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NASA NTRS2003

A Study of the X-ray Source Population in the Dwarf Galaxy NGC 6822

The dlrr galaxy NGC 6822 is a distant member of the Local Group. It is a site of recent star formation, rich in HII regions and OB associations, as well as containing an older globular cluster population. We present results of a deep Chandra observation of NGC 6822. The brightest source is extended and most likely a SNR. In addition to spectral analysis of the brightest sources, we extend the luminosity function down to the 10(sup)35 erg/s range.

Tennant, Allyn F.↗

NASA NTRS2018

Laboratory Measurements of X-ray Emission from Highly Charged Argon Ions

Uncertainties in atomic models will introduce noticeable additional systematics in calculating the flux of weak dielectronic recombination (DR) satellite lines, affecting the detection and flux measurements of other weak spectral lines. One important example is the Ar xvii Heβ DR, which is expected to be present in emission from the hot intracluster medium of galaxy clusters and could impact measurements of the flux of the 3.5 keV line that has been suggested as a secondary emission from a dark matter interaction. We perform a set of experiments using the Lawrence Livermore National Laboratory's electron beam ion trap (EBIT-I) and the X-ray Spectrometer quantum calorimeter (XRS/EBIT) to test the Ar xvii Heβ DR origin of the 3.5 keV line. We measured the X-ray emission following resonant DR onto helium-like and lithium-like Argon using EBIT-I's Maxwellian simulator mode at a simulated electron temperature of T(e) = 1.74 keV. The measured flux of the Ar xvii Heβ DR lined is too weak to account for the flux in the 3.5 keV line, assuming reasonable plasma parameters. We, therefore, rule out Ar xvii Heβ DR as a significant contributor to the 3.5 keV line. A comprehensive comparison between the atomic theory and the EBIT experiment results is also provided.

Esra Bulbul↗

NASA NTRSDate not supplied

The Athena/X-IFU, from Detector Development to Scientific Feasibility Studies via Simulations

The investigation of the physical hot and energetic phenomena in the Universe will further improve our understanding of the assembly of the largest structures and massive halos of galaxies, and of the role of black holes in shaping the Universe as we see it. Spatially resolved X-ray high-resolution spectroscopy will be a crucial tool to achieve these scientific goals. The X-IFU instrument onboard the Athena observatory will provide us with these capabilities through the use of arrays of Transition edge microcalorimeters detectors. These superconducting devices will deliver the required exquisite spectral resolution needed to achieve the core science objectives, such as the characterization of turbulence and bulk motions in the hot gaseous atmospheres of groups and clusters of galaxies in order to unveil the process of large scale structures assembly. I will present the Transition Edge Sensors principle, the status of the instrumental development for the X-IFU instrument, and discuss their performance in view of the scientific objectives of the Athena mission. I will further present the case of a feasibility study and optimisation of the observing strategy for the characterization of the internal dynamics of the intra-cluster medium, through the use of mock simulations of observations with the X-IFU instrument.

Sophie Beaumont↗

NASA NTRSDate not supplied

NASA’s Prototype Spectral Water Inversion Processor and Emulator (SWIPE): Towards Global Coastal and Inland Water Quality and Algal Biodiversity Monitoring

Degradation of Earth’s inland water resources due to anthropogenic perturbations and climate anomalies at both local and global scales continues to place human health at substantial risk. There is now a growing necessity to develop pragmatic approaches that allow timely and effective extrapolation of local processes, to spatially resolved global products, and to promote operational and sustainable resource policy management. This presentation will provide updates on NASA’s prototype open-source aquatic modeling platform, Spectral Water Inversion Processor and Emulator (SWIPE), which is a comprehensive, multi-faceted modeling platform for both forward and inverse modeling of diverse aquatic ecosystems from the benthos to top-of-atmosphere (TOA). SWIPE provides a cohesive application which leverages recent advancements in particle modeling, Big Data analytics, and machine learning to develop a high-fidelity synthetic training ground for sensitivity studies and algorithm development for multispectral or upcoming hyperspectral missions. Some of the prominent features of SWIPE to be discussed include: 1. Advanced hyperspectral modeling of globally diverse algal and non-algal particles using a novel two-layer coated sphere scattering model and radiative transfer modeling, 2. Massive, highly detailed synthetic spectral libraries of Analysis-Ready-Data (ARD) which include spectral libraries of particle microphysics, water biogeophysical and optical properties, as well as surface and TOA reflectances at 1 nm resolution, 3. An ensemble of pre-built analytic, machine learning, and deep learning inversion algorithms for various water quality and biodiversity related retrieval parameters and uncertainty quantification, 4. Sensor-agnostic water quality inversion at wide ranging spatial and spectral resolutions including a codebase for seamless application in the Google Earth Engine and NASA Earth Exchange (NEX) for planetary scale analysis. SWIPE will be a fully open-source platform based in python with comprehensive documentation, tutorials, and options for distributed computing on high performance computing clusters or on single, local machines. Further, we will discuss how we envision SWIPE contributing towards a global analysis of coastal and inland water quality dynamics.

top-of-atmosphere (TOA)↗

NASA NTRSDate not supplied

Ramdb: The NASA Raman Spectral Database (version 1.00).

Given that, in most instances, minimal sample preparation is required and due to its contactless instrument design, Raman spectroscopy is one of the most versatile vibrational spectroscopic techniques for the chemical analysis of environmental and biological specimens. The diversity of applications of Raman spectroscopy ranges anywhere from art [1] to planetary science missions [2]. The advancement in the use of Raman spectroscopy in Solar System missions, notably in post-mission sample return analysis, requires a spectral library holding the broad range of specimens that could be found in Solar System sources. For this purpose, we have initiated the development of a Raman spectral database (Ramdb) at NASA Ames Research Center. Currently, the database includes experimental and theoretical Raman spectra of PAHs [3, 4], as well as laboratory Raman spectra of amino acids, carbon allotropes, minerals, and analogs relevance to Earth Sciences [5], Exobiology [6], Planetary [7], and Astrochemistry [8] to name just a few examples. Ramdb can be found on the web at www.astrochemistry.org/ramdb, where raw and processed Raman spectra can be downloaded in CSV format. The laboratory Raman spectra are measured using a laser Raman spectrometer (JASCO NRS-5500-532QRI). The Raman instrument is equipped with three excitation lasers, with wavelengths of 405, 532, and 785 nm. A clean silicon substrate is used as the internal standard for wavenumber calibration. Powdered samples were prepared (microscopic >10 um, grounded microscopic < 10 um) on glass slides. Some raw data exhibited a background signal arising as a combination of laser-induced fluorescence from the sample. To correct this background, we developed a Python pipeline that uses open-source Python libraries. Ramdb provides both raw and processed (using Python pipeline) data, which includes tabulated Raman shift transitions and other measurement details. The theoretical Raman band positions of PAHs (pyrene monomers and tetramer clusters) were computed using density functional theory (DFT) with the help of the Gaussian 16 suite of programs [9]. In the near future, Ramdb will serve as a repository of Raman spectral data from Laboratory Astrophysics and Planetary Science experiments involving the irradiation of organic compounds under simulated space and planetary conditions. In addition, online and offline tools will be developed for utilising the database for comparison to the user’s sample.

N Punnakayathil↗

DOE OSTI2022

The MeerKAT Galaxy Cluster Legacy Survey I. Survey Overview and Highlights

MeerKAT’s large number (64) of 13.5 m diameter antennas, spanning 8 km with a densely packed 1 km core, create a powerful instrument for wide-area surveys, with high sensitivity over a wide range of angular scales. The MeerKAT Galaxy Cluster Legacy Survey (MGCLS) is a programme of long-track MeerKAT L-band (900–1670 MHz) observations of 115 galaxy clusters, observed for ~6–10 h each in full polarisation. The first legacy product data release (DR1), made available with this paper, includes the MeerKAT visibilities, basic image cubes at ~8" resolution, and enhanced spectral and polarisation image cubes at ~8" and 15" resolutions. Typical sensitivities for the full-resolution MGCLS image products range from ~3–5 μJy beam –1 . The basic cubes are full-field and span 2° × 2°. The enhanced products consist of the inner 1.2° × 1.2° field of view, corrected for the primary beam. The survey is fully sensitive to structures up to ~10' scales, and the wide bandwidth allows spectral and Faraday rotation mapping. Relatively narrow frequency channels (209 kHz) are also used to provide H I mapping in windows of 0 < z < 0.09 and 0.19 < z < 0.48. Here, in this paper, we provide an overview of the survey and the DR1 products, including caveats for usage. We present some initial results from the survey, both for their intrinsic scientific value and to highlight the capabilities for further exploration with these data. These include a primary-beam-corrected compact source catalogue of ~626 000 sources for the full survey and an optical and infrared cross-matched catalogue for compact sources in the primary-beam-corrected areas of Abell 209 and Abell S295. We examine dust unbiased star-formation rates as a function of cluster-centric radius in Abell 209, extending out to 3.5 R 200 . We find no dependence of the star-formation rate on distance from the cluster centre, and we observe a small excess of the radio-to-100 μm flux ratio towards the centre of Abell 209 that may reflect a ram pressure enhancement in the denser environment. We detect diffuse cluster radio emission in 62 of the surveyed systems and present a catalogue of the 99 diffuse cluster emission structures, of which 56 are new. These include mini-halos, halos, relics, and other diffuse structures for which no suitable characterisation currently exists. We highlight some of the radio galaxies that challenge current paradigms, such as trident-shaped structures, jets that remain well collimated far beyond their bending radius, and filamentary features linked to radio galaxies that likely illuminate magnetic flux tubes in the intracluster medium. We also present early results from the H I analysis of four clusters, which show a wide variety of H I mass distributions that reflect both sensitivity and intrinsic cluster effects, and the serendipitous discovery of a group in the foreground of Abell 3365.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1988

An assessment of AVIRIS data for hydrothermal alteration mapping in the Goldfield Mining District, Nevada

Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) data were acquired over the Goldfield Mining District, Nevada, in September 1987. Goldfield is one of the group of large epithermal precious metal deposits in Tertiary volcanic rocks, associated with silicic volcanism and caldera formation. Hydrothermal alteration consists of silicification along fractures, advanced agrillic and argillic zones further away from veins and more widespread propylitic zones. An evaluation of AVIRIS data quality was performed. Faults in the data, related to engineering problems and a different behavior of the instrument while on-board the U2, were encountered. Consequently, a decision was made to use raw data and correct them only for dark current variations and detector read-out-delays. New software was written to that effect. Atmospheric correction was performed using the flat field correction technique. Analysis of the data was then performed to extract spectral information, mainly concentrating on the 2 to 2.45 micron window, as the alteration minerals of interest have their distinctive spectral reflectance features in this region. Principally kaolinite and alunite spectra were clearly obtained. Mapping of the different minerals and alteration zones was attempted using ratios and clustering techniques. Poor signal-to-noise performance of the instrument and the lack of appropriate software prevented the production of an alteration map of the area. Spectra extracted locally from the AVIRIS data were checked in the field by collecting representative samples of the outcrops.

Carrere, Veronique↗

NASA NTRS1991

Land cover stratification using Landsat Thematic Mapper data in Sahelian and Sudanian woodland and wooded grassland

A standard methodology for thematic mapping of natural vegetation using remotely sensed imagery and digital image processing was modified to account for the spatial and spectral properties of semi-arid landscapes, and tested in study areas in the Sahelian and Sudanian zones, Mali. A principal components transformation of registered wet and dry season Landsat TM images produced a set of synthetic spectral channels differentiating vegetation cover between seasons, and allowed areas with annual grass growth to be distinguished from areas with woody cover. The transformed data were statistically clustered and clusters were assigned to vegetation type and density categories. In a separate step, the images were manually interpreted to differentiate broad soil classes. Four statistics were compared to evaluate the accuracy of the maps based on sample points from air photos. For the relatively detailed categories initially defined, map accuracies were substandard; however, when vegetation density classes were aggregated, overall accuracy was around 90 percent, and class accuracy was greater than 80 percent for most classes. This method is suitable for stratification and inventory of woody biomass at a regional scale in semi-arid woodland and wooded grassland.

Franklin, J.↗

DOE OSTI2022

The Effect of Geometry, Spin, and Orbital Optimization in Achieving Accurate, Correlated Results for Iron–Sulfur Cubanes

Iron–sulfur clusters comprise an important functional motif in the catalytic centers of biological systems, capable of enabling important chemical transformations at ambient conditions. This remarkable capability derives from a notoriously complex electronic structure that is characterized by a high density of states that is sensitive to geometric changes. The spectral sensitivity to subtle geometric changes has received little attention from correlated, large active space calculations, owing partly to the exceptional computational complexity for treating these large and correlated systems accurately. Here, to provide insight into this aspect, we report the first Complete Active Space Self Consistent Field (CASSCF) calculations for different geometries of the [Fe(II/III) 4 S 4 (SMe) 4 ] -2 clusters using two complementary, correlated solvers: spin-pure Adaptive Sampling Configuration Interaction (ASCI) and Density Matrix Renormalization Group (DMRG). We find that the previously established picture of a double-exchange driven magnetic structure, with minute energy gaps (<1 mHa) between consecutive spin states, has a weak dependence on the underlying geometry. However, the spin gap between the singlet and the spin state 2S + 1 = 19, corresponding to a maximal number of Fe-d electrons being unpaired and of parallel spin, is strongly geometry dependent, changing by a factor of 3 upon slight deformations that are still within biologically relevant parameters. The CASSCF orbital optimization procedure, using active spaces as large as 86 electrons in 52 orbitals, was found to reduce this gap compared to typical mean-field orbital approaches. Our results show the need for performing large active space calculations to unveil the challenging electronic structure of these complex catalytic centers and should serve as accurate starting points for fully correlated treatments upon inclusion of dynamical correlation outside the active space.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1994

Geometry and Unoccupied Electronic States of Ba and BaO on W(001)

A study aimed at understanding the geometrical and electronic properties of barium and oxygen coadsorbed on the tungsten(001) surface has been carried out by means of work-function measurements (Delta-phi), Auger-electron spectroscopy, low-energy electron diffraction, inverse photoelectron spectroscopy, and relativistic-electronic-structure calculations. A report of the experimental measurements and a comparison with theoretical results from embedded-cluster-model calculations are presented. Our experimental studies show that the work function of the W(001) surface (phi = 4.63 eV) is lowered to approximately 2.3-2.4 eV by coadsorption of 1 ML of Ba and O regardless of the order of deposition of these two species. The technique of IPS in the isochromat mode was used to determine the unoccupied electronic-energy band structure for ordered c (2 X 2) Ba and O layers on W(001). Several spectral features are observed above the Fermi level (E(F)), which we assign to transitions into Ba and W d-states. The measured two-dimensional electronic band structure is independent of the order of Ba and O deposition. Using embedded-cluster-model calculations, we investigated two possible adsorption configurations of an ordered c(2 X 2) adlayer of Ba and O on W(001): 'tilted,' where Ba and O are placed on alternate fourfold-hollow sites, and 'upright,' where the adsorbed atoms lay above the same site with Ba outer-most. The calculated densities of states for the tilted geometry show distinct peaks above E(F) originating from Ba and W d-orbitals and are in good agreement with the experimental results.

Lamouri, A.↗

DOE OSTI2025

Introducing the SLICE Method for estimating pebble-bed reactor inventories at equilibrium operation with SCALE

This paper introduces the SCALE Leap-In method for Cores at Equilibrium (SLICE) for estimating pebble-bed reactor equilibrium core isotopic inventories using capabilities in the SCALE code system, requiring only a small computational cluster and a few days of computation. This method uses an iterative approach that relies on (1) a surrogate spectrum model that captures spatial and time-dependent spectral conditions, (2) a multi-pass model that captures the pebble’s evolving nuclide inventory as a function of location and time in the core, and (3) a full-core model that captures the core’s spatial neutron flux distribution. The SLICE approach is applied to a generic fluoride salt–cooled high-temperature reactor, demonstrating fuel inventory convergence through nuclide concentration inspection across iterations and comparisons for core realizations with varying discretizations. Results agree within ~5% with another state-of-the-art code, with differences attributed to input parameter or modeling assumption variations in the equilibrium generation methods.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

NASA NTRS1985

Balloon-borne three-meter telescope for far-infrared and submillimeter astronomy

Presented are scientific objectives, engineering analysis and design, and results of technology development for a Three-Meter Balloon-Borne Far-Infrared and Submillimeter Telescope. The scientific rationale is based on two crucial instrumental capabilities: high angular resolution which approaches eight arcseconds at one hundred micron wavelength, and high resolving power spectroscopy with good sensitivity throughout the telescope's 30-micron to 1-mm wavelength range. The high angular resolution will allow us to resolve and study in detail such objects as collapsing protostellar condensations in our own galaxy, clusters of protostars in the Magellanic clouds, giant molecular clouds in nearby galaxies, and spiral arms in distant galaxies. The large aperture of the telescope will permit sensitive spectral line measurements of molecules, atoms, and ions, which can be used to probe the physical, chemical, and dynamical conditions in a wide variety of objects.

Fazio, G. G.↗

NASA NTRS1995

Massive black holes and light-element nucleosynthesis in a baryonic universe

We reexamine the model proposed by Gnedin & Ostriker (1992) in which Jeans mass black holes (M(sub BH) approximately = 10(exp 6) solar mass) form shortly after decoupling. There is no nonbaryonic dark matter in this model, but we examine the possibility that Omega(sub b) is considerably larger than given by normal nucleosynthesis. Here we allow for the fact that much of the high baryon-to-photon ratio material will collapse leaving the universe of remaining material with light-element abundances more in accord with the residual baryonic density (approximately = 10(exp -2)) than with Omega(sub 0) and the initial baryonic density (approximately = 10(exp -1)). We find that no reasonable model can be made with random-phase density fluctuations, if the power on scales smaller than 10(exp 6) solar mass is as large as expected. However, phase-correlated models of the type that might occur in connection with topological singularities can be made with Omega(sub b) h(exp 2) = 0.013 +/- 0.001, 0.15 approximately less than Omega(sub 0) approximately less than 0.4, which are either flat (Omega(sub lambda) = 1 - Omega(sub 0)) or open (Omega(sub lambda) = 0) and which satisfy all the observational constraints which we apply, including the large baryon-to-total mass ratio found in the X-ray clusters. The remnant baryon density is thus close to that obtained in the standard picture (Omega(sub b) h(exp 2) = 0.0125 +/- 0.0025; Walker et al. 1991). The spectral index implied for fluctuations in the baryonic isocurvature scenario, -1 less than m less than 0, is in the range expected by other arguments based on large-scale structure and microwave fluctuation constraints. The dark matter in this picture is in the form of massive black holes. Accretion onto them at early epochs releases high-energy photons which significantly heat and reionize the universe. But photodissociation does not materially change light-element abundances. A typical model gives bar-y approximately = 1 x 10(exp -5), n(sub e)/n(sub H)(z = 30) approximately = 0.1, and a diffuse gamma-ray background at 100 keV near the Cosmic Background Explorer Satellite (COBE) limit of the order of 10% of that observed which originates from high-redshift quasars. Reionization in this model occurs at redshift 600 and reaches (H II/H(sub tot) approximately = 0.1-0.2.

Gnedin, Nickolay Y.↗

NASA NTRS1995

Color evolution from z = 0 to z = 1

Rest frame Stroemgren photometry (3500 A, 4100 A, 4750 A, and 5500 A) is presented for 509 galaxies in 17 rich clusters between z = 0 and z = 1 as a test of color evolution. Our observations confirm a strong, rest frame, Butcher-Oemler effect where the fraction of blue galaxies increases from 20% at z = 0.4 to 80% at z = 0.9. We also find that a majority of these blue cluster galaxies are composed of normal disk or post-starburst systems based on color criteria. When comparing our colors to the morphological results from Hubble Space Telescope HST imaging, we propose that the blue cluster galaxies are a population of late-type, low surface brightness objects which fade and are then destroyed by the cluster tidal field. After isolating the red objects from Butcher-Oemler objects, we have compared the mean color of these old, non-star-forming objects with spectral energy distribution models in the literature as a test for passive galaxy evolution in ellipticals. We find good agreement with single-burst models which predict a mean epoch of galaxy formation at z = 5. Tracing the red envelope for ellipticals places the earliest epoch of galaxy formation at z = 10.

Rakos, Karl D.↗

NASA NTRS2009

X-Ray Calorimeter Arrays for Astrophysics

High-resolution x-ray spectroscopy is a powerful tool for studying the evolving universe. The grating spectrometers on the XMM and Chandra satellites started a new era in x-ray astronomy, but there remains a need for instrumentation that can provide higher spectral resolution with high throughput in the Fe-K band (around 6 keV) and can enable imaging spectroscopy of extended sources, such as supernova remnants and galaxy clusters. The instrumentation needed is a broad-band imaging spectrometer - basically an x-ray camera that can distinguish tens of thousands of x-ray colors. The potential benefits to astrophysics of using a low-temperature calorimeter to determine the energy of an incident x-ray photon via measurement of a small change in temperature was first articulated by S. H. Moseley over two decades ago. In the time since, technological progress has been steady, though full realization in an orbiting x-ray telescope is still awaited. A low-temperature calorimeter can be characterized by the type of thermometer it uses, and three types presently dominate the field. The first two types are temperature-sensitive resistors - semiconductors in the metal-insulator transition and superconductors operated in the superconducting-normal transition. The third type uses a paramagnetic thermometer. These types can be considered the three generations of x-ray calorimeters; by now each has demonstrated a resolving power of 2000 at 6 keV, but only a semiconductor calorimeter system has been developed to spaceflight readiness. The Soft X-ray Spectrometer on Astro-H, expected to launch in 2013, will use an array of silicon thermistors with I-IgTe x-ray absorbers that will operate at 50 mK. Both the semiconductor and superconductor calorimeters have been implemented in small arrays, kilo-pixel arrays of the superconducting calorimeters are just now being produced, and it is anticipated that much larger arrays will require the non-dissipative advantage of magnetic thermometers.

Kilbourne, Caroline A.↗

NASA NTRS2016

Search for Spectral Irregularities due to Photon-Axionlike-Particle Oscillations with the Fermi Large Area Telescope

We report on the search for spectral irregularities induced by oscillations between photons and axion-like particles (ALPs) in the gamma-ray spectrum of NGC 1275, the central galaxy of the Perseus cluster. Using 6 years of Fermi Large Area Telescope data, we find no evidence for ALPs and exclude couplings above 5 times 10 (sup -12) per gigaelectronvolt for ALP masses less than or approximately equal to 0.5 apparent magnitude (m (sub a)) less than or approximately equal to 5 nanoelectronvolts at 95 percent confidence. The limits are competitive withthe sensitivity of planned laboratory experiments, and, together with other bounds, strongly constrain thepossibility that ALPs can reduce the gamma-ray opacity of the Universe.

Ajello, M.↗

DOE OSTI2026

Hyaloscypha finlandica Metabolome Repository

This repository provides the curated data tables, manuscript figure and table exports, dependency records, and workflow scripts supporting an integrated comparative genomics and untargeted LC-MS/MS metabolomics analysis of Hyaloscypha finlandica strain PMI 746, a root-associated dark septate endophyte of poplar. The repository includes genome-mining summaries from antiSMASH, FunBGCeX, BGC-Prophet, and BiG-SCAPE; processed metabolomics inputs; metabolite annotation evidence; statistical outputs; and publication-facing figures and tables. Raw LC-MS/MS spectra, full genome/protein downloads, and large generated tool outputs are referenced through public archive/accession records and are not stored in Git.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRS1974

ERTS-1 imagery and native plant distributions

A method is developed for using ERTS spectral signature data to determine plant community distribution and phenology without resolving individual plants. An Exotech ERTS radiometer was used near ground level to obtain spectral signatures for a desert plant community, including two shrub species, ground covered with live annuals in April and dead ones in June, and bare ground. It is shown that comparisons of scene types can be made when spectral signatures are expressed as a ratio of red reflectivity to IR reflectivity or when they are plotted as red reflectivity vs. IR reflectivity, in which case the signature clusters of each component are more distinct. A method for correcting and converting the ERTS radiance values to reflectivity values for comparison with ground truth data is appended.

Musick, H. B.↗