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At least 505 records · Page 28

Functionalization of carbon nanotubes

Method and system for functionalizing a collection of carbon nanotubes (CNTs). A selected precursor gas (e.g., H.sub.2 or F.sub.2 or C.sub.nH.sub.m) is irradiated to provide a cold plasma of selected target particles, such as atomic H or F, in a first chamber. The target particles are directed toward an array of CNTs located in a second chamber while suppressing transport of ultraviolet radiation to the second chamber. A CNT array is functionalized with the target particles, at or below room temperature, to a point of saturation, in an exposure time interval no longer than about 30 sec.

Khare, Bishun N.↗

Functionalization of Carbon Nanotubes

Method and system for functionalizing a collection of carbon nanotubes (CNTs). A selected precursor gas (e.g., H2, or F2, or CnHm) is irradiated to provide a cold plasma of selected target particles, such as atomic H or F, in a first chamber. The target particles are directed toward an array of CNTs located in a second chamber while suppressing transport of ultraviolet radiation to the second chamber. A CNT array is functionalized with the target particles, at or below room temperature, to a point of saturation, in an exposure time interval no longer than about 30 sec.

Khare, Bishun N.↗

Space Shuttle MMOD Threat Mitigation Techniques

Prior to each shuttle mission, threat assessments are performed to determine the risk of critical penetration, payload bay door radiator tube leak and crew module window replacement from Micrometeoroid and Orbital Debris (MMOD). Mission parameters, such as vehicle attitude, exposure time and altitude are used as inputs for the analysis. Ballistic limit equations, based on hypervelocity impact testing of shuttle materials are used to estimate the critical particle diameters of the outer surfaces of the vehicle. The assessments are performed using the BUMPER computer code at the NASA/JSC Hypervelocity Impact Technology Facility (HITF). The most critical involves the calculation of Loss of Crew and Vehicle (LOCV) risk. An overview of significant MMOD impacts on the Payload Bay Door radiators, wing leading edge reinforced carbon-carbon (RCC) panels and crew module windows will be presented, along with a discussion of the techniques NASA has implemented to reduce the risk from MMOD impacts. This paper will describe on-orbit inspection of the RCC regions and the methods used discern hypervelocity impact damage. Impact damage contingency plans and on-orbit repair techniques will also be discussed. The wing leading edge impact detection system (WLEIDS) and it s role in the reduction of on-orbit risk reduction will be presented. Finally, an analysis of alternative shuttle flight attitudes on MMOD risk will be demonstrated.

Hyde, J. L.↗

The Solid Rocket Motor Slag Population: Results of a Radar-Based Regressive Statistical Evaluation

Solid rocket motor (SRM) slag has been identified as a potential source of man-made orbital debris. The possibility that SRMs (in addition to generating dust particles in the sub-millimeter range) may generate particles up to centimeters in size has caused concern regarding their contribution to the debris environment. Returned surfaces from space do not have sufficient area or exposure time to provide a clear picture of the SRM millimeter and centimeter debris population. Currently, radar observation is probably the only way to collect data showing the debris contribution from SRMs. Such observation is used to sample the debris environment, but it is difficult to obtain accurate orbital elements for the detected debris objects. NASA has developed several models to describe the different orbital debris populations, based on assumed debris production mechanisms to create clouds of debris objects that can be propagated in time. The NASA model, LEGEND (LEO-to-GEO Environment Debris), functions as a time-tested debris model for most debris sources. However, the current LEGEND model does not include contributions from the SRM population. An SRM model has recently been developed by NASA, based on purely theoretical details of SRM production and known SRM launches, but verification with hard data is needed. Because the detections of individual SRM objects cannot be deterministically separated from the total debris observed by radar, the validation of the SRM model can only be done by combining it with the LEGEND breakup model and comparing it with data. By applying observational constraints, the degree of SRM slag contribution to the environment may be estimated. This serves as an observationally sound method from which to calibrate a purely theoretical model into something more realistic. For this study, we use the populations observed by the Haystack radar from 1996 to present. For the SRM debris, we use a historical database of SRM launches, propellant masses, and estimated locations and times of tailoff to produce and propagate the SRM debris clouds. Comparisons with radar data from the ensuing years were made, and the SRM model was altered with respect to size and mass production of slag particles to reflect the populations estimated from the data. The result is a model SRM population that fits within the bounds of the observed environment and estimates of the production and contribution of SRM debris to the environment.

Horstman, Matthew F.↗

Space Plasma Ion Processing of the Lunar Soil: Modeling of Radiation-Damaged Rim Widths on Lunar Grains

Chemically and microstructurally complex altered rims around grains in the finest size fraction (<20 micron) of the lunar regolith are the result of multi-stage processes involving both solar ion radiation damage and nanoscale deposition of impact or sputter-derived vapors. The formation of the rims is an important part of the space weathering process, and is closely linked to key changes in optical reflectance and other bulk properties of the lunar surface. Recent application of field-emission scanning transmission electron microscope techniques, including energy dispersive X-ray spectral imaging, is making it easier to unravel the "nano-stratigraphy" of grain rims, and to delineate the portions of rims that represent Radiation-Amorphized (RA) host grain from overlying amorphous material that represents vapor/sputter deposits. For the portion of rims formed by host grain amorphization (henceforth called RA rims), we have been investigating the feasibility of using Monte Carlo-type ion-atom collision models, combined with experimental ion irradiation data, to derive predictive numerical models linking the width of RA rims to the grain s integrated solar ion radiation exposure time.

Chamberlin, S.↗

Enigmatic Moisture Effects on Al2O3 Scale and TBC Adhesion

Alumina scale adhesion to high temperature alloys is known to be affected primarily by sulfur segregation and reactive element additions. However, adherent scales can become partially compromised by excessive strain energy and cyclic cracking. With time, exposure of such scales to moisture can lead to spontaneous interfacial decohesion, occurring while the samples are maintained at ambient conditions. Examples of this Moisture-Induced Delayed Spallation (MIDS) are presented for NiCrAl and single crystal superalloys, becoming more severe with sulfur level and cyclic exposure conditions. Similarly, delayed failure or Desk Top Spallation (DTS) results are reviewed for thermal barrier coatings (TBCs), culminating in the water drop failure test. Both phenomena are discussed in terms of moisture effects on bulk alumina and bulk aluminides. A mechanism is proposed based on hydrogen embrittlement and is supported by a cathodic hydrogen charging experiment. Hydroxylation of aluminum from the alloy interface appears to be the relevant basic reaction.

Smialek, James L.↗

Chandra X-ray Observations of Young Clusters: Orion Flanking Fields Data - Volume II

We present results of Chandra observations of two flanking fields (FFs) in Orion, outside the Orion Nebula Cluster (ONC). The observations were taken with the ACIS-I camera with an exposure time of about 48 ks each field. We present a catalog of 417 sources, which includes X-ray luminosity, optical and infrared photometry, and X-ray variability information. We have found 91 variable sources, 33 of which have a flarelike light curve and 11 of which have a pattern of a steady increase or decrease over a 10 hr period. The optical and infrared photometry for the stars identified as X-ray sources are consistent with most of these objects being pre-main-sequence stars with ages younger than 10 Myr. We present evidence for an age difference among the X-ray-selected samples of NGC 2264, Orion FFs, and ONC, with NGC 2264 being the oldest and ONC being the youngest.

pre-main sequence↗

Observing Exoplanetary Ozone In The Mid-Ultraviolet

There are good reasons for pushing the spectral range of observation to shorter wavelengths than currently envisaged for terrestrial planet-finding missions utilizing with a 4-rn, diffraction-limited, optical telescope: (1) The angular resolution is higher, so that the image of an exoplanet is better separated from that of the much brighter star. (2) Due to the higher resolution, the exozodiacal background per resolution element is smaller, so exposure times are reduced for the same incident flux. (3) Most importantly, the sensitivity to the presence of life on habitable exoplanets is increased by a hundred-fold by access to the ozone biomarker at 250-300 nm. These benefits must be weighed against challenges arising from the faintness of exoplanets in the mid-UV. We will describe the benefits and the technical and cost challenges.

Heap, S.↗

Observing Exoplanets in the Mid-Ultraviolet

There are good reasons for pushing the spectral range of observation to shorter wavelengths than currently envisaged for terrestrial planet-finding missions utilizing with a 4-m, diffraction-limited, optical telescope: (1) The angular resolution is higher, so the image of an exoplanet is better separated from that of the much brighter star. (2) The exozodiacal background per resolution element is smaller, so exposure times are reduced for the same incident flux. (3) Most importantly, the sensitivity to the ozone biomarker is increased by several hundred-fold by access to the ozone absorption band at 250-300 nm. These benefits must be weighed against challenges arising from the faintness of exoplanets in the mid-UV. We will evaluate both the technical and cost challenges including image quality of large telescopes, advanced mirror coatings and innovative designs for enhanced optical throughput, and CCD detectors optimized for 250-400 nm.

Heap. Sara↗

Extremely Red Objects in the Lockman Hole

We investigate extremely red objects (EROs) using near- and mid-infrared observations in five passbands (3.6 to 24 microns) obtained from the Spitzer Space Telescope, and deep ground-based R and K imaging. The great sensitivity of the Infrared Array Camera (IRAC) camera allows us to detect 64 EROs (a surface density of 2.90 +/- 0.36 arcmin(exp -2); [3.6](sub AB) is less than 23.7) in only 12 minutes of IRAC exposure time, by means of an R - [3.6] color cut (analogous to the traditional red R - K cut). A pure infrared K - [3.6] red cut detects a somewhat different population and may be more effective at selecting z greater than 1.3 EROs. We find approximately 17% of all galaxies detected by IRAC at 3.6 or 4.5 microns to be EROs. These percentages rise to about 40% at 5.8 microns, and about 60% at 8.0 microns. We utilize the spectral bump at 1.6 microns to divide the EROs into broad redshift slices using only near-infrared colors (2.2/3.6/4.5 microns). We conclude that two-thirds of all EROs lie at redshift z greater than 1.3. Detections at 24 microns imply that at least 11% of 0.6 less than z and less than 1.3 EROs and at least 22% of z greater than 1.3 EROs are dusty star-forming galaxies.

galaxies↗

Enigmatic Moisture Effects on Al2O3 Scale and TBC Adhesion

Alumina scale adhesion to high temperature alloys is known to be affected primarily by sulfur segregation and reactive element additions. However adherent scales can become partially compromised by excessive strain energy and cyclic cracking. With time, exposure of such scales to moisture can lead to spontaneous interfacial decohesion, occurring while the samples are maintained at ambient conditions. Examples of this Moisture-Induced Delayed Spallation (MIDS) are presented for NiCrAl and single crystal superalloys, becoming more severe with sulfur level and cyclic exposure conditions. Similarly, delayed failure or Desk Top Spallation (DTS) results are reviewed for TBC s, culminating in the water drop failure test. Both phenomena are discussed in terms of moisture effects on bulk alumina and bulk aluminides. A mechanism is proposed based on hydrogen embrittlement and is supported by a cathodic hydrogen charging experiment. Hydroxylation of aluminum from the alloy interface appears to be the relevant basic reaction.

Smialek, James L.↗

Injecting Artificial Memory Errors Into a Running Computer Program

Single-event upsets (SEUs) or bitflips are computer memory errors caused by radiation. BITFLIPS (Basic Instrumentation Tool for Fault Localized Injection of Probabilistic SEUs) is a computer program that deliberately injects SEUs into another computer program, while the latter is running, for the purpose of evaluating the fault tolerance of that program. BITFLIPS was written as a plug-in extension of the open-source Valgrind debugging and profiling software. BITFLIPS can inject SEUs into any program that can be run on the Linux operating system, without needing to modify the program s source code. Further, if access to the original program source code is available, BITFLIPS offers fine-grained control over exactly when and which areas of memory (as specified via program variables) will be subjected to SEUs. The rate of injection of SEUs is controlled by specifying either a fault probability or a fault rate based on memory size and radiation exposure time, in units of SEUs per byte per second. BITFLIPS can also log each SEU that it injects and, if program source code is available, report the magnitude of effect of the SEU on a floating-point value or other program variable.

Bornstein, Benjamin J.↗

Detecting Exoplanets with the New Worlds Observer: The Problem of Exozodiacal Dust

Dust coming from asteroids and comets will strongly affect direct imaging and characterization of terrestrial planets in the Habitable Zones of nearby stars. Such dust in the Solar System is called the zodiacal dust (or 'zodi' for short). Higher levels of similar dust are seen around many nearby stars, confined in disks called debris disks. Future high-contrast images of an Earth-like exoplanet will very likely be background-limited by light scattered of both the local Solar System zodi and the circumstellar dust in the extrasolar system (the exozodiacal dust). Clumps in the exozodiacal dust, which are expected in planet-hosting systems, may also be a source of confusion. Here we discuss the problems associated with imaging an Earth-like planet in the presence of unknown levels of exozodiacal dust. Basic formulae for the exoplanet imaging exposure time as function of star, exoplanet, zodi, exozodi, and telescope parameters will be presented. To examine the behavior of these formulae, we apply them to the New Worlds Observer (NWO) mission. NWO is a proposed 4-meter UV/optical/near-IR telescope, with a free flying starshade to suppress the light from a nearby star and achieve the high contrast needed for detection and characterization of a terrestrial planet in the star's Habitable Zone. We find that NWO can accomplish its science goals even if exozodiacal dust levels are typically much higher than the Solar System zodi level. Finally, we highlight a few additional problems relating to exozodiacal dust that have yet to be solved.

Roberge, A.↗

Finding the First Galaxies

Astronomers study distant galaxies by taking long exposures in deep survey fields. They choose fields that are empty of known sources, so that they are statistically representative of the Universe as a whole. Astronomers can compare the distribution of the detected galaxies in brightness, color, morphology and redshift to theoretical models, in order to puzzle out the processes of galaxy evolution. In 2004, the Hubble Space Telescope was pointed at a small, deep-survey field in the southern constellation Fornax for more than 500 hours of exposure time. The resulting Hubble Ultra-Deep Field could see the faintest and most distant galaxies that the telescope is capable of viewing. These galaxies emitted their light less than 1 billion years after the Big Bang. From the Ultra Deep Field and other galaxy surveys, astronomers have built up a history of star formation in the universe. the peak occurred about7 billion years ago, about half of the age of the current universe, then the number of stars that were forming was about 15 time the rate today. Going backward in time to when the very first starts and galaxies formed, the average star-formation rate should drop to zero. but when looking at the most distant galaxies in the Ultra Deep field, the star formation rate is still higher than it is today. The faintest galaxies seen by Hubble are not the first galaxies that formed in the early universe. To detect these galaxies NASA is planning the James Webb Space Telescope for launch in 2013. Webb will have a 6.5-meter diameter primary mirror, much bigger than Hubble's 2.4-meter primary, and will be optimized for infrared observations to see the highly redshifted galaxies.

Gardner, Jonathan P.↗

Flexcam Image Capture Viewing and Spot Tracking

Flexcam software was designed to allow continuous monitoring of the mechanical deformation of the telescope structure at Palomar Observatory. Flexcam allows the user to watch the motion of a star with a low-cost astronomical camera, to measure the motion of the star on the image plane, and to feed this data back into the telescope s control system. This automatic interaction between the camera and a user interface facilitates integration and testing. Flexcam is a CCD image capture and analysis tool for the ST-402 camera from Santa Barbara Instruments Group (SBIG). This program will automatically take a dark exposure and then continuously display corrected images. The image size, bit depth, magnification, exposure time, resolution, and filter are always displayed on the title bar. Flexcam locates the brightest pixel and then computes the centroid position of the pixels falling in a box around that pixel. This tool continuously writes the centroid position to a network file that can be used by other instruments.

Rao, Shanti↗

Synthesis of Poly-Silicon Thin Films on Glass Substrate Using Laser Initiated Metal Induced Crystallization of Amorphous Silicon for Space Power Application

Poly-silicon thin films on glass substrates are synthesized using laser initiated metal induced crystallization of hydrogenated amorphous silicon films. These films can be used to fabricate solar cells on low cost glass and flexible substrates. The process starts by depositing 200 nm amorphous silicon films on the glass substrates. Following this, 200 nm of sputtered aluminum films were deposited on top of the silicon layers. The samples are irradiated with an argon ion cw laser beam for annealing. Laser power densities ranging from 4 to 9 W/cm2 were used in the annealing process. Each area on the sample is irradiated for a different exposure time. Optical microscopy was used to examine any cracks in the films and loss of adhesion to the substrates. X-Ray diffraction patterns from the initial results indicated the crystallization in the films. Scanning electron microscopy shows dendritic growth. The composition analysis of the crystallized films was conducted using Energy Dispersive x-ray Spectroscopy. The results of poly-silicon films synthesis on space qualified flexible substrates such as Kapton are also presented.

Abu-Safe, Husam H.↗

Functionalization of Carbon Nanotubes

Method and system for functionalizing a collection of carbon nanotubes (CNTs). A selected precursor gas (e.g., H2 or F2 or CnHm) is irradiated to provide a cold plasma of selected target species particles, such as atomic H or F, in a first chamber. The target species particles are d irected toward an array of CNTs located in a second chamber while suppressing transport of ultraviolet radiation to the second chamber. A CNT array is functionalized with the target species particles, at or below room temperature, to a point of saturation, in an exposure time interval no longer than about 30 sec. *Discrimination against non-target species is provided by (i) use of a target species having a lifetime that is much greater than a lifetime of a non-target species and/or (2) use of an applied magnetic field to discriminate between charged particle trajectories for target species and for non-target species.

Khare, Bishun N.↗

CMOS Camera Array With Onboard Memory

A compact CMOS (complementary metal oxide semiconductor) camera system has been developed with high resolution (1.3 Megapixels), a USB (universal serial bus) 2.0 interface, and an onboard memory. Exposure times, and other operating parameters, are sent from a control PC via the USB port. Data from the camera can be received via the USB port and the interface allows for simple control and data capture through a laptop computer.

Gat, Nahum↗