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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 505 records · Page 28
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Micromechanics analysis of space simulated thermal deformations and stresses in continuous fiber reinforced composites

Space simulated thermally induced deformations and stresses in continuous fiber reinforced composites were investigated with a micromechanics analysis. The investigation focused on two primary areas. First, available explicit expressions for predicting the effective coefficients of thermal expansion (CTEs) for a composite were compared with each other, and with a finite element (FE) analysis, developed specifically for this study. Analytical comparisons were made for a wide range of fiber/matrix systems, and predicted values were compared with experimental data. The second area of investigation focused on the determination of thermally induced stress fields in the individual constituents. Stresses predicted from the FE analysis were compared to those predicted from a closed-form solution to the composite cylinder (CC) model, for two carbon fiber/epoxy composites. A global-local formulation, combining laminated plate theory and FE analysis, was used to determine the stresses in multidirectional laminates. Thermally induced damage initiation predictions were also made.

Bowles, David E.↗
DOE OSTI2022

A behavior and physiology-based decision support tool to predict thermal comfort and stress in non-pregnant, mid-gestation, and late-gestation sows

Background: Although thermal indices have been proposed for swine, none to our knowledge differentiate by reproductive stage or predict thermal comfort using behavioral and physiological data. The study objective was to develop a behavior and physiology-based decision support tool to predict thermal comfort and stress in multiparous (3.28 ± 0.81) non-pregnant (n = 11), mid-gestation (n = 13), and late-gestation (n = 12) sows. Results: Regression analyses were performed using PROC MIXED in SAS 9.4 to determine the optimal environmental indicator [dry bulb temperature (T DB ) and dew point] of heat stress (HS) in non-pregnant, mid-gestation, and late-gestation sows with respiration rate (RR) and body temperature (T B ) successively used as the dependent variable in a cubic function. A linear relationship was observed for skin temperature (T S ) indicating that TDB rather than the sow HS response impacted TS and so TS was excluded from further analyses. Reproductive stage was significant for all analyses (P < 0.05). Heat stress thresholds for each reproductive stage were calculated using the inflections points of RR for mild HS and T B for moderate and severe HS. Mild HS inflection points differed for non-pregnant, mid-gestation, and late gestation sows and occurred at 25.5, 25.1, and 24.0 °C, respectively. Moderate HS inflection points differed for non-pregnant, mid-gestation, and late gestation sows and occurred at 28.1, 27.8, and 25.5 °C, respectively. Severe HS inflection points were similar for non-pregnant and mid-gestation sows (32.9 °C) but differed for late-gestation sows (30.8 °C). These data were integrated with previously collected behavioral thermal preference data to estimate the T DB that non-pregnant, mid-gestation, and late-gestation sows found to be cool (T DB < T DB preference range), comfortable (T DB = T DB preference range), and warm (T DB preference range < T DB < mild HS). Conclusions: The results of this study provide valuable information about thermal comfort and thermal stress thresholds in sows at three reproductive stages. The development of a behavior and physiology-based decision support tool to predict thermal comfort and stress in non-pregnant, mid-gestation, and late-gestation sows is expected to provide swine producers with a more accurate means of managing sow environments.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1984

The slab geometry laser. I - Theory

Slab geometry solid-state lasers offer significant performance improvements over conventional rod-geometry lasers. A detailed theoretical description of the thermal, stress, and beam-propagation characteristics of a slab laser is presented. The analysis includes consideration of the effects of the zig-zag optical path, which eliminates thermal and stress focusing and reduces residual birefringence.

Eggleston, J. M.↗
DOE OSTI2019

Performance of Composite Insulators Used for Electric Transmission under Extreme Climatic Conditions

Composite or polymeric insulators are being used in various parts of the world for high-voltage transmission and distribution lines. In some parts of India, places in the states like Rajasthan and Gujarat experience an increase in the daytime temperature up to 50 °C, while the nighttime temperature reduces as low as 3-5 °C. Because of these extreme temperature variations along with electric stress and humidity conditions, composite insulators have to perform well over their lifetime to ensure the reliability of the transmission network. In the present work, experimental conditions are simulated with temperature variation from 50 to 3-5 °C along with electrical stress, humidity variation, pollution, and ultraviolet radiations. Accelerated aging studies with these stresses are conducted to understand the degradation on the insulator similar to the field conditions. Surface resistivity measurements, leakage current analysis, and surface degradation studies using thermogravimetric analysis, scanning electron microscopy, energy-dispersive x-ray, and Fourier transform infrared spectroscopy (FTIR) are conducted. Some interesting results obtained from the study are presented. Experimentation under extreme conditions with polluted insulators showed considerable degradation which was inferred from the material testing analysis. The insulator slabs on which electrical stress was not applied showed a considerable peak at 1500 cm{sup −1} in the FTIR spectra, indicating the generation of low molecular weight PDMS chains from the bulk due to UV aging and thermal stress, while the degradation pattern of non-polluted sample was severe compared to the slab treated but was considerably less severe in comparison with the polluted insulator sample exhibiting pollution can considerably increase degradation rate.

36 MATERIALS SCIENCE↗
NASA NTRS1980

Effect of thermal cycling on ZrO2-Y2O3 thermal barrier coatings

The paper studies the comparative life of plasma-sprayed ZrO2-Y2O3 thermal barrier coatings on NiCrAlY bond coats on Rene 41 in short (4 min) and long (57 min) thermal cycles at 1040 C in a 0.3-Mach flame. Attention is given to determining the effect of short- and long-duration cycles on ZrO2-Y2O3 coatings, the cause of any cycle frequency effects, and methods to improve tolerance to thermal stress. Short cycles greatly reduced the life of the ceramic coating in terms of time at temperatures as compared to longer cycles, the failed coating indicating compressive failure. The experiments and stress calculations show that repeatedly subjecting a ceramic coating to high rates of initial heating has a more destructive influence on the coating than sustained operation at temperature. The effect of such thermal compressive stresses might be minimized through coating deposition and thickness control and by turbine cycle measurement to keep starting heating rates below critical values.

Mcdonald, G.↗
NASA NTRS1991

Residual thermal strains and stresses in nickel aluminide matrix composites

Thermally induced residual strains and stresses developed during postfabrication cooling in Saphikon/NiAl and tungsten/NiAl high-temperature composites are investigated through three-dimensional elastoplastic finite-element analyses. Average axial and transverse strains in the matrix are found to be tensile and compressive, respectively, and similar for both Saphikon and W-fiber-reinforced NiAl composites. It is suggested that the residual matrix stresses and strains are controlled more by the low-matrix yield stress than by the fiber/matrix expansion mismatch. Residual thermal strains in the matrix of these composites are measured by using a neutron-diffraction technique; the measured axial and transverse strains in the matrix are found to be in agreement with the computed values.

Saigal, A.↗
DOE OSTI2017

On the detachment of thin ITO films from silicon substrate by microsecond laser irradiation

A method for the separation of thin ITO (indium-tin-oxide) films from a silicon substrate by pulsed laser irradiation is studied. The method enables the detachment of films with thicknesses of 360 nm and more without their destruction. The separation process consists in successive irradiation of the surface with single microsecond laser pulses at a wavelength of 650 nm. Upon being detached from silicon substrates, the films produced by high-frequency magnetron sputtering have a transmittance of 65% in the visible spectral range and a resistivity of ~1.2 kΩ/□. The thermal stresses appearing in thin ITO films and leading to their detachment are estimated.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Synthesis of Bio-Based Repairable Polyimines with Tailored Properties by Lignin Fractionation

Developing sustainable polymers with low-value lignin remains a challenge. Herein, lignin-containing repairable polyimines were synthesized with tailored properties using lignin fractionation. First, softwood Kraft lignin is fractionated into a more homogeneous fraction with a lower molecular weight and a higher OH content. Next, Kraft lignin and its fraction are esterified by levulinic acid to introduce active ketone groups and subsequently condensed with oleylamine (OAm) and bis(3-aminopropyl)-terminated polydimethylsiloxane (PDMS) via a catalyst-free Schiff-base reaction to form grafted lignin-OAm copolymers and cross-linked lignin-PDMS polymer networks (MKL-P and MFL-P), respectively. Results show that lignin-OAm polyimines can be self-repaired and hot reprocessed under pressure, while lignin-PDMS polyimines can be repaired with the assistance of a healing agent, heat, and pressure. Dynamic mechanical analyses demonstrate that the stress–relaxation behaviors of the polyimines follow the Arrhenius law under thermal-stress activation, indicating the occurrence of transimination. Moreover, compared with Kraft lignin, the lignin fraction ameliorates the grafting density of ketones and enhances the cross-linking density of lignin-PDMS polyimine networks. The higher cross-linking density of MFL-P leads to superior stress–relaxation activation energy, thermal stability, hydrophobicity, and light-shielding ability but inferior repairability and translucency. Finally, this work provides insights into the polymerization of lignin-based polymer networks and the potential application of lignin-PDMS polyimines for repairable, translucent, anti-UV, and hydrophobic coatings.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Flow sensing by buckling monitoring of electrothermally actuated double-clamped micro beams

We report on a flow sensing approach based on deflection monitoring of a micro beam buckled by the compressive thermal stress due to electrothermal Joule's heating. The air stream, convectively cooling the device, affects both the critical buckling values of the electric current and the postbuckling deflections of the structure. After calibration, the flow velocity can be obtained from the deflection measurements. The quasi-static responses of 1000 μm and 2000 μm long, 10 μm wide, and 30 μm high single crystal silicon beams were consistent with the prediction of the model, which couples thermoelectric, thermofluidic, and structural domains. The deflection sensitivity of up to 1.5 μm/(m/s) and the critical current sensitivity of up to 0.43 mA/(m/s) were registered in the experiments. Our model and experimental results demonstrate the feasibility of the sensing approach and further suggest that simple, robust, and potentially downscalable beam-type devices may have use in flow velocity and wall shear stress sensors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

Residual stresses in functionally graded thermal barrier coatings

Functionally graded materials offer potential as a solution to the premature failure of thermal barrier coatings due to thermal residual stresses, however this solution has not been fully evaluated to date. An analytical methodology based on the bending of plates has been used to model the residual stress distribution through the layers of a functionally graded (FG) cermet top coat-bond layer-substrate system after cooling from a high deposition temperature. The model is then applied to two material systems with different trends in variation in the coefficient of thermal expansion from the substrate to the top coat layer. Increasing the number of layers reduces the discrete stress variations across the interfaces through the FG layers and reduces the propensity of interfacial cracking. While the stress in the top coat is always compressive for the Inconel substrate, the stress in the top coat is tensile in nature for the steel substrate when the ceramic volume fraction in the functionally graded layers is low. The stress in the top coat gradually becomes compressive with an increasing volume fraction of ceramic in the functionally graded top coat. The curvature of the TBC system follows a similar trend and changes its sign with increasing ceramic content for the steel substrate. In conclusion, the effect of the number of layers on the curvature gradually diminishes and the curvature becomes constant beyond only a few layers.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Time-resolved X-ray diffraction studies of laser-induced acoustic wave propagation in bilayer metallic thin crystals

Phonon propagation across the interface of a Cu/Ag(111) bilayer and transient lattice disorder, induced by a femtosecond 267 nm pulse, in Ag(111) crystal have been measured by means of time resolved X-ray diffraction. A “blast” force due to thermal stress induced by suddenly heated electrons is formed within two picoseconds after excitation and its “blast wave” propagation through the interface and Ag (111) crystal was monitored by the shift and broadening of the rocking curve, I vs. ω, as a function of time after excitation. Lattice disorder, contraction and expansion as well as thermal strain formation and wave propagation have also been measured. The experimental data and mechanism proposed are supported by theoretical simulations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Preparation and Thermal Expansion of Calcium Iron Zirconium Phosphates with the NaZr{sub 2}(PO{sub 4}){sub 3} Structure

Ca{sub 0.5(1+} {sub x)}Zr{sub 2–x}Fe{sub x}(PO{sub 4}){sub 3} phosphates have been synthesized by a sol–gel process. The individual compounds and solid solutions obtained crystallize in the NaZr{sub 2}(PO{sub 4}){sub 3} structure (trigonal symmetry, sp. gr. R3̄). Using high-temperature X-ray diffraction, we have determined their thermal expansion parameters in the temperature range from 25 to 800°C. With increasing x, the magnitudes of their linear thermal expansion coefficients and thermal expansion anisotropy decrease. Most of the synthesized phosphates can be rated as low-thermal-expansion compounds and can be regarded as materials capable of withstanding thermal “stress.”.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Interdiffusion and stress development in single-crystalline Pd/Ag bilayers

Interdiffusion and stress evolution in single-crystalline Pd/single-crystalline Ag thin films were investigated by Auger electron spectroscopy sputter-depth profiling and in-situ X-ray diffraction, respectively. The concentration-dependent chemical diffusion coefficient, as well as the impurity diffusion coefficient of Ag in Pd could be determined in the low temperature range of 356 °C–455 °C. As a consequence of the similarity of the strong concentration-dependences of the intrinsic diffusion coefficients, the chemical diffusion coefficient varies only over three orders of magnitude over the whole composition range, despite the large difference of six orders of magnitude of the self-diffusion coefficients of Ag in Ag and Pd in Pd. It is shown that the Darken-Manning treatment should be adopted for interpretation of the experimental data; the Nernst-Planck treatment yielded physically unreasonable results. Apart from the development of compressive thermal stress, the development of stress in both sublayers separately could be ascribed to compositional stress (tensile in the Ag sublayer and compressive in the Pd sublayer) and dominant relaxation processes, especially in the Ag sublayer. The effect of these internal stresses on the values determined for the diffusion coefficients is shown to be negligible.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗