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At least 505 records · Page 28

Applications of Silicon Carbide for High Temperature Electronics and Sensors

Silicon carbide (SiC) is a wide bandgap material that shows great promise in high-power and high temperature electronics applications because of its high thermal conductivity and high breakdown electrical field. The excellent physical and electronic properties of SiC allows the fabrication of devices that can operate at higher temperatures and power levels than devices produced from either silicon or GaAs. Although modern electronics depends primarily upon silicon based devices, this material is not capable of handling may special requirements. Devices which operate at high speeds, at high power levels and are to be used in extreme environments at high temperatures and high radiation levels need other materials with wider bandgaps than that of silicon. Many space and terrestrial applications also have a requirement for wide bandgap materials. SiC also has great potential for high power and frequency operation due to a high saturated drift velocity. The wide bandgap allows for unique optoelectronic applications, that include blue light emitting diodes and ultraviolet photodetectors. New areas involving gas sensing and telecommunications offer significant promise. Overall, the properties of SiC make it one of the best prospects for extending the capabilities and operational regimes of the current semiconductor device technology.

Silicon Carbide↗

Nanotip Carpets as Antireflection Surfaces

Carpet-like random arrays of metal-coated silicon nanotips have been shown to be effective as antireflection surfaces. Now undergoing development for incorporation into Sun sensors that would provide guidance for robotic exploratory vehicles on Mars, nanotip carpets of this type could also have many uses on Earth as antireflection surfaces in instruments that handle or detect ultraviolet, visible, or infrared light. In the original Sun-sensor application, what is required is an array of 50-micron-diameter apertures on what is otherwise an opaque, minimally reflective surface, as needed to implement a miniature multiple-pinhole camera. The process for fabrication of an antireflection nanotip carpet for this application (see Figure 1) includes, and goes somewhat beyond, the process described in A New Process for Fabricating Random Silicon Nanotips (NPO-40123), NASA Tech Briefs, Vol. 28, No. 1 (November 2004), page 62. In the first step, which is not part of the previously reported process, photolithography is performed to deposit etch masks to define the 50-micron apertures on a silicon substrate. In the second step, which is part of the previously reported process, the non-masked silicon area between the apertures is subjected to reactive ion etching (RIE) under a special combination of conditions that results in the growth of fluorine-based compounds in randomly distributed formations, known in the art as "polymer RIE grass," that have dimensions of the order of microns. The polymer RIE grass formations serve as microscopic etch masks during the next step, in which deep reactive ion etching (DRIE) is performed. What remains after DRIE is the carpet of nano - tips, which are high-aspect-ratio peaks, the tips of which have radii of the order of nanometers. Next, the nanotip array is evaporatively coated with Cr/Au to enhance the absorption of light (more specifically, infrared light in the Sun-sensor application). The photoresist etch masks protecting the apertures are then removed by dipping the substrate into acetone. Finally, for the Sun-sensor application, the back surface of the substrate is coated with a 57-nm-thick layer of Cr for attenuation of sunlight.

Bae, Youngsam↗

Ion-Exclusion Chromatography for Analyzing Organics in Water

A liquid-chromatography technique has been developed for use in the quantitative analysis of urea (and of other nonvolatile organic compounds typically found with urea) dissolved in water. The technique involves the use of a column that contains an ion-exclusion resin; heretofore, this column has been sold for use in analyzing monosaccharides and food softeners, but not for analyzing water supplies. The prior technique commonly used to analyze water for urea content has been one of high-performance liquid chromatography (HPLC), with reliance on hydrophobic interactions between analytes in a water sample and long-chain alkyl groups bonded to an HPLC column. The prior technique has proven inadequate because of a strong tendency toward co-elution of urea with other compounds. Co-elution often causes the urea and other compounds to be crowded into a narrow region of the chromatogram (see left part of figure), thereby giving rise to low chromatographic resolution and misidentification of compounds. It is possible to quantitate urea or another analyte via ultraviolet- and visible-light absorbance measurements, but in order to perform such measurements, it is necessary to dilute the sample, causing a significant loss of sensitivity. The ion-exclusion resin used in the improved technique is sulfonated polystyrene in the calcium form. Whereas the alkyl-chain column used in the prior technique separates compounds on the basis of polarity only, the ion-exclusion-resin column used in the improved technique separates compounds on the basis of both molecular size and electric charge. As a result, the degree of separation is increased: instead of being crowded together into a single chromatographic peak only about 1 to 2 minutes wide as in the prior technique, the chromatographic peaks of different compounds are now separated from each other and spread out over a range about 33 minutes wide (see right part of figure), and the urea peak can readily be distinguished from the other peaks. Although the analysis takes more time in the improved technique, this disadvantage is offset by two important advantages: Sensitivity is increased. The minimum concentration of urea that can be measured is reduced (to between 1/5 and 1/3 of that of the prior technique) because it is not necessary to dilute the sample. The separation of peaks facilitates the identification and quantitation of the various compounds. The resolution of the compounds other than urea makes it possible to identify those compounds by use of mass spectrometry.

Sauer, Richard↗

Quantitative Examination of a Large Sample of Supra-Arcade Downflows in Eruptive Solar Flares

Sunward-flowing voids above post-coronal mass ejection flare arcades were first discovered using the soft X-ray telescope aboard Yohkoh and have since been observed with TRACE (extreme ultraviolet (EUV)), SOHO/LASCO (white light), SOHO/SUMER (EUV spectra), and Hinode/XRT (soft X-rays). Supra-arcade downflow (SAD) observations suggest that they are the cross-sections of thin flux tubes retracting from a reconnection site high in the corona. Supra-arcade downflowing loops (SADLs) have also been observed under similar circumstances and are theorized to be SADs viewed from a perpendicular angle. Although previous studies have focused on dark flows because they are easier to detect and complementary spectral data analysis reveals their magnetic nature, the signal intensity of the flows actually ranges from dark to bright. This implies that newly reconnected coronal loops can contain a range of hot plasma density. Previous studies have presented detailed SAD observations for a small number of flares. In this paper, we present a substantial SADs and SADLs flare catalog. We have applied semiautomatic detection software to several of these events to detect and track individual downflows thereby providing statistically significant samples of parameters such as velocity, acceleration, area, magnetic flux, shrinkage energy, and reconnection rate. We discuss these measurements (particularly the unexpected result of the speeds being an order of magnitude slower than the assumed Alfven speed), how they were obtained, and potential impact on reconnection models.

Savage, Sabrina L.↗

Use of VUV Radiation to Control Elastomer Seal Adhesion

Due to their wide operating temperatures and low leakage rates, silicone elastomers are the only class of flight qualified elastomer materials that currently meet NASA's needs for various seal applications, which include docking and hatch seals for future space exploration vehicles. However, silicone elastomers are naturally sticky and exhibit sizeable adhesion when mated against metals and other silicone surfaces. This undesirable adhesion can make undocking spacecraft or opening a hatch problematic. Two approaches that can be used to reduce seal adhesion include use of grease or, application of low doses of atomic oxygen (AO). This paper investigates a third approach: the application of light doses of vacuum ultraviolet (VUV) radiation. Presented are the adhesion and leakage characteristics of S0383-70 silicone elastomer exposed to various VUV doses in the 115 to 200 nm wavelength range. The data indicate that adhesion is expected to be less than the target threshold maximum of 2 lb/in(exp2) after about 1 J/cm(exp2) of VUV exposure for seal-to-metal configurations and after 2 J/cm(exp2) for seal-to-seal configurations with no significant damage, or increase in seal leakage. This paper shows that VUV, without AO or grease, can be an effective means to reduce adhesion to the desired levels necessary for space seals with minimal change in seal leak rates.

deGroh, Henry C., III↗

Comparison of the Coronal Mass Ejection Shock Acceleration of Three Widespread SEP Events During Solar Cycle 24

We studied three solar energetic particle (SEP) events observed on 14 August 2010, 3 November 2011, and 5 March 2013 by Solar Terrestrial Relations Observatory (STEREO) A, B, and near-Earth (L1) spacecraft with a longitudinal distribution of particles greater than 90 degrees. Using a forward modeling method combined with extreme ultraviolet and white-light images, we determined the angular extent of the shock, the time and location (cobpoint) of the shock intersection with the magnetic field line connecting to each spacecraft, and compute the shock speed at the cobpoint of each spacecraft. We then examine whether the observations of SEPs at each spacecraft were accelerated and injected by the spatially extended shocks or whether another mechanism such as cross-field transport is required for an alternative explanation. Our analyses results indicate that the SEPs observed at the three spacecraft on 3 November, STEREO B (STB) and L1 on 14 August, and the 5 March SEP event at STEREO A (STA) can be explained by the direct shock acceleration. This is consistent with the observed significant anisotropies, short time delays between particle release times and magnetic connection times, and sharp rises in the SEP time profiles. Cross-field diffusion is the likely cause for the 14 August SEP event observed by STA and the 5 March SEPs observed by STB and L1 spacecraft, as particle observations featured weak electron anisotropies and slow rising intensity profiles. Otherwise, the wide longitudinal spread of these SEP increases would require an existence of a circumsolar shock, which may not be a correct assumption in the corona and heliosphere.

Xie, H.↗

Total and Spectral Solar Irradiance Sensor (TSIS) Project Status

TSIS-1 studies the Sun's energy input to Earth and how solar variability affects climate. TSIS-1 will measure both the total amount of light that falls on Earth, known as the total solar irradiance (TSI), and how that light is distributed among ultraviolet, visible and infrared wavelengths, called solar spectral irradiance (SSI). TSIS-1 will provide the most accurate measurements of sunlight and continue the long-term climate data record. TSIS-1 includes two instruments: the Total Irradiance Monitor (TIM) and the Spectral Irradiance Monitor (SIM), integrated into a single payload on the International Space Station (ISS). The TSIS-1 TIM and SIM instruments are upgraded versions of the two instruments that are flying on the Solar Radiation and Climate Experiment (SORCE) mission launched in January 2003. NASA Goddard's TSIS project responsibilities include project management, system engineering, safety and mission assurance, and engineering oversight for TSIS-1. TSIS-1 was installed on the International Space Station in December 2017. At the end of the 90-day commissioning phase, responsibility for TSIS-1 operations transitions to the Earth Science Mission Operations (ESMO) project at Goddard for its 5-year operations. NASA contracts with the University of Colorado Laboratory for Atmospheric and Space Physics (LASP) for the design, development and testing of TSIS-1, support for ISS integration, science operations of the TSIS-1 instrument, data processing, data evaluation, calibration and delivery to the Goddard Earth Science Data and Information Services Center (GES DISC).

TSIS↗

Large Interferometer For Exoplanets (LIFE) XIII. The value of Combining Thermal Emission and Reflected Light for the Characterization of Earth Twins

Context. Following the recommendations to NASA (in the Astro2020 Decadal survey) and ESA (through the Voyage2050 process), the search for life on exoplanets will be a priority in the next decades. Two concepts for direct imaging space missions are being developed for this purpose: the Habitable Worlds Observatory (HWO) and the Large Interferometer for Exoplanets (LIFE). These two concepts operate in different spectral regimes: HWO is focused on reflected light spectra in the ultraviolet, visible, and near-infrared (UV/VIS/NIR), while LIFE will operate in the mid-infrared (MIR) to capture the thermal emission of temperate exoplanets. Aims. In this study, we aim to assess the potential of HWO and LIFE to characterize a cloud-free Earth twin orbiting a Sun-like star at a distance of 10 pc, both as separate missions and in synergy with each other. We aim to quantify the increase in information that can be gathered by joint atmospheric retrievals on a habitable planet. Methods. We performed Bayesian retrievals on simulated data obtained by an HWO-like mission and a LIFE-like one separately, then jointly. We considered the baseline spectral resolutions currently assumed for these concepts and used two increasingly complex noise simulations, obtained using state-of-the-art noise simulators. Results. An HWO-like concept would allow one to strongly constrain H 2 O, O 2 , and O 3 in the atmosphere of a cloud-free Earth twin, while the atmospheric temperature profile is not well constrained (with an average uncertainty ≈100 K). LIFE-like observations would strongly constrain CO 2 , H 2 O, and O 3 and provide stronger constraints on the thermal atmospheric structure and surface temperature (down to ≈10 K uncertainty). For all the investigated scenarios, both missions would provide an upper limit on CH 4 . A joint retrieval on HWO and LIFE data would accurately define the atmospheric thermal profile and planetary parameters. It would decisively constrain CO 2 , H 2 O, O 2 , and O 3 and find weak constraints on CO and CH 4 . The significance of the detection is in all cases greater than or equal to the single-instrument retrievals. Conclusions. Both missions provide specific information that is relevant for the characterization of a terrestrial habitable exoplanet, but the scientific yield can be maximized by considering synergistic studies of UV/VIS/NIR+MIR observations. The use of HWO and LIFE together will provide stronger constraints on biosignatures and life indicators, with the potential to be transformative for the search for life in the Universe.

E Alei↗

Ultraviolet observations of classical Cepheids by OAO-2

OAO-2 observations of eight bright classical Cepheids in the wavelength region 1910 A to 4250 A are presented. The data for RT Aurigae, alpha Ursa Minoris, delta Cephei, and gamma Ophiuchi show excellent agreement with ground based photometry in the wavelength region of overlap and are consistent with a simple extrapolation of light curve properties from the visible region. However, in the ultraviolet, the light curve of beta Doradus shows two small flux bumps, at phases of 0.75 and 0.85, in addition to the well known bump at phase 0.0. All three bumps should probably be associated with the arrival of shocks at the stellar surface.

Hutchinson, J. L.↗

Susceptibility of extremophiles to far-UVC light for bioburden reduction in spacecraft assembly facilities

The prevention and reduction of microbial species entering and leaving Earth's biosphere is a critical aspect of planetary protection research. While various decontamination methods exist and are currently utilized for planetary protection purposes, the use of far-UVC light (200–230 nm) as a means for microbial reduction remains underexplored. Unlike conventional germicidal ultraviolet at 254 nm, which can pose a health risk to humans even with small exposure doses, far-UVC light poses minimal health hazard making it a suitable candidate for implementation in occupied areas of spacecraft assembly facilities. This study investigates the efficacy of far-UVC 222-nm light to inactivate bacteria using microbial species which are relevant to planetary protection either in vegetative cell or spore form. All the tested vegetative cells demonstrated susceptibility to 222-nm exposure, although susceptibility varied among the tested species. Notably, Deinococcus radiodurans, a species highly tolerant to extreme environmental conditions, exhibited the most resistance to far-UVC exposure with a dose of 112 mJ/cm 2 required for a 1-log reduction in survival. While spore susceptibility was similar across the species tested, Bacillus pumilus spores were the most resistant of the tested spores when analyzed with a bi-exponential cell killing model (D 90 of 6.8 mJ/cm 2 ). Overall, these results demonstrate the efficacy of far-UVC light for reducing microbial bioburden to help ensure the success and safety of future space exploration missions.

Ultraviolet light↗

Sol-Gel Glass Holographic Light-Shaping Diffusers

Holographic glass light-shaping diffusers (GLSDs) are optical components for use in special-purpose illumination systems (see figure). When properly positioned with respect to lamps and areas to be illuminated, holographic GLSDs efficiently channel light from the lamps onto specified areas with specified distributions of illumination for example, uniform or nearly uniform irradiance can be concentrated with intensity confined to a peak a few degrees wide about normal incidence, over a circular or elliptical area. Holographic light diffusers were developed during the 1990s. The development of the present holographic GLSDs extends the prior development to incorporate sol-gel optical glass. To fabricate a holographic GLSD, one records a hologram on a sol-gel silica film formulated specially for this purpose. The hologram is a quasi-random, micro-sculpted pattern of smoothly varying changes in the index of refraction of the glass. The structures in this pattern act as an array of numerous miniature lenses that refract light passing through the GLSD, such that the transmitted light beam exhibits a precisely tailored energy distribution. In comparison with other light diffusers, holographic GLSDs function with remarkably high efficiency: they typically transmit 90 percent or more of the incident lamp light onto the designated areas. In addition, they can withstand temperatures in excess of 1,000 C. These characteristics make holographic GLSDs attractive for use in diverse lighting applications that involve high temperatures and/or requirements for high transmission efficiency for ultraviolet, visible, and near-infrared light. Examples include projectors, automobile headlights, aircraft landing lights, high-power laser illuminators, and industrial and scientific illuminators.

Yu, Kevin↗

Ultraviolet colors of W Ursae Majoris - Gravity darkening, temperature differences, and the cause of W-type light curves

The paper presents photometry of the prototype W UMa binary system in three ultraviolet bands with the ANS satellite. It was found that W UMa has low-gravity darkening beta of 0.03; that temperature differences between the components not established by gravity darkening are insignificant; and that the bolometric albedo is not very large. It was also found that W UMa is limb-darkened in the ultraviolet region, and that the inner hemisphere of the less massive component is hotter than that predicted by gravity darkening and the reflection effect. It was concluded that about 20% of the surface area of the component responsible for large gravity darkening is covered by dark spots distributed uniformly in the longitudinal direction. An observational value of the convective darkening exponent of 0.054 plus or minus 0.02 is proposed.

Eaton, J. A.↗

Multiwavelength monitoring of the BL Lacertae object PKS 2155-304. 4: Multiwavelength analysis

Simultaneous X-ray, ultraviolet, optical, infrared, and radio monitoring data were used to test and constrain models of continuum emission from the BL Lacertae object PKS 2155-304. Intensively sampled ultraviolet and soft X-ray light curves showed a clear temporal correlation with the X-rays leading the ultraviolet by 2-3 hr. This lag was found to be significantly different from zero after an exhaustive comparison of four different techniques for measuring temporal correlations. Variations in the ultraviolet trough optical wave bands were also strongly correlated, with no measurable lag down to limiting timescales of approximately less than 1-2 hr. This strong correlation extends to the near-infrared, but the less intensive sampling precludes measurement of any lag beyomnd an upper limit of approximately less than 1 day. These lags and limits of the order of hours are much shorter than most rapid observed single-band variations. Because of the very sparse radio sampling, it was not possible to measure quantitatively the correlation and lag with shorter wavelengths, but the data do suggest that the radio may lag the optical/ultraviolet by approximately 1 week, with longer delays and weaker variations to longer radio wavelengths. The epoch-folding Q(exp 2) statistic was used to test for periodicity, and no evidence for strict or quasi-periodicity was found in any of the light curves. Because they lead the lower frequencies, the soft X-rays (approximately less than 1 keV) cannot arise from synchrotron self-Compton scattering. These results also rule out the accretion disk model, which predicts a measurable lag between ultraviolet/optical wavelength bands and a correlation between hardness and brightness, neither of which were seen. They are consistent with the entire radio through X-ray continuum arising from direct synchrotron emission from a relativistic jet. However, the tapered jet model, in which the X-ray emission is produced closer in, has problems explaining the magnitude of the ultraviolet/X-ray lag, because the X-ray-emitting electrons have very short lifetimes (t(sub 1/2) much less than 1 s). The result that the lag is much smaller than the variability timescale suggests instead that the radiation may be produced in a flattened region such as a shock front.

Edelson, R.↗

Ultraviolet photometry from the orbiting Astronomical Observatory. IX - The ultraviolet behavior of U Ophiuchi

Seven simultaneous light curves of U Oph have been obtained which cover a wavelength range from the blue part of the optical spectrum to just longward of L alpha in the ultraviolet. An analysis of these curves has been carried out to determine the spectral variation of limb and gravity darkening as well as to determine geometrical elements for the system. We conclude that (1) U Oph is gravity darkened to the extent expected from von Zeipel's law, (2) limb darkening increases toward shorter wavelengths, and (3) at the shortest wavelengths observed, the two stars are limb-darkened totally.

Source record↗

Crystal Growth of ZnSe and Related Ternary Compound Semiconductors by Vapor Transport

Interest in optical devices which can operate in the visible spectrum has motivated research interest in the II-VI wide band gap semiconductor materials. The recent challenge for semiconductor opto-electronics is the development of a laser which can operate at short visible wavelengths. In the past several years, major advances in thin film technology such as molecular beam epitaxy and metal organic chemical vapor deposition have demonstrated the applicability of II-VI materials to important devices such as light-emitting diodes, lasers, and ultraviolet detectors. With an energy gap of 2.7 eV at room temperature, and an efficient band- to-band transition, ZnSe has been studied extensively as the primary candidate for a blue light emitting diode for optical displays, high density recording, and military communications. By employing a ternary or quaternary system, the energy band gap of II-VI materials can be tuned to a specific range. While issues related to the compositional inhomogeneity and defect incorporation are still to be fully resolved, ZnSe bulk crystals and ZnSe-based heterostructures such as ZnSe/ZnSeS, ZnSe/ZnCdSe and ZnCdSe/ZnSeS have showed photopumped lasing capability in the blue-green region at a low threshold power and high temperatures. The demonstration of its optical bistable properties in bulk and thin film forms also make ZnSe a possible candidate material for the building blocks of a digital optical computer. Despite this, developments in the crystal growth of bulk H-VI semiconductor materials has not advanced far enough to provide the low price, high quality substrates needed for the thin film growth technology.

Su, Ching-Hua↗

Measuring the Photocatalytic Breakdown of Crystal Violet Dye using a Light Emitting Diode Approach

A simple method to estimate the photocatalytic reactivity performance of spray-on titanium dioxide coatings for transmissive glass surfaces was developed. This novel technique provides a standardized method to evaluate the efficiency of photocatalytic material systems over a variety of illumination levels. To date, photocatalysis assessments have generally been conducted using mercury black light lamps. Illumination levels for these types of lamps are difficult to vary, consequently limiting their use for assessing material performance under a diverse range of simulated environmental conditions. This new technique uses an ultraviolet (UV) gallium nitride (GaN) light emitting diode (LED) array instead of a traditional black light to initiate and sustain photocatalytic breakdown. This method was tested with a UV-resistant dye (crystal violet) applied to a titanium dioxide coated glass slide. Experimental control is accomplished by applying crystal violet to both titanium dioxide coated slides and uncoated control slides. A slide is illuminated by the UV LED array, at various light levels representative of outdoor and indoor conditions, from the dye side of the slide. To monitor degradation of the dye over time, a temperature-stabilized white light LED, whose emission spectrum overlaps with the dye absorption spectrum, is used to illuminate the opposite side of the slide. Using a spectrometer, the amount of light from the white light LED transmitted through the slide as the dye degrades is monitored as a function of wavelength and time and is subsequently analyzed. In this way, the rate of degradation for photocatalytically coated versus uncoated slide surfaces can be compared. Results demonstrate that the dye absorption decreased much more rapidly on the photocatalytically coated slides than on the control uncoated slides, and that dye degradation is dependent on illumination level. For photocatalytic activity assessment purposes, this experimental configuration and methodology minimizes many external variable effects and enables small changes in absorption to be measured. This research also compares the advantages of this innovative LED light source design over traditional mercury black light systems and non- LED lamp approaches. This novel technology begins to address the growing need for a standard method that can assess the performance of photocatalytic materials before deployment for large scale, real world use.

Ryan, Robert E.↗