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At least 505 records · Page 28

Skylab M551 Metals Melting Experiment

The objectives of the M551 Metals Melting Experiment are to (a) study behavior of molten metal, (b) characterize metals melted and solidified in the low gravity space environment compared to one-gravity of earth, and (c) determine feasibility of joining metals in space. The experiment used the electron beam (EB) and chamber of the M512 apparatus to make a dwell puddle and a melt in a rotating disc of varying thickness. Hence, the EB performed cut-through, full and partial penetration melts, in addition to a re-solidified button. The three disc materials were aluminum 2219-T87, 304 stainless steel and pure tantalum to provide a wide range of density and melting conditions. Observations to date include (a) the proof that EB welding, cutting and melting can be done successfully in low gravity. Earlier, some welding authorities had postulated that without gravity the EB would force the molten puddle out of contact. However, the experiment proved that surface tension forces predominate. (b) From the view-point of cast-solidification, small, equiaxed grains in Skylab specimens compared to large, elongated grains in ground-based specimens were observed. The former are thought to be associated with constitutional supercooling and nucleation where the latter are associated with dendritic solidification. In further support of the more equiaxed grain growth in Skylab, symmetric sub-grain patterns were frequently observed where there was much less symmetry in ground-based specimens. Further work is being done to explain the differences in solidification.

E C Mckannan↗

Preparing oxidizer coated metal fuel particles

A solid propellant composition of improved efficiency is described which includes an oxidizer containing ammonium perchlorate, and a powered metal fuel, preferably aluminum or beryllium, in the form of a composite. The metal fuel is contained in the crystalline lattice framework of the oxidizer, as well as within the oxidizer particles, and is disposed in the interstices between the oxidizer particles of the composition. The propellant composition is produced by a process comprising the crystallization of ammonium perchlorate in water, in the presence of finely divided aluminum or beryllium. A suitable binder is incorporated in the propellant composition to bind the individual particles of metal with the particles of oxidizer containing occluded metal.

Shafer, J. I.↗

Investigation and simulation of metallic spherules from lunar soils

The microstructure and chemical composition of metallic spherules from the lunar soil were studied by optical, electron-probe, and scanning-electron-microscope techniques. Metallic spherules produced experimentally were compared to the lunar spherules with respect to structure, chemistry, and cooling rates. The structure of the lunar spherules indicates an origin by solidification of molten globules of metal. The spherules are probably produced from both lunar and meteoric sources, the major source being the metal phase present in lunar rocks and soil.

Blau, P. J.↗

Metal abundances of RR Lyrae stars in galactic globular clusters

Results are reported for image-tube scanner measurements of Preston's (1959) metal-abundance indicator and metallic-line absorption in the G-band region (4285 to 4317 A) of 47 RR Lyrae stars in 12 galactic globular clusters and 67 RR Lyrae field stars. The relationship (Fe/H) is defined and determined from curve-of-growth analyses of 13 RR Lyrae field stars, while a comparison of metal-abundance vs metallic-line absorption relationships derived for the field and cluster stars indicates that both groups can be calibrated in the same way. Based on this calibration, (Fe/H) values are deduced for the globular-cluster stars and the clusters themselves. It is found that the alpha-rich phenomenon is present in these stars and is confined to calcium and titanium.

Butler, D.↗

Skylab M551 metals melting experiment

The objectives of the M551 Metals Melting Experiment were to: (1) study behavior of molten metal, (2) characterize metals melted and solidified in the low gravity space environment compared to one-gravity of earth, and (3) determine feasibility of joining metals in space. The experiment used the electron beam (EB) and chamber of the M512 apparatus to make a dwell puddle and a melt in a rotating disc of varying thickness. Hence, the EB performed cut-through, full and partial penetration melts, in addition to a resolidified button. The three disc materials were aluminum 2219-T87, 304 stainless steel, and pure tantalum to provide a wide range of density and melting conditions. Observations to date include the proof that EB welding, cutting, and melting can be done successfully in low gravity. Earlier, some welding authorities had postulated that without gravity the EB would force the molten puddle out of contact. However, the experiment proved that surface tension forces predominate. From the viewpoint of cast-solidification, small, equiaxed grains in Skylab specimens compared to large, elongated grains in ground based specimens were observed. The former are thought to be associated with constitutional supercooling and nucleation where the latter are associated with dendritic solidification. In further support of the more equiaxed grain growth in Skylab, symmetric subgrain patterns were frequently observed where there was much less symmetry in ground based specimens.

Poorman, R. M.↗

Transfer of molybdenum disulfide to various metals

Sliding friction experiments were conducted with molybdenum disulfide single crystals in contact with sputter cleaned surfaces of copper, nickel, gold, and 304 stainless steel. Transfer of the molybdenum disulfide to the metals was monitored with Auger electron spectroscopy. Results of the investigation indicate molybdenum disulfide transfers to all clean metal surfaces after a single pass over the metal surface with film thickness observed to increase with repeated passes over the same surfaces. Large particle transfer occurs when the orientation of the crystallites is other than basal. This is frequently accompanied by abrasion of the metal. Adhesion of molybdenum disulfide films occurred readily to copper and nickel, less readily to 304 stainless steel, and even less effectively to the gold, which indicates a chemical effect.

Barton, G. C.↗

Chemical fractionations in meteorites. VIII - Iron meteorites and the cosmochemical history of the metal phase

The chemical composition of the metal phase of iron meteorites is traced through an idealized traditional history from condensation, oxidation, and accretion in the nebula to melting, segregation, and freezing in a parent body, considering the following fifteen elements: Au, Co, Cu, Fe, Ga, Ge, Ir, Mo, Ni, Os, Pd, Pt, Re, Rh, and Ru. Twelve iron meteorite groups resolved by Scott and Wasson (1975) are considered in the framework of cosmochemical historical analysis. The parent bodies of five of these groups seem to have had a traditional history. The others seem to have had more unusual histories. For example, the composition of the metal in group IVB matches that predicted for the metal condensate at 1270 K, implying accretion at high temperatures; and the metal in group IVA has a composition indicative of aggregates undergoing progressive stages of partial melting.

Kelly, W. R.↗

New metal atom laser transitions in As, Bi, Ga, Ge, Hg, In, Pb, Sb, and Tl

A double discharge technique was used in the investigation. An initial discharge established between parallel arrays of tungsten pin electrodes was followed, after a variable time delay, by a high voltage (180 kV), short duration (50 nsec) secondary discharge between two aluminum main electrodes. Metal compounds, including metal alkyls, hydrides, and halides, were used to obtain the required metal atom concentrations. Twenty-four new laser transitions involving 9 different metal atoms were observed. The observed relations are shown in a number of partial energy-level diagrams.

Chou, M. S.↗

The metallic microstructures and thermal histories of severely reheated chondrites

The metallographic structures of eight severely reheated chondrites - Farmington, Ramsdorf, Orvinio, Wickenburg, Lubbock, Rose City, Arapahoe, and Tadjera - were studied using optical, SEM and electron microprobe techniques. The following metallographic criteria were used to estimate the post-shock residual temperature of the chondrites: melted metal-troilite appearance, presence of martensite, phosphorus enrichment of metal and averaging of central metal grain compositions. The presence of phosphides and secondary kamacite are due to slow post-shock cooling rates. Ni rim gradients indicate both extensive remelting of metal grains and relatively fast cooling.

Smith, B. A.↗

Friction and wear of single-crystal and polycrystalline maganese-zinc ferrite in contact with various metals

Sliding friction experiments were conducted with single-crystal (SCF) and hot-pressed polycrystalline (HPF) manganese-zinc ferrite in contact with various metals. Results indicate that the coefficients of friction for SCF and HPF are related to the relative chemical activity of those metals in high vacuum. The more active the metal, the higher the coefficient of friction. The coefficients of friction for both SCF and HPF were the same and much higher in vacuum than in argon at atmospheric pressure. All the metals tested transferred to the surface of both SCF and HPF in sliding. Both SCF and HPF exhibited cracking and fracture with sliding. Cracking in SCF is dependent on crystallographic characteristics. In HPF, cracking depends on the orientation of the individual crystallites.

Miyoshi, K.↗

Wear of single-crystal silicon carbide in contact with various metals in vacuum

Sliding friction experiments were conducted in vacuum with single crystal silicon carbide (0001) surface in contact with transition metals (tungsten, iron, rhodium, nickel, titanium, and cobalt), copper, and aluminum. The hexagon shaped cracking and fracturing of silicon carbide that occurred is believed to be due to cleavages of both the prismatic and basal planes. The silicon carbide wear debris, which was produced by brittle fracture, slides or rolls on both the metal and silicon carbide and produces grooves and indentations on these surfaces. The wear scars of aluminum and titanium, which have much stronger chemical affinity for silicon and carbon, are generally rougher than those of the other metals. Fracturing and cracking along the grain boundary of rhodium and tungsten were observed. These may be primarily due to the greater shear moduli of the metals.

Miyoshi, K.↗

Formation of metallic LiH

It is shown that a metallic form of LiH may be produced at the relatively low transition pressure of 1.1 mbar. LiH may thus be applied to studies of insulator-metal transition at high pressure. Experimental data is used to calculate LiH transition parameters: first, Herzfeld's criterion (1927) is used to determine the volume at which metallic behavior begins, and second, pressure-volume measurements for estimating the pressure at which this volume is achieved are extrapolated. For comparison, the same volume-pressure calculation is performed for H2, and it is found that the metallization of LiH should occur more easily than that of H2.

Vaisnys, J. R.↗

The origin of metal clasts in the Bencubbin meteoritic breccia

The Bencubbin meteorite is a shock-welded breccia consisting of a diverse collection of metal and silicate clasts. Several types of evidence suggest that the metal clasts in Bencubbin retain chemical abundances that were established during condensation. The Cr, Ni, P and trace element abundances are consistent with condensation calculations and are much closer to the predicted compositions of metal condensates than the CM metal particles. In addition, petrographic and chemical evidence strongly suggest that the breccia components were incorporated as solid clasts within the breccia prior to a shock heating event of very short duration, which did not produce significant metamorphic effects.

Newsom, H. E.↗

The Pd2Si - /Pd/ - Ni - solder plated metallization system for silicon solar cells

The rationale and application of a plated metal system, Pd2Si Pd - Ni - solder, is presented. This metallization system is particularly useful on shallow p-n junction solar cells. The advantages of such plated solar cell contacts are discussed. A process sequence for applying the metallization system is outlined. A specific example is presented, including chemical plating solution formulations and detailed process step descriptions. Electrical test data for solar cells metallized with the palladium-nickel-solder system are provided.

Coleman, M. G.↗

Analysis of uncertainties in turbine metal temperature predictions

An analysis was conducted to examine the extent to which various factors influence the accuracy of analytically predicting turbine blade metal temperatures and to determine the uncertainties in these predictions for several accuracies of the influence factors. The advanced turbofan engine gas conditions of 1700 K and 40 atmospheres were considered along with those of a highly instrumented high temperature turbine test rig and a low temperature turbine rig that simulated the engine conditions. The analysis showed that the uncertainty in analytically predicting local blade temperature was as much as 98 K, or 7.6 percent of the metal absolute temperature, with current knowledge of the influence factors. The expected reductions in uncertainties in the influence factors with additional knowledge and tests should reduce the uncertainty in predicting blade metal temperature to 28 K, or 2.1 percent of the metal absolute temperature.

Stepka, F. S.↗

Further development and application of polycrystalline metal whiskers

High strength metal whiskers have a larger versatile field of application than monocrystalline whiskers. Although polycrystalline metal whiskers can be used for composites, preferably by extrusion in thermoplastics or by infiltration of resins or metals into whisker networks, the chief application at present may be the production and various use of whisker networks. Such networks can be produced up to high degrees of porosity and besides high mechanical strength, they have high inside surfaces and high electric conductivity. There are for instance, applications concerning construction of electrodes for batteries and fuel cells, catalysts and also new heat-exchanger material, capable of preparing fuel oil and gasoline in order to assist a high-efficiency combustion. The technical application of polycrystalline metal whiskers require their modification as well as the construction of a pilot production unit.

Schladitz, H. J.↗

Metal-dielectric interactions

There is a wide variety of situations wherein metals are in solid state contact with dielectric materials. The paper reviews some of the factors that influence solid state interactions for metals in contact with dielectric surfaces. Since surfaces play an important part in these reactions, the use of analytical tools in characterizing surfaces is discussed. Adhesion, friction, and wear are utilized as indicators of the nature of interfacial bonding between metals and dielectrics can be effectively determined with adhesion and friction force measurements. Films present on the surface, such as oxygen or water vapor, markedly alter adhesive bond strength which in turn affects friction force and interfacial fracture when attempts are made to separate the contact regions. Analytical surface tools such as the field ion microscope, Auger emission spectroscopy, and X-ray photoelectron spectroscopy are very effective in providing insight into the effect of contact on the surfaces of metals and dielectrics.

Buckley, D. H.↗

Recent developments in liquid-metal embrittlement

The paper reviews developments in liquid-metal embrittlement of the past 7 years including data on cyclic loading. Embrittlement by solid and liquid metals and by hydrogen has many common features, although the mechanism of embrittler transport differs. Fracture may occur in each type of embrittlement by environmentally assisted shear and by reduced cohesion; embrittlement under cyclic loading has been widely observed, with stress level, temperature, and substrate alloy composition and grain size being the major variables. The degree of embrittlement between any combination of environment (i.e. hydrogen, liquid metal, or solid metal) and substrate depends upon the strength of the interaction with the substrate, the kinetics of embrittler transport, the mutual solubility of embrittler and substrate, and a large number of test and microstructural conditions. A method of calculating the most significant of these variables and the strength of interaction was reviewed and predictions of embrittlement in previously untested couples were made.

Stoloff, N. S.↗