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DOE OSTI2021

Refinement of Salt Dissolution Inhibitor Requirements (Final Report)

At Savannah River Site (SRS), High-Level Waste is stored in below-grade carbon steel tanks. This waste in part consists of sludge, salt cake, and/or supernate. Preparation of this waste for future processing involves dissolution of the salt cake layer. The salt dissolution process can create conditions that leave the carbon steel tanks susceptible to localized corrosion. The salt to be dissolved contains high concentrations of nitrate, that once released, create an environment that may be conducive to pitting corrosion and/or stress corrosion cracking (SCC) of carbon steel. The salt dissolution process also liberates interstitial liquid trapped between the salt crystals. This liquid is initially high in nitrite and hydroxide concentration. High pH and greater ratios of nitrite to nitrate act as inhibitors to minimize corrosion of carbon steel in high nitrate environments. However, as dissolution proceeds, the concentration of nitrate will increase, while the hydroxide and nitrite concentration of the interstitial liquid will deplete and become insufficient to prevent the onset of corrosion attack. Tank blending and addition of inhibitors are used to ensure adequate concentrations of hydroxide and nitrite. However, this is not desirable during salt dissolution as it can reduce process efficiency and increase the amount of waste that needs processing. It has been proposed that these corrosion control limits be revisited to evaluate the corrosion susceptibility of carbon steel in environments that more closely resemble current operating conditions at SRS. An experimental matrix was designed to evaluate the use of the pitting factor for supernate chemistries characteristic to SRS, particularly during the salt dissolution process. Two electrochemical methods were identified to determine the susceptibility of A537 and A285 low-carbon steels to pitting corrosion with this chemistry envelope at temperatures up to 75 °C. The predominant electrochemical test method was Cyclic Potentiodynamic Polarization (CPP) studies. Through CPP, the pitting factor was used, based on Hanford Site corrosion studies, to accurately identify pitting susceptibility within the compositional range studied with some conservatism. Additionally, sulfate was determined to have no statistically significant influence, at concentrations up to 0.6 M, on pitting behavior in more concentrated solutions where other aggressive species govern pitting susceptibility. Where CPP was inconclusive, Modified ASTM G192 was successfully used to evaluate pitting susceptibility conditions and allowed for a pass/fail result to be determined. In all cases, the pitting factor was determined to be applicable to the simulants tested, with this metric accurately predicting incidences in which pitting occurred. Based upon the findings in this work, a pitting factor of 1.2 is being proposed to build in a safety factor and remain consistent with the Hanford Site approach. Additionally, a minimum pH limit of 12 is proposed to ensure carbon steel passivity and localized corrosion the primary degradation mechanism. Susceptibility to SCC was evaluated using a reduced matrix of tests at 75 °C. No failures due SCC were observed at open circuit. In addition, tests polarized anodically by 200 mV only resulted in failures for trials with pitting factors less than 0.86. However, a test with a passing condition based upon the pitting factor metric (pitting factor = 1.40) did exhibit a failure with an applied potential of +300 mV vs. OCP. This result is contrary to the prediction based upon the pitting factor, however, a polarization of 300 mV, or even 200 mV, from open circuit is substantial. The relationship between these testing parameters and service environment/conditions and the desired level of conservatism in the metric should be further evaluated in the determination of the significance of this result. While the pitting factor accurately predicted susceptibility to SCC at temperatures up to 75 °C and with positive overpotentials up to 200 mV, the relatively small sample matrix and failure of a passing pitting factor with a 300 mV polarization resulted in an inconclusive determination of whether the pitting factor may be used for predicting susceptibility to SCC at temperatures between 50 °C and 75 °C. As such, additional testing is recommended to evaluate the validity of the pitting factor for SCC susceptibility prediction at temperatures between 50 °C and 75 °C.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Comparative Structural Rigidity Analysis of the NBSR DDE and the NBSR LEU Fuel Element

The National Bureau of Standards Reactor (NBSR) is a 20-MW heavy-water moderated and cooled, enriched-fuel, tank-type reactor located in the NIST Center for Neutron Research laboratory complex. NBSR is one of six U.S. high performance research reactors (USHPRR), including one critical facility, that actively collaborates with the National Nuclear Security Administration (NNSA) Material Management and Minimization (M3) Reactor Conversion Program to convert from the use of highly enriched uranium fuel to the use of low-enriched uranium (LEU, < 20 wt% U-235) fuel. On the LEU U-10Mo fuel qualification side, mini-plate and large-plate irradiations have been successfully performed, and more experiments are either ongoing or planned. As an additional experimental campaign to support licensing of the LEU fuel for the use in the NBSR, the NBSR Design Demonstration Element (DDE) will be a full-sized test element similar to the NBSR LEU fuel element and irradiated in a test reactor under conditions as prototypic of the NBSR LEU fuel element operating conditions as possible.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

DOE OSTI2025

Heavy-Duty Hydrogen Station Equipment Performance Device (HD HyStEP) Specifications and Design Considerations

The original Hydrogen Station Equipment Performance (HyStEP) device was commissioned in 2015 and was critical for the rapid validation of light-duty (LD) hydrogen fueling stations. As applications for hydrogen as a heavy-duty (HD) transportation fuel continue to grow, new heavy-duty stations are being developed to fuel these vehicles that require larger onboard storage tank systems to meet HD transportation demands and drive cycles. The differences in size and geometry from LD vehicles have driven the creation of new hydrogen fueling protocols that will enable safe and economical fueling of HD vehicles. With the new requirements that are set out in HD fueling protocols like SAE J601-5, a new HyStEP-like device is needed to evaluate the capabilities of high-flow hydrogen stations to fuel HD vehicles to the new protocol standard. To create a heavy-duty HyStEP (HD HyStEP) device, an effort has been undertaken to evaluate the requirements that would form the basis for the design of a successful HD HyStEP device. The primary design goal of this HD HyStEP device is its capability of following a test methodology similar to what is outlined in CSA HGV 4.3, which guides the validation of LD fueling dispensers but with adjustments to verify adherence to the HD fueling protocols (SAE J2601-5) for 70 MPa and 35 MPa pressure class vehicles rather than the LD fueling protocols (SAE J2601). The design presented here aims to provide information that enables the creation of an HD HyStEP device that achieves the primary design goal while being informed by the years of experience from the current HyStEP operators.

08 HYDROGEN↗

DOE OSTI2024

Model predictive control for optimal dispatch of chillers and thermal energy storage tank in airports

Cost of energy consumption is one of the biggest operational cost for airports, and it is increasing from time to time as airports expand to support growing number of passengers. Various factors affect the energy consumption including efficiency of airport Heating Ventilation and Air conditioning (HVAC) systems, which in turn depends on the efficiency of individual subsystems. Here, in this paper, we present an optimal scheduling method for the central plant system at Dallas Fort Worth airport, involving chillers, pumps, and a thermal energy storage (TES) system. A model predictive control (MPC) problem is formulated to minimize both energy and demand charge costs while satisfying the cooling needs of the airport. The proposed Mixed-Integer Nonlinear Programming (MINLP) formulation includes performance curve based models for chillers and pumps and a simplified state of charge model for TES. The formulation also includes predictions of cooling load and chilled water return temperature. Simulation results for a month in summer show savings around 10% compared to the baseline. Initial recommendations based on insights from simulation results to the manual operation procedures resulted in significant savings. Field test results show a 7% chiller efficiency improvement.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2022

Development, verification, and validation of comprehensive acoustic fluid-structure interaction capabilities in an open-source computational platform

The acoustic fluid-structure interaction (FSI) formulation is a practical numerical approach for the seismic analysis of fluid-filled tanks. However, there are no verification and validation studies reported in the literature that demonstrate the ability of an acoustic FSI numerical model to predict responses important to structural and mechanical design for intense translational and rotational earthquake inputs. Herein, an acoustic FSI formulation is implemented in the open-source Multiphysics Object-Oriented Simulation Environment (MOOSE), and is formally verified and validated using analytical solutions and code-to-code verification, and experimental data, respectively. The analytical solutions are for small amplitude, unidirectional seismic inputs. The code-to-code verification utilizes a previously verified and validated Arbitrary Lagrangian-Eulerian (ALE) numerical model in the commercial finite element code LS-DYNA. The validation studies utilize a comprehensive data set assembled from results of 3D earthquake-simulator tests of a fluid-filled vessel. The acoustic numerical model in MOOSE is verified and validated for hydrodynamic pressures and support reactions except for cases that involve significant convective response. For small amplitude inputs, numerically predicted wave heights match those of the analytical solutions. The numerical model is not verified and validated for wave height calculations under intense 3D seismic inputs. The run times for the acoustic FSI simulations in MOOSE are an order of magnitude, or more, shorter than for the corresponding ALE simulations in LS-DYNA. The utility of the MOOSE acoustic FSI implementation is demonstrated by seismic analysis of a building equipped with a fluid-filled, advanced nuclear reactor.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2020

Evaluating Transfer and Pumping of Slurries from Pulsed Jet Mixed Vessels

Due to gravity, solids in slurries will settle if density differences between the solids and liquid are positive (i.e., particle has a negative buoyant force) unless rheological properties and flow conditions are adequate to overcome the gravitational effects. The rate of settling depends on the force balance of the particle, which includes the surface forces associated with fluid rheology. Given the same fluid and solid properties, particles that are larger and denser tend to settle faster. When pumping slurry into a vessel at concentrations precluding hindered settling with insufficient mixing, particle and density distributions can result in preferential settling, creating stratification in the solids concentration within the vessel. For vessels with transfer line inlets located in the lower portion of the tank, the stratified solids concentration may be detrimental to the transfer system performance. Elevated concentrations of solids in the slurry entrained at the inlet to the transfer line can result in the effective viscosity or slurry bulk density exceeding the design limits of the pump. These conditions could result in plugging of the transfer line or onset of cavitation of the pumps because of excessive pressure drop. These conditions can be exacerbated with periodic inlet conditions existing at the transfer line inlet. Periodic conditions can result when vessel mixing is intermittent such as with pulsed jet mixers (PJM). The transfer line inlet conditions are impacted by the periodic nature of the PJM operations with respect to suspension of solids and their transport to the inlet of the transfer line. A scaling approach is presented, and corresponding test requirements are developed for assessing the prevention of plugging the pipeline. Line plugging mechanisms are addressed that do not include plugging due to steady-state high-density slurry entering the transfer line and reducing the net positive suction head available (NPSHA) at the pump inlet to below that required for pump operation. Items considered include the transition to reduced relative flow velocities, such that the critical pipe velocity for solids deposition, Ucd, is not maintained, and segregation of heavy solids during the transport. The recommended requirements to prevent plugging include: • Limits for viscosity and density for entrained slurry to prevent the pressure drop in the pipeline from exceeding pump capacity. • Limits for viscosity and density for entrained slurry to prevent the net positive suction head available (NPSHA) from falling below the net positive suction head required (NPSHR) for operating the pump. • Transfer line velocity and flow rate requirements to maintain solids in suspension, while avoiding line plugging that results from deposition of solids within the transfer line. This paper describes the development of the scaling and testing requirements to verify that proposed approaches for transfer and pump out are appropriately developed

periodic flow, mixing, pipeline plugging, scaling,↗

DOE OSTI2021

Antifoam Development for Eliminating Flammability Hazards and Decreasing Cycle Time in the Defense Waste Processing Facility

Foam, due to the high gas generation rates of boiling and chemical reaction offgasing, requires control measures to prevent the foam from contaminating the condensate and to facilitate efficient plant operation. Antifoam was utilized to minimize foam production during chemical processing in the DWPF and during High-Level Waste (HLW) evaporation at SRS and Hanford. However, the current antifoam used in the SRS DWPF increases flammability risk during chemical processing (generates three flammable degradation products) and while feeding the melter (can decompose to CO/hydrogen). It is also the likely source of methyl functional groups for the organo-mercury present in the tank farm and excessive mercury in Saltstone. Additionally, the planned startup of Salt Waste Processing Facility (SWPF), with much higher throughput, will challenge DWPF to process at higher gas generation rates. DWPF employs Antifoam 747, a superspreader produced by Momentive Performance Materials, as an antifoaming agent during waste processing. During DWPF chemical processing, antifoam must be effective up to boiling (i.e., up to 103°C) and between a pH of 3-13. Antifoam 747 is most effective at a pH range of 6-8 and degrades as pH deviates. In addition, SRNL identified three flammable antifoam degradation products using mass spectrometer (MS) and fourier transform infrared (FTIR) offgas analyzers during simulations. A new antifoam or a new method to control foam is needed to minimize DWPF processing time and reduce the risk of contamination. In addition, testing should be completed to ensure that other antifoams used in HLW processing do not have similar flammability hazards or cause unintended impacts in downstream processing.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2023

Product Consistency Test Results for the LAW HPVR Glasses

This report summarizes the chemical analysis of Product Consistency Test (PCT) leachates received from Pacific Northwest National Laboratory (PNNL). The leachates are from a series of simulated nuclear waste glasses designated Low-Activity Waste High PCT and VHT Response (LAW HPVR) glasses that were designed and fabricated at PNNL. The glasses included both quenched and canister centerline cooled glasses. The reported data will be used in the development, validation, and implementation of enhanced property/composition models for waste glass vitrification at Hanford. The elemental release for the study glasses is reported as normalized concentration (NC i ). NC i of several elements was computed for both the target and measured glass compositions, which were similar, resulting in no significant differences when computing the NC i values. The majority of the glasses exhibited NC B , NC Na , and NC Si values that were greater than the Hanford Tank Waste Treatment Plant (WTP) low-activity waste constraint of 4 g/L. Several blank solutions included with the study glasses had K, Na, and Si concentrations above the analytical detection limit. Additionally, several of the reference glasses that were included with the study glasses had Na concentrations that were higher than expected. The unexpected analyte concentrations in the reference glass and blank solutions were insignificant with respect to the reported NC i values, and are noted for completeness and their experimental relevance.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Glass Property-Composition Models for Support of Hanford WTP LAW Facility Operation

Current plans for the River Protection Project envision starting to vitrifying low-activity waste (LAW) by 2023 using a Direct Feed Low-Activity Waste (DFLAW) approach and subsequently using a full-pretreatment approach. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) LAW Facility will be operated and controlled using a LAW glass formulation algorithm (GFA), which requires several inputs based on research and development results. LAW glass property-composition models for several product quality and processing properties are key inputs for the LAW GFA. It is envisioned that the preliminary LAW GFA discussed by Kim and Vienna (2012) will be used for commissioning and initial radioactive operations of the WTP LAW Facility under Bechtel National, Inc. using the DFLAW approach. Then, an updated LAW GFA will be developed for implementation by the WTP operating contractor that takes over after WTP LAW Facility commissioning. This report documents the enhanced LAW glass property-composition models developed for use in the updated LAW GFA. The properties for which models were developed include Product Consistency Test (PCT) response, Vapor Hydration Test (VHT) response, viscosity at 1150 °C, electrical conductivity at 1150 °C, melter SO 3 tolerance at 1150 °C, and K-3 refractory corrosion at 1208 °C. Table S.1 lists the tables in this report that contain the recommended models for each of these properties. The model types recommended include partial quadratic mixture (PQM) models for viscosity, electrical conductivity, melter SO 3 tolerance and K-3 corrosion, bias corrected PQM model (bcPQM) for PCT, and logistic PQM model for VHT. The fits of model and validation subsets were found to be well predicted by the recommended models.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Hanford Waste Treatment Plant Effluent Management Facility Stack Effluent Monitoring: Sampling Probe Location Qualification Evaluation

The Hanford Tank Waste Treatment and Immobilization Plant Effluent Management facility (EMF) stack monitor location was qualified using the LV-S1 scale model stack as a baseline, augmented by the LB-S1 and LV-S2 scale model stacks to address the Direct Feed Low Activity Waste Effluent Management Facility Vessel Vent Process (DVP) injection into the main Active Confinement Ventilation (ACV) system duct. As required by the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999 standard, the scale models and its sampling locations were geometrically similar to the actual stack and the Reynolds numbers for both the actual and model stacks were >10,000. An additional criterion is that the product of the hydraulic diameter and mean velocity (DV) of the full-scale stack must be between 1/6 DV and 6 DV of the scale model stack tests. Verification tests of the EMF stack was performed at normal operating conditions. The minimum 1/6 DV value, along with the maximum 6 DV value from the scale model testing determines the range of stack flow rates for which the full-scale stack may be operated and remain in compliance with the stack verification criterion. Based on the LV-S1 scale model test DV values, the corresponding stack flow rates for the EMF stack are as listed in Table S1. Table S1. Effluent Management Facility Stack Qualified Flow Range. Stack Parameter EM-1 Minimum Qualified Stack Flow (scfm) 781 Maximum Qualified Stack Flow (scfm) 53,432 The remaining criteria for the stack verification to be considered valid involve the flow angle and velocity uniformity results. First, the flow angle at the full-scale stack must be =20°. Second, the velocity uniformity at the full-scale stack must be =20% coefficient of variance (COV). Finally, the velocity uniformity results for the actual and scale model stack tests must agree within 5% COV. These criteria were met through the full-scale stack test at the EMF. Flow angle results were less than 5°; all flow angle results were within the =20° criterion. The velocity uniformity results for each test condition ranged between 2.2% COV and 4.3% COV, which were all within the range of the target % COV values from the scale model tests on the LV-S1, LB-S1, and LV S2 scale models. Based on these stack verification test results, the EMF filtered exhaust stack sampling location meets the qualification criteria provided in the ANSI/HPS N13.1-1999 standard for all fan operating configurations. This includes each combination of ACV fan with the DVP exhausters. Further changes to the system configuration or operating conditions that are outside the qualified flow rates described in this report may require additional tests or analyses to determine compliance with the standard.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

Glass Property-Composition Models for Support of Hanford WTP LAW Facility Operation

Current plans for the River Protection Project envision starting to vitrifying low-activity waste (LAW) by 2023 using a Direct Feed Low-Activity Waste (DFLAW) approach and subsequently using a full-pretreatment approach. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) LAW Facility will be operated and controlled using a LAW glass formulation algorithm (GFA), which requires several inputs based on research and development results. LAW glass property-composition models for several product quality and processing properties are key inputs for the LAW GFA. It is envisioned that the preliminary LAW GFA discussed by Kim and Vienna (2012) will be used for commissioning and initial radioactive operations of the WTP LAW Facility under Bechtel National, Inc. using the DFLAW approach. Then, an updated LAW GFA will be developed for implementation by the WTP operating contractor that takes over after WTP LAW Facility commissioning. This report documents the enhanced LAW glass property-composition models developed for use in the updated LAW GFA. The properties for which models were developed include Product Consistency Test (PCT) response, Vapor Hydration Test (VHT) response, viscosity at 1150 °C, electrical conductivity at 1150 °C, melter SO3 tolerance at 1150 °C, and K-3 refractory corrosion at 1208 °C. Table S.1 lists the tables in this report that contain the recommended models for each of these properties. The model types recommended include partial quadratic mixture (PQM) models for viscosity, electrical conductivity, melter SO 3 tolerance and K-3 corrosion, bias corrected PQM model (bcPQM) for PCT, and logistic PQM model for VHT. The fits of model and validation subsets were found to be well predicted by the recommended models.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2024

Is a Generator the Only Solution When the Grid Fails? Optimizing Systems for Resiliency and Carbon Reduction: Preprint

Traditionally, buildings are dependent on utility infrastructure, and when a grid failure happens, end users rely on the closest source of energy storage to sustain operation until power is restored. For buildings, that typically means using an electric generator. This electric generator either uses on-site energy storage such as fossil fuels in a tank or a gas connection which is, in turn, tied to gas wells—also a form of energy storage. Generators are popular for their ease of implementation and low capital costs; however, they have limited value outside of disruptions, and they are a source of scope 1 emissions, or direct greenhouse gas emissions from sources controlled by the building owner. In contrast, some power generation and storage systems, such as photovoltaic (PV) panels and battery energy storage systems (BESS), can serve the same purpose during grid disruptions while presenting advantages outside of power failure. This paper explores methods for storing and converting energy on-site to increase building resiliency, focusing on solutions that minimize scope 1 emissions. We analyze the cost and carbon impacts of energy efficiency measures, PV arrays, and BESS, with and without generators, in a simulation test case. We find significant benefits can be achieved both during and outside of power failure events when designing systems that integrate the on-demand capability of generators, the low carbon energy supplied by PV, and the storage capabilities of BESS. Specifically, adding even minimal BESS and PV can result in downsizing the generator, increasing generator efficiency and requiring less fuel.

ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION↗

DOE OSTI2026

Formulation and Performance Evaluation of Epoxy Sealant Systems for Double-Shell Tank Bottom Refurbishment

The performance of epoxy sealants used in the refurbishment of double-shell tank (DST) systems requires balancing processability, thermomechanical stability, and adhesion to cementitious substrates. This study incorporates Heloxy 8 as a reactive diluent into Westlake 862 epoxy to tailor workability and cured-state properties. Rheological time-sweep analysis demonstrates that increasing the diluent content significantly reduces complex viscosity and extends workability, thereby improving pumpability and flow for large-area applications. However, the targeted 2-hour processing window is not fully achieved. Differential scanning calorimetry (DSC) confirms that all formulations cure at room temperature to glass transition temperatures ( T g ) at least 20 °C above the maximum DST operating temperature (27 °C), thereby ensuring service in the glassy regime. Dynamic mechanical analysis (DMA) reveals formulation-dependent reductions in tan delta and increases in storage modulus, indicating increasingly elastic and mechanically stable networks with diluent incorporation. Pull-off adhesion testing shows that modified formulations (70–90% Westlake epoxy) exhibit significantly higher adhesion strengths than the unmodified system. Grout cohesive failure indicates that interfacial bonding exceeds substrate strength. Collectively, these results demonstrate that controlled reactive diluent incorporation enables optimization of processing behavior, interfacial adhesion, and thermomechanical performance, supporting the suitability of the modified epoxy systems as durable sealant layers for cementitious barrier applications in hazardous waste containment infrastructure.

Differential scanning calorimetry↗

DOE OSTI2023

Evaluation of High Level Waste Sludge Processing Behavior

The U.S. Department of Energy’s (DOE) Hanford Site has 177 underground storage tanks that contain wastes from past nuclear fuel reprocessing and waste-management operations. Over 20% of this waste is in the form of an insoluble sludge that will require slurry modification before its transfer to the Waste Treatment and Immobilization Plant (WTP). Specific WTP acceptance criteria for waste feed delivery describe the physical and chemical characteristics of the waste that must be met before the waste is transferred to the WTP. One challenging requirement relates to the undissolved solids (UDS) composition in a waste feed because the waste contains solid particles that settle, and their concentration and relative proportion can change during the transfer of the waste in individual batches. A key uncertainty is the ability to transfer and mix wastes with large variations in UDS concentrations and resulting settling rates. To address this uncertainty, a number of small scale mixing and settling tests have been conducted to determine the mobilization performance of variable chemistry simulants. Comparison of the size and density of the particulate for each simulant to that of southeast area Hanford sludge was made using metrics for particle mobilization, suspension, settling, and pipeline transfer where dependance on particle size and density may be different, including: 1. Settling velocity, 2. Critical shear stress for erosion, 3. Just-suspended impeller speed, and 4. Pipeline critical transport velocity. Existing high-level waste sludge data has shown the effect that increasing Al concentration has on resulting settled solids. This differential settling of particles in the sludge has the possibility of resulting in solids segregation during feed preparation and uneven particle distribution during pipeline transportation or mixer jet pump operations. Understanding the predictive capabilities of HLW solids settling and transport as well as potential remedies for addressing disparate sludge behaviors can help provide technical guidance during HLW flowsheet planning.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Experimental Evaluation of Thermal Storage Performance of a Dual-Purpose Underground Thermal Battery

A geothermal heat pump (GHP) system is an energy-efficient building heating and cooling technology with great potential for reducing energy consumption and decarbonization. However, applications of GHP are still limited due to the high cost, of which 30% is related to the cost of installing the conventional vertical bore ground heat exchangers, which are usually installed in boreholes 60 meters deep. A dual-purpose underground thermal battery (DPUTB) has been developed to offer a low-cost ground heat exchanger with a built-in thermal storage capacity. The DPUTB innovatively integrates a shallow-bore ground heat exchanger (the outer tank), which can be installed in a borehole less than 6 m deep, with thermal energy storage (TES) (the inner tank). DPUTB has the potential to reduce the cost of a ground source heat pump system while allowing shifting the electric demand of the building served by the GHP system from peak to off-peak hours of the electric grid by charging and discharging the thermal storage. A lab-scale (1:125 in volume) DPUTB prototype was built. Phase change material (PCM) was added to increase the thermal storage capacity and maintain the supply water temperature from the TES within the desired range for direct cooling operation during the discharge period. As PCMs are critical to the TES performance of the DPUTB, this study compared the influence of different PCMs (including salt hydrate and organic PCMs) on the discharge performance of the DPUTB. The thermal State of Charge (SoC) of the DPUTB was used to compare the performance resulting from using different PCMs. Test results indicate that the organic PCM (Methyl Laurate) outperforms salt-hydrate PCMs due to a lower melting temperature and a narrower melting temperature range during the phase change process. The results of this study provide a guide for PCM selection and the optimal design of DPUTB.

Wang, Lingshi↗

DOE OSTI2023

Modeling Assessment of Residential Air-to-Water Heat Pumps Coupled with Cooling Thermal Storage

This study explored the performance and operating cost viability of air-to-water heat pumps (AWHPs) coupled with thermal energy storage (TES) in efficient new residential construction. AWHPs are an emerging technology in this country, but offer promise in terms of high efficiency, fully contained and factory charged outdoor refrigeration system, and hydronic delivery capabilities, which facilitates zoning, ducts in conditioned space, and TES integration for summer load-shifting. Although this AWHP+TES strategy is not yet mainstream, the authors feel that in ten years as decarbonization efforts proceed and TOU rates become more common, strategies such as this will be more accessible. Validated EnergyPlus simulation models were developed based on detailed monitoring data collected over several years at Pacific Gas and Electric's CVRH laboratory test homes located in Stockton, California. One of the CVRH test homes (1,962 ft 2 two-story) had been testing various AWHP systems and configurations over the past six years. The validated model was then updated with high efficiency IECC ZERH envelope and component requirements for climate zones 1-5, including ducts in conditioned space thermal distribution. Simulations were completed for the 1,962 ft 2 home in each climate zone for a minimum efficiency ASHP, an AWHP coupled with a fan coil, and an AWHP coupled with TES sized to eliminate summer on-peak compressor operation. To maintain consistency in reporting energy use estimates, all cases were run with a similar indoor thermostat control strategy to pre-cool the house below the nominal 76 degrees Fahrenheit set point prior to the on-peak period and float slightly above the set point during the peak period. The AWHP+TES configuration was controlled to alternately condition the indoor space or to charge the TES tanks prior to the beginning of the on-peak. Three composite TOU rates were developed based on existing TOU rates across the U.S. to provide differing economic scenarios to evaluate customer bill impacts throughout the summer. Two of the TOU rates had short three-hour peak periods, while the third rate had a longer seven-hour duration peak period. AWHP modeling projections were based on the observed field performance of the Chiltrix CX34 variable speed unit. Other products on the market or entering the market in the near term would likely perform differently.

25 ENERGY STORAGE↗

DOE OSTI2021

Wear in particle based CSP systems from particle abrasion and attrition at high temperature

High temperature particle-based receivers offer distinct advantages over conventional molten salt receivers due to their ability to achieve temperatures above 700 ºC, direct absorption of solar energy as they fall through a beam of concentrated sunlight, and the relative ease of storage (and retrieval using a secondary working fluid) in insulated storage tanks. The use of particles, however, also raises concerns with material degradation from the flow of hot or cold particles through discharge hoppers or along the inner receiver surfaces and other system components (e.g. tubes, valves etc.), depending on operating mode of the receiver. The flow of particles over surfaces may result in loss of material from abrasive wear, impact erosion from impingement under gravitational fall and particle attrition as particles fall and move on top of each other. In the present study, the performance of candidate materials and particles were evaluated through a series of abrasion erosion and particle attrition experiments at room temperature as well as at 800 °C. Candidate materials were subject to abrasive wear from particles at low particle to material velocities inside a resistance heated kiln, and analyzed for changes in mass and surface morphology using cross-sectional scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS) tests. The wear rate for different specimens was noted to be largely driven by the strength of chromia scales built on the specimens from exposure to high temperature. Particle attrition measurements explored the susceptibility of particles to breakdown from particle to particle interaction and the generation of fines from this process. At the low velocities expected in particle based CSP plants, the particles tested exhibited near negligible breakdown. However, changes in the particle hardness at 800 ºC resulted in a significantly higher particle breakdown to sizes <40 microns raising potential environmental concerns. In addition to particle breakdown, it was also noted that the sample had oxides from the stainless steel test setup mixed in with the particles. Similar oxides can be expected to turn up in the utility scale particle based CSP plants as well. The presence of oxide was also noted to affect the solar absorptivity of the mixture compared to a clean initial specimen, potentially resulting in a change in the overall efficiency of the CSP plant.

14 SOLAR ENERGY↗

DOE OSTI2026

Spectrograph stabilization using a single-delay interferometer on the Hale Telescope

We describe a technique for spectrograph stabilization useful when conventional mitigation techniques of vacuum tanks, thermal insulation, and laser frequency comb may be impractical, expensive, heavy, or bulky. This includes spectrographs on airborne platforms or mounted on telescopes where they suffer a changing gravity vector or other drifts. Placing a fixed-delay interferometer in series with a spectrograph forms an externally dispersed interferometer (EDI). This produces a uniform sinusoidal comb multiplying input spectrum, creating (through heterodyning) beats (moiré patterns). In Fourier space for low frequencies up to the comb frequency, the moiré generated signal counter-rotates to ordinary spectra under an unknown disperser wavenumber drift Δx. This generates a large negative feedback signal useful in a conceptual control loop, to converge rapidly to a stable spectrum and yield Δx. A modified EDI data analysis algorithm (“crossfading”) combines frequency-weighted moiré with conventional spectrum to cancel net output spectrum reaction to Δx. Needing only a single-delay, this is a practical improvement over prior crossfading analyses requiring multiple delays. We test crossfading on ThAr data near 4850 cm−1 taken on Hale telescope in an earlier project. In a single pass, we reduce drift 20 times. Using seven iterations, we reduce 0.5 cm−1 (31 km/s Doppler equivalent) drift to 4×10−7 cm−1 (2.5 cm/s). The interferometer delay can wander, because linearity of phase versus wavenumber interpolates science features between bracketing calibrating spectral references. Second, mathematically reversing the heterodyning effect doubles effective spectral resolution without changing disperser slit.

Erskine, David J [Lawrence Livermore National Labo↗