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Highlights of the Version 8 SBUV and TOMS Datasets Released at this Symposium

Last October was the 25th anniversary of the launch of the SBUV and TOMS instruments on NASA's Nimbus-7 satellite. Total Ozone and ozone profile datasets produced by these and following instruments have produced a quarter century long record. Over time we have released several versions of these datasets to incorporate advances in UV radiative transfer, inverse modeling, and instrument characterization. In this meeting we are releasing datasets produced from the version 8 algorithms. They replace the previous versions (V6 SBUV, and V7 TOMS) released about a decade ago. About a dozen companion papers in this meeting provide details of the new algorithms and intercomparison of the new data with external data. In this paper we present key features of the new algorithm, and discuss how the new results differ from those released previously. We show that the new datasets have better internal consistency and also agree better with external datasets. A key feature of the V8 SBUV algorithm is that the climatology has no influence on inter-annual variability and trends; it only affects the mean values and, to a limited extent, the seasonal dependence. By contrast, climatology does have some influence on TOMS total O3 trends, particularly at large solar zenith angles. For this reason, and also because TOMS record has gaps, md EP/TOMS is suffering from data quality problems, we recommend using SBUV total ozone data for applications where the high spatial resolution of TOMS is not essential.

Bhartia, Pawan K.↗

Self Validation of Radiance Measurements from the CERES (TRMM)Instrument

Eight continuous months of earth-nadir-viewing radiance measurements from the 3-channel Tropical Rainfall Measuring Mission (TRMM,) Clouds and the Earth's Radiant Energy System (CERES) scanning radiometric measurement instrument, have been analyzed. While previous remote sensing satellites, such as the Earth Radiation Budget Experiment (ERBE) covered all subsets of the broadband radiance spectrum (total, longwave and shortwave.) CERES has two subset channels (window and shortwave) which do not give continuous frequency coverage over the total band. Previous experience with ERBE indicated the need for us to model the equivalent daytime longwave radiance using a window channel regression, which will allow us to validate the performance of the instrument using a three-channel inter-comparison. Limiting our consideration to the fixed azimuth plane, cross-track, scanning mode (FAPS), each nadir-viewing measurement was averaged into three subjective categories called daytime, nighttime, and twilight. Daytime was defined as any measurement taken when the solar zenith angle (SZA) was less than 90 ; nighttime was taken to be any measurement where the SZA was greater than 117 ; and twilight was everything else. Our analysis indicates that there are only two distinct categories of nadir-view data; daytime, and non-daytime (i.e., the union of the nighttime and twilight sets); and that the CERES longwave radiance is predictable to an accuracy of 1%, based on the SZA, and window channel measurements.

Paden, Jack↗

Asymmetry in the Diurnal Variation of Surface Albedo

Remote sensing of surface properties and estimation of clear-sky and surface albedo generally assumes that the albedo depends only on the solar zenith angle. The effects of dew, frost, and precipitation as well as evaporation and wind can lead to some systematic diurnal variability resulting in an asymmetric diurnal cycle of albedo. This paper examines the symmetry of both surface-observed albedos and top-of-the-atmosphere (TOA) albedos derived from satellite data. Broadband and visible surface albedos were measured at the Department of Energy Atmospheric Radiation Measurement (ARM) Program Southern Great Plains Central Facility, at some fields near the ARM site, and over a coniferous forest in eastern Virginia. Surface and wind conditions are available for most cases. GOES-8 satellite radiance data are converted to broadband albedo using bidirectional reflectance functions and an empirical narrowband-to-broadband relationship. The initial results indicate that surface moisture has a significant effect and can change the albedo in the afternoon by 20% relative to its morning counterpart. Such effects may need to be incorporated in mesoscale and even large-scale models of atmospheric processes.

Mayor, S.↗

Estimation of Instantaneous TOA Albedo at 670 nm over Ice Clouds from POLDER Multidirectional Measurements

An algorithm that determines the 670-nm top-of-atmosphere (TOA) albedo of ice clouds over ocean using Polarization and Directionality of the Earth's Reflectance ( POLDER) multidirectional measurements is developed. A plane-parallel layer of ice cloud with various optical thicknesses and light scattering phase functions is assumed. For simplicity, we use a double Henyey-Greenstein phase function to approximate the volume-averaged phase function of the ice clouds. A multidirectional reflectance best-fit match between theoretical and POLDER reflectances is used to infer effective cloud optical thickness, phase function and TOA albedo. Sensitivity tests show that while the method does not provide accurate independent retrievals of effective cloud optical depth and phase function, TOA albedo retrievals are accurate to within similar to 3% for both a single layer of ice clouds or a multilayer system of ice clouds and water clouds. When the method is applied to POLDER measurements and retrieved albedos are compared with albedos based on empirical angular distribution models (ADMs), zonal albedo differences are generally smaller than similar to 3%. When albedos are compared with those on the POLDER-I ERB and Cloud product, the differences can reach similar to 15% at small solar zenith angles.

Sun, W.↗

Top-of-Atmosphere Shortwave Broadband Observed Radiance and Estimated Irradiance over Polar Regions from Clouds and the Earth's Radiant Energy System (CERES) Instruments on Terra

Empirical angular distribution models for estimating top-of-atmosphere shortwave irradiances from radiance measurements over permanent snow, fresh snow and sea ice are developed using CERES measurements on Terra. Permanent snow angular distribution models depend on cloud fraction, cloud optical thickness, and snow brightness. Fresh snow and sea ice angular distribution models depend on snow and sea ice fraction, cloud fraction, cloud optical thickness, and snow and ice brightness. These classifications lead to 10 scene types for permanent snow and 25 scene types for fresh snow and sea ice. The average radiance over clear-sky permanent snow is more isotropic with satellite viewing geometry than that over overcast permanent snow. On average, the albedo of clear-sky permanent snow varies from 0.65 to 0.68 for solar zenith angles between 60$logical and\circ$ and 80 deg, while the corresponding albedo of overcast scenes varies from 0.70 to 0.73. Clear-sky permanent snow albedos over Antarctica estimated from two independent angular distribution models are consistent to within 0.6%, on average. Despite significant variability in sea ice optical properties with season, the estimated mean relative albedo error is -1 % for very dark sea ice and 0.1% for very bright sea ice when albedos derived from different viewing angles are averaged. The estimated regional root-mean-square (RMS) relative albedo error is 5.6% and 2.6% when the sea ice angular distribution models are applied to a region that contains very dark and very bright sea ice, respectively. Similarly, the estimated relative albedo bias error for fresh snow is -0.1% for very dark snow.

Kato, S.↗

View angle dependence of cloud optical thicknesses retrieved by MODIS

This study examines whether cloud inhomogeneity influences the view angle dependence of MODIS cloud optical thickness (tau) retrieval results. The degree of cloud inhomogeneity is characterized through the local gradient in 11 microns brightness temperature. The analysis of liquid phase clouds in a one year long global dataset of Collection 4 MODIS data reveals that while optical thickness retrievals give remarkably consistent results for all view directions if clouds are homogeneous, they give much higher tau-values for oblique views than for overhead views if clouds are inhomogeneous and the sun is fairly oblique. For solar zenith angles larger than 55deg, the mean optical thickness retrieved for the most inhomogeneous third of cloudy pixels is more than 30% higher for oblique views than for overhead views. After considering a variety of possible scenarios, the paper concludes that the most likely reason for the increase lies in three-dimensional radiative interactions that are not considered in current, one-dimensional retrieval algorithms. Namely, the radiative effect of cloud sides viewed at oblique angles seems to contribute most to the enhanced tau-values. The results presented here will help understand cloud retrieval uncertainties related to cloud inhomogeneity. They complement the uncertainty estimates that will start accompanying MODIS cloud products in Collection 5 and may eventually help correct for the observed view angle dependent biases.

Marshak, Alexander↗

Stratospheric NO and NO(sub 2) Abundances from ATMOS Solar-Occultation Measurements

Using results from a time-dependent photochemical model to calculate the diurnal variation of NO and NO(sub 2), we have corrected Atmospheric Trace Molecule Spectroscopy (ATMOS) solar-occultation retrievals of the NO and NO(sub 2) abundances at 90 solar zenith angle. Neglecting to adjust for the rapid variation of these gases across the terminator results in potential errors in retrieved profiles of approx. 20 percent for NO(sub 2) and greater than 100 percent for NO at altitudes below 25 KM.

NO NO2 ATMOS↗

Measurements of Nitrogen Dioxide Total Column Amounts using a Brewer Double Spectrophotometer in Direct Sun Mode

NO2 column amounts were measured for the past 2 years at Goddard Space Flight Center, Greenbelt, Maryland, using a Brewer spectrometer in direct Sun mode. A new bootstrap method to calibrate the instrument is introduced and described. This technique selects the cleanest days from the database to obtain the solar reference spectrum. The main advantage for direct Sun measurements is that the conversion uncertainty from slant column to vertical column is negligible compared to the standard scattered light observations where it is typically on the order of 100% (2sigma) at polluted sites. The total 2sigma errors of the direct Sun retrieved column amounts decrease with solar zenith angle and are estimated at 0.2 to 0.6 Dobson units (DU, 1 DU approx. equal to 2.7 10(exp 16) molecules cm(exp -2)), which is more accurate than scattered light measurements for high NO2 amounts. Measured NO2 column amounts, ranging from 0 to 3 DU with a mean of 0.7 DU, show a pronounced daily course and a strong variability from day to day. The NO2 concentration typically increases from sunrise to noon. In the afternoon it decreases in summer and stays constant in winter. As expected from the anthropogenic nature of its source, NO2 amounts on weekends are significantly reduced. The measurements were compared to satellite retrievals from Scanning Image Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY). Satellite data give the same average NO2 column and show a seasonal cycle that is similar to the ground data in the afternoon. We show that NO2 must be considered when retrieving aerosol absorption properties, especially for situations with low aerosol optical depth.

Cede, Alexander↗

SAUNA Ozone Profile Comparison: SBUV/2 and MLS versus Sondes and Lidar

The Sodankyla Total Column Ozone Intercomparison (SAUNA) was held in Sodankyla, Finland in March-April 2006 and February-March 2007 in support of Aura validation. The purpose of SAUNA was to assess the comparative performance of the ground-based instruments and algorithms when measuring total column ozone at large solar zenith angles and high total column ozone amounts. Results showed that the ozone profiles from the satellite instruments (MLS on Aura and SBUV/2 on NOAA 16) generally agreed with profiles from the ground-based instruments (lidar and sondes) within 10%. The largest differences were seen in the profile below 20 km, consistent with our conclusion that spatial variability in the lower stratosphere and upper troposphere is a significant source of disagreement in these comparisons. The total column ozone comparison shows that SBUV/2 and OMI agree well with the double Brewer instruments provided the scenes are carefully matched.

McPeters, R. D.↗

Energy Deposition Processes in Titan's Upper Atmosphere

Most of Titan's atmospheric organic and nitrogen chemistry, aerosol formation, and atmospheric loss are driven from external energy sources such as Solar UV, Saturn's magnetosphere, solar wind and galactic cosmic rays. The Solar UV tends to dominate the energy input at lower altitudes of approximately 1100 km but which can extend down to approximately 400 km, while the plasma interaction from Saturn's magnetosphere, Saturn's magnetosheath or solar wind are more important at higher altitudes of approximately 1400 km, but the heavy ion plasma [O(+)] of approximately 2 keV and energetic ions [H(+)] of approximately 30 keV or higher from Saturn's magnetosphere can penetrate below 950km. Cosmic rays with energies of greater than 1 GeV can penetrate much deeper into Titan's atmosphere with most of its energy deposited at approximately 100 km altitude. The haze layer tends to dominate between 100 km and 300 km. The induced magnetic field from Titan's interaction with the external plasma can be very complex and will tend to channel the flow of energy into Titan's upper atmosphere. Cassini observations combined with advanced hybrid simulations of the plasma interaction with Titan's upper atmosphere show significant changes in the character of the interaction with Saturn local time at Titan's orbit where the magnetosphere displays large and systematic changes with local time. The external solar wind can also drive sub-storms within the magnetosphere which can then modify the magnetospheric interaction with Titan. Another important parameter is solar zenith angle (SZA) with respect to the co-rotation direction of the magnetospheric flow. Titan's interaction can contribute to atmospheric loss via pickup ion loss, scavenging of Titan's ionospheric plasma, loss of ionospheric plasma down its induced magnetotail via an ionospheric wind, and non-thermal loss of the atmosphere via heating and sputtering induced by the bombardment of magnetospheric keV ions and electrons. This energy input evidently drives the large positive and negative ions observed below approximately 1100 km altitude with ion masses exceeding 10,000 daltons. We refer to these ions as seed particles for the aerosols observed below 300 km altitude. These seed particles can be formed, for example, from the polymerization of acetylene (C2H2) and benzene (C6H6) molecules in Titan's upper atmosphere to form polycyclic aromatic hydrocarbons (PAH) and/or fullerenes (C60). In the case of fullerenes, which are hollow spherical carbon shells, magnetospheric keV [O(+)] ions can become trapped inside the fullerenes and eventually find themselves inside the aerosols as free oxygen. The aerosols are then expected to fall to Titan's surface as polymerized hydrocarbons with trapped free oxygen where unknown surface chemistry can take place.

Sittler, Edward C., Jr.↗

OMI Validation from the SAUNA and ARCTAS Campaigns

Initial results are presented on Ozone Monitoring Instrumnet (OMI) validation from the Sodankyla Total Column Ozone Intercomparison (SAUNA) and from the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) campaign. SAUNA was held in Sodankyla, Finland in March-April 2006 and February-March 2007 in support of Aura validation. The purpose of SAUNA was to assess the comparative performance of the ground-based instruments and algorithms when measuring total column ozone at large solar zenith angles and high total column ozone amounts. Results showed that the ozone profiles from the satellite instruments (MLS on Aura and SBUV/2 on NOAA 16) generally agreed with profiles from the ground-based instruments (lidar and sondes) within 10%. The ARCTAS spring campaign was flown out of Fairbanks, Alaska, from, April 1 - April 19, 2008. The purpose of ARCTAS was to study arctic haze and pollution sources in the arctic, but also to provide validation of CALIPSO and Aura. The differences between the OMI OMTO3 ozone retrieval and the DOAS ozone are examined.

McPeters, R. D.↗

Lidar Measurements of Stratospheric Ozone, Aerosols and Temperature during the SAUNA Campaign at Sodankyla, Finland

The Sodankyla Total Column Ozone Intercomparison (SAUNA) campaign took place at the Finnish Meteorological Institute Arctic Research Center (FMI-ARC) at Sodankyla, Finland (67.37 N) in two separate phases during early spring 2006, and winter 2007. These campaigns has several goals: to determine and improve the accuracy of total column ozone measurements during periods of low solar zenith angle and high total column ozone; to determine the effect of ozone profile shape on the total column retrieval; and to make validate satellite ozone measurements under these same conditions. The GSFC Stratospheric Ozone Lidar (STROZ), which makes profile measurements of ozone temperature, aerosols and water vapor participated in both phases of the campaign. During the deployments, more than 30 profile measurements were made by the lidar instrument, along with Dobson, Brewer, DOAS, ozonesonde, and satellite measurements. The presentation will concentrate on STROZ lidar results from the second phase of the campaign and comparisons with other instruments will be discussed. This will include both ground-based and satellite comparisons.

McGee, T.↗

Validation of Improved Broadband Shortwave and Longwave Fluxes Derived From GOES

Broadband (BB) shortwave (SW) and longwave (LW) fluxes at TOA (Top of Atmosphere) are crucial parameters in the study of climate and can be monitored over large portions of the Earth's surface using satellites. The VISST (Visible Infrared Solar Split-Window Technique) satellite retrieval algorithm facilitates derivation of these parameters from the Geostationery Operational Environmental Satellites (GOES). However, only narrowband (NB) fluxes are available from GOES, so this derivation requires use of narrowband-to-broadband (NB-BB) conversion coefficients. The accuracy of these coefficients affects the validity of the derived broadband (BB) fluxes. Most recently, NB-BB fits were re-derived using the NB fluxes from VISST/GOES data with BB fluxes observed by the CERES (Clouds and the Earth's Radiant Energy Budget) instrument aboard Terra, a sun-synchronous polar-orbiting satellite that crosses the equator at 10:30 LT. Subsequent comparison with ARM's (Atmospheric Radiation Measurement) BBHRP (Broadband Heating Rate Profile) BB fluxes revealed that while the derived broadband fluxes agreed well with CERES near the Terra overpass times, the accuracy of both LW and SW fluxes decreased farther away from the overpass times. Terra's orbit hampers the ability of the NB-BB fits to capture diurnal variability. To account for this in the LW, seasonal NB-BB fits are derived separately for day and night. Information from hourly SW BB fluxes from the Meteosat-8 Geostationary Earth Radiation Budget (GERB) is employed to include samples over the complete solar zenith angle (SZA) range sampled by Terra. The BB fluxes derived from these improved NB-BB fits are compared to BB fluxes computed with a radiative transfer model.

Khaiyer, Mandana M.↗

Radiation Dry Bias of the Vaisala RS92 Humidity Sensor

The comparison of simultaneous humidity measurements by the Vaisala RS92 radiosonde and by the Cryogenic Frostpoint Hygrometer (CFH) launched at Alajuela, Cosla Rica, during July 2005 reveals a large solar radiation dry bias of the Vaisala RS92 humidity sensor and a minor temperature-dependent calibration error. For soundings launched at solar zenith angles between 10" and 30 , the average dry bias is on the order of 9% at the surface and increases to 50% at 15 km. A simple pressure- and temperature-dependent correction based on the comparison with the CFH can reduce this error to less than 7% at all altitudes up to 15.2 km, which is 700 m below the tropical tropopause. The correction does not depend on relative humidity, but is able to reproduce the relative humidity distribution observed by the CFH.

Vomel, H.↗

Combining Satellite and in Situ Data with Models to Support Climate Data Records in Ocean Biology

The satellite ocean color data record spans multiple decades and, like most long-term satellite observations of the Earth, comes from many sensors. Unfortunately, global and regional chlorophyll estimates from the overlapping missions show substantial biases, limiting their use in combination to construct consistent data records. SeaWiFS and MODIS-Aqua differed by 13% globally in overlapping time segments, 2003-2007. For perspective, the maximum change in annual means over the entire Sea WiFS mission era was about 3%, and this included an El NinoLa Nina transition. These discrepancies lead to different estimates of trends depending upon whether one uses SeaWiFS alone for the 1998-2007 (no significant change), or whether MODIS is substituted for the 2003-2007 period (18% decline, P less than 0.05). Understanding the effects of climate change on the global oceans is difficult if different satellite data sets cannot be brought into conformity. The differences arise from two causes: 1) different sensors see chlorophyll differently, and 2) different sensors see different chlorophyll. In the first case, differences in sensor band locations, bandwidths, sensitivity, and time of observation lead to different estimates of chlorophyll even from the same location and day. In the second, differences in orbit and sensitivities to aerosols lead to sampling differences. A new approach to ocean color using in situ data from the public archives forces different satellite data to agree to within interannual variability. The global difference between Sea WiFS and MODIS is 0.6% for 2003-2007 using this approach. It also produces a trend using the combination of SeaWiFS and MODIS that agrees with SeaWiFS alone for 1998-2007. This is a major step to reducing errors produced by the first cause, sensor-related discrepancies. For differences that arise from sampling, data assimilation is applied. The underlying geographically complete fields derived from a free-running model is unaffected by solar zenith angle requirements and obscuration from clouds and aerosols. Combined with in situ dataenhanced satellite data, the model is forced into consistency using data assimilation. This approach eliminates sampling discrepancies from satellites. Combining the reduced differences of satellite data sets using in situ data, and the removal of sampling biases using data assimilation, we generate consistent data records of ocean color. These data records can support investigations of long-term effects of climate change on ocean biology over multiple satellites, and can improve the consistency of future satellite data sets.

Gregg, Watson↗

Estimation of Smoothing Error in SBUV Profile and Total Ozone Retrieval

Data from the Nimbus-4, Nimbus-7 Solar Backscatter Ultra Violet (SBUV) and seven of the NOAA series of SBUV/2 instruments spanning 41 years are being reprocessed using V8.6 algorithm. The data are scheduled to be released by the end of August 2011. An important focus of the new algorithm is to estimate various sources of errors in the SBUV profiles and total ozone retrievals. We discuss here the smoothing errors that describe the components of the profile variability that the SBUV observing system can not measure. The SBUV(/2) instruments have a vertical resolution of 5 km in the middle stratosphere, decreasing to 8 to 10 km below the ozone peak and above 0.5 hPa. To estimate the smoothing effect of the SBUV algorithm, the actual statistics of the fine vertical structure of ozone profiles must be known. The covariance matrix of the ensemble of measured ozone profiles with the high vertical resolution would be a formal representation of the actual ozone variability. We merged the MLS (version 3) and sonde ozone profiles to calculate the covariance matrix, which in general case, for single profile retrieval, might be a function of the latitude and month. Using the averaging kernels of the SBUV(/2) measurements and calculated total covariance matrix one can estimate the smoothing errors for the SBUV ozone profiles. A method to estimate the smoothing effect of the SBUV algorithm is described and the covariance matrixes and averaging kernels are provided along with the SBUV(/2) ozone profiles. The magnitude of the smoothing error varies with altitude, latitude, season and solar zenith angle. The analysis of the smoothing errors, based on the SBUV(/2) monthly zonal mean time series, shows that the largest smoothing errors were detected in the troposphere and might be as large as 15-20% and rapidly decrease with the altitude. In the stratosphere above 40 hPa the smoothing errors are less than 5% and between 10 and 1 hPa the smoothing errors are on the order of 1%. We validate our estimated smoothing errors by comparing the SBUV ozone profiles with other ozone profiling sensors.

Kramarova, N. A.↗

Program for Computing Albedo

Simple Thermal Environment Model (STEM) is a FORTRAN-based computer program that provides engineering estimates of top-of-atmosphere albedo and outgoing long-wave radiation (OLR) for use in analyzing thermal loads on spacecraft near Earth. The thermal environment of a spacecraft is represented in STEM as consisting of direct solar radiation; short-wave radiation reflected by the atmosphere of the Earth, as characterized in terms of the albedo of the Earth; and OLR emitted by the atmosphere of the Earth. STEM can also address effects of heat loads internal to a spacecraft. Novel features of STEM include (1) the use of Earth albedo and OLR information based on time series of measurements by Earth Radiation Budget Experiment satellites in orbit; (2) the ability to address thermal time constants of spacecraft systems by use of albedo and OLR values representing averages over a range of averaging times; and (3) the ability to address effects, on albedo and OLR values, of satellite orbital inclination, the angle between the plane of a spacecraft orbit and the line between the centers of the Earth and Sun, the solar zenith angle, and latitude.

Justus, Carl G.↗

Use of In Situ and Airborne Multiangle Data to Assess MODIS- and Landsat-based Estimates of Surface Albedo

The quantification of uncertainty of global surface albedo data and products is a critical part of producing complete, physically consistent, and decadal land property data records for studying ecosystem change. A current challenge in validating satellite retrievals of surface albedo is the ability to overcome the spatial scaling errors that can contribute on the order of 20% disagreement between satellite and field-measured values. Here, we present the results from an uncertain ty analysis of MODerate Resolution Imaging Spectroradiometer (MODIS) and Landsat albedo retrievals, based on collocated comparisons with tower and airborne multi-angular measurements collected at the Atmospheric Radiation Measurement Program s (ARM) Cloud and Radiation Testbed (CART) site during the 2007 Cloud and Land Surface Interaction Campaign (CLAS33 IC 07). Using standard error propagation techniques, airborne measurements obtained by NASA s Cloud Absorption Radiometer (CAR) were used to quantify the uncertainties associated with MODIS and Landsat albedos across a broad range of mixed vegetation and structural types. Initial focus was on evaluating inter-sensor consistency through assessments of temporal stability, as well as examining the overall performance of satellite-derived albedos obtained at all diurnal solar zenith angles. In general, the accuracy of the MODIS and Landsat albedos remained under a 10% margin of error in the SW(0.3 - 5.0 m) domain. However, results reveal a high degree of variability in the RMSE (root mean square error) and bias of albedos in both the visible (0.3 - 0.7 m) and near-infrared (0.3 - 5.0 m) broadband channels; where, in some cases, retrieval uncertainties were found to be in excess of 20%. For the period of CLASIC 07, the primary factors that contributed to uncertainties in the satellite-derived albedo values include: (1) the assumption of temporal stability in the retrieval of 500 m MODIS BRDF values over extended periods of cloud-contaminated observations; and (2) the assumption of spatial 45 and structural uniformity at the Landsat (30 m) pixel scale.

Roman, Miguel O.↗