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Building Effective Collaborations to Bring Innovation into Waste Management and Decommissioning - 16477

A strong record of research collaboration has been developing between the UK nuclear industry and key universities with nuclear specialism over the past 15 years or so. The DISTINCTIVE program, focusing on decommissioning, immobilization and storage solutions for nuclear waste inventories is an example. It is a consortium of eleven universities funded by the Engineering and Physical Sciences Research Council, National Nuclear Laboratory, Nuclear Decommissioning Authority and Sellafield Limited. The motivation for industry collaboration with universities is explained and the current progress of DISTINCTIVE in the context of these motivations is assessed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Radioactive waste management approaches for developed countries

Nuclear power has demonstrated over the last 30 years its capacity to produce base-load electricity at a low, predictable and stable cost due to the very low economic dependence on the price of uranium. However the management of used nuclear fuel remains the “Achilles’ Heel” of this energy source since the storage of used nuclear fuel is increasing as evidenced by the following number with 2,000 tons of UNF produced each year by the 104 US nuclear reactor units which equates to a total of 62,000 spent fuel assemblies stored in dry cask and 88,000 stored in pools. Two options adopted by several countries will be presented. The first one adopted by Europe, Japan and Russia consists of recycling the used nuclear fuel after irradiation in a nuclear reactor. Ninety six percent of uranium and plutonium contained in the spent fuel could be reused to produce electricity and are worth recycling. The separation of uranium and plutonium from the wastes is realized through the industrial PUREX process so that they can be recycled for re-use in a nuclear reactor as a mixed oxide (MOX) fuel. The second option undertaken by Finland, Sweden and the United States implies the direct disposal of used nuclear fuel into a geologic formation. One has to remind that only 30% of the worldwide used nuclear fuel are currently recycled, the larger part being stored (70% in pool) waiting for scientific or political decisions. A third option is emerging with a closed fuel cycle which will improve the global sustainability of nuclear energy. This option will not only decrease the volume amount of nuclear waste but also the long-term radiotoxicity of the final waste, as well as improving the long-term safety and the heat-loading of the final repository. At the present time, numerous countries are focusing on the R&D recycling activities of the ultimate waste composed of fission products and minor actinides (americium and curium). Several new chemical extraction processes, such as TRUSPEAK, ALSEP, EXAM, or LUCA are pursued worldwide and their approaches will be highlighted.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Default Radioactive and Hazardous Waste Management (RHWM) Dose Conversion Factors (DCFs) and Weighting Factors and plutonium-239 equivalent Curie (PE-Ci) methodology for acceptance into the Waste Storage Facilities

DOE-STD-5506-2007 (Ref. 1) is the standard that provides the methodology for preparing hazard analysis and accident analysis for transuranic (TRU) waste facilities. The Waste Storage Facilities hazard and accident analysis for the DSA is developed in accordance with DOE-STD- 5506-2007. Two related issues need to be addressed when implementing DOE-STD-5506-2007 regarding the calculation of consequences from TRU waste releases in accident analysis: Consequences determined in accident analysis must be modeled using inhalation Dose Conversion Factors (DCFs) that are consistent with those from the International Commission on Radiological Protection Publication 72 (ICRP-72, Ref. 2).; The use of a statistical Material at Risk (MAR) representing the distribution of radiological loading of TRU waste containers based on the use of a plutonium-239 equivalent Curie (PE-Ci) methodology. The PE-Ci methodology simplifies accident analysis by allowing one to model releases based on the Curie value of one standard nuclide (e.g., Pu-239) instead of needing to model releases for every potential nuclide of interest. This is accomplished by normalizing the Curie value of all nuclides to a single Curie value of a standard nuclide by using a Weighting Factor that is a ratio of the DCFs associated with the nuclides and that of the standard nuclide. By using the ICRP-72 DCFs to calculate PE-Ci values used in the statistical MAR, the accident analysis that uses that statistical MAR will be consistent with the consequence methodology identified in DOE-STD- 5506-2007.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Radioactive Waste Management in HANARO (High Flux Advanced Neutron Application Reactor) - 16076

HANARO (High Flux Advanced Neutron Application Reactor) is a research reactor at the Korea Atomic Energy Research Institute (KAERI). Currently, it is the only research reactor generating a high neutron flux for neutron science and technology and the production of radioisotopes in Korea. Various kinds of radioactive wastes such as wastewater, spent ion exchange resins, solid waste and gaseous waste are generated from HANARO, as in other nuclear reactors. The most important feature of the radioactive waste in HANARO is that some radioactive waste is contaminated with tritium because HANARO uses heavy water as a reflector. At present, the waste generated from HANARO is transferred to and treated or stored at the Radioactive Waste Treatment Facility (RWTF) of KAERI. However, the RWTF does not have proper technology to treat radioactive waste contaminated with tritium from HANARO. Therefore, it is imperative to have a proper means to reduce the amount of radioactive waste and handle it more safely. (authors)

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The root causes of siting failures in nuclear waste management - 15652

For many decades, the global nuclear industry and associated governments have attempted to establish new facilities for the storage and disposal of nuclear wastes. Success has been rare (France, Sweden and Finland being the examples) and remains elusive for many programs despite attempts to change the selection process in some cases. Success has been aided by local and national consent in the few cases that are proceeding. A small study of several countries lack of success is examined to determine the dominant reasons for such failures. The goal of the study is to inform the planning process for efforts to site new facilities by feeding back some lessons learned from past failed efforts. This limited review of international experience indicates that there is no simple approach available for siting deep geologic disposal or even centralized storage facilities. A number of countries have tried multiple times to find an acceptable site. Two studies [1, 2] clearly indicate that there must be adequate assurance of social as well as technical acceptability for successfully siting such facilities. It is evident that even though the technology and science may be proven, it is the politics and public engagement in siting processes that dominate the failures. However, the detailed reasons within each effort present a richer set of lessons. This paper will summarize the findings and present them such that they can be used to inform future siting efforts by a nation. (authors)

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Request for Funding for the 2016 Air & Waste Management Association Visibility Conference on Atmospheric Optics:Aerosols, Visibility, and the Radiative Balance

This international conference will provide a technical forum on advances in the scientific understanding of the effects of aerosols on urban, regional, continental, and global-scale haze and the radiative balance. The conference will take a multipronged approach and address scientific topics (e.g., related to measurements, modeling, etc.) as well as regulatory and policy issues. There will be sessions on black and brown carbon, as recent research has shown the importance of these particles for radiative forcing. In addition, there will be sessions related to the synergistic and increasing concerns of the effects of atmospheric nitrogen and carbonaceous material on haze, climate change, and nitrogen deposition on ecosystems. Conference learning will be enhanced with a half day excursion and hikes in Grand Teton National Park and a Night Sky Program.

54 ENVIRONMENTAL SCIENCES↗

AI-powered municipal solid waste management: a comprehensive review from generation to utilization

The accumulation of municipal solid waste (MSW) continues to rise due to burgeoning population, rapid global urbanization and economic growth, intensifying ecological concerns associated with landfills and greenhouse gas (GHG) emissions. Over the past 2 decades, global waste generation has surged by 50%, with one-third remaining uncollected and about 70% sent to landfills. This review examines the critical role of integrating emerging technologies, such as advanced sensors and artificial intelligence (AI), into end-to-end MSW management to alleviate landfill burdens. The suitability of various AI tools for different stages of MSW management is assessed, alongside the deployment of advanced sensors including hyperspectral cameras, computer vision systems, and internet of things (IoT) devices for material identification. Applications of genetic algorithms and reinforcement learning for optimizing collection routes, reducing costs, and lowering emissions are highlighted. Life cycle assessment (LCA) across all stages of MSW management is also reviewed, along with future trends in leveraging generative AI, natural language processing (NLP), and agent-based AI systems to analyze waste generation patterns and public sentiment. Efficient collection and handling can be enhanced through route optimization with geographic information systems and real-time bin-level monitoring. Furthermore, sensor-embedded, real-time object detection systems paired with robotics enable material characterization and automated sorting, thereby lowering costs and diverting waste from landfills into value-added products for diverse industrial sectors including packaging, chemicals, textiles, metals and glass, transportation, and electronics industries. Without intervention, global waste is projected to reach 4.54 billion tons by 2050, contributing direct economic costs of $\$$400 billion and roughly 2.38 billion tons of CO 2 -equivalent emissions annually. This review demonstrates how AI-driven, end-to-end solutions for MSW management can mitigate economic and environmental challenges, while directly supporting the United Nations Sustainable Development (UNDP) goals related to innovation and infrastructure (SDG 9), sustainable cities (SDG 11), responsible consumption and production (SDG 12), and climate action (SDG 13).

09 BIOMASS FUELS↗

Co-treating flue gas desulfurized effluent and produced water enables novel waste management and recovery of critical minerals

Herein this study reports a novel approach of resource recovery from co-managing two geographically co-located and chemically complementary wastewaters using a pilot-scale treatment process. Designed to treat flue gas desulfurized (FGD) effluent from combustion powerplants and produced water (PW) from energy industries, the process consists of soda-ash softening, nanofiltration (NF), and reverse osmosis (RO). Recovered products are barite, calcite, and low-salinity water. Using field-collected waters, the results show that softening at pH 8.5 produces calcite (yield: 30 kg/m 3 treated water), a chemical used as SO ₂(g) scrubbers. NF treatment under an applied pressure of 3.5 MPa yields a permeate stream laden with monovalent ions (water recovery 60%) and a concentrate stream with a sulfate concentration 1.8 times of the feedwater concentration. Mixing the NF concentrate and PW at a volumetric ratio of 1.0 precipitates a high-density barite material (4.1 g/cm 3 , yield: ~7.5 kg/m 3 mixture) – a critical mineral commonly used as a weighting agent in drilling. The RO treatment recovers >64% water as the permeate, which can be readily used as cooling make-up water at the powerplants. The RO concentrate stream can be further processed in a thermal evaporative system for additional water recovery and brine production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Environmental control and waste management system design concept

Passive device contains both solid and liquid animal waste matter for extended period without being cleaned and without contaminating animal. Constant airflow dries solid waste and evaporates liquid matter. Technique will maintain controlled atmospheric conditions and cage cleanliness during periods of 6 months to 1 year.

Gandy, A. R.↗

Economic and environmental review of Waste-to-Energy systems for municipal solid waste management in medium and small municipalities

Highlights: • Proposed methodology selects the optimal solution for energy valorisation of MSW. • Economic, environmental and territorial factors for WtE have been analysed. • Energy valorization is economically viable in medium-low production areas. • WtE generate territorial and environmental benefits in MSW management. - Abstract: The application of Directive 2008/98/CE on Municipal Solid Waste (MSW) implies the need to introduce technologies to generate energy from waste. Incineration, the most widely used method, is difficult to implement in low populated areas because it requires a large amount of waste to be viable (100,000 tons per year). This paper analyses the economic and environmental costs of different MSW-to-Energy technologies (WtE) in an area comprising of 13 municipalities in southern Spain. We analyse anaerobic digestion (Biomethanization), the production of solid recovered fuel (SRF) and gasification, and compare these approaches to the present Biological Mechanical Treatment (BMT) with elimination of the reject in landfill, and incineration with energy recovery. From an economic standpoint the implementation of WtE systems reduces the cost of running present BMT systems and incineration; gasification presents the lowest value. From the environmental standpoint, Life Cycle Assessment shows that any WtE alternatives, including incineration, present important advantages for the environment when compared to BMT. Finally, in order to select the best alternative, a multi-criteria method is applied, showing that anaerobic digestion is the optimal solution for the area studied.

09 BIOMASS FUELS↗

Panel Session 116: Waste Management from Remediation of Legacy Sites or Unplanned Releases

Past experiences have shown that there is often a disconnect between Indigenous societies and Western society. This disconnect can be attributed to different value systems between these two group and is not limited to the USA and Canada but also extends into Australia, New Zealand, and the Central Asia Republics (the 'five Stans'). The intent of this Panel Session to give voice to representatives from Indigenous communities, the challenges presented in remediation processes, and potential solutions. Standard risk assessment assumptions developed for Western societies often do not adequately address the cultural and spiritual values that may be unique to indigenous societies. This panel focused on the perspectives of Indigenous societies (e.g., Indian Tribes (US), First Nations (Canada)) related to risk assessment of environmental remediation challenges, including deep geological disposal of HLW and ILW, near-surface disposal of LLW and in-situ entombment of nuclear reactor components, and environmental remediation of abandoned uranium mines and historic wastes. Standard risk assessment assumptions often do not adequately address the cultural and spiritual values that may be unique to indigenous societies. Factoring those into a risk assessment that still meets regulatory requirements and policies such as reasonably anticipated land use at US EPA CERCLA sites can be challenging but has the potential to lead to a site or facility approach that is more accepted. Panelists with presentations: The U.S. Nuclear Regulatory Commission Regulatory Process - A Path for Indigenous Knowledge? (Francis Cameron); Local Community Perceptions and Remediation Projects (Michelle Roberts); Indigenous Perspectives on Risk Assessment (Bob Watts); Navajo Superfund Program: Fundamental Law and Traditional Ecological Knowledge (Dariel Yazzie); Risk Assessment: Two Indigenous Approaches (Whitney Fraser)

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The Belgian program for low and intermediate short lived waste management: from 1985 to license application

On 31 January 2013, ONDRAF/NIRAS, the Belgian Agency for Radioactive Waste and Enriched Fissile Materials, has introduced the construction and operation license application for the surface disposal facility for category A waste at Dessel. The objective of this paper is to present the development of this national programme. First the key milestones and their impact on the development of the project will be highlighted. This includes in particular: 1) the turning point in 1994, when ONDRAF/NIRAS converts its purely technic-scientific work method into an approach of participation that allows for societal aspects to be taken into account and 2) the decision of the government in 2006 in favour of the surface disposal of category A waste in Dessel. Then the paper presents the pillars of the long-term safety of a surface disposal and the principles for site selection and how they were applied to the surface disposal facility for category A waste at Dessel. The pillars of the long-term safety of a surface disposal are: (1) the passive confinement and isolation provided by the Engineering Barrier System (2) the contribution to this passive isolation and confinement by the site (3) the limitation of the radioactive source term, and (4) the control and monitoring measures. (authors)

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Decommissioning of the TRIGA mark II and III and radioactive waste management

KAERI has carried out decommissioning projects for two research reactors (KRR-1 and 2). The decommissioning project of KRR-1 (TRIGA Mark II) and 2 (TRIGA Mark III) was launched in 1997 with a total budget of 23.25 million US dollars. KRR-2 and all auxiliary facilities were already decommissioned, and KRR-1 is being decommissioned now. Much more dismantled waste is generated than in any other operations of nuclear facilities. Thus, the waste needs to be reduced and stabilized through decontamination or treatment before disposal. This paper introduces the current status of the decommissioning projects and describes the volume reduction and conditioning of decommissioning waste for final disposal. (authors)

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Solid waste management of temple floral offerings by vermicomposting using Eisenia fetida

Highlights: ► Effective management of temple floral offerings using E. fetida. ► Physico-chemical properties in TW VC were better especially EC, C/N, C/P and TK. ► TW VC as plant growth promoter at much lower application rates than KW and FYW VC. - Abstract: Recycling of temple waste (TW) mainly comprising of floral offerings was done through vermitechnology using Eisenia fetida and its impact on seed germination and plant growth parameters was studied by comparing with kitchen waste (KW) and farmyard waste (FYW) vermicompost (VC). The worm biomass was found to be maximum in TW VC compared to KW and FYW VCs at both 40 and 120 days old VCs. Physico-chemical analysis of worm-worked substrates showed better results in TW VC especially in terms of electrical conductivity, C/N, C/P and TK. 10% TW VC–water extract (VCE) showed stimulatory effect on germination percentage of chickpea seeds while KW and FYW VCE proved effective at higher concentration. Variation in growth parameters was also observed with change in the VC–soil ratio and TW VC showed enhanced shoot length, root length, number of secondary roots and total biomass at 12.5% VC compared to KW and FYW VC.

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Design for waste-management system

Study was made and system defined for water-recovery and solid-waste processing for low-rise apartment complexes. System can be modified to conform with unique requirements of community, including hydrology, geology, and climate. Reclamation is accomplished by treatment process that features reverse-osmosis membranes.

Guarneri, C. A.↗