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Characterizing Martian X-ray Amorphous Materials through Terrestrial Analogs

X-ray amorphous materials (i.e., lacking long-range crystallographic order) have been identified on the martian surface from orbit and in-situ. Initial models of orbital IR spectral data identified volcanic glasses [e.g., 1], but subsequent interpretations suggested that amorphous silicates are dominantly secondary in nature and formed from water-rock interactions [e.g., 2-4]. ThermalIR spectra from the Mini-Thermal Emission Spectrometer on the Spirit rover show evidence for the amorphous secondary product opaline silica[e.g., 5].X-ray diffraction (XRD) measurements by the CheMin instrument on the Mars Science Laboratory rover have identified 20-70 wt.% amorphous materials in every sample analyzed in Gale crater to date [e.g., 6]. Mass balance calculations using CheMin results and bulk elemental measurements by the Alpha Particle X-ray Spectrometer suggest the amorphous component in Gale crater is variably enriched in Si, Fe, and S[e.g., 7,8].The compositions are not consistent with pure volcanic glass, indicating water must have been involved in the formation of amorphous materials in Gale crater. We seek to better constrain the conditions under which amorphous materials on Mars formed by studying the composition and short-range atomic order of amorphous materials in terrestrial analog environments via XRD and transmission electron microscopy (TEM).

E. B. Rampe↗

Lightning Enriched Global Precipitation Feature Database

The Tropical Rainfall Measurement Mission (TRMM) has provided a wealth of insight about lightning and precipitation in the tropics. However TRMM did not provide coverage outside the tropics and sub-tropics (i.e., beyond ±38°latitude), and hence it was unable to sample the lightning activity and precipitation features over a large fraction of mid-latitude continents and oceans, including extratropical cyclone storm tracks. The Global Precipitation Measurement (GPM) mission picks up where TRMM left off in that it provides information on precipitation features in the mid-and high latitudes (up to 65°N/S). However, GPM lacks a lightning instrument that can provide additional insights into mid-latitude thunderstorm activity and distribution. Hence we integrate observations from coincident the ISS Lightning Imaging Sensor (LIS) and the World Wide Lightning Location Network (WWLLN) observations with measurements from the GPM constellation of satellites, in particular to extend the existing GPM Precipitation Feature (PF) database so its data parameters are similar to that of the TRMM PF database (i.e., precipitation + lighting). Currently, WWLLN and ISS-LIS lightning have been collocated into precipitation features defined from GPM core satellite and constellation satellites observations.

Precipitation↗

Characterizing Martian X-Ray Amorphous Materials Through Terrestrial Analogs

X-ray amorphous materials (i.e., lacking long-range crystallographic order) have been identified on the martian surface from orbit and in-situ. Initial models of orbital IR spectral data identified volcanic glasses [e.g., 1], but subsequent interpretations suggested that amorphous silicates are dominantly secondary in nature and formed from water-rock interactions [e.g., 2-4]. Thermal IR spectra from the Mini-Thermal Emission Spectrometer on the Spirit rover show evidence for the amorphous secondary product opaline silica [e.g., 5]. X-ray diffraction (XRD) measurements by the CheMin instrument on the Mars Science Laboratory rover have identified 20-70 wt.% amorphous materials in every sample analyzed in Gale crater to date [e.g., 6]. Mass balance calculations using CheMin results and bulk elemental measurements by the Alpha Particle X-ray Spectrometer suggest the amorphous component in Gale crater is variably enriched in Si, Fe, and S [e.g., 7,8]. The compositions are not consistent with pure volcanic glass, indicating water must have been involved in the formation of amorphous materials in Gale crater. We seek to better constrain the conditions under which amorphous materials on Mars formed by studying the composition and short-range atomic order of amorphous materials in terrestrial analog environments via XRD and transmission electron microscopy (TEM).

E B Rampe↗

Residual glasses and melt inclusions in basalts from DSDP Legs 45 and 46 - Evidence for magma mixing

Microprobe analyses of natural glasses in basalts recovered by Legs 45 and 46 of the Deep Sea Drilling Project are reported and interpreted in the context of other geochemical, petrographic and experimental data on the same rocks (Rhodes et al., 1978). Residual glass compositions in the moderately evolved aphyritic and abundantly phyric basalts within each site indicate that none of the units is related to any other or to a common parent by simple fractional crystallization. The compositional trends, extensive disequilibrium textures in the plagioclase phenocrysts and the presence in evolved lavas of refractory plagioclase and olivine phenocrysts bearing primitive melt inclusions provide evidence that magma mixing had a major role in the genesis of the Leg 45 and 46 basalts. The magma parental to these basalts was most likely characterized by high Mg/(Mg + Fe/+2/), CaO/Al2O3, CaO/Na2O and low lithophile concentrations. A mixing model involving incremental enrichment of magmaphile elements by repeated episodes of mixing of relatively primitive and moderately evolved magmas, followed by a small amount of fractionation is consistent with the characteristics of the basalts studied.

Dungan, M. A.↗

Carbonate deposition during the late Proterozoic Era: an example from Spitsbergen

Carbonate sediments reflect the physico-chemical and biological circumstances of their formation; thus, features of limestones and dolomites may provide insights into both environmental and evolutionary change through geological time. The Upper Proterozoic (approx 800-700 Ma) Akademikerbreen Group, Spitsbergen, comprises 2000 m of carbonates, with only minor intercalations of quartz arenite and shale. Although Proterozoic carbonates are often seen as predominantly dolomitic, the Akademikerbreen Group is about 45 percent limestone. Stromatolites are conspicuous in outcrop but constitute only 25 percent of the total section. Micrites and coarser intraclastic carbonates derived mainly from micritric precursors comprise 60 percent of the group, while oolites make up the remaining 15 percent. Distinctive sedimentary features of the group include giant (up to 16 mm) ooids, very early diagenetic calcite nodules and cements, micrites containing subaqueous shrinkage cracks filled with equant microspar cement, and strong 13C enrichment in both carbonates and co-occurring organic matter. The principal features of Akademikerbreen carbonates are widely distributed in coeval successions. However, these rocks appear to differ from older limestones and dolomites in their relative abundance of grainstones and, perhaps, micrites, as well as their paucity of tufa-like laminates and columnar or coniform stromatolites that preserve petrographic evidence of in situ precipitation as a dominant means of carbonate accretion. Upper Proterozoic carbonates also differ from Paleozoic accumulations, but the transition is not abrupt. Most changes accompanying the Proterozoic/Phanerozoic transition can be interpreted in terms of the consequences rather than the causes of metazoan and metaphyte evolution, including the evolution of biomineralization. Carbonate sedimentology reinforces data from other sources which indicate the last 200 to 300 Ma of the Proterozoic Eon was a distinctive interval of Earth history.

NASA Discipline Number 52-30↗

An HST study of galactic inerstellar zinc and chromium

We present a survey of interstellar Zn II and Cr II absorption extracted from the Hubble Space Telescope Goddard High Resolution Spectrograph (HST GHRS) data archive. We find clear evidence for an enhanced depletion of Zn from the gas phase with increasing fractional abundance of molecular hydrogen f(H2). Our lower limit to the Galactic interstellar metallicity is approximately 65% of the solar value as determined by the measured Zn abundances in the lowest f(H2) sightlines, (N(Zn)/N(H(sup 0)(sub tot)) = -0.19 +/- 0.04. The correspondingly high depletion of Cr with respect to solar (N(Cr/N(H(sup 0)(sub tot)) = -1.44 +/- 0.26 indicates that there are significant amounts of dust present in these lines of sight. The Galactic abundances of Zn and Cr in the ISM provide a fundamental reference point which is used to understand the metal enrichment and dust formation history of damped Lyman alpha QSO absorption-line systems, normally believed to arise from intervening precursors to modern disk galaxies. Although the spread in Zn abundances is large for both the local ISM and in damped Lyman alpha systems, we still find a substantial difference (factor of 4-10) in metallicity between the two sets. This survey and future observations of more distant objects which probe the full extent of the Milky Way halo provide a more complete picture of the enrichment and depletion characteristics of present-day galaxies.

Roth, Katherine C.↗

The Origin and Distribution of Heavy Elements in HCG 62

We present recent data on the compact group HCG 62 taken with AXAF CCD Imaging Spectrometer-S (ACIS-S) on Chandra. The sparseness of groups and their relatively simple dynamical history allow the properties of the Intergalatic Medium (IGM) to be more directly related to galaxy evolution than may be possible in clusters, and their lower gas temperatures produce strong lines from a broader range of elements than is the case in hotter clusters. This observation exploits the high X-ray brightness of HCG 62 to determine accurately the abundances of heavy elements as a function of position in the group, to test whether abundance variations are associated with individual galaxies, and to trace the origin of the enrichment.

Vrtilek, Jan↗

Scientific Highlights and Status of the Mars Science Laboratory Mission, Years 9 through 12

We present the scientific highlights and status from years 9-12 of NASA’s Mars Science Laboratory mission, with its Curiosity rover. A thermochemolysis-based sample analysis revealed a variety of organic molecules preserved in clay mineral-rich lake/lake margin deposits of the Glen Torridon region. The stratigraphically higher clay-sulfate mineral transition on Aeolis Mons was found to be associated with a lithological change from lacustrine to dry aeolian depositional environments. Water intermittently returned to the surface after the increase in aridity, including during the deposition of wave ripple strata which indicate a climate capable of sustaining an ice-free lake in the early Hesperian. The overlying Mg sulfate-bearing unit has both poly- and monohydrated Mg sulfates and is also enriched in iron carbonate of a purity consistent with chemical sedimentation and therefore atmospheric sequestration. A channel-incised canyon within Gediz Vallis and distal alluvial deposits recorded numerous fluvial and debris flow events after the deposition, lithification, and erosion of the clay- and sulfate-bearing units. Bright clasts found in Gediz Vallis canyon are composed of native sulfur. The investigation of the modern atmosphere and environment focused on the influence of the crater and mountain topography and captured high-altitude noctilucent and iridescent clouds. Radiation monitoring now spans an 11-year solar cycle. Rover systems and science instruments remain capable of addressing mission scientific objectives. All ten scientific instruments continue to return high-value data despite degradation of the Chemistry and Camera instrument’s high-voltage system, loss of multispectral imaging capability, and loss of active neutron spectroscopy. The mission has mitigated the loss of redundant brakes on two arm joints, additional wheel wear, and highly reduced capability of the redundant flight computer. Efficiency improvements in rover energy utilization and operations staffing have allowed the mission team to maintain a high level of productivity despite declining rover power generation and funding.

Mars↗

Cryogenic hydrogen-induced air-liquefaction technologies

Extensive use of a special advanced airbreathing propulsion archives data base, as well as direct contacts with individuals who were active in the field in previous years, a technical assessment of cryogenic hydrogen induced air liquefaction, as a prospective onboard aerospace vehicle process, was performed and documented in 1986. The resulting assessment report is summarized. Technical findings relating the status of air liquefaction technology are presented both as a singular technical area, and also as that of a cluster of collateral technical areas including: Compact lightweight cryogenic heat exchangers; Heat exchanger atmospheric constituents fouling alleviation; Para/ortho hydrogen shift conversion catalysts; Hydrogen turbine expanders, cryogenic air compressors and liquid air pumps; Hydrogen recycling using slush hydrogen as heat sinks; Liquid hydrogen/liquid air rocket type combustion devices; Air Collection and Enrichment System (ACES); and Technically related engine concepts.

Escher, William J. D.↗

Fragments of ancient lunar crust: Ferroan noritic anorthosites from the descartes region of the Moon

Noritic anorthosite clasts from breccia 67016 have bulk compositions similar to that of the upper crust of the Moon and petrogenetic affinities with pristine ferroan anorthosites. Rb-Sr and Sm-Nd isotopic compositions of mineral separates from one of these clasts suggest very old (greater than or = 4.4 Ga) ages, but interpretation of these data is complicated by the multi-stage history of the clasts which involved magmatic crystallization, brecciation, subsolidus recrystallization, and sulfide metasomatism. These clasts record some of the earliest events on the Moon, including early crust formation, accretionary bombardment, and degassing of the lunar interior. Modal analyses of these clasts show they are now composed of about 70 percent plagioclase, 28 percent pyroxene, 2 percent troilite, and minor amounts of ilmenite and chromite. No metallic iron, phosphates, or other trace phases were observed. Olivine is very rare, occurring only as relicts within secondary troilite+pyroxene intergrowths which may reflect reaction of olivine with sulfurous vapors. PIXE proton microprobe analyses of the sulfides show that the metasomatism was accompanied by enrichments of Cu, Zn, Ni, Se, and Sb. The clasts have been only mildly shocked since the observed texture was established. Major and minor element mineral compositions are very homogeneous and strikingly similar to those of pristine ferroan anorthosites. Pyroxene compositions indicate equilibration temperatures of 850-900 C. Except for the sulfide and chalcophile element metasomatism, these clasts appear to be essentially monomict and probably represent a noritic member of the ferroan anorthosite suite. Their low Ni contents and Ni/Co ratios are consistent with the interpretation of these clasts as igneous rocks which have escaped mixing with meteoritic material.

Norman, M. D.↗

X-ray constraints on the intergalactic medium

We use ROSAT Position Sensitive Proportional Counter (PSPC) spectra of z approximately equal 3 quasars to constrain the density and temperature of the intergalactic medium (IGM). Strong low-energy cutoffs in PSPC spectra of high-redshift quasars are common. However, the absence of absorption toward some high-redshift quasars can be used to put limits on the possible cosmological density, Omega(sub G), of a hot diffuse intergalactic medium (IGM), via an X-ray Gunn-Peterson test using edge and line opacity in the soft X-rays. The K-edges of oxygen, neon, and carbon and the L-edge of iron produce most of the absorption which is spread out by the redshift of the source. We assume an isotropic, isothermal, nonevolving model of the IGM and calculate the optical depth of this absorption. We find that this test can constrain an enriched IGM at temperatures near 10(exp 5) - 10(exp 6) K, intermediate between the hot IGM ruled out by COBE, and the cold IGM ruled out by the traditional Ly alpha Gunn -Peterson test. Photoionization if the IGM by the ultraviolet and X-ray background has a large effect. We give results for three z approximately equal 3 quasars and discuss how the various trade-offs among temperature, abundance, and backgroud radiation strength affect the limits on Omega (sub G). In addition to the high-redshift case, we discuss techniques for constraining the IGM using X-ray spectra of low-redhift quasars (z approximately equal 0.1 - 0.3). Currently available X-ray spectral data have insufficient energy resolution to constrain the IGM umambiguously, and so expected detection limits for future high-resolution spectrometers are presented. We find that with a large effective area (approximately 2000 sq cm), it is possible to substantially constrain or detect the IGM at the densities which are typically predicted.

Aldcroft, Thomas↗

Preliminary Modeling of CH3D From 4000 to 4550 cm (exp-1)

A new study of 12CH3D line positions and intensities was performed for the upper portion of the Enneadecad polyad between 4000 and 4550/cm. For this, FTIR spectra were recorded with D-enriched methane samples (at 80 K with a Bruker 125 IFS at 0.005/cm resolution and at 291 K with the McMath-Pierce FTS at 0.011/cm resolution, respectively). Line positions and intensities were retrieved by least square curve-fitting procedures and analyzed using the effective Hamiltonian and the effective dipole moment expressed in terms of irreducible tensor operators adapted to symmetric top molecules. Initially, only the cold spectrum was used to identify quantum assignments and predict 12CH3D relative intensities in this region. To assign higher quanta up to J equal 14, additional line positions and intensities were obtained from two room temperature spectra. In the final stage, measured intensities from both the cold and the room temperature data were normalized to corresponding values at 296 K and then averaged. Combining the two temperature datasets confirmed the assumed quantum assignments and also demonstrated the relative accuracies to be better than 70.0002/cm for line positions and at least +/-6% for intensities so that approx.1160 features were selected. Including additional assignments from the room temperature spectra alone permitted 1362 line intensities of 11 bands (involving 23 vibrational symmetry components) to be reproduced with an RMS of 9%. Over 4085 selected positions for 12 bands were modeled to 0.008/cm. Nevertheless a number of known assignments could not be modeled to within our experimental precisions. More work is needed to obtain a complete characterization of this complex polyad.

Nikitin, A. V.↗

Implications of isotopic compositions of N and Ne in the Martian atmosphere to temporal evolution of its atmosphere and regolith

The isotopic compositions of N and Ne in the Martian atmosphere are governed by several factors, principal among which are the temporal evolution in (1) the absolute surface pressure of oxygen, (2) the physicochemical characteristics of the regolith, and finally (3) the N-15 enrichment expected due to preferential hydrodynamical escape of N-14 (due to solar wind bombardment). Each of these factors is unique to Mars. In fact, no other planet offers the uniquely favorable situations for N-15 and Ne-21 enrichments. The cosmogenic production of N-15 is, in particular, unique. It promises to provide very valuable constraints on the temporal evolution of the martian CO2 and H2O, both in the atmosphere and regolith. The rate of production of cosmogenic (spallation) N-15 is dependent on the surface pressure of oxygen, the principal target element for formation of N-15. In view of the relatively high O/N ratio in the martian atmosphere, relatively high N-15/N ratio are expected to arise from cosmogenic reactions. The added bonus comes from the fact that an appreciable production of N-15 is expected in the martian regolith because of its thin atmosphere. From model calculations it is shown that if accurate isotopic composition data become available for N and Ne, it should be possible to put robust constraints on the time averages martian oxygen surface pressure and subsurface water in the upper layers.

Lal, D.↗

New analysis of the Voyager UVS H Lyman-alpha emission of Saturn

The limb to limb Lyman-alpha reflectivities observed with the Voyager ultraviolet spectrometer (UVS) instruments during the fly-by of Saturn are reanalyzed using a revised H Lyman-alpha sensitivity for the Voyager 1 instrument. The new sensitivity reconciles the measured intensities to those of Voyager 2 and gives a coherent set of data. To fit the UV airglow observations, four sources are considered: (1) H resonance and H2 Rayleigh scattering of solar Lyman-alpha radiation, (2) the interplanetary Lyman-alpha radiation, (3) a possible internal source of unknown origin, (4) the possibility of atmospheric turbulence recently proposed to explain the Lyman-alpha bulge of Jupiter. The analysis supports neither a dominant collisional excitation source for the UV emissions nor the presence of strong atmospheric turbulence. The best fit, in terms of brightness but also in terms of shape of the limb to limb profile (that is to say independent on the absolute calibrations), is obtained for pure resonance and Rayleigh scattering of solar and interstellar wind line in an atmosphere enriched in atomic hydrogen up to three times the standard model. Influx of water from the rings of Saturn may provide a means for producing such enhanced H densities in the upper atmosphere.

Jaffel, L. Ben↗

MG Isotopic Measurement of FIB-Isolated Presolar Silicate Grains

The majority of presolar oxide and silicate grains are ascribed to origins in low-mass red giant and asymptotic giant branch (AGB) stars based on their O isotopic ratios. However, a minor population of these grains (< 10%) has O isotopic ratios incompatible with these sources. Two principle alternative sources are higher-than-solar metallicity (Z) stars or, more likely, supernovae (SN) [1-3]. These rare (Group 4) grains [3] are characterized by enrichments in O-18, and typically also enrichments in O-17. An even rarer subset of grains with extremely large enrichments in O-17 and smaller depletions in O-18 were suggested to come from binary star systems [2]. To establish the origins of these isotopically unusual grains, it is necessary to examine isotopic systems in addition to O. Presolar silicates offer several elements diagnostic of their stellar sources and nuclear processes, including O, Si, Mg, Fe and Ca. However, the database for minor element isotopic compositions in silicates is seriously lacking. To date only two silicate grains have been analyzed for Mg [4] or Fe [5]. One major complicating factor is their small size (average ~230 nm), which greatly limits the number of measurements that can be performed on any one grain and makes it more difficult to obtain statistically relevant data. This problem is compounded because the grains are identified among isotopically solar silicates, which contribute a diluting signal in isotopic measurements [1]. Thus, relatively small isotopic anomalies are missed due to this dilution effect. By applying focused ion beam (FIB) milling, we obtain undiluted Mg isotopic ratios of isolated rare presolar silicate grains to investigate their sources.

Messenger, Scott R.↗

The Connection Between Small Gamma-Ray Flares and SEPs with COMPTEL/CGRO

While it is clear that particle acceleration is occurring during flares, what is less clear is the connection between the neutral radiation observed concommitant with the flare and the in-situ observations of SEPs. For the largest SEP events, where current instruments possess the sensitivity to observe nuclear-related gamma-ray emission, the origin of SEPs is generally divided between an escaping accelerated flare population and a population of coronal particles (or some admixture) accelerated through CME-driven shocks. Small flares, as defined by their X-ray emission, have been found to correlate with the presence of small "impulsive" (enriched in electrons and heavy nuclei) SEP events, suggesting that small SEP events are originally flare particles. The difficulty with this interpretation is that small flares lack detectable nuclear-related gamma-ray emission. Whether this emission is there or not is unclear because current instruments capable of high-energy gamma-ray observations operate above the sensitivity threshold for observing gammaray emission from small flares (< C-class). The COMPton TELescope (COMPTEL) aboard the Compton Gamma Ray Observatory (CGRO) provided unprecedented, and as yet unsurpassed, sensitivity to y rays in the 0.7 to 30 MeV energy range and neutrons in the 20 to 150 MeV energy range. This, combined with its nine years of operation, has produced a unique data set of observations for almost a complete solar cycle. The COMPTEL archival data offers the best possibility to investigate a connection between SEP observations in space and small-flare gamma-ray emission. We present preliminary results of a small-flare search within the COMPTEL archival data and discuss the correlation between already well-established compilations of SEP events and small impulsive or 3He-rich SEP events. Establishing a connection and determining the characterization of this connection, would signify an important development in our understanding of how and where flare particles are accelerated and how these very same particles escape into the interplanetary medium. Equally important would be demonstrating the inconsistencies or poor correlation between gamma-ray emission and small impulsive SEP events.

deNolfo, Georgia↗

Airborne measurements of tropospheric ozone destruction and particulate bromide formation in the Arctic

Aircraft profiles of O3 concentrations over the Arctic ice pack in spring exhibit a depletion of O3 beneath the surface temperature inversion. One such profile from the NOAA WP-3D Arctic Gas and Aerosol Sampling Program (AGASP) flights in April, 1986 north of Alert, NWT (YLT, 82.5 N) is shown. The gradient of O3 across the temperature inversion, which is essentially a step function from tropospheric values (35 to 40 ppbv) to 0, is somewhat masked by a 1-min running mean applied to the data. Evidence is presented that O3 destruction beneath the Arctic temperature inversion is the result of a photochemical reaction between gaseous Br compounds and O3 to produce particulate Br aerosol. It is noted that in springtime, O3 at the Alert Baseline Station regularly decreases from 30 to 40 ppbv to near 0 over the period of a few hours to a day. At the same time, there is a production of particulate Br with a near 1.0 anti-correlation to O3 concentration. Surface concentrations of bromoform in the Arctic exhibit a rapid decrease following polar sunrise. AGASP aircraft measurements of filterable bromine particulates in the Arctic (March-April, 1983 and 1986) are shown. The greatest concentrations of Br aerosol (shown as enrichment factors relative to to Na in seawater, EFBR (Na)) were observed in samples collected beneath the surface temperature inversion over ice. Samples collected at the same altitude over open ocean (off Spitzbergen) labeled Marine did not exhibit similar Br enrichments. A second region of particulate Br enrichment was observed in the lower stratosphere, which regularly descends to below 500 mb (5.5 km) in the high Arctic. The NOAA WP-3D flew in the stratosphere on all AGASP flights and occasionally measured O3 concentrations in excess of 300 ppbv.

Schnell, Russell C.↗

The mini-CIDEX GC/IMS: Analysis of cometary ice and dust

Comets are recognized as among the most scientifically important objects in the solar system. They are presumed relics of the early primitive material in the solar nebula and are believed to have provided a general enrichment of volatiles to the inner solar system. The Cometary Coma Chemical Composition (C4) Mission, a proposed Discovery-Class Mission, will analyze materials released into the coma, providing information leading to the understanding of the chemical composition and make-up of the cometary nucleus. As one of two scientific instruments in the C4 spacecraft, an advanced and streamlined version of the Cometary Ice and Dust Experiment (CIDEX), a mini-CIDEX, will employ an X-Ray Fluorescence (XRF) spectrometer to determine bulk elemental composition of cometary dust grains and a Gas Chromatograph/Ion Mobility Spectrometer (GC/IMS) for determination of the molecular composition of dust and ices following stepwise pyrolysis and combustion. A description of the mini-CIDEX IMS will be provided as well as data from analyses conducted using the mini-CIDEX breadboard instrument.

Kojiro, Daniel R.↗