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At least 505 records · Page 28

Development and Processing of Nickel Aluminide-Carbide Alloys

With the upper temperature limit of the Ni-based superalloys attained, a new class of materials is required. Intermetallics appear as likely candidates because of their attractive physical properties. With a relatively low density, high thermal conductivity, excellent oxidation resistance, high melting point, and simple crystal structure, nickel aluminide (NiAl) appears to be a potential candidate. However, NiAl is limited in structural applications due to its low room temperature fracture toughness and poor elevated temperature strength. One approach to improving these properties has been through the application of eutectic composites. Researchers have shown that containerless directional solidification of NiAl-based eutectic alloys can provide improvement in both the creep strength and fracture toughness. Although these systems have shown improvements in the mechanical properties, the presence of refractory metals increases the density significantly in some alloys. Lower density systems, such as the carbides, nitrides, and borides, may provide NiAl-based eutectic structure. With little or no information available on these systems, experimental investigation is required. The objective of this research was to locate and develop NiAl-carbide eutectic alloys. Exploratory arc-melts were performed in NiAl-refractory metal-C systems. Refractory metal systems investigated included Co, Cr, Fe, Hf, Mo, Nb, Ta, Ti, W, and Zr. Systems containing carbides with excellent stability (i.e.,HfC, NbC, TaC, TiC, and ZrC) produced large blocky cubic carbides in an NiAl matrix. The carbides appeared to have formed in the liquid state and were randomly distributed throughout the polycrystalline NiAl. The Co, Cr, Fe, Mo, and W systems contained NiAl dendrites with a two-phase interdendritic microconstituent present. Of these systems, the NiAl-Mo-C system had the most promising microstructure for in-situ composites. Three processing techniques were used to evaluate the NiAl-Mo-C system: arc-melting, slow cooling, and containerless directional solidification. Arc-melting provided a wide range of compositions in an economical and simple fashion. The slow cooled ingots provided larger ingots and slower cooling rates than arc-melting. Directional solidification was used to produce in-situ composites consisting of NiAl reinforced with molybdenum carbides.

Newport, Timothy Scott↗

Supersonic solutions of the solar-wind equations

We re-examine the inviscid solar-wind equations with heat conduction from below, and establish a fundamentally new approach for finding stellar solutions. Although the problem is fourth order, only two independent integration constants can be assigned, since two boundary conditions that are required to specify well-behaved supersonic solutions determine the values of the other two constants. The solar-wind-model of Noble and Scarf are essentially accurate for practical purposes, but in a fundamental sense they are not self-consistent. At the supersonic level, the ratio of thermal energy to gravitational potential, (kTr/GMm)(sub s), must lie in a narrow range, between 0.4375 and about 0.40, to permit well-behaved solutions for ionized hydrogen. For a supersonic solution this ratio uniquely determines the constants A and epsilon, which in turn govern not only the escape flux and the energy flux per particle but also T'(lambda approaches 0), the temperature gradient at infinity. It is very difficult to find solutions by trial and error, without employing T'(0) as a guide to the iteration of A and epsilon, because not only must (kTr/GMm)(sub s) be chosen within the acceptable range but then either A or epsilon must be guessed with phenomenal accuracy. Otherwise the numerical integration of temperature and expansion velocity do not yield acceptable values at infinity.

Chamberlain, Joseph W.↗

Technology and Advanced Development for a Non-Toxic Orbital Maneuvering System and Reaction Control System for Orbiter Upgrade

NASA intends to pursue technology applications to upgrade the Space Shuttle Orbiter OMS and RCS systems with non-toxic propellants. The primary objectives of an upgraded OMS/RCS are improved safety and reliability, reduced operations and maintenance costs while meeting basic OMS/RCS operational and performance requirements. The OMS/RCS has a high degree of direct interaction with the crew and requires subsystem and components that are compatible with integration into the orbiter vehicle with regard to external mold-line, power and thermal control The non-toxic propulsion technology is also applicable to future Human Exploration and Development of Space (HEDS) missions. The HEDS missions have similar requirements for attitude control and lander descent/ascent propulsion and which will emphasize the use of In-Situ Resource for propellants. When used as a regenerative coolant as in the Shuttle Orbiter OMS combustion chamber, non-toxic fuels such as ethanol are limited in their cooling capacity by the bulk temperature rise permitted to prevent film boiling or possible coking. Typical regeneratively cooled chambers are constructed from highly conductive copper, which maximizes heat transfer, or from low conductivity materials like stainless steel that can also exacerbate cooling problems. For an ethanol cooled application the heat transfer into the fluid must be controlled to reduce the fuel coolant bulk temperature rise. An approach to provide this control is the subject of this report. This report is being issued to document work done by Aerojet on NASA contract NAS 8-98042. Specifically, this project investigates of the use of ethanol, a designated non-toxic fuel, as a coolant for the Space Shuttle Orbital Maneuvering System Engine combustion chamber. The project also addresses a cost reducing fabrication technique for construction of such a combustion chamber. The study contained three major sub-tasks: an analytical investigation and trade study which included layout of a flight type chamber concept, the fabrication and evaluation of formed platelet liner panels and the preparation and testing of mechanical properties specimens representative of a novel hot gas wall concept.

Hayes, W. A.↗

Goodrich Electro-Optical Systems AMSD Progress Update and Test Plans

The goal of the Advanced Mirror System Demonstrator (AMSD) program is to develop and demonstrate technology for low mass primary mirror systems that can be produced at low cost and with short manufacturing times. In addition, specific performance objectives must be demonstrated at ambient and cryogenic temperatures. The Goodrich approach for AMSD is based on a thin facesheet supported through an array of figure-control actuators by a passive, stiff reaction structure. The facesheet is fused silica figured to the desired sphere by a novel process referred to as Stressed Mirror Polishing and light-weighted by water jet milling. The mirror facesheet and the reaction structure are CTE-matched For cryogenic operation. Progress update on the design, the fabrication and the test plans, both ambient and cryogenic, will be presented.

Garcia, Enrique↗

Some Recent Studies With the Solid-Ionomer Electrochemical Capacitor

Giner, Inc., has developed a high-energy-density, all-solid-ionomer electro-chemical capacitor, completely free of liquid electrolyte. The novel features of this device include: (1) a three-dimensional metal oxide-particulate-ionomer composite electrode structure and (2) a unitized repeating cell element. The composite electrode structures are bonded to opposite sides of a thin sheet of a solid proton-conducting ionomer membrane and form an integrally bonded membrane and electrode assembly (MEA). Individual MEAs can be stacked in series as bipolar elements to form a multiple cell device. The discharge characteristics and energy storage properties of these devices are described. Typical capacitance measured for a unit cell is 1 F/cm. Life testing of a multicell capacitor on an intermittent basis has shown that, over a 10,000-hour period, the capacitance and resistance of the cell has remained invariant. There has been no maintenance required on the device since it was fabricated. Other multicell units of shorter life duration have exhibited similar reliable performance characteristics. Recent work has focused on increasing the capacitance of the unitized structure and improving the low-temperature characteristics. The approaches and experimental results will be presented. Some possible advanced NASA applications for these unique all-solid-ionomer devices will be discussed.

Sarangapani, S.↗

A Comparison of Techniques for Scheduling Earth-Observing Satellites

Scheduling observations by coordinated fleets of Earth Observing Satellites (EOS) involves large search spaces, complex constraints and poorly understood bottlenecks, conditions where evolutionary and related algorithms are often effective. However, there are many such algorithms and the best one to use is not clear. Here we compare multiple variants of the genetic algorithm: stochastic hill climbing, simulated annealing, squeaky wheel optimization and iterated sampling on ten realistically-sized EOS scheduling problems. Schedules are represented by a permutation (non-temperal ordering) of the observation requests. A simple deterministic scheduler assigns times and resources to each observation request in the order indicated by the permutation, discarding those that violate the constraints created by previously scheduled observations. Simulated annealing performs best. Random mutation outperform a more 'intelligent' mutator. Furthermore, the best mutator, by a small margin, was a novel approach we call temperature dependent random sampling that makes large changes in the early stages of evolution and smaller changes towards the end of search.

Globus, Al↗

Improvements to the Synthesis of Polyimide Aerogels

Cross-linked polyimide aerogels are viable approach to higher temperature, flexible insulation for inflatable decelerators. Results indicate that the all-polyimide aerogels are as strong or stronger than polymer reinforced silica aerogels at the same density. Currently, examining use of carbon nanofiber and clay nanoparticles to improve performance. Flexible, polyimide aerogels have potential utility in other applications such as space suits, habitats, shelter applications, etc. where low dusting is desired

Meador, Mary Ann B.↗

NASA Tech Briefs, April 2012

Topics include: Computational Ghost Imaging for Remote Sensing; Digital Architecture for a Trace Gas Sensor Platform; Dispersed Fringe Sensing Analysis - DFSA; Indium Tin Oxide Resistor-Based Nitric Oxide Microsensors; Gas Composition Sensing Using Carbon Nanotube Arrays; Sensor for Boundary Shear Stress in Fluid Flow; Model-Based Method for Sensor Validation; Qualification of Engineering Camera for Long-Duration Deep Space Missions; Remotely Powered Reconfigurable Receiver for Extreme Environment Sensing Platforms; Bump Bonding Using Metal-Coated Carbon Nanotubes; In Situ Mosaic Brightness Correction; Simplex GPS and InSAR Inversion Software; Virtual Machine Language 2.1; Multi-Scale Three-Dimensional Variational Data Assimilation System for Coastal Ocean Prediction; Pandora Operation and Analysis Software; Fabrication of a Cryogenic Bias Filter for Ultrasensitive Focal Plane; Processing of Nanosensors Using a Sacrificial Template Approach; High-Temperature Shape Memory Polymers; Modular Flooring System; Non-Toxic, Low-Freezing, Drop-In Replacement Heat Transfer Fluids; Materials That Enhance Efficiency and Radiation Resistance of Solar Cells; Low-Cost, Rugged High-Vacuum System; Static Gas-Charging Plug; Floating Oil-Spill Containment Device; Stemless Ball Valve; Improving Balance Function Using Low Levels of Electrical Stimulation of the Balance Organs; Oxygen-Methane Thruster; Lunar Navigation Determination System - LaNDS; Launch Method for Kites in Low-Wind or No-Wind Conditions; Supercritical CO2 Cleaning System for Planetary Protection and Contamination Control Applications; Design and Performance of a Wideband Radio Telescope; Finite Element Models for Electron Beam Freeform Fabrication Process Autonomous Information Unit for Fine-Grain Data Access Control and Information Protection in a Net-Centric System; Vehicle Detection for RCTA/ANS (Autonomous Navigation System); Image Mapping and Visual Attention on the Sensory Ego-Sphere; HyDE Framework for Stochastic and Hybrid Model-Based Diagnosis; and IMAGESEER - IMAGEs for Education and Research.

Source record↗

Ex-situ Heat Treatment of TEM Foils in a Custom Titanium Fixture: A Case Study on Ni-based Superalloy

The advancement of microstructural characterization at the nanoscale is critical to understanding the microstructural evolution and performance of engineering materials. Transmission electron microscopy (TEM) plays a vital role in such investigations, particularly when coupled with controlled ex- and in-situ experiments. In this study, we introduce a novel method for ex-situ heat treatment (HT) of TEM foils using a custom-designed fixture, made from pure titanium, and vacuum furnace to inhibit oxidation. This approach ensures precise temperature control and minimal sample contamination during HT, critical for substructural characterization and analysis of metallic materials. The fixture consists of a titanium base with three slits, for three sample foils, and a titanium cap for closure. The entire assembly is placed in a vacuum heat treatment furnace with high vacuum capability to prevent oxidation. To validate the effectiveness of the setup, precipitation behavior and microstructural changes were studied in an IN725 variant heat-treated at 500°C for 1 hour and 282 variant heat-treated at 700°C for 1 hour, as case studies.

electron microscopy↗

Modeling Contact Angle vs. Temperature for the Quartz-Water-Decane System

Innovative approaches are needed to improve the efficiency of oil recovery technologies to meet the growing demands of fossil-fuel based energy consumption. Enhanced oil recovery (EOR) methods such as low-salinity waterflooding and chemically tuned waterflooding aim to optimize the reservoir’s wetting properties, detaching oil globules from rock surfaces and allowing easier oil flow through pore throats. This wetting behavior is commonly quantified by contact angle measurements of the rock-oil-brine interface, which have been thoroughly investigated and theorized for many systems at ambient temperatures and pressures. However, few studies exist for extending contact angle theories away from ambient conditions. In this paper, we model the contact angles of a quartz-water-decane system at elevated temperatures using the surface tension component (STC) approach. Temperature-dependent van der Waals [Lifshitz-van der Waals (LW)] interactions and hydrogen-bonding (acid-base) interactions were calculated and are incorporated into the model for the quartz-water-decane interface. Additionally, the Hough and White procedure was used to create temperature-dependent dielectric functions of quartz, water, and normal decane for calculations of Hamaker coefficients. Hamaker coefficients calculated this way are highly linear with temperature and agree well with Israelachvili’s approximation. The acid-base interactions likely contribute the most to system wettability changes. Resulting contact angles of the quartz-water-decane system shift from water-wet (16°) to slightly water-wet (57.4°) as temperature increases. The model was also successfully verified for the quartz-air-water system. Our results can be used in future studies to determine optimal injected water compositions for specific rock-oil-brine and other systems with consideration of reservoir temperature.

02 PETROLEUM↗

Forecasting Commercial Building Electricity Consumption, Zone Airflow and Zone Temperature: Update - Development of a Generalized Machine Learning Approach

The U.S. power grid is being transformed to make it smarter, more efficient, and cleaner. This transformation is leading to the addition of a significant of energy generated by distributed, variable, and renewable resources. Because of the variable nature of renewable generation, the short- and long-term supply and demand imbalances are less predictable, and conventional approaches to mitigating the imbalances will be less efficient or cost effective. To address this challenge and to support the mission and the vision of the U.S. Department of Energy’s (DOE’s) Office of Energy Efficiency and Renewable Energy (EERE) Building Technologies Office has developed a Grid-Interactive Efficient Building Strategy. The strategy focuses on simultaneously improving building energy efficiency and supporting reliability and resilience of the electric grid more efficiently and at a lower cost. In addition, EERE and DOE’s Office of Electricity created an initiative led by DOE and supported by the national laboratories under the Grid Modernization Lab Consortium structure to enhance grid modernization. The work reported in this document is part of the first set of projects funded under the initiative to design, develop, and validate scalable transactive control technologies for the commercial buildings sector. Transactive controls requires the ability of individual end-use loads to express flexibility as a function of a transactive signal (e.g., price). Empirical grey- and black-box models have been widely used to express flexibility. Although this approach is generally easy to construct and simple to use, it does not capture non-linear behavior that some end-use loads represent. Therefore, Pacific Northwest National Laboratory (PNNL) with support from Western Washington University conducted this research to explore the use of deep machine learning (ML) techniques. The work reported in this document is limited to forecasting whole building electricity consumption, the zone airflow and the zone temperature predictions.

24 POWER TRANSMISSION AND DISTRIBUTION↗

TX Cancri - Which component is hotter

The question is considered of whether the W-type light curves of TX Cnc result from a slightly higher temperature for the low-mass component or from a relatively strong classical gravity-darkening law. Photometric parameters for this W UMa binary area derived using light curves from four epochs exhibiting dissimilar behavior. The analysis is performed for up to five colors, and solutions are obtained by two different approaches in which the temperature difference between the components is treated as a free parameter or is determined by the surface gravitational field. The results of the second approach show that the polar effective temperature of the low-mass star is about 30 K cooler than that of the high-mass star, while the results of the first approach show the low-mass star to be 125 to 175 K hotter. Preference is given to the second approach because gravity darkening provides a simple and adequate explanation of the light curves. Epoch-to-epoch changes in the gravity-darkening and albedo parameters are taken as suggesting differences in the degree of thermal contact over a time scale of a few years.

Wilson, R. E.↗

A new hue capturing technique for the quantitative interpretation of liquid crystal images used in convective heat transfer studies

A new image processing based color capturing technique for the quantitative interpretation of liquid crystal images used in convective heat transfer studies is presented. This method is highly applicable to the surfaces exposed to convective heating in gas turbine engines. It is shown that, in the single-crystal mode, many of the colors appearing on the heat transfer surface correlate strongly with the local temperature. A very accurate quantitative approach using an experimentally determined linear hue vs temperature relation is found to be possible. The new hue-capturing process is discussed in terms of the strength of the light source illuminating the heat transfer surface, the effect of the orientation of the illuminating source with respect to the surface, crystal layer uniformity, and the repeatability of the process. The present method is more advantageous than the multiple filter method because of its ability to generate many isotherms simultaneously from a single-crystal image at a high resolution in a very time-efficient manner.

Camci, C.↗

Rotating Intershaft Brush Seal Project

The pursuit of high Mach number flight presents several challenges to the airframe and engine design engineers. Most obvious is the resulting high temperatures encountered as the aircraft approaches Mach 3 and above. The encountered high temperatures and shaft speeds of engines require rethinking in the areas of material selections, component design and component operating life. In the area of sump compartment sealing, one of the most difficult sealing applications is the sealing of an engine s rear sump. Normally this sump will need some method of sealing between two rotating shafts. This sealing operation is done with an intershaft seal. The aft sump region also presents an additional design requirement for the intershaft seal. This region has to absorb the engine s thermal growth, which means that in the seal area, axial movement, on the order of 0.30 in., between the rotating shafts must be tolerated. A new concept or new technology of sealing an intershaft sump configuration is being developed. This concept, called a rotating intershaft brush seal has key attributes that will allow this seal to perform better, in the demanding environment of sealing an aft sump with two rotating shafts, when compared to today s sealing technology of labyrinth and carbon sea

Krawiecki, Stephen↗

Multi-scale fission product release model with comparison to AGR data

TRistructural ISOtropic (TRISO) particle fuel is central to several advanced, high-temperature reactor designs. Each particle consists of a fuel kernel encapsulated by three layers of carbon and ceramics that prevent the release of fission products and ensure physical integrity. Despite outstanding retention properties, fission product release has been observed from intact particles. To better understand and quantify fission product release from TRISO particles, a multiscale, mechanistic model of fission product transport is being developed by the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program. Previous work focused on silver (Ag) transport and improved Ag release predictions. The work described in this report builds on this experience to better understand cesium (Cs) transport in silicon carbide (SiC), the main barrier to the release of fission products. Atomistic simulations provide bulk and grain boundary (GB) Cs diffusivities in SiC, which are used by phase field simulations in the mesoscale code Marmot to determine the temperature, microstructure, and irradiation-dependent Cs diffusivity at the mesoscale in SiC. This approach attributes the different temperature regimes experimentally observed for Cs diffusivities in SiC to a transition from bulk-dominated diffusivity at high temperatures to a GB-dominated regime at low temperatures, providing new insight. The multiscale, mechanistic effective diffusivity is then implemented in the fuel performance code BISON and further validated by comparing Cs release predictions from Advanced Gas Reactor (AGR)-1 and AGR-2 post-irradiation measurements. The new model improves BISON’s predictability. This document also reports improvements made on Ag transport modeling by accounting for different GB types having different diffusivities. Moreover, this report details preliminary efforts to model palladium (Pd) attack of the SiC at the mesoscale using a phase field approach. Pd attack and its impact on accelerated Ag transport remains a misunderstood phenomenon, and we use the model to demonstrate that the formation of lamellae that has been observed in experiments can be explained by the reaction of Pd with SiC to form alternating layers of graphite and Pd 2 Si. This effort aims to improve our understanding of the reaction and eventually provide a model for BISON to account for Pd penetration and its effects on fission product release.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Comparative analysis of thermal management systems in electric vehicles at extreme weather conditions: Case study on Nissan Leaf 2019 Plus, Chevrolet Bolt 2020 and Tesla Model 3 2020

With the surge in electric vehicle (EV) adoption and the need for extended driving ranges, optimizing energy efficiency, particularly through thermal management, is critical, especially in extreme weather. Managing the substantial energy needed for cabin climate control and battery temperature regulation can increase energy demands by over 50 %, severely limiting range. This study conducts a comparative analysis of thermal management systems (TMS) in three popular EV vehicles, 2020 Chevrolet Bolt, 2019 Nissan Leaf Plus, and 2020 Tesla Model 3, evaluating their distinct TMS configurations and performance under varied weather conditions. Using both numerical simulations and experimental data collected on a controlled test bench at Argonne National Laboratory, we assess how TMS architecture and operational modes influence energy consumption and range. A comprehensive TMS model was developed, integrating cabin and battery thermal sub-models in the Autonomie software platform, to simulate temperature fluctuations and range impacts. Cabin climate was modeled using a mono-zonal approach, while battery cell temperature distribution was estimated through a 2D nodal structure. Each vehicle's distinct TMS setup was evaluated: the Chevrolet Bolt and Tesla Model 3 use a dual evaporator vapor compression cycle with a PTC heater for the cabin and a coolant loop for battery thermal management; the Nissan Leaf Plus employs a heat pump with a PTC heater for the cabin and air-cooling for the battery. Tests conducted at ambient temperatures of 35°C, 22°C, -7°C, and -18°C reveal significant differences in energy use and range reduction across both configurations and conditions. At 35°C, the Tesla Model 3, Chevrolet Bolt, and Nissan Leaf Plus have a range reduction of 8%, 9%, and 13%, respectively, due to air conditioning. In winter, heating technology is paramount; at -7°C, the Nissan Leaf's heat pump configuration achieves a lower range reduction (19.3%) compared to the Tesla and Chevrolet Bolt PTC heaters, which reduce range by 28.3% and 31%, respectively. Further, this study provides valuable insights for automotive engineers, EV technology researchers, and thermal management system designers aiming to enhance electric vehicle performance by understanding how different weather conditions and TMS architectures impact energy consumption and driving range.

33 ADVANCED PROPULSION SYSTEMS↗

Finite element analyses of plane thermal entry-length flows

It is pointed out that the design of actively cooled engine and airframe structures for hypersonic flight requires strong interaction between fluid, thermal, and structural analyses. Research programs are being conducted to develop an integrated thermal-structural analysis capability based upon the finite element method. In connection with these programs, a finite element engineering approach has been developed based upon a number of assumptions customarily used in practical heat transfer analysis. An evaluation is conducted of the finite element engineering approach for entry-length flows. The evaluation makes use of an analysis of plane thermal entry-length flows by a finite element approach utilizing mean fluid temperatures with a convection coefficient. Another analysis is based on a finite element continuum approach, taking into account the rigorous momentum, mass, and energy equations of viscous, incompressible flow. The engineering approach was found to give excellent agreement with the rigorous continuum approach for Peclet number values not less than 100.

Thornton, E. A.↗

Probabilistic structural analysis of space propulsion system LOX post

The probabilistic structural analysis program NESSUS (Numerical Evaluation of Stochastic Structures Under Stress; Cruse et al., 1988) is applied to characterize the dynamic loading and response of the Space Shuttle main engine (SSME) LOX post. The design and operation of the SSME are reviewed; the LOX post structure is described; and particular attention is given to the generation of composite load spectra, the finite-element model of the LOX post, and the steps in the NESSUS structural analysis. The results are presented in extensive tables and graphs, and it is shown that NESSUS correctly predicts the structural effects of changes in the temperature loading. The probabilistic approach also facilitates (1) damage assessments for a given failure model (based on gas temperature, heat-shield gap, and material properties) and (2) correlation of the gas temperature with operational parameters such as engine thrust.

Newell, J. F.↗