxide surfaces

A first step which frequently occurs in the reduction of dioxygen, e.g., at the cathode of the alkaline fuel cell, is the two-electron reduction to the peroxyl ion, HO bar 2. For the efficiency of the fuel cell, this ion must be further reduced, or decomposed, to OH(-). Rate constants for HO bar 2 decomposition have been determined in 31 percent KOH at 25 C for the following catalysts in the form of suspended powders and Teflon-bonded electrodes: Pt, Au, cobalt tetrametoxyl phenyl porphyrin (CoTMPP), and La sub 0.5Pb sub 0.5MnO3. Rates were normalized to unit surface area measured by several methods as suitable. Where possible, four methods were used to measure rate constants: gasometric, oxygen probe, rotating disk electrode, and open-circuit potential decay. Steady-state polarization was also tried but was not as satisfactory. Comparisons are given for the methods in regard to reliability, applicability to the material, and convenience.

Chaffins, Scott A.↗

Computer aided mechanogenesis of skeletal muscle organs from single cells in vitro

Complex mechanical forces generated in the growing embryo play an important role in organogenesis. Computerized application of similar forces to differentiating skeletal muscle myoblasts in vitro generate three dimensional artificial muscle organs. These organs contain parallel networks of long unbranched myofibers organized into fascicle-like structures. Tendon development is initiated and the muscles are capable of performing directed, functional work. Kinetically engineered organs provide a new method for studying the growth and development of normal and diseased skeletal muscle.

Vandenburgh, Herman H.↗

VIPER project

The VIPER project has so far produced a formal specification of a 32 bit RISC microprocessor, an implementation of that chip in radiation-hard SOS technology, a partial proof of correctness of the implementation which is still being extended, and a large body of supporting software. The time has now come to consider what has been achieved and what directions should be pursued in the future. The most obvious lesson from the VIPER project was the time and effort needed to use formal methods properly. Most of the problems arose in the interfaces between different formalisms, e.g., between the (informal) English description and the HOL spec, between the block-level spec in HOL and the equivalent in ELLA needed by the low-level CAD tools. These interfaces need to be made rigorous or (better) eliminated. VIPER 1A (the latest chip) is designed to operate in pairs, to give protection against breakdowns in service as well as design faults. We have come to regard redundancy and formal design methods as complementary, the one to guard against normal component failures and the other to provide insurance against the risk of the common-cause failures which bedevil reliability predictions. Any future VIPER chips will certainly need improved performance to keep up with increasingly demanding applications. We have a prototype design (not yet specified formally) which includes 32 and 64 bit multiply, instruction pre-fetch, more efficient interface timing, and a new instruction to allow a quick response to peripheral requests. Work is under way to specify this device in MIRANDA, and then to refine the spec into a block-level design by top-down transformations. When the refinement is complete, a relatively simple proof checker should be able to demonstrate its correctness. This paper is presented in viewgraph form.

Kershaw, John↗

Measuring Microwave Conductivities Of Superconducting Films

Microwave conductivities of thin films of high-temperature superconductors like YBa(3)Cu(3)O(7-delta) measured by noninvasive, nondestructive microwave-power-transmission method. Measurements yield useful information on superconducting and normal states of films and contribute to evaluation of films for use in microwave devices.

Bhasin, K. B.↗

Computer-aided mechanogenesis of skeletal muscle organs from single cells in vitro

Complex mechanical forces generated in the growing embryo play an important role in organogenesis. Computerized application of similar forces to differentiating skeletal muscle myoblasts in vitro generate three dimensional artificial muscle organs. These organs contain parallel networks of long unbranched myofibers organized into fascicle-like structures. Tendon development is initiated and the muscles are capable of performing directed, functional work. Kinetically engineered organs provide a new method for studying the growth and development of normal and diseased skeletal muscle.

Vanderburgh, Herman H.↗

Damping formulas and experimental values of damping in flutter models

The problem of determining values of structural damping for use in flutter calculations is discussed. The concept of equivalent viscous damping is reviewed and its relation to the structural damping coefficient g introduced in NACA Technical Report No. 685 is shown. The theory of normal modes is reviewed and a number of methods are described for separating the motions associated with different modes. Equations are developed for use in evaluating the damping parameters from experimental data. Experimental results of measurements of damping in several flutter models are presented.

Coleman, Robert P↗

An extended theory of thin airfoils and its application to the biplane problem

The report presents a new treatment, due essentially to von Karman, of the problem of the thin airfoil. The standard formulae for the angle of zero lift and zero moment are first developed and the analysis is then extended to give the effect of disturbing or interference velocities, corresponding to an arbitrary potential flow, which are superimposed on a normal rectilinear flow over the airfoil. An approximate method is presented for obtaining the velocities induced by a 2-dimensional airfoil at a point some distance away. In certain cases this method has considerable advantage over the simple "lifting line" procedure usually adopted. The interference effects for a 2-dimensional biplane are considered in the light of the previous analysis. The results of the earlier sections are then applied to the general problem of the interference effects for a 3-dimensional biplane, and formulae and charts are given which permit the characteristics of the individual wings of an arbitrary biplane without sweepback or dihedral to be calculated. In the final section the conclusions drawn from the application of the theory to a considerable number of special cases are discussed, and curves are given illustrating certain of these conclusions and serving as examples to indicate the nature of the agreement between the theory and experiment.

Millikan, Clark B↗

Vaccum Gas Tungsten Arc Welding, phase 1

This two year program will investigate Vacuum Gas Tungsten Arc Welding (VGTAW) as a method to modify or improve the weldability of normally difficult-to-weld materials. VGTAW appears to offer a significant improvement in weldability because of the clean environment and lower heat input needed. The overall objective of the program is to develop the VGTAW technology and implement it into a manufacturing environment that will result in lower cost, better quality and higher reliability aerospace components for the space shuttle and other NASA space systems. Phase 1 of this program was aimed at demonstrating the process's ability to weld normally difficult-to-weld materials. Phase 2 will focus on further evaluation, a hardware demonstration and a plan to implement VGTAW technology into a manufacturing environment. During Phase 1, the following tasks were performed: (1) Task 11000 Facility Modification - an existing vacuum chamber was modified and adapted to a GTAW power supply; (2) Task 12000 Materials Selection - four difficult-to-weld materials typically used in the construction of aerospace hardware were chosen for study; (3) Task 13000 VGTAW Experiments - welding experiments were conducted under vacuum using the hollow tungsten electrode and evaluation. As a result of this effort, two materials, NARloy Z and Incoloy 903, were downselected for further characterization in Phase 2; and (4) Task 13100 Aluminum-Lithium Weld Studies - this task was added to the original work statement to investigate the effects of vacuum welding and weld pool vibration on aluminum-lithium alloys.

Weeks, J. L.↗

Vacuum Gas Tungsten Arc Welding

A two-year program investigated vacuum gas tungsten arc welding (VGTAW) as a method to modify or improve the weldability of normally difficult-to-weld materials. After a vacuum chamber and GTAW power supply were modified, several difficult-to-weld materials were studied and key parameters developed. Finally, Incoloy 903 weld overlays were produced without microfissures.

Weeks, J. L.↗

Grapevine Remote Sensing Analysis of Phylloxera Early Stress (GRAPES): Remote Sensing Analysis Summary

High spatial resolution airborne imagery was acquired in California's Napa Valley in 1993 and 1994 as part of the Grapevine Remote sensing Analysis of Phylloxera Early Stress (GRAPES) project. Investigators from NASA, the University of California, the California State University, and Robert Mondavi Winery examined the application of airborne digital imaging technology to vineyard management, with emphasis on detecting the phylloxera infestation in California vineyards. Because the root louse causes vine stress that leads to grapevine death in three to five years, the infested areas must be replanted with resistant rootstock. Early detection of infestation and changing cultural practices can compensate for vine damage. Vineyard managers need improved information to decide where and when to replant fields or sections of fields to minimize crop financial losses. Annual relative changes in leaf area due to phylloxera infestation were determined by using information obtained from computing Normalized Difference Vegetation Index (NDVI) images. Two other methods of monitoring vineyards through imagery were also investigated: optical sensing of the Red Edge Inflection Point (REIP), and thermal sensing. These did not convey the stress patterns as well as the NDVI imagery and require specialized sensor configurations. NDVI-derived products are recommended for monitoring phylloxera infestations.

Lobitz, Brad↗

Experimental Evaluation of Cermet Turbine Stator Blades for Use at Elevated Gas Temperatures

The suitability of cermets for turbine stator blades of a modified turbojet engine was determined at an average turbine-inlet-gas temperature of 2000 F. Such an increase in temperature would yield a premium in thrust from a service engine. Because the cermet blades require no cooling, all the available compressor bleed air could be used to cool a turbine made from conventional ductile alloys. Cermet blades were first run in 100-hour endurance tests at normal gas temperatures in order to evaluate two methods for mounting them. The elevated gas-temperature test was then run using the method of support considered best for high-temperature operation. After 52 hours at 2000 F, one of the group of four cermet blades fractured probably because of end loads resulting from thermal distortion of the spacer band of the nozzle diaphragm. Improved design of a service engine would preclude this cause of premature failure.

Chiarito, Patrick T.↗

Investigations of Pressure Distribution on Fast Flying Bodies

The question to be treated is: how high is the pressure in the bow wave caused by a body flying at supersonic speed, and how far reaching are the destructive effects of that wave? The pressure distribution on an s.S. and an S. projectile of normal speed has been ascertained already by the methods of measurement used at the Ballistic Institute of the Technical Academy of the German Air Forces. Now similar investigations of the conditions on especially fast-flying bodies were carried out.

Stamm, G.↗

Laser Surveying

NASA technology has produced a laser-aided system for surveying land boundaries in difficult terrain. It does the job more accurately than conventional methods, takes only one-third the time normally required, and is considerably less expensive. In surveying to mark property boundaries, the objective is to establish an accurate heading between two "corner" points. This is conventionally accomplished by erecting a "range pole" at one point and sighting it from the other point through an instrument called a theodolite. But how do you take a heading between two points which are not visible to each other, for instance, when tall trees, hills or other obstacles obstruct the line of sight? That was the problem confronting the U.S. Department of Agriculture's Forest Service. The Forest Service manages 187 million acres of land in 44 states and Puerto Rico. Unfortunately, National Forest System lands are not contiguous but intermingled in complex patterns with privately-owned land. In recent years much of the private land has been undergoing development for purposes ranging from timber harvesting to vacation resorts. There is a need for precise boundary definition so that both private owners and the Forest Service can manage their properties with confidence that they are not trespassing on the other's land.

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