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At least 505 records · Page 28

Materials development for precision segmented reflector applications

The requirements developed to guide the selection of current and future materials for precision segmented reflectors are presented along with a list of desirable properties. Some potential candidate materials including modified fiber reinforced organic matrix composites as well as carbon/carbon composites, graphite/glass composites, and metal matrix composites are identified. It is noted that in the near term, it is likely that modified fiber reinforced organic matrix composites have good applicability. In the longer term, materials such as carbon/carbon composites, graphite/glass composites and metal matrix composites may provide the best mix of properties.

Coulter, Daniel R.↗

Evaluation of the Terminal Sequencing and Spacing System for Performance Based Navigation Arrivals

NASA has developed the Terminal Sequencing and Spacing (TSS) system, a suite of advanced arrival management technologies combining timebased scheduling and controller precision spacing tools. TSS is a ground-based controller automation tool that facilitates sequencing and merging arrivals that have both current standard ATC routes and terminal Performance-Based Navigation (PBN) routes, especially during highly congested demand periods. In collaboration with the FAA and MITRE's Center for Advanced Aviation System Development (CAASD), TSS system performance was evaluated in human-in-the-loop (HITL) simulations with currently active controllers as participants. Traffic scenarios had mixed Area Navigation (RNAV) and Required Navigation Performance (RNP) equipage, where the more advanced RNP-equipped aircraft had preferential treatment with a shorter approach option. Simulation results indicate the TSS system achieved benefits by enabling PBN, while maintaining high throughput rates-10% above baseline demand levels. Flight path predictability improved, where path deviation was reduced by 2 NM on average and variance in the downwind leg length was 75% less. Arrivals flew more fuel-efficient descents for longer, spending an average of 39 seconds less in step-down level altitude segments. Self-reported controller workload was reduced, with statistically significant differences at the p less than 0.01 level. The RNP-equipped arrivals were also able to more frequently capitalize on the benefits of being "Best-Equipped, Best- Served" (BEBS), where less vectoring was needed and nearly all RNP approaches were conducted without interruption.

terminal sequencing↗

Femtosecond Laser Tagging Characterization of a Sweeping Jet Actuator Operating in the Compressible Regime

A sweeping jet (SWJ) actuator operating over a range of nozzle pressure ratios (NPRs) was characterized with femtosecond laser electronic excitation tagging (FLEET), single hot-wire anemometry (HWA) and high-speed/phase-averaged schlieren. FLEET velocimetry was successfully demonstrated in a highly unsteady, oscillatory flow containing subsonic through supersonic velocities. Qualitative comparisons between FLEET and HWA (which measured mass flux since the flow was compressible) showed relatively good agreement in the external flow profiles. The spreading rate was found to vary from 0.5 to 1.2 depending on the pressure ratio. The precision of FLEET velocity measurements in the external flow field was poorer (is approximately equal to 25 m/s) than reported in a previous study due to the use of relatively low laser fluences, impacting the velocity fluctuation measurements. FLEET enabled velocity measurements inside the device and showed that choking likely occurred for NPR ≥ 2.0, and no internal shockwaves were present. Qualitative oxygen concentration measurements using FLEET were explored in an effort to gauge the jet's mixing with the ambient. The jet was shown to mix well within roughly four throat diameters and mix fully within roughly eight throat diameters. Schlieren provided visualization of the internal and external flow fields and showed that the qualitative structure of the internal flow does not vary with pressure ratio and the sweeping mechanism observed for incompressible NPRs also probably holds for compressible NPRs.

Peters, Christopher J.↗

Titanium porous-transport layers for PEM water electrolysis prepared by tape casting

While the porous-transport layer (PTL) is a key component in PEM electrolyzers, it is one of the most underexplored due to limited available structures. In this work, we present a novel PTL design for PEM water electrolyzers enabled by a cost-effective, scalable tape-casting technique. Here, a precise control of the PTL pore structure is achieved by incorporating poreformers of various sizes, and by varying the titanium and poreformer ratio. The structures are characterized with SEM and synchrotron X-ray computed tomography imaging techniques. Comprehensive electrochemical performance analysis demonstrates that higher titanium loading provides improved contact at the catalyst-layer/PTL interface but suffers from severe mass-transport losses due to gas bubbles. We solve this mass-transport problem by mixing in large poreformer beads that produce a highly porous structure with excellent gas removal properties yet still maintaining mechanical integrity. The PTL fabricated with 60:40 Ti:PMMA ratio and 60 μm PMMA bead size outperformed the standard commercial Ti powder-based PTL by 62 mV at 4 A/cm 2 .

25 ENERGY STORAGE↗

Vaporizable endoskeletal droplets via tunable interfacial melting transitions

Liquid emulsion droplet evaporation is of importance for various sensing and imaging applications. The liquid-to-gas phase transformation is typically triggered thermally or acoustically by low–boiling point liquids, or by inclusion of solid structures that pin the vapor/liquid contact line to facilitate heterogeneous nucleation. However, these approaches lack precise tunability in vaporization behavior. Here, we describe a previously unused approach to control vaporization behavior through an endoskeleton that can melt and blend into the liquid core to either enhance or disrupt cohesive intermolecular forces. This effect is demonstrated using perfluoropentane (C 5 F 12 ) droplets encapsulating a fluorocarbon (FC) or hydrocarbon (HC) endoskeleton. FC skeletons inhibit vaporization, whereas HC skeletons trigger vaporization near the rotator melting transition. Our findings highlight the importance of skeletal interfacial mixing for initiating droplet vaporization. Tuning molecular interactions between the endoskeleton and droplet phase is generalizable for achieving emulsion or other secondary phase transitions, in emulsions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dual dressed black holes as the end point of the charged superradiant instability in $\mathcal{N} = 4$ Yang Mills

Charged Black holes in AdS_5 × S^5 A d S 5 × S 5 suffer from superradiant instabilities over a range of energies. Hairy black hole solutions (constructed within gauged supergravity) have previously been proposed as endpoints to this instability. We demonstrate that these hairy black holes are themselves unstable to the emission of large dual giant gravitons. We propose that the endpoint to this instability is given by Dual Dressed Black Holes (DDBH)s; configurations consisting of one, two, or three very large dual giant gravitons surrounding a core AdS A d S black hole with one, two, or three SO(6) S O ( 6 ) chemical potentials equal to unity. The dual giants each live at AdS A d S radial coordinates of order \sqrt{N} N and each carry charge of order N^2 N 2 . The large separation makes DDBHs a very weakly interacting mix of their components and allows for a simple computation of their thermodynamics. We conjecture that DDBHs dominate the phase diagram of \mathcal{N}=4 𝒩 = 4 Yang-Mills over a range of energies around the BPS plane, and provide an explicit construction of this phase diagram, briefly discussing the interplay with supersymmetry. We develop the quantum description of dual giants around black hole backgrounds and explicitly verify that DDBHs are stable to potential tunneling instabilities, precisely when the chemical potentials of the core black holes equal unity. We also construct the 10-dimensional DDBH bulk solutions.

Choi, Sunjin (ORCID:0000000283310199)↗

Bayesian Fit to NOvA Data Subsamples for Three Flavor Oscillation Analysis

NOvA (NuMI Off-Axis $\nu_e$ Appearance) is a long baseline neutrino experiment designed to measure the oscillation of muon neutrinos to electron neutrinos over a distance of 810 km. NOvA uses a near and far detector to observe $\nu_\mu$ disappearance and $\nu_e$ appearance of neutrinos produced by the NuMI beam at Fermilab. NOvA uses a Bayesian analysis framework in addition to its Frequentist method to measure neutrino oscillation parameters such as the mixing angles, mass ordering, and CP-violating phase. We report preliminary results of Bayesian fits to representative NOvA datasets. Comparison of fits to $\nu_\mu$ disappearance and $\nu_e$ appearance enables a cross-check of NOvA results with reactor $\bar{\nu_e}$ disappearance measurements. NOvA also searches for violation of Lorentz invariance by analyzing fits of forward horn current (FHC) versus reverse horn current (RHC) samples. The results validate and advance NOvA's contributions to precision measurements of neutrino properties.

Zhao, Larry [Fermilab]↗

Geochemistry of grain-size fractions of soils from the Taurus-Littrow valley floor

Results are presented for a study in which high-precision instrumental neutron activation analysis was applied to determine the abundances of seven rare-earth and nine other elements in two grain-size fractions (90 to 150 microns and less than 20 microns) of eight soils from the Taurus-Littrow Valley floor and one Apollo 11 bulk-soil fraction with grain sizes of less than 1 mm. Compositional differences between the two size fractions of two valley-floor soils are examined, and mixing of soil components is investigated. It is found that a five-component mixing model describes very adequately the chemical composition of bulk soils with grain sizes of less than 1 mm as mixtures of local Apollo 17 rock types (basalt, anorthositic gabbro, noritic breccia), orange glass, and meteorites, but does not describe well the chemical compositions of the other two size fractions. A ten-component model is used to show that the compositions of those two size fractions can be well represented as mixtures of the five components if the mineralogy and chemical composition of the basalt component are allowed to vary in the size fractions.

Korotev, R. L.↗

Recent advances in superconducting-mixer simulations

Over the last few years, considerable progress have been made in the development of techniques for fabricating high-quality superconducting circuits, and this success, together with major advances in the theoretical understanding of quantum detection and mixing at millimeter and submillimeter wavelengths, has made the development of CAD techniques for superconducting nonlinear circuits an important new enterprise. For example, arrays of quasioptical mixers are now being manufactured, where the antennas, matching networks, filters and superconducting tunnel junctions are all fabricated by depositing niobium and a variety of oxides on a single quartz substrate. There are no adjustable tuning elements on these integrated circuits, and therefore, one must be able to predict their electrical behavior precisely. This requirement, together with a general interest in the generic behavior of devices such as direct detectors and harmonic mixers, has lead us to develop a range of CAD tools for simulating the large-signal, small-signal, and noise behavior of superconducting tunnel junction circuits.

Withington, S.↗

Breaking Kelvin-Helmholtz waves and cloud-top entrainment as revealed by K-band Doppler radar

Radars have occasionally detected breaking Kelvin-Helmholtz (KH) waves under clear-air conditions in the atmospheric boundary layer and in the free troposphere. However, very few direct measurements of such waves within clouds have previously been reported and those have not clearly documented wave breaking. In this article, we present some of the most detailed and striking radar observations to date of breaking KH waves within clouds and at cloud top and discuss their relevance to the issue of cloud-top entrainment, which is believed to be important in convective and stratiform clouds. Aircraft observations reported by Stith suggest that vortex-like circulations near cloud top are an entrainment mechanism in cumuliform clouds. Laboratory and modeling studies have examined possibility that KH instability may be responsible for mixing at cloud top, but direct observations have not yet been presented. Preliminary analyses shown here may help fill this gap. The data presented in this paper were obtained during two field projects in 1991 that included observations from the NOAA Wave Propagation Laboratory's K-band Doppler radar (wavelength = 8.7 mm) and special rawinsonde ascents. The sensitivity (-30 dBZ at 10 km range), fine spatial resolution (375-m pulse length and 0.5 degrees beamwidth), velocity measurement precision (5-10 cm s-1), scanning capability, and relative immunity to ground clutter make it sensitive to non-precipitating and weakly precipitating clouds, and make it an excellent instrument to study gravity waves in clouds. In particular, the narrow beam width and short pulse length create scattering volumes that are cylinders 37.5 m long and 45 m (90 m) in diameter at 5 km (10 km) range. These characteristics allow the radar to resolve the detailed structure in breaking KH waves such as have been seen in photographic cloud images.

Martner, Brooks E.↗

Understanding the Stabilization and Tunability of Divalent Europium 2.2.2B Cryptates

Lanthanides such as europium with more accessible divalent states are useful for studying redox stability afforded by macrocyclic organic ligands. Substituted cryptands, such as 2.2.2B cryptand, that increase the oxidative stability of divalent europium also provide coordination environments that support synthetic alterations of Eu(II) cryptate complexes. Two single crystal structures were obtained containing nine-coordinate Eu(II) 2.2.2B cryptate complexes that differ by a single coordination site, the occupation of which is dictated by changes in reaction conditions. A crystal structure containing a [Eu(2.2.2B)Cl] + complex is obtained from a methanol–THF solvent mixture, while a methanol–acetonitrile solvent mixture affords a [Eu(2.2.2B)(CH 3 OH)] 2+ complex. While both crystals exhibit the typical blue emission observed in most Eu(II) containing compounds as a result of 4f 6 5d 1 to 4f 7 transitions, computational results show that the substitution of a Cl– anion in the place of a methanol molecule causes mixing of the 5d excited states in the Eu(II) 2.2.2B cryptate complex. Additionally, magnetism studies reveal the identity of the capping ligand in the Eu(II) 2.2.2B cryptate complex may also lead to exchange between Eu(II) metal centers facilitated by π-stacking interactions within the structure, slightly altering the anticipated magnetic moment. Finally, the synthetic control present in these systems makes them interesting candidates for studying less stable divalent lanthanides and the effects of precise modifications of the electronic structures of low valent lanthanide elements.

Anions↗

Diversifying Composition Leads to Hierarchical Composites with Design Flexibility and Structural Fidelity

Although significant progress has been made in the self-assembly of nanostructures, present successes heavily rely on precision in building block design, composition, and pair interactions. These requirements fundamentally limit our ability to synthesize macroscopic materials where the likelihood of impurity inclusion escalates and, more importantly, to access molecular-to-nanoscopic-to-microscopic-to-macroscopic hierarchies, since the types and compositions of building blocks vary at each stage. Inspired by biological blends and high-entropy alloys, we hypothesize that diversifying the blend’s composition can overcome these limitations. Increasing the number of components increases mixing entropy, leading to the dispersion of different components and, as a result, enhances interphase miscibility, weakens the dependence on specific pair interactions, and enables long-range cooperativity. This hypothesis is validated in complex blends containing small molecules, block copolymer-based supramolecules, and nanoparticles/colloidal particles. Hierarchically structured composites can be obtained with formulation flexibility in the filler selection and blend composition. It is worth noting that, by adding small molecules, we can solve the size constraint that plagues traditional block copolymer/nanoparticle blends. Detailed characterization and simulation further confirm that each component is distributed to locally mediate unfavorable interactions, cooperatively mitigate composition fluctuations, and retain structural fidelity. Furthermore, the blends have sufficient mobility to access tunable microstructures without compromising the order of the nanostructure. Besides establishing a kinetically viable pathway to release current constraints in the composite design and to navigate uncertainties during structure formation over multiple length scales, the present study demonstrates that entropy-driven behaviors can be realized in systems beyond high-entropy alloys despite inherent differences between metal alloys and organic/inorganic hybrids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Deterministic Fabrication of Large-Area, High-Crystallinity Oxide Moiré Superlattices

Oxide twistronics extends moiré engineering beyond van der Waals materials, offering a promising platform for accessing emergent interfacial phenomena arising from the strong coupling of lattice, charge, and orbital degrees of freedom in complex oxides. However, deterministic fabrication of high-crystallinity oxide moiré superlattices over large lateral dimensions remains challenging due to the three-dimensional bonding network of oxides. Here, we demonstrate a scalable, generalized fabrication strategy that enables the formation of high-crystallinity oxide moiré superlattices with clean, chemically bonded interfaces and precisely controlled twist angles down to nominal values of 0.1°, achieving subdegree twist-angle accuracy across large contiguous lateral dimensions approaching the millimeter scale. Using NaNbO3 as a model system, we show that the resulting interlayer coupling drives pronounced structural reconstruction that modifies both the phase structure and ferroelectric domain configuration. Synchrotron-based X-ray 3D reciprocal space mapping reveals the emergence of a single-phase state in twisted bilayers, in contrast to the mixed-phase structure observed in single-layer membranes prior to twist assembly. The structural signatures are further consistent with gradual lattice rotation distributed along the thickness direction that may accommodate interfacial shear strain, distinct from reconstruction observed in van der Waals moiré systems which primarily occurs through in-plane stacking rearrangement. This collective lattice response is correlated with twist-dependent nanoscale electromechanical modulations observed by piezoresponse force microscopy. These results establish a scalable materials platform for oxide twistronics and support the implementation of twist-engineered functionalities in practical, macroscale device architectures.

Ghanbari, Reza [North Carolina State University (N↗

Hot bottom burning in asymptotic giant branch stars and its effect on oxygen isotopic abundances

A self-consistent calculation of asymptotic giant branch (AGB) evolution was carried out, including nucleosynthesis at the base of the convective envelope (hot bottom burning). Hot bottom burning was found to occur for stars between approximately 4.5 and approximately 7 solar mass, producing envelopes with O-18/O-16 less than or equal to 10(exp -6) and 10(exp -3) approximately less than or equal O-17/O-16 approximately less than or equal to 10(exp -1). The O-17 abundance depends sensitively on the nuclear O-17-destruction rate; this rate is only loosely constrained by the requirement that first and second dredge-up models match O-isotope observations of red giant branch (RGB) stars (Boothroyd, Sackmann, & Wasserburg 1994). In some cases, high mass-loss rates can terminate hot bottom burning before further O-17 enrichment takes place or even before all O-18 is destroyed. These predictions are in accord with the very limited stellar observations of J type carbon stars on the AGB and with some of the circumstellar Al2O3 grains from meteorites. In contrast, precise data from a number of grains and data from most low-mass S and C AGB stars (approximately less than 1.7 solar mass) lie in a region of the O-18/O-16 versus O-17/O-16 diagram that is not accessible by first and second dredge-up or by hot bottom burning. We conclude that for AGB stars, the standard models of stellar evolution are not in accord with these observations. We surmise that an additional mixing mechanism must exist that transports material from the cool bottom of the stellar convective envelope to a depth at which O-18 is destroyed. This 'cool bottom processing' mechanism on the AGB is similar to extra mixing mechanisms proposed to explain the excess C-13 (and depleted C-12) observed in the earlier RGB stage of evolution and the large Li-7 depletion observed in low-mass main-sequence stars.

Boothroyd, Arnold I.↗

A New Source of Space Weather Data

The twin STEREO spacecraft were launched on October 26,2006 and, after spending several weeks in alignment orbits, became operational in heliocentric orbits on January 2 1,2007. The spacecraft are now in orbits similar to Earth's and are separating from each other at a rate of about 45 degrees per year as viewed from the sun. The STEREO spacecraft are each equipped with a complement of EUV, and white light imagers as well as particles and fields in situ instruments and a radio burst tracker. In addition to full resolution data downloaded once per day, each spacecraft broadcasts a real time telemetry 'beacon' stream containing compressed images and typically one minute averages of solar wind measurements and radio intensities. These real time data streams are received by a mix of NOAA and NASA-managed tracking stations and the data is transmitted by these stations to the STEREO Science Center at NASA Goddard Space Flight Center where they are processed into useable parameters with a latency of less than five minutes from receipt. As the two spacecraft recede from the sun-Earth line, triangulation of the imaging and radio measurements should allow better estimate of the speed and direction of coronal mass ejections, allowing a more precise estimate of their arrival at Earth. In situ particles and fields measurements, particularly for the spacecraft (Behind) trailing Earth in its orbit, will sample the solar wind that will eventually co-rotate around to the sun-Earth line. Late in the prime mission when the spacecraft are very far (>90 degrees) from the sun-Earth line, observations from the Behind spacecraft, will be particularly valuable for providing a preview of active regions well beyond the sun's East limb (as seen from Earth). Continually updated STEREO space weather data can be viewed and downloaded at http:/lstereo-ssc.nascom.nasa.govldata/beacon/.

Kaiser, Michael L.↗

Diagnosing the Sensitivity of Local Land-Atmosphere Coupling via the Soil Moisture-Boundary Layer Interaction

The inherent coupled nature of earth s energy and water cycles places significant importance on the proper representation and diagnosis of land atmosphere (LA) interactions in hydrometeorological prediction models. However, the precise nature of the soil moisture precipitation relationship at the local scale is largely determined by a series of nonlinear processes and feedbacks that are difficult to quantify. To quantify the strength of the local LA coupling (LoCo), this process chain must be considered both in full and as individual components through their relationships and sensitivities. To address this, recent modeling and diagnostic studies have been extended to 1) quantify the processes governing LoCo utilizing the thermodynamic properties of mixing diagrams, and 2) diagnose the sensitivity of coupled systems, including clouds and moist processes, to perturbations in soil moisture. This work employs NASA s Land Information System (LIS) coupled to the Weather Research and Forecasting (WRF) mesoscale model and simulations performed over the U.S. Southern Great Plains. The behavior of different planetary boundary layers (PBL) and land surface scheme couplings in LIS WRF are examined in the context of the evolution of thermodynamic quantities that link the surface soil moisture condition to the PBL regime, clouds, and precipitation. Specifically, the tendency toward saturation in the PBL is quantified by the lifting condensation level (LCL) deficit and addressed as a function of time and space. The sensitivity of the LCL deficit to the soil moisture condition is indicative of the strength of LoCo, where both positive and negative feedbacks can be identified. Overall, this methodology can be applied to any model or observations and is a crucial step toward improved evaluation and quantification of LoCo within models, particularly given the advent of next-generation satellite measurements of PBL and land surface properties along with advances in data assimilation schemes.

Santanello, Joseph A., Jr.↗

Nitrogen Dioxide Observations from the Geostationary Trace Gas and Aerosol Sensor Optimization (GeoTaso) Airborne Instrument: Retrieval Algorithm and Measurements During DISCOVER-AQ Texas 2013

The Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument is a test bed for upcoming air quality satellite instruments that will measure backscattered ultraviolet, visible and near-infrared light from geostationary orbit. GeoTASO flew on the NASA Falcon aircraft in its first intensive field measurement campaign during the Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) Earth Venture Mission over Houston, Texas, in September 2013. Measurements of backscattered solar radiation between 420 and 465 nm collected on 4 days during the campaign are used to determine slant column amounts of NO2 at 250 m x 250 m spatial resolution with a fitting precision of 2.2 x 10(exp 15) molecules/sq cm. These slant columns are converted to tropospheric NO2 vertical columns using a radiative transfer model and trace gas profiles from the Community Multiscale Air Quality (CMAQ) model. Total column NO2 from GeoTASO is well correlated with ground-based Pandora observations (r = 0.90 on the most polluted and cloud-free day of measurements and r = 0.74 overall), with GeoTASO NO2 slightly higher for the most polluted observations. Surface NO2 mixing ratios inferred from GeoTASO using the CMAQ model show good correlation with NO2 measured in situ at the surface during the campaign (r = 0.85). NO2 slant columns from GeoTASO also agree well with preliminary retrievals from the GEO-CAPE Airborne Simulator (GCAS) which flew on the NASA King Air B200 (r = 0.81, slope = 0.91). Enhanced NO2 is resolvable over areas of traffic NOx emissions and near individual petrochemical facilities.

Aerosol Sensor Optimization↗

Highly Structured Slow Solar Wind Emerging From an Equatorial Coronal Hole

At solar minimum, the solar wind is observed at high solar latitudes as a predominantly fast (> 500 km/s), highly Alfvenic, rarefied stream of plasma originating deep within coronal holes, while near the ecliptic plane it is interspersed with a more variable slow (< 500 kms) wind. The precise origins of the slow wind streams are less certain, with theories and observations supporting sources from the tips of helmet streamers, interchange reconnection near coronal hole boundaries, and origins within coronal holes with highly diverging magnetic fields. The heating mechanism required to drive the solar wind is also an open question and candidate mechanisms include Alfven wave turbulence, heating by reconnection in nanoflares, ion cyclotron wave heating and acceleration by thermal gradients1. At 1 au, the wind is mixed and evolved and much of the diagnostic structure of these sources and processes has been lost. Here we present new measurements from Parker Solar Probe at 36 to 54 solar radii that show clear evidence of slow, Alfvenic solar wind emerging from a small equatorial coronal hole. The measured magnetic field exhibits patches of large, intermittent reversals associated with jets of plasma and enhanced Poynting flux and interspersed in a smoother and less turbulent flow with near-radial magnetic field. Furthermore, plasma wave measurements suggest electron and ion velocity-space micro-instabilities that have been identified with plasma heating and thermalization processes. Our measurements suggest an impulsive mechanism associated with solar wind energization and a heating role for micro-instabilities and provide strong evidence for low latitude coronal holes as a significant contribution to the source of the slow solar wind.

Solar physics↗