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At least 505 records · Page 28

Evidence for Extended Aqueous Alteration in CR Carbonaceous Chondrites

We are currently studying the chemical interrelationships between the main rockforming components of carbonaceous chondrites (hereafter CC), e.g. silicate chondrules, refractory inclusions and metal grains, and the surrounding meteorite matrices. It is thought that the fine-grained materials that form CC matrices are representing samples of relatively unprocessed protoplanetary disk materials [1-3]. In fact, modern non-destructive analytical techniques have shown that CC matrices host a large diversity of stellar grains from many distinguishable stellar sources [4]. Aqueous alteration has played a role in homogeneizing the isotopic content that allows the identification of presolar grains [5]. On the other hand, detailed analytical techniques have found that the aqueously-altered CR, CM and CI chondrite groups contain matrices in which the organic matter has experienced significant processing concomitant to the formation of clays and other minerals. In this sense, clays have been found to be directly associated with complex organics [6, 7]. CR chondrites are particularly relevant in this context as this chondrite group contains abundant metal grains in the interstitial matrix, and inside glassy silicate chondrules. It is important because CR are known for exhibiting a large complexity of organic compounds [8-10], and only metallic Fe is considered essential in Fischer-Tropsch catalysis of organics [11-13]. Therefore, CR chondrites can be considered primitive materials capable to provide clues on the role played by aqueous alteration in the chemical evolution of their parent asteroids.

Trigo-Rodriquez, J. M.↗

A Case Study Using Modeling and Simulation to Predict Logistics Supply Chain Issues

Optimization of critical supply chains to deliver thousands of parts, materials, sub-assemblies, and vehicle structures as needed is vital to the success of the Constellation Program. Thorough analysis needs to be performed on the integrated supply chain processes to plan, source, make, deliver, and return critical items efficiently. Process modeling provides simulation technology-based, predictive solutions for supply chain problems which enable decision makers to reduce costs, accelerate cycle time and improve business performance. For example, United Space Alliance, LLC utilized this approach in late 2006 to build simulation models that recreated shuttle orbiter thruster failures and predicted the potential impact of thruster removals on logistics spare assets. The main objective was the early identification of possible problems in providing thruster spares for the remainder of the Shuttle Flight Manifest. After extensive analysis the model results were used to quantify potential problems and led to improvement actions in the supply chain. Similarly the proper modeling and analysis of Constellation parts, materials, operations, and information flows will help ensure the efficiency of the critical logistics supply chains and the overall success of the program.

Tucker, David A.↗

Marking Tests to Certify Part Identification Processes for Use in Low Earth Orbit

The primary purpose for the MISSE marking tests was to define Data Matrix symbol marking processes that will remain readable after exposure to Low Earth Orbit environments. A wide range of different Data Matrix symbol marking processes and materials, including some still under development, were evaluated. The samples flown on MISSE 1 and 2 were in orbit for 3 years and 348 days, MISSE 3 and 4 were in orbit for 1 year and 15 days, MISSE 6 was in orbit for 1 year and 130 days, and MISSE 8 was in orbit for 2 years and 55 days. The initial MISSE marking tests clearly reflected that intrusive marking processes can be successfully used for this purpose. All of the intrusive marking processes tested exceeded program expectations and met 100 percent of the principle investigators objectives. However, subsequent tests demonstrated that some additive marking processes will also satisfy the requirements. This was an unexpected result.

Roxby, D. L.↗

Evidence for the acceleration of ionospheric O/+/ in the magnetosheath of Venus

Plasma spectra from 12 orbits of the Pioneer-Venus Orbiter are reported which suggest the presence of ionospheric material in the magnetosheath plasma near and sunward of the terminator plane. Each spectrum shows a high E/q peak, consistent with O(+) moving at a speed lower than or comparable to that of the ambient magnetosheath plasma. It is pointed out that even though the data set is limited, the most intense heavy-ion fluxes clearly occur at altitudes less than a few thousand km. With the identification of the energetic component at O(+), the data reveal a trend for the speed of O(+) near the planet to be lower than the local magnetosheath speed, whereas the two speeds are comparable at altitudes above a few thousand km. These data, in combination with related observations that indicate O(+) moving at ambient speed in the distant wake, suggest that ionospheric material is swept up by the magnetosheath, accelerated to ambient speed within a few thousand km, and carried back through the wake region.

Mihalov, J. D.↗

Development of a Near-Real Time Hail Damage Swath Identification Algorithm for Vegetation

The Midwest is home to one of the world's largest agricultural growing regions. Between the time period of late May through early September, and with irrigation and seasonal rainfall these crops are able to reach their full maturity. Using moderate to high resolution remote sensors, the monitoring of the vegetation can be achieved using the red and near-infrared wavelengths. These wavelengths allow for the calculation of vegetation indices, such as Normalized Difference Vegetation Index (NDVI). The vegetation growth and greenness, in this region, grows and evolves uniformly as the growing season progresses. However one of the biggest threats to Midwest vegetation during the time period is thunderstorms that bring large hail and damaging winds. Hail and wind damage to crops can be very expensive to crop growers and, damage can be spread over long swaths associated with the tracks of the damaging storms. Damage to the vegetation can be apparent in remotely sensed imagery and is visible from space after storms slightly damage the crops, allowing for changes to occur slowly over time as the crops wilt or more readily apparent if the storms strip material from the crops or destroy them completely. Previous work on identifying these hail damage swaths used manual interpretation by the way of moderate and higher resolution satellite imagery. With the development of an automated and near-real time hail swath damage identification algorithm, detection can be improved, and more damage indicators be created in a faster and more efficient way. The automated detection of hail damage swaths will examine short-term, large changes in the vegetation by differencing near-real time eight day NDVI composites and comparing them to post storm imagery from the Moderate Resolution Imaging Spectroradiometer (MODIS) aboard Terra and Aqua and Visible Infrared Imaging Radiometer Suite (VIIRS) aboard Suomi NPP. In addition land surface temperatures from these instruments will be examined as for hail damage swath identification. Initial validation of the automated algorithm is based upon Storm Prediction Center storm reports but also the National Severe Storm Laboratory (NSSL) Maximum Estimated Size Hail (MESH) product. Opportunities for future work are also shown, with focus on expansion of this algorithm with pixel-based image classification techniques for tracking surface changes as a result of severe weather.

Bell, Jordan R.↗

The identification of group II inclusions in carbonaceous chondrites by electron probe microanalysis of perovskite

The technique developed by Kornacki (1984) for identifying group II Ca/Al-rich inclusions in carbonaceous chondrites by electron-microprobe analysis of the ZrO2 or Y2O3 content of their perovskite component is demonstrated using material from 20 Allende inclusions. The results are presented in tables and graphs and compared with findings obtained by other procedures. Group II inclusions are found to have perovskites generally containing less than 0.10 wt pct ZrO2 and/or Y2O3 (average of several grains), while those of groups I, III, V, and VI have more than 0.25 wt pct ZrO2. Analysis of data on eight Allende Ca/Al-rich inclusions shows that 75 percent of the fine-grained inclusions belong to group II. The implications of these findings for fractionation processes in the primitive solar nebula are indicated.

Kornacki, A. S.↗

Improved discrimination in photographic density contouring

Density discrimination can be accomplished through use of special photographic contouring material which has two sensitive layers (one negative, one positive) on single support. Process will be of interest to investigators who require finer discrimination of densities of original photograph for purposes such as identification of crops and analysis of energy levels of radiating objects.

Godding, R. A.↗

Automated solvent concentrator

Designed for automated drug identification system (AUDRI), device increases concentration by 100. Sample is first filtered, removing particulate contaminants and reducing water content of sample. Sample is extracted from filtered residue by specific solvent. Concentrator provides input material to analysis subsystem.

Griffith, J. S.↗

Carbon/graphite fiber risk analysis and assessment study: Assessment of risk to the Lockheed Model L-1011 commercial transport aircraft

The risk associated with the accidental release of carbon/graphite fibers (CF) from fires on commercial transport aircraft incorporating composite materials was assessed. Data are developed to evaluate the potential for CF damage to electrical and electronic equipment, assess the cost risk, and evaluate the hazard to continued operation. The subjects covered include identification of susceptible equipments, determination of infiltration transfer functions, analysis of airport operations, calculation of probabilities of equipment failures, assessment of the cost risk, and evaluation of the hazard to continued operation. The results show the risks associated with CF contamination are negligible through 1993.

Daniledes, J.↗

Microgravity Science and Application Program tasks, 1989 revision

The active research tasks, as of the fiscal year 1989, of the Microgravity Science and Applications Program, NASA Office of Space Science and Applications, involving several NASA Centers and other organizations are compiled. The purpose is to provide an overview of the program scope for managers and scientists in industry, university, and government communities. The scientists in industry, university, and government communities. An introductory description of the program, the strategy and overall goal, identification of the organizational structures and people involved, and a description of each task are included. Also provided is a list of recent publications. The tasks are grouped into several major categories: electronic materials, solidification of metals, alloys, and composites; fluids, interfaces, and transport; biotechnology; glasses and ceramics; combustion science; physical and chemistry experiments (PACE); and experimental technology, facilities, and instrumentation.

Source record↗

A Preliminary Investigation of the E-Beam Induced Polymerization of Maleimide and Norbornene End-capped Polyimides

A research area of high activity in connection with aerospace engineering has been the development of polymer thermosetting resins that can resist temperature as high as 300 C while maintaining adequate toughness, and providing ease of processing to enable low temperature and low cost composite fabrication methods. In order to meet such requirements, sequential interpenetrating polymer networks (IPNs) based on bismaleimide (BMI) and cyanate ester (CE) monomers were investigated. In these systems, a polycyanurate network is first formed in the presence of BMI and appropriate reactive diluent monomers and in a second step, a network based on the BMI is created in the presence of a fully formed polycyanurate network. The materials developed can be processed at relatively low temperature (less than 150 C) and with the aid of electron beam (EB) curing. Of major importance to the success of this work was the identification of a reactive diluent that improves ease of processing and has tailored reactivity to allow for the controlled synthesis of CE-BMI sequential IPNs. Based on solubility and reactivity of a number of reactive diluents, N-acryloylmorpholine (AMP) was selected as a comonomer for BMI copolymerization. A donor-acceptoreaction mechanism was suggested to explain the relative reactivity of a variety of reactive diluents towards maleimide functionality. The optimum processing parameters for the formation of the first network were determined through the study of metal catalyzed cure and hydrolysis of cyanate esters, whereas the reaction behavior for second network formation in terms of the influence of EB dose rate and temperature was elucidated through an in-situ kinetics study of maleimide and AMP copolymerization. Structure-property relationships were developed which allowed for the design of improved resin systems. In particular, appropriate network coupler possessing cyanate ester and maleimide functionality was synthesized to link the polycyanurate first network to the BMI/AMP second network and thus form linked sequential IPNs (LIPNs). Consequently, Tg as high as 370 C was achieved and a fracture toughness of 120 Joules per square meters was obtained for resin systems that possess adequately low viscosity for processing using liquid molding techniques at low temperature.

Palmese, Giuseppe R.↗

Analysis of Bioburden Associated with Nonmetallic Spacecraft Materials

Planetary Protection (PP) requirements help to ensure the integrity of life-detection science conducted on solar system bodies, particularly those with liquid water. Such requirements are often met by a combination of cleaning and verification steps to reduce microbial contamination (i.e. bioburden) to an acceptable limit. There are only two cleaning methods approved by the National and Space Administration (NASA), vapor hydrogen peroxide (VHP) and heat microbial reduction (HMR), the latter of which is the most commonly employed. However, HMR can be harsh and produce its own concerns about material integrity, like aging or increasing hardness. When bioburden reduction methods cannot be employed, the project must rely on assumed NASA specification values of bioburden which can cause compliance issues with strict PP bioburden limitations. This work aimed to more accurately define the risk of contamination of a target body by providing empirical data associated with raw materials commonly used in solid rocket motors for lander missions. In this study, we pulverized nonmetallic materials using a cryogenic grinder, then analyzed the resulting substrate for microbial colony forming units (CFU). We found that many nonmetallic materials do not harbor large bioburden when compared with the NASA specification values, though a range existed depending on the material, treatment, and handling. The results from this work provide quantitative data to help reduce concerns of contamination, while also providing a foundation for follow up studies into additional sterilization methods and molecular identification of contaminating microbes.

Planetary Protection↗

Effect of Preloading on Fatigue Strength in Dynamic Fatigue Testing of Ceramic Materials at Elevated Temperatures

Previously derived solutions of fatigue strength as a function of preloading were verified by applying preloads to elevated temperature dynamic fatigue tests of 96 wt% alumina at 1000 C and NC 132 silicon nitride at 1100 C. The technique was found very useful in identification and control of the governing failure mechanism when multiple failure mechanisms, such as slow crack growth, creep and oxidation occurred simultaneously at elevated temperatures.

Choi, Sung R.↗

Crystallographic Oxide Phase Identification of Char Deposits Obtained from Space Shuttle Columbia Window Debris

Analyzing the remains of Space Shuttle Columbia has proven technically beneficial years after the vehicle breakup. This investigation focused on charred deposits on fragments of Columbia overhead windowpanes. Results were unexpected relative to the engineering understanding of material performance in a reentry environment. The TEM analysis demonstrated that the oxides of aluminum and titanium mixed with silicon oxides to preserve a history of thermal conditions to which portions of the vehicle were exposed. The presence of Ti during the beginning of the deposition process, along with the thermodynamic phase precipitation upon cool down, indicate that temperatures well above the Ti melt point were experienced. The stratified observations implied that additional exothermic reaction, expectedly metal combustion of a Ti structure, had to be present for oxide formation. Results are significant for aerospace vehicles where thermal protection system (TPS) breaches cause substructures to be in direct path with the reentry plasma. 1

Olivas, J. D.↗

Methods of measurement for semiconductor materials, process control, and devices

Activities directed toward the development of methods of measurement for semiconductor materials, process control, and devices are described. Topics investigated include: measurements of transistor delay time; application of the infrared response technique to the study of radiation-damaged, lithium-drifted silicon detectors; and identification of a condition that minimizes wire flexure and reduces the failure rate of wire bonds in transistors and integrated circuits under slow thermal cycling conditions. Supplementary data concerning staff, standards committee activities, technical services, and publications are included as appendixes.

Bullis, W. M.↗

Data and results from a study of internal convective cooling systems for hypersonic aircraft

An extensive survey of current and future airframe construction materials and coolants was conducted, so that the most promising candidates could be examined for cooled-panel, cooling-system and airframe concepts. Consideration was given to over 100 structural materials, 50 coolants, 6 classes of structural panel concepts, 4 classes of thermal panel concepts with numerous variations, and 3 overall cooled airframe design approaches, including unshielded, shielded, and dual temperature types. The concept identification and parametric comparison phase examined all major elements of the convectively cooled airframe, including the differing requirements at various locations on the aircraft. The parametric results were used for the investigation to two separate vehicles, a hypersonic transport with a length of 96 meters (314 feet) and a weight of 24,000 kg (528,600 lb) and a hypersonic research airplane, with a length of 25m (80 ft) and a weight of 20,300 kg (447,000 lb).

Anthony, F. M.↗

Reliability and engineering of thin-film photovoltaic modules

Objectives were to: examine thin-film cell attributes that influence module performance and reliability, explore the lessons and applicability of crystalline-silicon module technology to thin-film modules, review the current status of thin-film module technologies, and identify problem areas and needed research. A major need is to separate the effects and resons for reversible degradatin from nonreversible degradation. Amorphous-silicon (a-Si) reliability investigations are focusing on exploratory research investigations, accelerated Arrhenius-type testing of a-Si cells, real-time outdoor exposure testing of a-Si cells, cell failure analysis, and failure mechanism research. Studies included the reduction in strength of glass by high temperature depositions on glass and laser scribing, encapsulation materials development needs, and the testing of modules. The new materials and processes in thin-film modules will require a delinquent reliability effort, including: establishment of mechanism-specific reliability goals; quantification of mechanism parameter dependencies; prediction of expected long-term degradation; identification of cost-effective solutions; and testing and failure analysis of trial solutions.

Royal, E. L.↗

Microscale Distribution of Hydrogen Isotopes in Two Carbonaceous Chondrites

Hydrogen isotopes are highly variable among primitive meteorites and interplanetary dust particles (IDPs) [1, 2]. In particular, many primitive objects exhibit D (and N-15) enrichments, relative to terrestrial values, thought to represent partial preservation of presolar material fractionated in molecular clouds. However, the diversity of D/H ratios among IDPs and chondrites indicates a complex history of processing in the solar nebula and on meteorite parent bodies. Deconvolving this record requires identification and characterization of the carriers of D enrichments in different objects. Isotopic imaging has proven to be a powerful method to quantitatively explore the distribution of D/H ratios on a one to several m scale in IDPs [2-4] and the CR chondrite Renazzo [5, 6]. In this study, we have used ion imaging to explore the microscale D/H distribution of two carbonaceous chondrites, Tagish Lake (unique) and Al Rais (CR2). Previous D/H measurements (on a ~tens of microns scale) of Tagish Lake matrix fragments by Messenger [7] and Engrand et al. [8] have found different results, most likely related to the analytical techniques used. Previous work has also shown a large range of D/H ratios in CR chondrites, including very large variations on a scale of a few microns [5, 6, 9].

Young, A. F.↗