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At least 505 records · Page 28

NSUF RTE completion report for 23-4780: Microstructural Defect Induced Thermal Conductivity Reduction in Uranium Nitride and Thorium Nitride

Uranium nitride (UN) is known to have a higher thermal conductivity than traditional oxide fuels, which could lead to a more efficient energy transport and lower local temperature during its lifetime. But the thermal transport performance of UN in extreme environments has not been systematic studied. This study investigated the irradiation induced microstructural defects in UN and the impacts on thermal conductivity. The samples were produced by spark plasma sintering at University of Texas-San Antonio (UTSA), Los Alamos National Laboratory (LANL), and Idaho National Laboratory (INL). Thermal conductivity of UN before and after 2MeV proton irradiation were measured by using laser metrology at INL in a temperature range of 77-295K. Thermal conductivity measurements in this wide, cryogenic temperature range is critical to understand the phonon scattering mechanisms between the thermal energy carrier, phonons, and different types of irradiation-induced defects. In order to ensure the measurements were conducted in the same grains and minimize the impact of the local heterogeneities, the measurement locations were highlighted by fiducial marks using the focused ion beam (FIB) with grain orientation identified using the electron backscatter diffraction (EBSD) at the Center of Advanced Energy Studies (CAES). Irradiation experiment was conducted at the Ion Beam Laboratory at Texas A&M University (TAMU). A total of 6 samples were irradiated with different irradiation doses and temperatures. After irradiation, the microstructure was characterized by using Transmission Electron Microscope (TEM) at CAES (also in the FIB marks).

36 - MATERIALS SCIENCE↗

Standard Characterization Techniques for Inorganic Phase Change Materials

Salt hydrates are promising candidates for phase change materials (PCMs) because of their low cost and high energy storage capacity. However, practical applications of salt hydrate based PCMs are limited due to their poor thermal cycling performance caused by phase separation and supercooling. Various techniques, including differential scanning calorimetry (DSC) and transient plane source (TPS) have been used to characterize salt hydrate based PCMs but may not provide full understanding of the degradation mechanism. In this manuscript, salt hydrate and graphite composites are prepared. Temperature history (T-History) method and X-ray diffraction (XRD) are utilized for measuring melting temperature, energy storage, and latent heat degradation of the PCM composites. Highlighting the importance of each technique and how each technique plays an important role in analyzing salt hydrates performance accurately. Temperature history, and X-ray diffraction are also used in conjunction to precisely predict the cause of degradation in salt hydrate PCMs with thermal cycling, as in most literatures the cause of degradation in salt hydrate are attributed to phase segregation, supercooling, and change in stichometry water concentration without any scientific validation.

Kumar, Navin↗

Characterization of Highly Thermally Conductive Organic Substrates for a Double-Sided Cooled Power Module

Abstract Silicon-Carbide (SiC) power devices have become a promising option for traditional Silicon (Si) due to the superior material properties. To fully take advantage of the SiC devices, a high-performance power device packaging solution is necessary. This study proposes a cost-effective double-sided cooled (DSC) 1.2 kV SiC half-bridge power module using organic epoxy-resin composite dielectric (ERCD) substrates. The high mechanical and thermal performance of the power module is achieved by the low-modulus, moderate thermal conductivity, and relatively thin (120 μm) layer of ERCD material compared with traditional metal-clad ceramic approaches. This novel organic dielectric can withstand high voltage (5 kV @ 120 μm) and operate up to 250°C continuously, which is indispensable for high power applications. The thermal modeling results show that the equivalent thermal resistance junction-to-case (Rjc_eq) of the DSC power module using dual direct bonded copper (DBC) is 17% higher than the dual ERCD configuration. Furthermore, a non-insulated DSC power module concept is proposed for maximizing thermal performance by considering thermal vias in the ERCD substrate and direct-soldered heat sink. A thought process for optimization of thermal via design is demonstrated and it shows up to 24% of improvement on thermal performance compared with the insulated DSC power module.

Double-sided cooling, epoxy-resin composite dielec↗

Adaptive thermal stabilization of an integrated photonic spectrometer using parasitic interference fringes

Parasitic fringe drift from unwanted scatterings limits the long-term stability of waveguide-based optical spectrometers. Yet their spectral features provide relevant information that can be used to improve performance of the spectrometer. We show that fringe drift can be extracted and utilized to perform accurate thermal stabilization, especially in the case of integrated waveguide sensors. In this Letter, effective stabilization of a methane silicon photonic sensor is demonstrated, and significant reduction in fringe noise is clearly observed.

Teng, Chu C.↗

Oklo Sponsored Testing using PELICAN: System, Subchannel, and High-Fidelity Software Validation (Final CRADA Report)

Argonne National Laboratory (the Contractor), located in Lemont IL, and Oklo, Inc., (the Participant), headquartered in Santa Clara, CA, propose to enter into a Cooperative Research and Development Agreement (CRADA) to perform a gap analysis of thermal hydraulic data, perform prototypical fuel assembly pressure drop and cavitation model validation, generate the experimental data as well as the corresponding uncertainties for this matrix and, finally, develop the validation models with the Argonne system level code SAS4A/SASSYS-1, the Argonne subchannel analysis code DASSH, the Argonne high fidelity code Nek5000, and/or the Idaho National Laboratory code Pronghorn Subchannel. The work outlined below will significantly improve the experimental and validation database currently available for liquid metal fast reactors, thus making it a viable part of a comprehensive reactor design and licensing suite to be used by the participant.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Developing a Composite Vacuum Insulated Panel (VIP) Insulation/Vinyl Siding Composite Technology for Retrofitting Residential Walls

This paper reports on a project that has attempted to seize on an opportunity to take a giant leap forward in commercializing a technology that would address a key opportunity to achieve energy savings in the existing residential housing stock. It is typically very difficult to increase the R-value of the walls in existing residential housing as doing so from the inside is disruptive and there have not been good solutions to increase thermal envelope performance from the exterior through adding continuous insulation due to the additional work required to fit existing architectural features to the new wall thickness and to reclad the façade. A high thermal resistivity or R-value per inch product that can be used in these applications offers an excellent solution.This paper summarizes a three-year research project to a produce vacuum insulated panel (VIP)/vinyl siding that would have sufficient R-value to meet the continuous insulation requirements of the 2018 International Energy Conservation Code (IECC, 2018) in all climate zones and has a much thinner profile that will facilitate its application to existing residential homes without the need for expensive retrimming of the architectural details. The paper will supply information on the development of the technology, its thermal modelling, testing, voice of user sessions to solicit input from architects, designers, manufacturers, contractors, and installers, and a techno-economic analysis to gauge its competitiveness with existing product options.

Desjarlais, Andre Omer↗

Developing a Composite Vacuum Insulated Panel (VIP) Insulation/Vinyl Siding Composite Technology for Retrofitting Residential Walls

This paper reports on a project that has attempted to seize on an opportunity to take a giant leap forward in commercializing a technology that would address a key opportunity to achieve energy savings in the existing residential housing stock. It is typically very difficult to increase the R-value of the walls in existing residential housing as doing so from the inside is disruptive and there have not been good solutions to increase thermal envelope performance from the exterior through adding continuous insulation due to the additional work required to fit existing architectural features to the new wall thickness and to reclad the facade. A high thermal resistivity or R-value per inch product that can be used in these applications offers an excellent solution. This paper summarizes a three-year research project to a produce vacuum insulated panel (VIP)/vinyl siding that would have sufficient R-value to meet the continuous insulation requirements of the 2018 International Energy Conservation Code (IECC, 2018) in all climate zones and has a much thinner profile that will facilitate its application to existing residential homes without the need for expensive retrimming of the architectural details. The paper will supply information on the development of the technology, its thermal modelling, testing, voice of user sessions to solicit input from architects, designers, manufacturers, contractors, and installers, and a techno-economic analysis to gauge its competitiveness with existing product options.

Desjarlais, Andre↗

Chemical heterogeneity modulated zero thermal expansion alloy over super-wide temperature range

Chemical heterogeneity is usually avoided in solution chemistry, but it may still occur with sometimes dramatic effects on target materials and their properties. Here, we propose chemical heterogeneity as a counterintuitive strategy to design high-performance zero thermal expansion (ZTE) alloys. We apply this approach in a Hf-Ti-Fe alloy with excess Fe in the Hf/Ti sublattice and produce Hf/Ti concentration alternations at the micro level. Such chemical heterogeneity regulates local magnetic interactions in alloy and triggers a dispersed magnetic phase transition that modulates the thermal expansions at the micro level and hence results in a remarkable ZTE behavior over a super-wide temperature window from 10 to 480 K. This mechanism is supported by comprehensive studies on morphological microstructures, crystal and magnetic structures, and theoretical calculations. The strategy of local chemical heterogeneity opens up an avenue to design ZTE and the related functional materials directly via microstructure engineering.

36 MATERIALS SCIENCE↗

High Flux Isotope Reactor Uncertainty Factors

This report provides a brief summary of the uncertainty factors used for High Flux Isotope Reactor (HFIR) steady-state heat transfer analyses. These factors are mainly used in the HFIR Steady-State Heat Transfer Code (HSSHTC) to perform core thermal margin evaluations that determine safe reactor operation. The attempt to classify these factors stems from the assumption that the current approach is characterized by an excess of conservatism, thereby restricting reactor performance. The work documented herein was of a limited scope and pertained mainly to factors’ description and initial grouping based on their functional use. Suggestions are provided for further evaluation for the low-enriched uranium (LEU) to the uranium silicide dispersion fuel (U 3 Si 2 -Al).

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Hydrophobic, Thermal Shock-and-Corrosion-Resistant XSBR Latex-Modified Lightweight Class G Cement Composites in Geothermal Well Energy Storage Systems

Energy losses can be significantly reduced if thermally insulating cement is used for energy storage and recovery. The thermal conductivity (TC) of the currently used cement is between 1 and 1.2 W/mK. In this study we assessed the ability of polystyrene (PS)–polybutadiene (PB)–polyacrylic acid (PAA) terpolymer (cross-linked styrene–butadiene rubber, XSBR) latex to improve thermal insulating properties and thermal shock (TS) resistance of class G ordinary Portland cement (OPC) and fly ash cenosphere (FCSs) composites in the temperature range of 100–175 °C. The composites autoclaved at 100 °C were subjected to three cycles, one cycle: 175 °C heat → 25 °C water quenching). In hydrothermal and thermal (TS) environments at elevated temperatures in cement slurries the XSBR latex formed acrylic calcium complexes through acid–base reactions, and the number of such complexes increased at higher temperatures due to the XSBR degradation with formation of additional acrylic groups. As a result, these complexes offered the following five advanced properties to the OPC-based composites: (1) enhanced hydrophobicity; (2) decreased water-fillable porosity; (3) reduced TC for water-saturated composites; (4) minimized loss of compressive strength, Young’s modulus, and compressive fracture toughness after TS; and (5) abated pozzolanic activity of FCSs, which allowed FCSs to persist as thermal insulators under strongly alkaline conditions of cement slurries. Additionally, XSBR-modified slurries possessed improved workability and decreased slurry density due to the air-entraining effect of latex, which resulted in further improvement of thermal insulation performance of the modified composites.

15 GEOTHERMAL ENERGY↗

Multifunctional Superelastic Graphene Aerogels Derived from Ambient-Dried Graphene Oxide/Camphene Emulsions

Graphene oxide (GO) emulsions have been widely adopted to fabricate lightweight graphene aerogels (GAs). However, preparing high-performance GAs from conventional GO emulsions under ambient conditions seems rather challenging because of the structural collapse caused by strong capillary forces during drying. Here, we report a new, low-cost route to prepare high-performance, multifunctional GAs by the ambient drying of GO/camphene emulsions. Benefiting from the liquid-solid and solid-gas phase transitions of camphene, highly porous GO aerogels were obtained under ambient conditions. Moreover, the thermally annealed GO aerogels exhibited excellent mechanical properties, fire resistance, thermal insulation performance, and oil adsorption capability.

ambient drying↗

Design and optimization of higher order mode couplers for the superconducting cavities of the PERLE energy recovery linac

The Powerful Energy Recovery Linac for Experiments (PERLE) is an energy recovery linac (ERL) facility based on superconducting radio-frequency (SRF) technology to be hosted at the Laboratoire de Physique des 2 Infinis Irène Joliot-Curie (IJCLab) in France. With a target beam power of 10 MW, PERLE aims to demonstrate the high-current, continuous wave, multi-pass operation to validate options for future high-energy machines, such as the 50 GeV ERL proposed for the Large Hadron electron Collider (LHeC) and the Future Circular electron-hadron Collider (FCC-eh), and host dedicated particle physics and nuclear experiments. In high-current ERLs, the regenerative Beam Breakup (BBU), emerging from the beam and cavity Higher Order Modes (HOMs) interaction, is a major concern for their stable operation. Beam-induced HOMs can increase the cavity heat load at cryogenic temperature and cause beam instabilities. HOM couplers are installed in the cavity beam pipes to absorb HOM energy and mitigate these effects. This thesis presents the design and optimization of several coaxial HOM couplers for the 5-cell 801.58 MHz elliptical Nb cavities of the 500 MeV PERLE ERL configuration. The RF transmission of the HOM couplers was optimized to enhance the damping of the most dangerous HOMs. The optimized HOM couplers were integrated into endgroups to simulate their damping performance and thermal behavior. The optimized HOM couplers were 3D-printed in epoxy and copper-coated. Low-power RF measurements were conducted on the produced HOM couplers installed in copper PERLE-type cavities to validate their damping performance and propose several endgroups for the PERLE 5-cell cavity to mitigate HOMs below the BBU instability limits.

Barbagallo, Carmelo↗

Phonon Thermal Transport in UO 2 via Self-Consistent Perturbation Theory

Computing thermal transport from first-principles in UO 2 is complicated due to the challenges associated with Mott physics. Here, we use irreducible derivative approaches to compute the cubic and quartic phonon interactions in UO 2 from first principles, and we perform enhanced thermal transport computations by evaluating the phonon Green’s function via self-consistent diagrammatic perturbation theory. Our predicted phonon lifetimes at T = 600 K agree well with our inelastic neutron scattering measurements across the entire Brillouin zone, and our thermal conductivity predictions agree well with previous measurements. Finally, both the changes due to thermal expansion and self-consistent contributions are nontrivial at high temperatures, though the effects tend to cancel, and interband transitions yield a substantial contribution.

36 MATERIALS SCIENCE↗

Thermal energy storage in concrete utilizing a thermosiphon heat exchanger

The performance of a lab-scale concrete thermal energy storage (TES) module with a 2-kWh thermal capacity is evaluated at temperatures up to 400 °C. The TES module uses conventional normal weight concrete with thermal and mechanical properties that are tailored for use as a solid thermal energy storage media. A thermosiphon heat exchanger is used to provide rapid heat transfer into the concrete module, which is reinforced with a steel pipe outer shell. The charging and discharging cycles are examined to assess the thermal performance of the concrete and thermosiphon. Based on the results of testing, the thermosiphon is able to repeatably charge the concrete module from 300 to 400 °C over a 4-h period. After 2250 total hours of charge and discharge cycles, there was no observed delamination between the concrete and the thermosiphon or the steel jacket reinforcement. Non-destructive measurements of the concrete indicated no significant degradation of the solid storage media. The experimental results are then used to validate a numerical model of the concrete TES module for parametric study. Finally, varying insulation conditions were analyzed using this model to determine practical configurations for regular operation of the proposed concrete TES module.

25 ENERGY STORAGE↗

Beam Induced Heating Analysis Update for the EIC Vacuum Chamber Components

One of the challenges of designing the Electron-Ion Col lider (EIC) is to mitigate beam-induced heating due to the intense electron and hadron beams. Heating of the ESR vac uum chamber components is mainly due to beam-induced resistive wall (RW) losses and synchrotron radiation. For the HSR heating is mainly due to large radial offsets and heat conduction from room temperature to cryogenic tem perature for cryo-components. In this paper, we provide an update on the beam-induced heating and thermal analysis of some critical ESR vacuum chamber components, such as the ESR Large Angle Bremhustraulung Monitor (LABM). We also provide a similar update for critical HSR vacuum com ponents, including the cryo-cooled BPM button assembly, beam screen, abort kicker, and polarimeter. To perform the thermal analyses, the resistive wall loss on individual compo nents is calculated with CST and the synchrotron radiation (if exists) is evaluated using SynRad. These losses, along with realistic boundary conditions are then fed to ANSYS to determine the temperature distribution.

43 PARTICLE ACCELERATORS↗

Margin to Onset of Nucleate Boiling studies for MITR and NBSR Design Demonstration Experiments

The United State High Performance Research Reactor (USHPRR) program aims to eliminate more than 200kg of High Enriched Uranium (HEU) from commerce annually by converting five U.S. high-performance research reactors and one associated critical assembly to Low Enriched Uranium (LEU) fuel using a high-density alloy of uranium-10 wt% molybdenum (U-10Mo). The Massachusetts Institute of Technology Reactor (MITR) and the National Bureau of Standards Reactor (NBSR) are two of five research reactors selected for this program. Previous studies have addressed the thermal-hydraulics performance of the fuel Design Demonstration Elements (DDE) for these reactors under conservative assumptions in the Belgian Reactor (BR)-2. This report extends these previous studies by analyzing the margins to Onset of Nucleate Boiling (ONB) for these two DDEs under the conservative conditions used in the previous thermal-hydraulics analyses

42 ENGINEERING↗

ECAR-6332 Rev 3 RELAP5-3D Thermal-Hydraulic Analysis of MARVEL Microreactor - Final Design

This document reports the thermal hydraulic analyses results for the MARVEL microreactor, final design, including dry criticality, normal operation, operational transients and a set of very-low probability transients caused by accident conditions. The ultimate scope of this document is to demonstrate the MARVEL microreactor thermal hydraulic performances and its inherent safety. First, the list of the operational and accidental transients with the corresponding acceptance criteria are recalled. Then, details of the final design, the key input parameters, the assumptions, and the methodology used for performing the deterministic safety analyses are presented. Finally, the analyses results are provided, demonstrating the satisfaction of the corresponding acceptance criteria.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗

Performance Comparison of Helium and sCO 2 as Coolants for Modular Finger-Type Divertors

Several studies at the Georgia Institute of Technology have evaluated the thermal and fluids performance of the helium-cooled modular divertor with multiple jets (HEMJ) over the past decade. This finger-type divertor was studied both experimentally at nearly prototypical conditions and numerically at fully prototypical operating conditions using experimentally validated simulations. Recently, supercritical carbon dioxide (sCO 2 ) has been studied as the primary coolant in power cycles and other applications in various systems, in part because CO 2 achieves the high densities typical of supercritical fluids at relatively low temperatures and pressures, with a critical point of (7.38 MPa, 31°C). This density makes it possible to realize very compact and efficient sCO 2 power cycles. The feasibility of sCO 2 as a coolant for plasma-facing components, specifically the divertor, was therefore evaluated as part of the Fusion Energy System Studies design study activities. This work compares the thermal-fluid performance of helium and sCO 2 in the HEMJ divertor geometry using numerical simulations at prototypical conditions: inlet temperatures T i = 600°C to 700°C, pressures p ≈ 10 MPa, and steady-state incident heat fluxes on the tile q″ < 17 MW/m 2 . The performance is quantified here as the maximum heat flux that can be accommodated by the plasma-facing tile, the pumping power fraction, defined as the ratio of the coolant pumping power to the incident thermal power, and the operating stress limits based on ASME pressure vessel criteria. As expected, helium requires lower mass flow rates and pumping power fractions within imposed maximum temperature limits for the HEMJ pressure boundary. However, it also appears that neither helium nor sCO 2 can remove 10 MW/m 2 of incident heat flux while meeting ASME pressure vessel criteria. Finally, the numerical modeling reveals that sCO 2 may remove slightly higher incident heat fluxes than helium due to the imposed stress limits due to the sCO 2 coolant resulting in smaller local temperature gradients, albeit at a considerably higher pumping power fraction.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗