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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Computational test of the infinite order sudden approximation for excitation of linear rigid rotors by collisions with atoms

The infinite order sudden approximation for excitation of linear rigid rotors by collisions with atom is tested by comparing integral state-to-state cross sections with accurate close coupling and coupled states results. The systems studied are HCl-Ar, HCl-He, CO-He, HCN-He, CS-H2 and OCS-H2. With the exception of diatomic hydrides (e.g., HCl) which have atypically large rotational constants the method is found to be very accurate to remarkably low collision energies. This approximation should generally be extremely useful for thermal energy collisions.

Green, S.↗
NASA NTRSDate not supplied

Impacts of aerosol size-dependent below-cloud scavenging on tropospheric aerosol in the NASA GEOS model

Wet deposition is the major sink for a suite of tropospheric aerosols, and thus largely affects the global distribution and lifetime of aerosols as well as the formation of clouds in the atmosphere. In this study, we implement the aerosol size-dependent below-cloud scavenging (BCS; washout) parameterization of Croft et al. (Atmos. Chem. Phys., 2009; hereafter referred to as C09) in the GOCART bulk aerosol scheme coupled with the NASA Goddard Earth Observing System (GEOS) model, and evaluate the simulated tropospheric aerosols against surface, airborne, and satellite observations. The current below-cloud scavenging in GOCART employs a first-order removal function with a constant scavenging coefficient that is independent of aerosol sizes and precipitation fluxes. The C09 BCS parameterization instead calculates aerosol below-cloud scavenging coefficients based on a size-dependent collision efficiency between aerosol particles and raindrops (or snow crystals). A look-up table of compiled collision efficiencies provides scavenging coefficients for sixty aerosol sizes and nine rain flux rates. We determine instantaneous coefficients according to the C09 BCS look-up table, precipitation fluxes, and a log-normal size distribution of aerosols. The implemented BCS parameterization tends to result in a large diversity of scavenging coefficient values with higher magnitudes, leading to more efficient scavenging. The model-simulated global mean tropospheric Pb-210 aerosol lifetime decreases from 7.4 days to 5.8 days. The separate consideration of rain and snow conditions in the scavenging coefficient lookup table leads to a bi-mode distribution of scavenging coefficients. These changes also cause increased mass fractions of smaller aerosols compared to the current simulation. We examine the impacts of the C09 BCS parameterization on the simulated aerosol vertical profiles, tropospheric lifetimes, and deposition fluxes through comparisons with NASA aircraft measurements (ATom), surface observations of aerosol concentrations (IMPROVE) and wet deposition fluxes (NADP and APQMP), and MODIS aerosol optical depth (AOD) retrievals.

Aerosols↗
NASA NTRS1982

Measurement of soil moisture using remote sensing multisensor radiation techniques

Theoretical modeling as well as laboratory and field measurement were coupled with analysis of aircraft data obtained from controlled sites in an effort to enhance understanding of the microwave response due to soil moisture so as to specify sensor parameters and develop inversion algorithms. Models to predict the complex dielectric constant were produced which led to the interpretation of the results in terms of a matrix potential rather than simply moisture content. Similar advances were made in the development of coherent and incoherent radiative transfer models and rough surface scattering models.

Waite, W. P.↗
NASA NTRS1990

Measurements and mechanisms of localized aqueous corrosion in aluminum-lithium alloys

Like most heat treatable aluminum alloys, localized corrosion and stress corrosion of Al-Li-Cu alloys is strongly dependent on the nature and distribution of second phase particles. To develop a mechanistic understanding of the role of localized corrosion in the stress corrosion process, bulk samples of T(sub 1) (Al2CuLi) and a range of Al-Cu-Fe impurity phases were prepared for electrochemical experiments. Potentiodynamic polarization and galvanic couple experiments were performed in standard 0.6 M NaCl and in simulated crevice solutions to assess corrosion behavior of these particles with respect to the alpha-Al matrix. A comparison of time to failure versus applied potential using a constant load, smooth bar SCC test technique in Cl(-), Cl(-)/CrO4(2-), and Cl(-)/CO3(2-) environments shows that rapid failures are to be expected when applied potentials are more positive than the breakaway potential (E sub br) of T(sub 1) (crack tip) but less than E(sub br) of alpha-Al (crack walls). It is shown that this criterion is not satisfied in aerated Cl(-) solutions. Accordingly, SCC resistance is good. This criterion is satisfied, however, in an alkaline isolated fissure exposed to a CO2 containing atmosphere. Rapid failure induced by these fissures was recently termed preexposure embrittlement. Anodic polarization shows that the corrosion behavior of T(sub 1) is relatively unaffected in alkaline CO3(2-) environments but the alpha-Al phase is rapidly passivated. X ray diffraction of crevice walls from artificial crevices suggests that passivation of alpha-Al occurs as hydrotalcite-type compound (LiAl2(OH)6)2(+) - CO3(2-) - nH2O.

Buchheit, Rudolph G., Jr.↗
NASA NTRS1992

Measurement of the magnetic anisotropy energy constants for magneto-optical recording media

Measurement of the magneto-optical polar Kerr effect is performed on rare earth-transition metal (RE-TM) amorphous films using in-plane fields. From this measurement and the measurement of the saturation magnetization using a vibrating sample magnetometer (VSM), the magnetic anisotropy constants are determined. The temperature dependence is presented of the magnetic anisotropy in the range of -175 to 175 C. The results show a dip in the anisotropy near magnetic compensation. This anomaly is explained based on the finite exchange coupling between the rare earth and transition metal subnetworks.

Hajjar, R. A.↗
NASA NTRS1990

Computation of rotor aerodynamic loads in forward flight using a full-span free wake analysis

The development of an advanced computational analysis of unsteady aerodynamic loads on isolated helicopter rotors in forward flight is described. The primary technical focus of the development was the implementation of a freely distorting filamentary wake model composed of curved vortex elements laid out along contours of constant vortex sheet strength in the wake. This model captures the wake generated by the full span of each rotor blade and makes possible a unified treatment of the shed and trailed vorticity in the wake. This wake model was coupled to a modal analysis of the rotor blade dynamics and a vortex lattice treatment of the aerodynamic loads to produce a comprehensive model for rotor performance and air loads in forward flight dubbed RotorCRAFT (Computation of Rotor Aerodynamics in Forward Flight). The technical background on the major components of this analysis are discussed and the correlation of predictions of performance, trim, and unsteady air loads with experimental data from several representative rotor configurations is examined. The primary conclusions of this study are that the RotorCRAFT analysis correlates well with measured loads on a variety of configurations and that application of the full span free wake model is required to capture several important features of the vibratory loading on rotor blades in forward flight.

Quackenbush, Todd R.↗
NASA NTRS1994

Atmospheric effects on the mapping of Martian thermal inertia and thermally derived albedo

The most widely used thermal inertia data for Mars assumes the atmospheric contribution is constant and equal to 2 percent of the maximum solar insolation. Haberle and Jakosky investigated the effect of including a dusty CO2 atmosphere and sensible heat exchange with the surface on thermal inertia. We recently utilized Haberle and Jakosky's coupled surface-atmosphere model to investigate the effects of such an atmosphere on the thermally derived albedo. The thermally derived albedo is the albedo which, together with the thermal inertia, provides model surface temperatures which best match the observed temperatures. New maps are presented of thermal inertia and thermally derived albedo which incorporate dust opacities derived from IRTM data.

Hayashi, J. N.↗
NASA NTRS1994

Heterogeneous Reactions of ClONO2, HCl, and HOCl on Liquid Sulfuric Acid Surfaces

The heterogeneous reactions of ClONO2 + H2O yields HNO3 + HOCl (1), ClONO2 + HCl yields C12 + HNO3 (2), and HOCl + HCl yields Cl2 + H2O (3) on liquid sulfuric acid surfaces have been studied using a fast flow reactor coupled to a quadrupole mass spectrometer. The main objectives of the study are to investigate: (a) the temperature dependence of these reactions at a fixed H2O partial pressure typical of the lower stratosphere (that is, by changing temperature at a constant water partial pressure, the H2SO4 content of the surfaces is also changed), (b) the relative importance or competition between reactions 1 and 2, and (c) the effect of HNO3 on the reaction probabilities due to the formation of a H2SO4/HNO3/H2O ternary system. The measurements show that all the reactions depend markedly on temperature at a fixed H2O partial pressure: they proceed efficiently at temperatures near 200 K and much slower at temperatures near 220 K. The reaction probability (gamma(sub 1)) for ClONO2 hydrolysis approaches 0.01 at temperatures below 200 K, whereas the values for gamma(sub 2) and gamma(sub 3) are on the order of a few tenths at 200 K. Although detailed mechanisms for these reactions are still unknown, the present data indicate that the competition between ClONO2 hydrolysis and ClONO2 reaction with HCl may depend on temperature (or H2SO4 Wt %): in the presence of gaseous HCl at stratospheric concentrations, reaction 2 is dominant at lower temperatures (less than 200 K), but reaction 1 becomes important at temperatures above 210 K. Furthermore, reaction probability measurements performed on the H2SO4/HNO3/ H2O ternary solutions do not exhibit noticeable deviation from those performed on the H2SO4/H2O binary system, suggesting little effect of HNO3 in sulfate aerosols on the ClONO2 and HOCl reactions with HCl. The results reveal that significant reductions in the chlorine-containing reservoir species (such as ClONO2 and HCl) can take place on stratospheric sulfate aerosols at high latitudes in winter and early spring, even at temperatures too warm for Polar Stratospheric Clouds (PSCs) to form or in regions where nucleation of PSCs is sparse. This is particularly true under elevated sulfuric acid loading, such as that after the eruption of Mt. Pinatubo. Comparisons between our results and those presently available have also been made.

Zhang, Renyi↗
NASA NTRS2010

Method of Obtaining High Resolution Intrinsic Wire Boom Damping Parameters for Multi-Body Dynamics Simulations

The goal of NASA's Magnetospheric MultiScale (MMS) mission is to understand magnetic reconnection with sensor measurements from four spinning satellites flown in a tight tetrahedron formation. Four of the six electric field sensors on each satellite are located at the end of 60- meter wire booms to increase measurement sensitivity in the spin plane and to minimize motion coupling from perturbations on the main body. A propulsion burn however, might induce boom oscillations that could impact science measurements if oscillations do not damp to values on the order of 0.1 degree in a timely fashion. Large damping time constants could also adversely affect flight dynamics and attitude control performance. In this paper, we will discuss the implementation of a high resolution method for calculating the boom's intrinsic damping, which was used in multi-body dynamics simulations. In summary, experimental data was obtained with a scaled-down boom, which was suspended as a pendulum in vacuum. Optical techniques were designed to accurately measure the natural decay of angular position and subsequently, data processing algorithms resulted in excellent spatial and temporal resolutions. This method was repeated in a parametric study for various lengths, root tensions and vacuum levels. For all data sets, regression models for damping were applied, including: nonlinear viscous, frequency-independent hysteretic, coulomb and some combination of them. Our data analysis and dynamics models have shown that the intrinsic damping for the baseline boom is insufficient, thereby forcing project management to explore mitigation strategies.

Yew, Alvin G.↗
NASA NTRS2019

Time Resolved Irradiance of an Integrating Sphere Illuminated by a Mode-Locked Optical Parametric Oscillator

Tunable laser based illumination sources have been adopted by a number of recent hyperspectral instruments for pre-launch spectral radiometric calibration. Some of these sources use mode-locked cavity configurations, which produce a pulse train and create an undesirable fluctuation in the radiometric source at the mode locking frequency. Although typically this frequency is several orders of magnitude higher than the instrument response, care must be taken to ensure the resultant calibration is not biased due to detector or electronic saturation effects. The temporal averaging properties of an integrating sphere can be used to reduce high frequency fluctuations to an acceptable level. In this work, the time resolved output of an integrating sphere coupled with a mode-locked source was measured. A 76 cm diameter sphere with 30 cm output aperture was illuminated using a mode-locked pulse train at 76 MHz, with single pulse durations of 12 ps. The time constant of the sphere was found to be 36 ns, and the resultant temporal averaging of pulses produced a maximum time varying irradiance at the output of 20% of the mean. The form of this time variance is a sawtooth pattern, with a sharp rise during the introduction of each pulse into the sphere followed by a slower decay between pulses. A comparison of instrument calibration data generated with this integrating sphere using both a mode locked source and a continuous wave source is also given. .

McAndrew, Brendan↗
NASA NTRSDate not supplied

Disorder to Order in Interface Patterns: Thermal Noise to Limit Cycle Transition in Dendrite Sidebranch Formation

Thin sample directional solidification experiments have been carried out in the model succinonitrile-camphor system to examine the origin of secondary branches in dendrite morphologies. Thermal noise at the dendrite tip creates interface instabilities which amplify to form sidebranches. This is accepted as the primary mode of sidebranching in dendritic growth from an undercooled melt and occurs in directional solidification of dendrites. The proposed limit cycle couples the growth of the tip with the initiation of the sidebranch. Directional solidification of curved interfaces is a driven dissipative system with the potential to form a limit cycle. Two sets of experiments were performed, the first holding velocity constant and evolving the gradient and the second imposing oscillating velocities around the natural period of sidebranching. Both experimental methods were found to characterize a transition from disordered sidebranching induced by thermal noise to ordered sidebranching produced by the limit cycle mechanisms. This is the first quantitative measurement of previously hypothesized limit cycle growth. These experiment sets have been quantitatively analyzed for dynamic behavior seen in limit cycles. High-quality data sets of the tip and instability enable the measurement of the FFT and analysis through a power spectrum. At low gradients, the sidebranches are found to be excited by thermal noise far away from the tip. As the gradient increases and velocity is held constant, the distance between the instability and tip decreases until limit cycle growth is found between the tip of the primary dendrite and the first forming sidebranch. An alternative to the deterministic limit cycles seen in experiments of gradient evolution is a limit cycle actively driven through the square wave oscillation of velocity. Crucial observations of the solidified microstructure conclude that this produced periodic interconnected bridges between the primary dendrites. This is a finding with potentially significant implications for commercial applications.

Trevor Lyons↗
NASA NTRS1974

Minimization of the prime power consumption of a coupling-modulated gas laser transmitter

The present article addresses itself to the prime power requirements of a coupling-modulated gas laser transmitter. The latter consists of a gas discharge tube and electrooptic modulator inside a laser resonator. In performing the calculations, the laser discharge length and the modulator voltage are simultaneously varied so that the transmitted power remains constant. In this way, tradeoffs can be made between the prime power supplied individually to the discharge tube and to the modulator driver to obtain a transmitter configuration that minimizes the total prime power consumption. An analytical expression is derived that describes the effects of information bandwidth and transmitter output power on the prime power requirements. Specific numerical results are obtained for a CO2 laser transmitter based on presently available experimental data.

Degnan, J. J.↗
NASA NTRS1989

Collisional excitation of interstellar molecules - Deuterated water, HDO

Using an accurate theoretical interacting potential and coupled-channel molecular scattering calculations, excitation rates for deuterated water (HDO) in collisions with He atoms were computed. Data are presented for rates among the 34 rotational levels with energy below 400/cm for temperatures between 50 and 500 K. Excitation rate constants were determined using data from fixed energy cross sections averaged over thermal (Boltzmann) distributions of collision energies. Based on the agreement (for H2O) of rates from two different theoretical potentials and on agreement with the limited experimental data, the larger rates for HDO were estimated to be generally accurate to better than 50 percent.

Green, Sheldon↗
NASA NTRS2003

The critical role of velocity storage in production of motion sickness

We propose that motion sickness is mediated through the orientation properties of velocity storage in the vestibular system that tend to align eye velocity produced by the angular vestibulo-ocular reflex (aVOR) with gravito-inertial acceleration (GIA). (GIA is the sum of the linear accelerations acting on the head. In the absence of translational accelerations, gravity is the GIA.) We further postulate that motion sickness produced by cross-coupled vestibular stimulation can be characterized by a metric composed of the disparity between the axis of eye rotation and the GIA, the strength of the response to angular motion, and the response duration, as determined by the central vestibular time constant, that is, by the time constant of velocity storage. The nodulus and uvula of the vestibulocerebellum are likely to be the central sites where the disparity is sensed, where the vestibular time constants are habituated, and where links are made to the autonomic system to produce the symptoms and signs.

Non-NASA Center↗
NASA NTRS1997

Correspondence between discrete and continuous models of excitable media: trigger waves

We present a theoretical framework for relating continuous partial differential equation (PDE) models of excitable media to discrete cellular automata (CA) models on a randomized lattice. These relations establish a quantitative link between the CA model and the specific physical system under study. We derive expressions for the CA model's plane wave speed, critical curvature, and effective diffusion constant in terms of the model's internal parameters (the interaction radius, excitation threshold, and time step). We then equate these expressions to the corresponding quantities obtained from solution of the PDEs (for a fixed excitability). This yields a set of coupled equations with a unique solution for the required CA parameter values. Here we restrict our analysis to "trigger" wave solutions obtained in the limiting case of a two-dimensional excitable medium with no recovery processes. We tested the correspondence between our CA model and two PDE models (the FitzHugh-Nagumo medium and a medium with a "sawtooth" nonlinear reaction source) and found good agreement with the numerical solutions of the PDEs. Our results suggest that the behavior of trigger waves is actually controlled by a small number of parameters.

Non-NASA Center↗
NASA NTRS2004

Arylethynyl Substituted 9,lO-Anthraquinones: Tunable Stokes Shifts by Substitution and Solvent Polarity

2-Arylethynyl- and 2,6- and 2,7-diarylethynyl-substituted 9,lO-anthraquinones were synthesized via Sonogashira coupling reactions of 2-bromo-, 2,6-dibromo-, and 2,7-dibromo-9,10- anthraquinone with para-substituted phenylacetylenes. While the redox properties of those compounds are almost insensitive to substitution, their absorption maxima are linearly related to the Hammett constants with different slopes for electron donors and electron acceptors. ABI compounds are photoluminescent both in solution (quantum yields of emission <= 6 %), and as solids. The emission spectra have the characteristics of charge-transfer bands with large Stokes shifts (100-250 nm). The charge-transfer character of the emitting state is supported by large dipole moment differences between the ground and the excited state as concluded on the basis of molecular modeling and Lippert-Mataga correlations of the Stokes shifts with solvent polarity. Maximum Stokes shifts are attained by both electron-donating and -withdrawing groups. This is explained by a destabilization of the HOMO by electron donors and a stabilization of the LUMO by electron acceptors. X-ray crystallographic analysis of, for example, 2,7-bisphenylethynfl- 9,lO-anthraquinone reveals a monoclinic P21In space group and no indication for pi-overlap that would promote quenching, thus explaining emission from the solid state. Representative reduced forms of the title compounds were isolated as stable acetates of the corresponding dihydrs-9,10- anthraquinones. The emission of these compounds is blue-shifted relative to the parent oxidized forms and is attributed to internal transitions in the dihydro-9,lO-anthraquinone core.

Yang, Jinhua↗
NASA NTRS2012

Decadal Trends in Abundance, Size and Condition of Antarctic Toothfish in McMurdo Sound, Antarctica, 1972-2010

We report analyses of a dataset spanning 38 years of near-annual fishing for Antarctic toothfish Dissostichus mawsoni, using a vertical setline through the fast ice of McMurdo Sound, Antarctica, 1972-2010. This constitutes one of the longest biological time series in the Southern Ocean, and certainly the longest for any fish. Fish total length, condition and catch per unit effort (CPUE) were derived from the more than 5500 fish caught. Contrary to expectation, length-frequency was dominated by fish in the upper half of the industrial catch. The discrepancy may be due to biases in the sampling capabilities of vertical (this study) versus benthic (horizontal) fishing gear (industry long lines), related to the fact that only large Antarctic toothfish (more than 100 cm TL) are neutrally buoyant and occur in the water column. Fish length and condition increased from the early 1970s to the early 1990s and then decreased, related to sea ice cover, with lags of 8 months to 5 years, and may ultimately be related to the fishery (which targets large fish) and changes in the Southern Annular Mode through effects on toothfish main prey, Antarctic silverfish Pleuragramma antarcticum. CPUE was constant through 2001 and then decreased dramatically, likely related to the industrial fishery, which began in 1996 and which concentrates effort over the Ross Sea slope, where tagged McMurdo fish have been found. Due to limited prey choices and, therefore, close coupling among mesopredators of the Ross Sea, Antarctic toothfish included, the fishery may be altering the trophic structure of the Ross Sea.

Ainley, David G.↗
NASA NTRS1995

Feasibility of Coupling Between a Single-Mode Elliptical-Core Fiber and a Single Mode Rib Waveguide Over Temperature

To determine the feasibility of coupling the output of an optical fiber to a rib waveguide in a temperature environment ranging from 20 C to 300 C, a theoretical calculation of the coupling efficiency between the two was investigated. This is a significant problem which needs to be addressed to determine whether an integrated optic device can function in a harsh temperature environment. Because the behavior of the integrated-optic device is polarization sensitive, a polarization-preserving optic fiber, via its elliptical core, was used to couple light with a known polarization into the device. To couple light energy efficiently from an optical fiber into a channel waveguide, the design of both components should provide for well-matched electric field profiles. The rib waveguide analyzed was the light input channel of an integrated-optic pressure sensor. Due to the complex geometry of the rib waveguide, there is no analytical solution to the wave equation for the guided modes. Approximation or numerical techniques must be utilized to determine the propagation constants and field patterns of the guide. In this study, three solution methods were used to determine the field profiles of both the fiber and guide: the effective-index method (EIM), Marcatili's approximation, and a Fourier method. These methods were utilized independently to calculate the electric field profile of a rib channel waveguide and elliptical fiber at two temperatures, 20 C and 300 C. These temperatures were chosen to represent a nominal and a high temperature that the device would experience. Using the electric field profile calculated from each method, the theoretical coupling efficiency between the single-mode optical fiber and rib waveguide was calculated using the overlap integral and results of the techniques compared. Initially, perfect alignment was assumed and the coupling efficiency calculated. Then, the coupling efficiency calculation was repeated for a range of transverse offsets at both temperatures. Results of the calculation indicate a high coupling efficiency can be achieved when the two components were properly aligned. The coupling efficiency was more sensitive to alignment offsets in the y direction than the x, due to the elliptical modal profile of both components. Changes in the coupling efficiency over temperature were found to be minimal.

Tuma, Margaret L.↗