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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Uncertainty Quantification in Vibro-Acoustics Diagnosis of Alkali-Silica Reaction Degradation in Medium-Sized Concrete Samples

The objectives of this ongoing research project focus on health monitoring and data analytics of concrete slabs containing reactive aggregates and thus subjected to degradation due to alkali-silica reaction (ASR). A controlled concrete slab with four pockets of reactive aggregates (pure silica, wells, placitas, and spratt) was cast at Vanderbilt University and cured in representative conditions to accelerate degradation due to ASR. A set of four concrete samples were also cast and cured at the University of Alabama for ASR testing. Of these four samples, two slabs contained reactive aggregates while the other two had the non-reactive aggregate counterparts mixed throughout the samples. Vibro-acoustic testing was used on these slabs to locate ASR damage within the reactive samples. Vibro-acoustic modulation (VAM) is a vibration-based NDE method that utilizes signatures of nonlinear dynamic interactions on contact surfaces of crack or delamination damage to detect and localize the damage. VAM analysis was conducted on both the Vanderbilt and Alabama samples using multiple variables for damage detection and localization. The results from the data analysis of the vibro-acoustic testing on concrete slabs cured at Vanderbilt University and the University of Alabama are discussed in detail in this report. Results for damage localization are dependent on multiple variables used in the vibro-acoustic modulation experiments. A major focus of this report is to quantify the uncertainty in the diagnosis due to multiple factors and uncertainty sources. The uncertainty quantification methodology presented in this report was applied to VAM-based diagnosis and prognosis. However, the methodology is general, and is capable of being applied to multiple technique that collect spatially distributed data. Future work needs to investigate the incorporation of uncertainty quantification in developing a robust Prognostics and Health Management framework. Digital image correlation is a three-dimensional, full-field, optical NDE technique to measure contour, deformation, vibration, and strain. The application of the digital image correlation technique to study ASR-related degradation on a large concrete specimen at the University of Tennessee is discussed and observations are presented in this report.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

“Thought experiments” as dry-runs for “tough experiments”: novel approaches to the hydration behavior of oxyanions

We explore the deconvolution of correlations for the interpretation of the microstructural behavior of aqueous electrolytes according to the neutron diffraction with isotopic substitution (NDIS) approach toward the experimental determination of ion coordination numbers of systems involving oxyanions, in particular, sulfate anions. We discuss the alluded interplay in the title of this presentation, emphasized the expectations, and highlight the significance of tackling the challenging NDIS experiments. Specifically, we focus on the potential occurrence of N$2+\atop{i}$ ...SO$2-\atop{4}$ pair formation, identify its signature, suggest novel ways either for the direct probe of the contact ion pair (CIP) strength and the subsequent correction of its effects on the measured coordination numbers, or for the determination of anion coordination numbers free of CIP contributions through the implementation of null-cation environments. For that purpose we perform simulations of NiSO 4 aqueous solutions at ambient conditions to generate the distribution functions required in the analysis (a) to identify the individual partial contributions to the total neutron-weighted distribution function, (b) to isolate and assess the contribution of N$2+\atop{i}$ ...SO$2-\atop{4}$ pair formation, (c) to test the accuracy of the neutron diffraction with isotope substitution based coordination calculations and X-ray diffraction based assumptions, and (d) to describe the water coordination around both the sulfur and oxygen sites of the sulfate anion. In conclusion, we finally discuss the strength of this interplay on the basis of the inherent molecular simulation ability to provide all pair correlation functions that fully characterize the system microstructure and allows us to “reconstruct” the eventual NDIS output, i.e., to take an atomistic “peek” (e.g., see Figure 1) at the local environment around the isotopically-labeled species before any experiment is ever attempted, and ultimately, to test the accuracy of the “measured” NDIS-based coordination numbers against the actual values by the “direct” counting.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Heteronuclear Correlation SSNMR Spectroscopy with Indirect Detection under Fast Magic-Angle Spinning [Book Chapter]

The main focus of this chapter is to address experimental strategies on the subject by providing a hands-on guide to fast MAS experiments, with a particular focus on indirect detection. Although our experience is limited to our respective laboratories in Ames and Yokohama, we hope that our descriptions of experimental setups and optimization procedures are sufficiently general to be applicable to all modern instruments. The chapter is organized as follows. Section 2 below introduces briefly the fast MAS technology and its main advantages. In Section 3, we describe the hardware associated with this remarkable technology and provide practical advices on its use, including procedures for loading and unloading the samples, maintaining the probe, reducing t 1 noise, etc. In Section 4, we describe the principles and hands-on aspects of experiments involving the indirect detection of spin-1/2 and 14 N nuclei

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A status report on the characterization of the microgravity environment of the International Space Station

A primary objective of the International Space Station is to provide a long-term quiescent environment for the conduct of scientific research for a variety of microgravity science disciplines. Since continuous human presence on the space station began in November 2000 through the end of Increment-6, over 1260 hours of crew time have been allocated to research. However, far more research time has been accumulated by experiments controlled on the ground. By the end of the time period covered by this paper (end of Increment-6), the total experiment hours performed on the station are well over 100,000 hours (Expedition 6 Press Kit: Station Begins Third Year of Human Occupation, Boeing/USA/NASA, October 25, 2002). This paper presents the results of the on-going effort by the Principal Investigator Microgravity Services project, at NASA Glenn Research Center, in Cleveland, Ohio, to characterize the microgravity environment of the International Space Station in order to keep the microgravity scientific community apprised of the reduced gravity environment provided by the station for the performance of space experiments. This paper focuses on the station microgravity environment for Increments 5 and 6. During that period over 580 Gbytes of acceleration data were collected, out of which over 34,790 hours were analyzed. The results presented in this paper are divided into two sections: quasi-steady and vibratory. For the quasi-steady analysis, over 7794 hours of acceleration data were analyzed, while over 27,000 hours were analyzed for the vibratory analysis. The results of the data analysis are presented in this paper in the form of a grand summary for the period under consideration. For the quasi-steady acceleration response, results are presented in the form of a 95% confidence interval for the station during "normal microgravity mode operations" for the following three attitudes: local vertical local horizontal, X-axis perpendicular to the orbit plane and the Russian torque equilibrium attitude. The same analysis was performed for the station during "non-microgravity mode operations" to assess the station quasi-steady acceleration environment over a long period of time. The same type of analysis was performed for the vibratory, but a 95th percentile benchmark was used, which shows the overall acceleration magnitude during Increments 5 and 6. The results, for both quasi-steady and vibratory acceleration response, show that the station is not yet meeting the microgravity requirements during the microgravity mode operations. However, it should be stressed that the requirements apply only at assembly complete, whereas the results presented below apply up to the station's configuration at the end of Increment-6. c2004 Elsevier Ltd. All rights reserved.

ISS Project↗

What's Left for a Computational Chemist To Do in the Age of Machine Learning?

Machine learning (ML) has become a central focus of the computational chemistry community. In this paper, I will first discuss my personal history in the field. Then I will provide a broader view of how this resurgence in ML interest echoes and advances upon earlier efforts. Although numerous changes have brought about this latest wave, one of the most significant is the increased accuracy and efficiency of low-cost methods (e.g., density functional theory or DFT) that have made it possible to generate large data sets for ML models. ML has also been used to bypass, guide, or improve DFT. The field of computational chemistry thus finds itself at a crossroads as ML both augments and supersedes traditional efforts. I will present what I believe the role of the computational chemist will be in this evolving landscape, with specific focus on my experience in the development of autonomous workflows in computational materials discovery for open-shell transition-metal chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Experimental investigation of the effect of pore size distribution on nano-particle capture efficiency within ceramic particulate filters

The effect of the pore size distribution on size-resolved filtration efficiency was investigated for two ceramic particulate filters using particulate matter (PM) generated by a spark-ignition direct-injection engine fueled with gasoline. The cordierite filter tested had a porosity of 43%, a median pore diameter (d_50) of 12 µm, and a wide pore size distribution with a lognormal standard deviation (s’) of 0.3. The aluminum titanate filter had very similar porosity, d_50, and thickness, but significantly narrower pore size distribution (s’ = 0.1). The testing of two filters under identical experimental conditions enabled the impact of the pore size distribution on filtration performance to be evaluated. Filtration experiments were performed focusing on just the filter wall, starting from a clean filter until the transition to cake filtration (filtration efficiency > 99%). Time-resolved particle size distribution measurements were used to evaluate the progression of filtration performance and estimate trapped mass within the filter. The aluminum titanate filter, with a narrow pore size distribution, exhibited significantly better diffusion capture efficiency. The negative impact of higher flow velocity on diffusion capture efficiency was more pronounced for a narrower pore size distribution. Flow distributions measured using capillary-flow porometry were used to develop a cylindrical pore flow model to understand the impact of the differences in pore size distribution on observed trends in diffusion capture efficiency within a clean filter. The model helps demonstrate how large pores on the high end of a wider pore size distribution can carry a large fraction of the flow, with less efficient capture of small particles by diffusion. The experimental results and data demonstrate that the bubble point diameter and width of the pore size distribution significantly influence diffusion capture efficiencies for filters with very similar median pore diameter, porosity, and thickness.

aerosol filtration, Aftertreatment, ceramic exhaus↗

Recent and planned hydrodynamic instability experiments on indirect-drive implosions on the National Ignition Facility

At National Ignition Facility (NIF), yield amplification due to alpha particle heating approached ~3 in the highest performing inertial confinement fusion (ICF) implosions, while yield amplification of ~15-30 is needed for ignition. Hydrodynamic instabilities are a major factor in degradation of implosions while understanding and mitigation of the instabilities are critical to achieving ignition. This article describes recent and planned hydrodynamic instability experiments with several focused platforms that have been developed to directly measure these instabilities in all phases of ICF implosions. Measurements of ripple-shock generation at OMEGA laser have indicated initial seeds for the instabilities in three ablators - plastic (CH), beryllium, and high-density carbon (HDC). Hydrodynamic Growth Radiography (HGR) platform was used to measure instability growth at the ablation front in the acceleration phase of implosions. This platform used pre-imposed 2-D perturbations for growth factor measurements at different perturbation wavelengths and was also used to measure growth of “native roughness” modulations, fill tubes, and capsule support membranes or “tents”. Also, in the acceleration phase several new experimental platforms have been or are being developed to measure instability growth at the ablator-ice interface. In the deceleration phase of implosions, “self-emission” and “self-backlighting” platforms were developed to measure perturbations near peak compression. This article reviews recent progress and results.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Study of hydraulic fracturing processes in shale formations with complex geological settings

Hydraulic fracturing has been applied to extract gas from shale-gas reservoirs. Complicated geological settings, such as spatial variability of the rock mass properties, local heterogeneities, complex in situ stress field, and pre-existing bedding planes and faults, could make hydraulic fracturing a challenging task. In order to effectively and economically recover gas from such reservoirs, it is crucial to explore how hydraulic fracturing performs in such complex geological settings. For this purpose, numerical modelling plays an important role because such conditions cannot be reproduced by laboratory experiments. This study focuses on the analysis of the influence of confining formations and pre-existing bedding planes and faults on the hydraulically-induced propagation of a vertical fracture, which will be called injection fracture, in a shale-gas reservoir. An elastic-brittle model based on material property degradation was implemented in a 2D finite-difference scheme and used for rock elements subjected to tension and shear failure. A base case is considered, in which the ratio SR between the magnitudes of the horizontal and vertical stresses, the permeability k c of the confining formations, the elastic modulus E p and initial permeability k p of the bedding plane and the initial fault permeability k F are fixed at reasonable values. In addition, the influence of multiple bedding planes, is investigated. Changes in pore pressure and permeability due to high pressure injection lasting 2 h were analysed. Results show that in our case during the injection period the fracture reaches the confining formations and if the permeability of those layers is significantly larger than that of the shale, the pore pressure at the extended fracture tip decreases and fracture propagation becomes slower. After shut-in, the pore pressure decreases more and the fracture does not propagate any more. For bedding planes oriented perpendicular to the maximum principal stress direction and with the same elastic properties as the shale formation, results were found not to be influenced by their presence. In such a scenario, the impact of multiple bedding planes on fracture propagation is negligible. On the other hand, a bedding plane softer than the surrounding shale formation leads to a fracture propagation asymmetrical vertically with respect to the centre of the injection fracture with a more limited upward fracture propagation. A pre-existing fault leads to a decrease in fracture propagation because of fault reactivation with shear failure. This results in a smaller increase in injection fracture permeability and a slight higher injection pressure than that observed without the fault. Results of a sensitivity analysis show that fracture propagation is influenced by the stress ratio SR, the permeability k c of the confining formations and the initial permeability k p of the bedding plane more than the other major parameters.

58 GEOSCIENCES↗

Hydrodynamic instability experiments with three-dimensional modulations at the National Ignition Facility

The first hydrodynamic instability growth measurements with three-dimensional (3D) surface-roughness modulations were performed on CH shell spherical implosions at the National Ignition Facility (NIF) [G. H. Miller, E. I. Moses, and C. R. Wuest, Opt. Eng. 43, 2841 (2004)]. The initial capsule outer-surface amplitudes were increased approximately four times, compared with the standard specifications, to increase the signal-to-noise ratio, helping to qualify a technique for measuring small 3D modulations. The instability growth measurements were performed using x-ray through-foil radiography based on time-resolved pinhole imaging. Averaging over 15 similar images significantly increased the signal-to-noise ratio, making possible a comparison with 3D simulations. At a convergence ratio of ~2.4, the measured modulation levels were ~3 times larger than those simulated based on the growth of the known imposed initial surface modulations. Several hypotheses are discussed, including increased instability growth due to modulations of the oxygen content in the bulk of the capsule. In conclusion, future experiments will be focused on measurements with standard 3D ‘native-roughness’ capsules as well as with deliberately imposed oxygen modulations.

42 ENGINEERING↗

Sixth user workshop on high-power lasers at the linac coherent light source

The international user workshop on High-Power Lasers at the Linac Coherent Light Source (LCLS) was held at SLAC National Accelerator Laboratory (SLAC) in Menlo Park, CA on September 25-26, 2018. More than 100 scientists attended the workshop, which focused on recent experiments and developments at the LCLS – Matter in Extreme Conditions (MEC) end station and, more generally, the scientific frontiers that can be explored using the combination of highpower lasers and the LCLS hard X-ray free electron laser (XFEL). This workshop was the sixth annual meeting in a series that has promoted information exchange between users and has provided recommendations on capability upgrades at LCLS-MEC.

47 OTHER INSTRUMENTATION↗

The Dynamics of Megafire Smoke Plumes in Climate Models: Why a Converged Solution Matters for Physical Interpretations

As the climate system warms, megafires have become more frequent with devastating effects. A byproduct of these events is the creation of smoke plumes that can rise into the stratosphere and spread across the globe where they reside for many months. To gain a deeper understanding of the plume dynamics, global climate simulations of a megafire were performed at a wide range of grid spacings from 2.0° down to 7 km, including a 7 km nonhydrostatic experiment. The analysis focuses on how the resolved dynamics affects the specification of the plume characteristics such as injection height and black carbon (BC) mass. Prior studies initialize the smoke plume at one or a few grid points and this is shown here to produce severely dissipative dynamics. In order to validate such simulations with observations, enhancements of the plume characteristics to offset the dissipation is necessary. Using a numerically converged simulation, sensitivity tests show that to approximate the observed stratospheric lifetime, a reduction in BC fraction by 50% is necessary for external mixtures. The vorticity dynamics of the plume is also analyzed with a Lagrangian budget to understand the mechanisms responsible for the evolution of a collocated anticyclonic vortex. The results can be distilled down into a simple conceptual model. As the plume rises, the air diverges at the top of the updraft where the largest concentrations of smoke are found. This divergence induces a dilution of the background cyclonic absolute vorticity producing an anticyclonic vortex. Vortex decay occurs from opposite arguments.

54 ENVIRONMENTAL SCIENCES↗

Existence of a virtual cathode close to a strongly electron emissive wall in low density plasmas

The interaction between an electron emissive wall, electrically biased in a plasma, is revisited through a simple fluid model. We search for realistic conditions of the existence of a non-monotonic plasma potential profile with a virtual cathode as it is observed in several experiments. We mainly focus our attention on thermionic emission related to the operation of emissive probes for plasma diagnostics, although most conclusions also apply to other electron emission processes. An extended Bohm criterion is derived involving the ratio between the two different electron densities at the potential minimum and at the background plasma. The model allows a phase-diagram analysis, which confirms the existence of the non-monotonic potential profiles with a virtual cathode. This analysis shows that the formation of the potential well critically depends on the emitted electron current and on the velocity at the sheath edge of cold ions flowing from the bulk plasma. As a consequence, a threshold value of the governing parameter is required, in accordance to the physical nature of the electron emission process. The latter is a threshold wall temperature in the case of thermionic electrons. Experimental evidence supports our numerical calculations of this threshold temperature. Besides this, the potential well becomes deeper with increasing electron emission, retaining a fraction of the released current which limits the extent of the bulk plasma perturbation. This noninvasive property would explain the reliable measurements of plasma potential by using the floating potential method of emissive probes operating in the so-called strong emission regime.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Toward Exascale: Overview of Large Eddy Simulations and Direct Numerical Simulations of Nuclear Reactor Flows with the Spectral Element Method in Nek5000

At the beginning of the last decade, Petascale supercomputers (i.e., computers capable of more than 1 petaFLOP) emerged. Now, at the dawn of exascale supercomputing, we provide a review of recent landmark simulations of portions of reactor components with turbulence-resolving techniques that this computational power has made possible. In fact, these simulations have provided invaluable insight into flow dynamics, which is difficult or often impossible to obtain with experiments alone. We focus on simulations performed with the spectral element method, as this method has emerged as a powerful tool to deliver massively parallel calculations at high fidelity by using large eddy simulation or direct numerical simulation. We also limit this paper to constant-property incompressible flow of a Newtonian fluid in the absence of other body or external forces, although the method is by no means limited to this class of flows. We briefly review the fundamentals of the method and the reasons it is compelling for the simulation of nuclear engineering flows. We review in detail a series of Petascale simulations, including the simulations of helical coil steam generators, fuel assemblies, and pebble beds. Even with Petascale computing, however, limitations for nuclear modeling and simulation tools remain. In particular, the size and scope of turbulence-resolving simulations are still limited by computing power and resolution requirements, which scale with the Reynolds number. In the final part of this paper, we discuss the future of the field, including recent advancements in emerging architectures such as GPUbased supercomputers, which are expected to power the next generation of high-performance computers.

computational fluid dynamics↗

Ab initio description of bcc iron with correlation matrix renormalization theory

We applied the ab initio spin-polarized correlation matrix renormalization theory to the ferromagnetic state of the bulk bcc iron. We showed that it was capable of reproducing the equilibrium physical properties and the pressure-volume curve in good comparison with experiments. We then focused on the analysis of its local electronic correlations. By exploiting different local fluctuation-related physical quantities as measures of electronic correlation within target orbits, we elucidated the different roles of t 2g and e g states in both spin channels and presented compelling evidence to showcase this distinction in their electronic correlation.

3-dimensional systems↗

Revealing the dark matter halo with axion direct detection

The next generation of axion direct-detection experiments may rule out or confirm axions as the dominant source of dark matter. Here we develop a general likelihood-based framework for studying the time-series data at such experiments, with a focus on the role of dark matter astrophysics, to search for signatures of the QCD axion or axionlike particles. Here we illustrate how in the event of a detection the likelihood framework may be used to extract measures of the local dark matter phase-space distribution, accounting for effects such as annual modulation and gravitational focusing, which is the perturbation to the dark matter phase-space distribution by the gravitational field of the Sun. Moreover, we show how potential dark matter substructure, such as cold dark matter streams or a thick dark disk, could impact the signal. For example, we find that when the bulk dark matter halo is detected at 5σ global significance, the unique time-dependent features imprinted by the dark matter component of the Sagittarius stream, even if only a few percent of the local dark matter density, may be detectable at ~2σ significance. A corotating dark disk, with lag speed ~50 km/s, that is ~20% of the local dark matter density could dominate the signal, while colder but as-of-yet unknown substructure may be even more important. Our likelihood formalism, and the results derived with it, are generally applicable to any time-series-based approach to axion direct detection.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Prototypes of self-powered radiation detectors employing intrinsic high-energy current

Purpose: The authors experimentally investigate the effect of direct energy conversion of x-rays via selfpowered Auger- and photocurrent, potentially suitable to practical radiation detection and dosimetry in medical applications. Experimental results are compared to computational predictions. The detector the authors consider is a thin-film multilayer device, composed of alternating disparate electrically conductive and insulating layers. This paper focuses on the experiments while a companion paper introduces the fundamental concepts of high-energy current (HEC) detectors. Methods: The energy of ionizing radiation is directly converted to detector signal via electric current induced by high-energy secondary electrons generated in the detector material by the incident primary radiation. The HEC electrons also ionize the dielectric and the resultant charge carriers are selfcollected due to the contact potential of the disparate electrodes. Thus, an electric current is induced in the conductors in two different ways without the need for externally applied bias voltage or amplification. Thus, generated signal in turn is digitized by a data acquisition system. To determine the fundamental properties of the HEC detector and to demonstrate its feasibility for medical applications, the authors used a planar geometry composed of multilayer microstructures. Various detectors with up to seven conducting layers with different combinations of materials (250 μm Al, 35 μm Cu, 100 μm Pb) and air gaps (100 μm) were exposed to nearly plane-parallel 60–120 kVp x-ray beams. For the experimental design and verification, the authors performed coupled electron–photon radiation transport computations. The detector signal was measured using a commercial data acquisition system with 24 bits dynamic range, 0.4 fC sensitivity, and 0.9 ms sampling time. Results: Measured signals for the prototype detector varied depending on the number of layers, material type, and incident photon energy, and it was in the range of 30–150 nA/cm{sup 2} for unit air kerma (1 Gy), which is viable for practical applications. The experiments had an excellent agreement with the computations. Within the examined range of 60–120 kVp, the energy dependence of the HEC (normalized to the x-ray tube output) was relatively small. Conclusions: Based on the experimental results for 100 ms sampling time, it would be possible to measure the time dependence of x-ray beams for x-ray tube current of 0.1 mA or higher. Significant advantages of the HEC device are that generation of its signal does not require external power supply, it can be made in any size and shape, including flexible curvilinear forms, and it is inexpensive. It remains to be determined, which of the potential applications in medical dosimetry (both in vivo and external), or radiation protection would benefit from such selfpowered detectors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Experimental results on TMDs

QCD factorisation for semi-inclusive deep inelastic scattering (DIS) at low transverse momentum in the current-fragmentation region has been established recently, providing a rigorous basis to study the transverse-momentum-dependent (TMD) distribution and fragmentation functions of partons from semi-inclusive DIS data using different spin-dependent and spin-independent observables. The main focus of the experiments were the measurements of various single- and double-spin asymmetries in hadron electro-production ( ep↑ → ehX with unpolarised, longitudinally and transversely polarised targets. The joint use of a longitudinally polarised beam and longitudinally and transversely polarised targets allowed to measure double-spin asymmetries related to leading-twist distribution functions describing the transverse-momentum distribution of longitudinally and transversely polarised quarks in a longitudinally and transversely polarised nucleons (helicity and worm-gear TMDs). The single-spin asymmetries measured with transversely polarised targets, provided access to specific leading-twist parton distribution functions: the transversity, the Sivers function and the so-called “pretzelosity” function. Within this review we present the current status and some future measurements of TMDs worldwide.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Chapter 14: Spectroscopy of Ground- and Excited-State Charge Carriers in Single-Wall Carbon Nanotubes

A host of both natural processes and man-made technologies rely upon the flow of electronic charge to transport and inter-convert energy over widely varying time scales. Semiconductor-based technologies rely upon careful control over both the ground-state densities of electrons or holes (in n- or p-type semiconductors, respectively) and the dynamic processes that occur for minority and/or majority charge carriers in the excited state. Single-walled carbon nanotubes (SWCNTs) have now been demonstrated as useful elements in a wide range of energy conversion (and other) technologies, including photovoltaics, thermoelectrics, digital logic, and quantum information processing. Elucidating the fundamental mechanisms at play in these technologies hinges upon a deep understanding of the energies and densities of energetic species (e.g. charge carriers, excitons, phonons) and the dynamic processes that define the interconversion between these species when the SWCNTs are exposed to perturbations (e.g. illumination, heat, bias). As such, a large body of work has been devoted to spectroscopic measurements of electrons and holes in SWCNTs over a broad range of energy and timescales. In this chapter, we discuss some critical aspects of using spectroscopic techniques to probe charge carriers in both the ground and excited state of SWCNTs, with a particular focus on recent experiments involving highly enriched semiconducting SWCNTs.

36 MATERIALS SCIENCE↗