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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Regional variations in the stability and diffusion of water-ice in the Martian regolith

Geologic evidence suggests subsurface water-ice has played an important role in the formation of Martian landforms. Forms of mass-wasting such as debris aprons and flow patterns on valley floors suggest creep deformation of ice-laden soil, while thermokarst and chaotic terrain suggest once extensive deposits of ground ice that were later removed. The global distribution of ice-related morphology was mapped. The mapping showed regional variation, in both latitude and longitude, in the distribution of debris aprons, concentric fill craters, and 'softened' crater profiles.

Mellon, Michael T.↗
NASA NTRS2014

Interstellar Organics, the Solar Nebula, and Saturn's Satellite Phoebe

The diffuse interstellar medium inventory of organic material (Pendleton et al. 1994, Pendleton & Allamandola 2002) was likely incorporated into the molecular cloud in which the solar nebula condensed. This provided the feedstock for the formation of the Sun, major planets, and the smaller icy bodies in the region outside Neptune's orbit (transneptunian objects, or TNOs). Saturn's satellites Phoebe, Iapetus, and Hyperion open a window to the composition of one class of TNO as revealed by the near-infrared mapping spectrometer (VIMS) on the Cassini spacecraft at Saturn. Phoebe (mean diameter 213 km) is a former TNO now orbiting Saurn. VIMS spaectral maps of PHoebe's surface reveal a complex organic spectral signature consisting of prominent aromatic (CH) and alophatic hydrocarbon (CH2, CH3) absorption bands (3.2-3.6 micrometers). Phoebe is the source of a huge debris ring encircling Saturn, and from which particles (approximately 5-20 micrometer size) spiral inward toward Saturn. They encounter Iapetus and Hperion where they mix with and blanket the native H2O ice of those two bodies. Quantitative analysis of the hydrocarbon bands on Iapetus demonstrates that aromatic CH is approximately 10 times as abundant as aliphatic CH2+CH3, significantly exceeding the strength of the aromatic signature in interplanetary dust particles, comet particles, ad in carbonaceous meteorites (Cruikshank et al. 2013). A similar excess of aromatics over aliphatics is seen in the qualitative analysis of Hyperion and Phoebe itself (Dalle Ore et al. 2012). The Iapetus aliphatic hydrocarbons show CH2/CH3 approximately 4, which is larger than the value found in the diffuse ISM (approximately 2-2.5). In so far as Phoebe is a primitive body that formed in the outer regions of the solar nebula and has preserved some of the original nebula inventory, it can be key to understanding the content and degree of procesing of the nebular material. There are other Phoebe-like TNOs that are presently beyond our ability to study in the organic spectral region, but JWST will open that possibility for a number of objects. We now need to explore and understand the connection of this organic-bearing Solar System material to the solar nebula the the inventory of ISM materials incorporated therein.

Interstellar↗
DOE OSTI2024

Growth of organized flow coherent motions within a single-stream shear layer: 4D-PTV measurements

Abstract This study investigates the evolution of a single-stream shear layer (SSSL) originating from a wall boundary layer past a backward-facing step. Utilizing a time-resolved 3D-Particle Tracking Velocimetry (4D-PTV) technique, we track the trajectories of fluorescent particles to gain insight into the flow characteristics of the SSSL. A compact water tunnel facility ( $$\textrm{Re}_\tau =1\,240$$ Re τ = 1 240 ) is fabricated to obtain an SSSL with a perpendicular slow entrainment stream past the separation edge. A hybrid interpolation approach that combines ensemble binning and Gaussian weighting is implemented to derive minimally filtered mean and instantaneous lower- and higher-order flow field parameters. Spanwise-dominant coherent motion accompanied by finer flow scales is observed to grow due to flow entrainment through “nibbling” actions of small-scale vortices, “engulfing” by large-scale vortices, and vortex pairing events. Furthermore, the non-zero-speed stream edge grows relatively faster than the zero-speed stream edge, showing a strong asymmetry in mixing composition across a mixing layer. The SSSL reaches self-similarity at a streamwise distance of $$\approx 55\,\theta _{0}$$ ≈ 55 θ 0 , where $$\theta _0$$ θ 0 is the initial momentum thickness from the separation edge, i.e., considerably shorter than reported in previous studies. A literature comparison of growth rate parameters raises intriguing questions regarding a potential inclusive growth scaling unifying the free shear layers. A turbulent kinetic energy (TKE) budget analysis reveals a negative production region immediately downstream of the separation edge attributed to a large positive streamwise gradient of streamwise velocity. In the self-similar region, the phase-averaged flow mapping demonstrates a larger concentration of turbulence production rate around the outer edges of spanwise vortices, specifically at the intersection of braids and vortices. Furthermore, a spatial separation exists in the regions of peak production and dissipation rates within the vortex core region favoring dissipation. The braids exhibit a larger concentration of turbulence diffusion rates, indicating their function as a conduit for exchanging turbulence between neighboring coherent motions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2020

Improvements to a class of hybrid methods for radiation transport: Nyström reconstruction and defect correction methods

In this study, two modifications are introduced for improving the accuracy, versatility, and robustness of a class of hybrid methods for radiation transport. In general, such methods are constructed by splitting the radiative flux into collided and uncollided components to which low- and high-resolution angular approximations are applied, respectively. In this work we focus on discrete ordinates discretizations of high and low order. The first modification we introduce changes the way in which the collided component is mapped into the uncollided component at the end of each time step in a simulation. The new mapping is a Nyström-type reconstruction that is applicable to arbitrary discrete ordinates quadratures, is guaranteed to preserve positivity of the solution provided that all ordinate weights are positive, is significantly more accurate than previous methods, and can be readily extended to other discretizations such as moment methods, finite element methods, and diffusion approximations. The second modification leverages integral deferred correction (IDC) to iteratively correct for the splitting error introduced by the inconsistency in angular discretization between the collided and uncollided components, in addition to improving the accuracy of the low-order temporal error that is treated by traditional IDC methods. Numerical tests in one- and two-dimensional geometries are used to demonstrate the increased accuracy and efficiency of the proposed modifications. It is found that the two techniques combined yield methods with solution accuracy and memory requirements comparable to that of monolithic discrete ordinates methods while reducing runtime by as much as a factor of between two and ten, depending on the problem.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Informing air–carbon ablation modeling with theoretical calculations of atomic oxygen and nitrogen interacting with carbon surfaces

To understand the gas–surface chemistry above the thermal protection system of a hypersonic vehicle, it is necessary to map out the kinetics of key elementary reaction steps. In this work, extensive periodic density functional theory (DFT) calculations are performed to elucidate the interaction of atomic oxygen and nitrogen with both the basal plane and edge sites of highly oriented pyrolytic graphite (HOPG). Reaction energies and barriers are determined for adsorption, desorption, diffusion, recombination, and several reactions. These DFT results are compared with the most recent finite-rate model for air–carbon ablation. Our DFT results corroborated some of the parameters used in the model but suggest that further refinement may be necessary for others. The calculations reported here will help to establish a predictive kinetic model for the complex reaction network present under hypersonic flight conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1985

Flow control in a diffusing S-Duct

Accurate measurements have been made of secondary flow in a 1.51 area ratio diffusing 30 deg - 30 deg S-Duct with circulair cross section. Turbulent flow was entering the duct at Mach number of 0.6, the boundary layer thickness at the duct entrance was ten percent of the duct inlet diameter. Through measurements made, local flow velocity vector as well as static and total pressures mapping of the flow at several stations were obtained. Strong secondary flow was measured in the first bend which continued into the second bend with new vorticity produced in there in the opposite direction. Surface oil flow visualization and wall pressures indicated a region of separated flow starting at theta approximately equal to 22 deg on the inside of the first bend up to theta approximately equal to 44 deg on the outside of the second bend. The flow separated in 'cyclone' form and never reattached in the duct. As a result of the secondary flow and the flow separation, significant total pressure distortion was observed at the exit of the duct. Using flow control devices the separation was eliminated while the exit distortion was improved.

Vakili, A. D.↗
NASA NTRS1992

The parsec-scale jets in 3C 273 and 3C 345

We present recent centimeter-wavelength 'global-array' VLBI images of the quasars 3C 273 and 3C 345 with dynamic ranges in excess of 3000:1. They trace the jet emission on scales from r about 5 parsecs out to about 200 parsecs. The maps of 3C273 at 18 cm wavelength show a well-collimated one-sided jet with a wavy ridge line; these wiggles exist on size scales ranging from about 1 pc to over 10 kpc. We show that the well-known superluminal flow extends to r about 120 pc. Images of 3C 345 at 6 cm wavelength from data taken in 1989 and 1990 show surprising features not seen in lower dynamic-range maps of this otherwise well-studied quasar: the inner part of the jet shows edge-brightening, which is important for modeling of jet confinement. The jet fades out very abruptly at r about 40 pc, then reappears at about 70 pc; beyond 70 pc, the resumed jet flares and is more diffuse than an extrapolation of the inner jet would predict. This morphology is reminiscent of M 87, and is suggestive of a shock wave.

Unwin, Stephen C.↗
NASA NTRS2003

A 4 MPC X-Ray Filament Falling into the Cluster A85

We have completed a first paper confirming the ROSAT observation of a merging filamentary structure associated with the rich cluster A85. We detected a portion of the extended 4 Mpc filament first seen by the ROSAT PSPC. We confirm that there is an extended feature, aligned at the same position angle as the major axis of the central cD, the bright cluster galaxies, and nearby groups and clusters. We find that the X-ray emission from the filament is best described by thermal emission with a temperature of approx. 2 keV, which is significantly lower than the ambient cluster medium, but is significantly higher than anticipated for a gas in a weakly bound extended filament. It is not clear whether this is a filament of diffuse emission, a chain of several groups of galaxies, or stripped gas from the infalling south blob. In conclusion, the XMM-Newton observations confirmed that there really is a highly elongated filamentary like structure extending from the the merging south clump to the south east of Abell-85 along the direction defined by all the structures pointed out by Durret et al. (1998b). The fact that the spatial structure of the X-ray filament detected by XMM-Newton cannot be exactly superimposed to that obtained from ROSAT data shows that it is still difficult to determine exactly its nature. However, the X-ray spectrum from this structure is most likely thermal and its temperature is about 2.0 keV, consistent with that of groups. This value is notably cooler than that of the main cluster: the temperature map by Markevitch et al. (1998) shows the presence of gas at about 3-4 keV in the region at a distance from the cluster center at least as far as the northern part of the ellipse. So, we appear to be seeing cool gas as it enters the cluster core. Another possibility is that the filament is associated with the wake of cool stripped gas left behind by the south blob as it falls onto the cluster. In this case, the 'filament', whether it is diffuse or made of groups, would not really be a filament in the large scale structure formation sense. Besides X-ray observations with a much better signal to noise ratio, which probably will have to wait for the next generation of X-ray satellites, optical data can shed light on this question. With this purpose, we intend to perform wide field imaging in various bands to estimate galaxy photometric redshifts and determine how galaxies are distributed in the 'filament' area.

Forman, William↗
DOE OSTI2023

The Linkage Between Electro-Chemical Mechanical Instabilities in Battery Materials

Battery chemistry must be diversified to achieve a sustainable energy landscape by effectively utilizing renewable energy sources. Alkali metal-ion, all-solid-state, metal–air batteries, and multivalent batteries offer unique cost, safety, raw material abundance, energy, and power density solutions. However, realizing these “beyond Li-ion batteries” must uncover their working principles and performance & property relationships. In this aspect, mitigating chemo-mechanical instabilities in the structure and surface of the electrodes plays a crucial role in their performance. Unfortunately, the coupling between electrochemical and mechanical interactions is often poorly understood due to a lack of operando characterization. Here, this review article explains the working principles of curvature measurement and digital image correlation for measuring stress and strain generations in battery materials. We provided specific examples of how these operando mechanical measurements shed light on instabilities in alkali metal ion electrodes, solid electrolytes, Li-O 2 batteries, and aqueous Zn-ion batteries. Operando mechanical measurements offer an effective way to map changes in the physical fingerprint of the battery materials, therefore providing crucial information to elucidate instabilities in battery materials.

25 ENERGY STORAGE↗
DOE OSTI2022

Durable High-Power Membrane Electrode Assemblies with Low Pt Loading

Recent progress in developing and implementing Pt-alloy cathode catalysts and thin (10-15 micron) low resistance membranes has enabled high performance state of art (SOA) membrane electrode assembly (MEA) with low Pt loading. However, these high performing MEAs do not meet durability requirements, especially at peak power, because of complex degradation mechanisms that are sensitive to the materials, MEA design, and fuel cell operating strategy. Specifically, power degradation of the cathode occurs via Pt and Co dissolution as well as deterioration of O 2 transport properties. Additionally, thin membranes are subject to failure due to manufacturing defects in the adjacent gas diffusion media and electrodes and the formation of membrane-attacking radical species caused by high gas crossover. In this project led by General Motors LLC (GM), the objective was to enhance the durability of SOA MEA through optimization of operating conditions, instead of new materials development. Along with our project partners, we have mapped the impact of operating conditions on the durability of SOA MEA. Output of the project include a low Pt loading SOA MEA that exceeds Department of Energy (DOE) 2020 target of >1 W/cm 2 at rated power and pathway to achieve >5000 h of durability. Durability studies in the project provide a detailed understanding of failure modes and operating condition sensitivity on cathode and membrane failure, critical for defining operating conditions and hybridization strategies that can guide system controls to maximize low-Pt MEA life. The project also generated and validated degradation models that will provide future research direction, critical for guiding future cycles of automotive MEA development.

08 HYDROGEN↗
NASA NTRS1974

Far-infrared emission from H II regions. II - Multicolor photometry of selected sources and 2.2 min resolution maps of M42 and NGC 2024

Medium- and broad-bandwidth photometric measurements have been made of seven compact H II regions at wavelengths between 30 and 650 microns. The results are consistent with the hypothesis that the far-infrared flux is continuum radiation from dust grains. Color temperatures range from 33 to 85 K. For most of the sources, the infrared flux is low enough so that the dust could conceivably be mixed with the ionized gas. In at least one case, however, the far-infrared spectrum and luminosity of the source cannot be reconciled with reasonable grain models unless the far-infrared flux comes from a shell surrounding the H II region. M42 (Orion) and NGC 2024 (Orion B) have been mapped at 90 microns with a resolution (half-power beam diameter) of 2.2 min. Although the peak far-infrared brightness in M42 occurs at the position of the Kleinmann-Low infrared nebula, most of the flux originates in a more extended (about 6 x 8 min) source. The energy for the diffuse component could be supplied by the stars in the Trapezium cluster. However, the single early-type star visible in NGC 2024 is not luminous enough to account for either the infrared flux or the observed free-free flux.

Harper, D. A.↗
NASA NTRS1978

An image based information system - Architecture for correlating satellite and topological data bases

The paper describes the development of an image based information system and its use to process a Landsat thematic map showing land use or land cover in conjunction with a census tract polygon file to produce a tabulation of land use acreages per census tract. The system permits the efficient cross-tabulation of two or more geo-coded data sets, thereby setting the stage for the practical implementation of models of diffusion processes or cellular transformation. Characteristics of geographic information systems are considered, and functional requirements, such as data management, geocoding, image data management, and data analysis are discussed. The system is described, and the potentialities of its use are examined.

Bryant, N. A.↗
NASA NTRS1990

Contributions of late-type dwarf stars to the soft X-ray diffuse background

Comprehensive calculations of the contribution of late-type dwarf stars to the soft X-ray diffuse background are presented. The mean X-ray luminosity as derived from optically and X-ray selected samples is examined, using the Bahcall-Soneira Galaxy model to describe the spatial distribution of stars and recent results on the X-ray spectra. The model calculations are compared with the Wisconsin sky maps in the C, M1, M2, I and J bands to assess the uncertainties of the calculations. Contributions of up to 10 percent to the M2 and I band background at high Galactic latitudes are found, while at low Galactic latitudes late-type stars contribute up to 40 percent of the background. However, a Galactic ridge as well as a relatively isotropic component still remains unexplained, even with the added contribution of the extrapolated high-energy power law.

Schmitt, J. H. M. M.↗
NASA NTRS1991

IRAS detection of very cold dust in the Lynds 134 cloud complex

IRAS maps at 60 and 100 microns of the complex of dark clouds containing L1345, L183, and L1780 are presented and discussed. Extended regions are apparent where the 60 micron emission is very low compared to the 100 micron emission. The 60-100 micron flux ratio has a constant value of 0.2 in the outer diffuse parts of the clouds but suddenly drops to less than 0.03 in the opaque cloud centers. A geometrical model is used to show that the drop occurs in a narrow transition layer that has not been resolved by IRAS. The observations provide direct evidence for dust temperatures colder than 15 K in dark clouds. A number of 60 micron-deficient regions are defined using the quantity Delta I(100) = I(60)/Theta, where Theta is the ratio I(60)/I(100) in the diffuse parts of the complex. Delta I(100) is highly proportional to extinction and (C-13)O column density. The relationships indicate that the dust temperature must be constant over a large fraction of the volume sampled by Delta I(100). An upper limit of 4.8 g/sq cm is obtained for the mass absorption coefficient of dust at 100 microns.

Laureijs, R. J.↗
NASA NTRS1998

Earth Probe Total Ozone Mapping Spectrometer (TOMS) Data Product User's Guide

Two data products from the Earth Probe Total Ozone Mapping Spectrometer (EP/TOMS) have been archived at the Distributed Active Archive Center, in the form of Hierarchical Data Format files. The EP/ TOMS began taking measurements on July 15, 1996. The instrument measures backscattered Earth radiance and incoming solar irradiance; their ratio is used in ozone retrievals. Changes in the reflectivity of the solar diffuser used for the irradiance measurement are monitored using a carousel of three diffusers, each exposed to the degrading effects of solar irradiation at different rates. The algorithm to retrieve total column ozone compares measured Earth radiances at sets of three wavelengths with radiances calculated for different total ozone values. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard deviation random error is 2 percent, and the drift is less than 0.5 percent over the first year of data. The Level-2 product contains the measured radiances, the derived total ozone amount, and reflectivity information for each scan position. The Level-3 product contains daily total ozone and reflectivity in a 1-degree latitude by 1.25 degrees longitude grid. Level-3 files containing estimates of LTVB at the Earth surface and tropospheric aerosol information are also available, Detailed descriptions of both HDF data-files and the CD-ROM product are provided.

McPeters, R.↗
DOE OSTI2024

ForceGen: End-to-end de novo protein generation based on nonlinear mechanical unfolding responses using a language diffusion model

Through evolution, nature has presented a set of remarkable protein materials, including elastins, silks, keratins and collagens with superior mechanical performances that play crucial roles in mechanobiology. However, going beyond natural designs to discover proteins that meet specified mechanical properties remains challenging. Here, we report a generative model that predicts protein designs to meet complex nonlinear mechanical property-design objectives. Our model leverages deep knowledge on protein sequences from a pretrained protein language model and maps mechanical unfolding responses to create proteins. Via full-atom molecular simulations for direct validation, we demonstrate that the designed proteins are de novo, and fulfill the targeted mechanical properties, including unfolding energy and mechanical strength, as well as the detailed unfolding force-separation curves. Our model offers rapid pathways to explore the enormous mechanobiological protein sequence space unconstrained by biological synthesis, using mechanical features as the target to enable the discovery of protein materials with superior mechanical properties.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2000

Quiescent Giant Molecular Cloud Cores in the Galactic Center

We have used the Long Wavelength Spectrometer (LWS) aboard the Infrared Space Observatory (ISO) to map the far-infrared continuum emission (45-175 micrometer) toward several massive Giant Molecular Cloud (GMC) cores located near the Galactic center. The observed far-infrared and submillimeter spectral energy distributions imply low temperatures (approx. 15 - 22 K) for the bulk of the dust in all the sources, consistent with external heating by the diffuse ISRF and suggest that these GMCs do not harbor high- mass star-formation sites, in spite of their large molecular mass. Observations of FIR atomic fine structure lines of C(sub II) and O(sub I) indicate an ISRF enhancement of approx. 10(exp 3) in the region. Through continuum radiative transfer modeling we show that this radiation field strength is in agreement with the observed FIR and submillimeter spectral energy distributions, assuming primarily external heating of the dust with only limited internal luminosity (approx. 2 x 10(exp 5) solar luminosity). Spectroscopic observations of millimeter-wave transitions of H2CO, CS, and C-34S carried out with the Caltech Submillimeter Observatory (CSO) and the Institut de Radio Astronomie Millimetrique (IRAM) 30-meter telescope indicate a gas temperature of approx. 80 K, significantly higher than the dust temperatures, and density of approx. 1 x 10(exp 5)/cc in GCM0.25 + 0.01, the brightest submillimeter source in the region. We suggest that shocks caused by cloud collisions in the turbulent interstellar medium in the Galactic center region are responsible for heating the molecular gas. This conclusion is supported by the presence of wide-spread emission from molecules such as SiO, SO, and CH3OH, which are considered good shock tracers. We also suggest that the GMCs studied here are representative of the "typical", pre-starforming cloud population in the Galactic center.

Lis, D. C.↗