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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2004

On the Use of Deep Convective Clouds to Calibrate AVHRR Data

Remote sensing of cloud and radiation properties from National Oceanic and Atmospheric Administration (NOAA) Advanced Very High Resolution Radiometer (AVHRR) satellites requires constant monitoring of the visible sensors. NOAA satellites do not have onboard visible calibration and need to be calibrated vicariously in order to determine the calibration and the degradation rate. Deep convective clouds are extremely bright and cold, are at the tropopause, have nearly a Lambertian reflectance, and provide predictable albedos. The use of deep convective clouds as calibration targets is developed into a calibration technique and applied to NOAA-16 and NOAA-17. The technique computes the relative gain drift over the life-span of the satellite. This technique is validated by comparing the gain drifts derived from inter-calibration of coincident AVHRR and Moderate-Resolution Imaging Spectroradiometer (MODIS) radiances. A ray-matched technique, which uses collocated, coincident, and co-angled pixel satellite radiance pairs is used to intercalibrate MODIS and AVHRR. The deep convective cloud calibration technique was found to be independent of solar zenith angle, by using well calibrated Visible Infrared Scanner (VIRS) radiances onboard the Tropical Rainfall Measuring Mission (TRMM) satellite, which precesses through all solar zenith angles in 23 days.

Doelling, David R.↗
NASA NTRS1992

Radiation Transport Around Axisymmetric Blunt Body Vehicles Using a Modified Differential Approximation

A moment method for computing 3-D radiative transport is applied to axisymmetric flows in thermochemical nonequilibrium. Such flows are representative of proposed aerobrake missions. The method uses the P-1 approximation to reduce the governing system of integro-di erential equations to a coupled set of partial di erential equations. A numerical solution method for these equations given actual variations of the radiation properties in thermochemical nonequilibrium blunt body flows is developed. Initial results from the method are shown and compared to tangent slab calculations. The agreement between the transport methods is found to be about 10 percent in the stagnation region, with the difference increasing along the flank of the vehicle.

Hartung, Lin C.↗
NASA NTRS2004

Spatially Complete Surface Albedo Data Sets: Value-Added Products Derived from Terra MODIS Land Products

Spectral land surface albedo is an important parameter for describing the radiative properties of the Earth. Accordingly it reflects the consequences of natural and human interactions, such as anthropogenic, meteorological, and phenological effects, on global and local climatological trends. Consequently, albedos are integral parts in a variety of research areas, such as general circulation models (GCMs), energy balance studies, modeling of land use and land use change, and biophysical, oceanographic, and meteorological studies. Recent observations of diffuse bihemispherical (white-sky) and direct beam directional hemispherical (black-sky ) land surface albedo included in the MOD43B3 product from MODIS instruments aboard NASA's Terra and Aqua satellite platforms have provided researchers with unprecedented spatial, spectral, and temporal characteristics. Cloud and seasonal snow cover, however, curtail retrievals to approximately half the global land surfaces on an annual equal-angle basis, precluding MOD43B3 albedo products from direct inclusion in some research projects and production environments.

Moody, Eric G.↗
NASA NTRS2005

Of Ashes and Atoms

This feature length DVD documentary, reviews the history of the Plum Brook Nuclear Reactor from the initial settlers of the area, through its use as a munitions facility during the second World War to the development of the nuclear facility and its use as one of the first nuclear test reactors built in the United States, and the only one built by NASA. It concludes with the beginning of the decommissioning of the facility. There is a brief review of the reactor design, and its workings. Through discussions with the NASA engineers and operators of the facility, the film reviews the work done to advance the knowledge of the effects of radiation, the properties of radiated materials, and the work to advance the state of the art in nuclear propulsion. The film shows footage of public tours, and shows actual footage of the facility in operation, and after its shutdown in 1973. The DVD was narrated by Kate Mulgrew, who leads the viewer through the history of the facility to its eventual ongoing decommissioning, and return to the state of pastoral uses.

Source record↗
NASA NTRS2005

Effective Radius of Ice Cloud Particle Populations Derived from Aircraft Probes

The effective radius(r(sub e)) is a crucial variable in representing the radiative properties of cloud layers in general circulation models. This parameter is proportional to the condensed water content (CWC) divided by the extinction (sigma). For ice cloud layers, parameterizations for r(sub e), have been developed from aircraft in-situ measurements 1) indirectly, using data obtained from particle spectrometer probes and assumptions or observations about particle shape and mass to get the ice water content (IWC) and area to get sigma, and recently 2) from probes that measure IWC and sigma directly. This study compares [IWC/sigma] derived from the two methods using data sets acquired from comparable instruments on two aircraft, one sampling clouds at mid-levels and the other at upper-levels during the CRYSTAL-FACE field program in Florida in 2002. The sigma and IWC derived by each method are compared and evaluated in different ways for each aircraft data set. Direct measurements of sigma exceed those derived indirectly by a factor of two to two and a half. The IWC probes, relying on ice sublimation, appear to measure accurately except when the IWC is high or the particles too large to sublimate completely during the short transit time through the probe. The IWC estimated from the particle probes are accurate when direct measurements are available to provide constraints and useful information in high IWC/large particle situations. Because of the discrepancy in sigma estimates between the direct and indirect approaches, there is a factor of 2 to 3 difference in [IWC/sigma] between them. Although there are significant uncertainties involved in its use, comparisons with several independent data sources suggest that the indirect method is the more accurate of the two approaches. However, experiments are needed to resolve the source of the discrepancy in sigma.

Heymsfield, Andrew J.↗
NASA NTRS2002

Cloud Microphysics and Absorption Validation

Vertical distributions of particle size and habit were developed from in-situ data collected from three midlatitude cirrus field campaigns (FIRE-1, FIRE-2, and ARM IOP). These new midlatitude microphysical models were used to develop new cirrus scattering models at a number of wavelengths appropriate for use with the MODIS imager (Nasiri et al. 2002). This was the first successful collaborative effort between all the investigators on this proposal. Recent efforts have extended the midlatitude cirrus cloud analyses to tropical cirrus, using in-situ data collected during the Tropical Rainfall Measurement Mission (TRMM) Kwajalein field campaign in 1999. We note that there are critical aspects to the work: a) Improvement in computing the scattering and radiative properties of ice crystals; b) Requirement for copious amounts of cirrus in-situ data, presented in terms of both particle size and habit distributions; c) Development of cirrus microphysical and optical models for various satellite, aircraft, and ground-based instruments based on the theoretical calculations and in-situ measurements; d) Application to satellite data.

Ackerman, Steven↗
NASA NTRS2006

Aerosol-Water Cycle Interaction: A New Challenge in Monsoon Climate Research

Long recognized as a major environmental hazard, aerosol is now known to have strong impacts on both regional and global climate. It has been estimated that aerosol may reduce by up to 10% of the seasonal mean solar radiation reaching the earth surface, producing a global cooling effect that opposes global warming (Climate Change 2001). This means that the potential perils that humans have committed to global warming may be far greater than what we can detect at the present. As a key component of the Earth climate system, the water cycle is profoundly affected by the presence of aerosols in the atmosphere. Through the so-called direct effect , aerosol scatters and/or absorbs solar radiation, thus cooling the earth surface and changing the horizontal and vertical radiational heating contrast in the atmosphere. The heating contrast drives anomalous atmospheric circulation, resulting in changes in convection, clouds, and rainfall. Another way aerosol can affect the water cycle is through the so-called indirect effects, whereby aerosol increases the number of cloud condensation nuclei, prolongs life time of clouds, and inhibits the growth of cloud drops to raindrops. This leads to more clouds, and increased reflection of solar radiation, and further cooling at the earth surface. In monsoon regions, the response of the water cycle to aerosol forcing is especially complex, not only because of presence of diverse mix of aerosol species with vastly different radiative properties, but also because the monsoon is strongly influenced by ocean and land surface processes, land use, land change, as well as regional and global greenhouse warming effects. Thus, sorting out the impacts of aerosol forcing, and interaction with the monsoon water cycle is a very challenging problem. In this talk, I will offer some insights into how aerosols may impact the Asian monsoon based on preliminary results from satellite observations and climate model experiments. Specifically, I will discuss the elevated heat pump hypothesis, involving atmospheric heating by absorbing aerosols (dust and black carbon) over the southern slopes of the Himalayas, and feedback with the deep convection, in modifying monsoon water cycle over South .and East Asia. The role of aerosol forcing relative to those due to sea surface temperature and land surface processes, as well as observation requirements to verify such a hypothesis will also be discussed.

Lau, William K. M.↗
NASA NTRS2000

MISR Science Data Validation Plan Summary Charts

The purpose of the MISR experiment is to acquire systematic multi-angle imagery for global monitoring over a multi-year period of top-of-atmosphere and surface albedos and to measure the shortwave radiative properties of aerosols, clouds, and surface scenes.

MISR science data validation plan summary charts↗
NASA NTRS2006

NASA Balloon Technology Activities

The National Aeronautics and Space Administration (NASA) Balloon Program technology development efforts are fundamental to improving the capabilities of the balloon systems, better understanding of the flight dynamics, and to support the science missions throughout the next decade. Building on the foundations of the 20-year research and development program, a technology roadmap has been generated which identifies specific areas of interest to NASA and the vision of future developments. The major components of the roadmap are: vehicle systems, ballooncraft systems, operational and safety support systems, and planetary vehicles. Within each of these major components, technologies are targeted that will provide both better understanding and foster advancements. The Program's technology thrust areas are directed both in broad efforts that touch on a number of the major components as well as specific tasks that address elements within a specific component. Advances in vehicle systems have focused on producing better balloon designs. This is being attempted through the use of improved inputs into the ba!loon des@ process. Central to this is an increasing the understanding of materials used to fabricate balloons. Testing techniques have been improved with better bi-axial characterization of the balloon materials. More realistic radiative properties of the balloon films and components have also been made. Analytical assessments of the balloon designs are also key in improving balloon designs. These analytical assessments have been accomplished using improving analysis tools and an increased understanding of the float environment. Details of these improvements will be presented. To help improve the operational and flight safety of the balloons, improved flight performance predictions have been made using new analytical tools as well as incorporating the increased understanding of the float environment. These two have combined to allow for improved post-flight balloon performance correlations. A potential to significantly improve the potential safety of a long duration flight can be accomplished using some form of a trajectory modification system. An overview of the development efforts for a trajectory modification system will be presented. A number of efforts will be presented that are focused on the improvement of the ballooncraft systems. Planetary ballooning activities have benefited from a number of separate but related technology advancements made by the NASA Balloon Program's technology developments. The tools, techniques, and advancements made for balloon design and balloon analysis are directly applicable to the processes to develop planetary balloons for either Mars or Venus. An overview of the NASA Balloon Program's role in these efforts and testing will be presented. The technology roadmap, as well as specific projects and recent advancements, will be presented. This overview will demonstrate the technology advancements made by the NASA Balloon Program are focusing on leading balloon developments into the future.

Fairbrother, Debora A.↗
NASA NTRS2007

Electrification in Hurricanes over the Tropical Americas: Implication for Stratospheric Water Vapor

This study explores the relation between lightning activity and water vapor in the Tropical Tropopause Layer (TTL) over hurricane systems in the Tropical Americas. The hypothesis herein is that hurricanes that exhibit enhanced lightning activity are associated with stronger updrafts that can transport more moisture directly into the TTL (and subsequently into the tropical stratosphere) or even directly into the tropical stratosphere over this region. The TTL over the Tropical Americas, which includes the Caribbean and Gulf of Mexico, is of particular interest, because summertime cold point tropopause is the lowest in height and thus the warmest in temperature over the tropics. The latter condition implies higher saturation values and thus potential for more water vapor to enter the stratosphere. Climate forecast is very sensitive to stratospheric water vapor abundance, because of the key role that water vapor plays in regulating the chemical and radiative properties of the stratosphere. Given the potential for increases in hurricane intensity and frequency under predicted warmer conditions, it becomes essential to understand the effect of hurricanes on stratospheric water vapor. In this study, we use a combination of ground and space-borne observations as well as trajectory calculations. The observations include: cloud-to-ground (CG) lightning data from the U.S. National Lightning Detection Network (NLDN), geostationary infrared observations from the National Climatic Data Center Hurricane Satellite (HURSAT) data set, cloud properties from Aqua-MODIS, and water vapor from Aura-MLS. We analyze hurricanes from the 2005 season when Aura-MLS data are available, namely: Dennis, Emily, Katrina, Rita, and Wilma. Our analysis consists of examining CG lightning, cloud-top properties, and TTL water vapor (i.e., 100 and 147 mb) over the hurricane while it remains over water in the Tropical Americas region. We investigate daily as well as diurnal statistical properties. The hurricanes analyzed in this study showed that lightning activity is negatively correlated with minimum infrared brightness temperature and positively correlated with 100-mb water vapor. An examination of the maxima in water vapor observed over the hurricane not only shows larger magnitudes, but also larger differences between water vapor averages and water vapor maxima over the hurricane as lightning activity increases. Trajectory calculations are performed using the Flextra model in order to investigate the fate of the moister air masses found in the TTL.

Pittman, Jasna V.↗
NASA NTRS2006

Optically Thin Liquid Water Clouds: Their Importance and Our Challenge

Many of the clouds important to the Earth's energy balance, from the tropics to the Arctic, are optically thin and contain liquid water. Longwave and shortwave radiative fluxes are very sensitive to small perturbations of the cloud liquid water path (LWP) when the liquid water path is small (i.e., < g/sq m) and, thus, the radiative properties of these clouds must be well understood to capture them correctly in climate models. We review the importance of these thin clouds to the Earth's energy balance, and explain the difficulties in observing them. In particular, because these clouds are optically thin, potentially mixed-phase, and often (i.e., have large 3-D variability), it is challenging to retrieve their microphysical properties accurately. We describe a retrieval algorithm intercomparison that was conducted to evaluate the issues involved. The intercomparison included eighteen different algorithms to evaluate their retrieved LWP, optical depth, and effective radii. Surprisingly, evaluation of the simplest case, a single-layer overcast cloud, revealed that huge discrepancies exist among the various techniques, even among different algorithms that are in the same general classification. This suggests that, despite considerable advances that have occurred in the field, much more work must be done, and we discuss potential avenues for future work.

Turner, D. D.↗
NASA NTRSDate not supplied

Multi-angle Imaging SpectroRadiometer

MISR views the sunlit Earth simultaneously at nine widely spaced angles and provides ongoing global coverage with high spatial detail. Its imagery is carefully calibrated to provide accurate measures of the brightness, contrast, and color of reflected sunlight. MISR provides new types of information for scientists studying Earth's climate, such as the regional and global distribution of different types of atmospheric particles and aerosols. The change in reflection at different view angles provides the means to distinguish aerosol types, cloud forms, and land surface cover. Combined with stereoscopic techniques, this enables construction of 3-D cloud models and estimation of the total amount of sunlight reflected by Earth's diverse environments. MISR was built for NASA by the Jet Propulsion Laboratory (JPL) in Pasadena, California. It is part of NASA's first Earth Observing System (EOS) spacecraft, the Terra spacecraft, which was launched into polar orbit from Vandenberg Air Force Base on December 18, 1999. MISR has been continuously providing data since February 24, 2000. [Mission Objectives] The MISR instrument acquires systematic multi-angle measurements for global monitoring of top-of-atmosphere and surface albedos and for measuring the shortwave radiative properties of aerosols, clouds, and surface scenes in order to characterize their impact on the Earth's climate. The Earth's climate is constantly changing -- as a consequence of both natural processes and human activities. Scientists care a great deal about even small changes in Earth's climate, since they can affect our comfort and well-being, and possibly our survival. A few years of below-average rainfall, an unusually cold winter, or a change in emissions from a coal-burning power plant, can influence the quality of life of people, plants, and animals in the region involved. The goal of NASA's Earth Observing System (EOS) is to increase our understanding of the climate changes that are occurring on our planet, and the reasons for these changes, so we are better equipped to anticipate and prepare for the future. The MISR instrument is a part of EOS. Its role is to measure the amount of sunlight scattered in different directions under natural conditions. These measurements will help quantify the amount of solar energy that heats the Earth's surface and atmosphere, and the changes that occur in them over the lifetime of the MISR instrument. From the MISR observations, we are also learning more about those components of the Earth's environment that scatter sunlight: particles in the atmosphere, the planet's surface, and clouds. MISR monitors changes in surface reflection properties, in atmospheric aerosol content and composition, and in cloudiness. Scientists use these data to study land use changes, air pollution, volcanic eruptions, as well as processes such as desertification, deforestation, and soil erosion. As part of the EOS program, computer models that predict future climate will be improved by the results of these studies. [Temporal_Coverage: Start_Date=2000-02-24; Stop_Date=] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180].

Diner, David J.↗
NASA NTRS2008

LASE Measurements of Water Vapor, Aerosol, and Cloud Distributions in Saharan Air Layers and Tropical Disturbances

LASE (Lidar Atmospheric Sensing Experiment) onboard the NASA DC-8 was used to measure high resolution profiles of water vapor and aerosols, and cloud distributions in 14 flights over the eastern Atlantic region during the NAMMA (NASA African Monsoon Multidisciplinary Analyses) field experiment, which was conducted from August 15 to September 12, 2006. These measurements were made in conjunction with flights designed to study African Easterly Waves (AEW), Tropical Disturbances (TD), and Saharan Aerosol Layers (SALs) as well as flights performed in clear air and convective regions. As a consequence of their unique radiative properties and dynamics, SAL layers have a significant influence in the development of organized convection associated with TD. Interactions of the SAL with tropical air during early stages of the development of TD were observed. These LASE measurements represent the first simultaneous water vapor and aerosol lidar measurements to study the SAL and its impact on TDs and hurricanes. Seven AEWs were studied and four of these evolved into tropical storms and three did not. Three out of the four tropical storms evolved into hurricanes.

Ismail, Syed↗
NASA NTRS2006

Aerosol-Water Cycle Interaction: A New Challenge in Monsoon Climate Research

Long recognized as a major environmental hazard, aerosol is now known to have strong impacts on both regional and global climate. It has been estimated that aerosol may reduce by up to 10% of the seasonal mean solar radiation reaching the earth surface, producing a global cooling effect that opposes global warming (Climate Change 2001). This means that the potential perils that humans have committed to global warming may be far greater than what we can detect at the present. As a key component of the Earth climate system, the water cycle is profoundly affected by the presence of aerosols in the atmosphere. Through the so-called "direct effect", aerosol scatters and/or absorbs solar radiation, thus cooling the earth surface and changing the horizontal and vertical radiational heating contrast in the atmosphere. The heating contrast drives anomalous atmospheric circulation, resulting in changes in convection, clouds, and rainfall. Another way aerosol can affect the water cycle is through the so-called "indirect effects", whereby aerosol increases the number of cloud condensation nuclei, prolongs life time of clouds, and inhibits the growth of cloud drops to raindrops. This leads to more clouds, and increased reflection of solar radiation, and further cooling at the earth surface. In monsoon regions, the response of the water cycle to aerosol forcing is especially complex, not only because of presence of diverse mix of aerosol species with vastly different radiative properties, but also because the monsoon is strongly influenced by ocean and land surface processes, land use, land change, as well as regional and global greenhouse warming effects. Thus, sorting out the impacts of aerosol forcing, and interaction with the monsoon water cycle is a very challenging problem. In this talk, I will offer some insights into how aerosols may impact the Asian monsoon based on preliminary results from satellite observations and climate model experiments. Specifically, I will discuss the "elevated heat pump" hypothesis, involving atmospheric heating by absorbing aerosols (dust and black carbon) over the southern slopes of the Himalayas, and feedback with the deep convection, in modifying monsoon water cycle over South and East Asia. The role of aerosol forcing relative to those due to sea surface temperature and land surface processes, as well as observation requirements to verify such a hypothesis will also be discussed.

Lau, William K. M.↗
NASA NTRS2008

Chandra Confirmation of a Pulsar Wind Nebula in DA 495

As part of a multiwavelength study of the unusual radio supernova remnant DA 495, we present observations made with the Chandra X-ray Observatory. Imaging and spectroscopic analysis confirms the previously detected X-ray source at the heart of the annular radio nebula, establishing the radiative properties of two key emission components: a soft unresolved source with a blackbody temperature of 1 MK consistent with a neutron star, surrounded by a nontherma1 nebula 40" in diameter exhibiting a power-law spectrum with photon index Gamma = 1.63, typical of a pulsar wind nebula. Morphologically, the nebula appears to be slightly extended along a direction, in projection on the sky, previously demonstrated to be of significance in radio and ASCA observations; we argue that this represents the orientation of the pulsar spin axis. At smaller scales, a narrow X-ray feature is seen extending out 5" from the point source, but energetic arguments suggest that it is not the resolved termination shock of the pulsar wind against the ambient medium. Finally, we argue based on synchrotron lifetimes in the nebular magnetic field that DA 495 represents the first example of a pulsar wind nebula in which electromagnetic flux makes up a significant part, together with particle flux, of the neutron star's wind.

Arzoumanian, Z.↗
NASA NTRS2008

Understanding Differences Between Co-Incident CloudSat, Aqua/MODIS and NOAA18 MHS Ice water Path Retrievals Over the Tropical Oceans

Accurate measurement of the physical and radiative properties of clouds and their representation in climate models continues to be a challe nge. Model parameterizations are still subject to a large number of t unable parameters; furthermore, accurate and representative in situ o bservations are very sparse, and satellite observations historically have significant quantitative uncertainties, particularly with respect to particle size distribution (PSD) and cloud phase. Ice Water Path (IWP), or amount of ice present in a cloud column, is an important cl oud property to accurately quantify, because it is an integral measur e of the microphysical properties of clouds and the cloud feedback pr ocesses in the climate system. This paper investigates near co-incident retrievals of IWP over tropical oceans using three diverse measurem ent systems: radar from CloudSat, Vis/IR from Aqua/MODIS, and microwa ve from NOAA-18IMHS. CloudSat 94 GHz radar measurements provide high resolution vertical and along-orbit structure of cloud reflectivity a nd enable IWP (and IWC) retrievals. Overlapping MODIS measurements of cloud optical thickness and phase allow estimates of IWP when cloud tops are identified as being ice. Periodically, NOAA18 becomes co-inci dent in space I time to enable comparison of A-Train measurements to IWP inferred from the 157 and 89 GHz channel radiances. This latter m easurement is effective only for thick convective anvil systems. We s tratify these co-incident data (less than 4 minutes separation) into cirrus only, cirrus overlying liquid water clouds, and precipitating d eep convective clouds. Substantial biases in IWP and ice effective ra dius are found. Systematic differences in these retrievals are consid ered in light of the uncertainties in a priori assumptions ofPSDs, sp ectral sensitivity and algorithm strategies, which have a direct impact on the IWP product.

Pittman, Jasna↗
NASA NTRS2004

Enabling Technologies for High-accuracy Multiangle Spectropolarimetric Imaging from Space

Satellite remote sensing plays a major role in measuring the optical and radiative properties, environmental impact, and spatial and temporal distribution of tropospheric aerosols. In this paper, we envision a new generation of spaceborne imager that integrates the unique strengths of multispectral, multiangle, and polarimetric approaches, thereby achieving better accuracies in aerosol optical depth and particle properties than can be achieved using any one method by itself. Design goals include spectral coverage from the near-UV to the shortwave infrared; global coverage within a few days; intensity and polarimetric imaging simultaneously at multiple view angles; kilometer to sub-kilometer spatial resolution; and measurement of the degree of linear polarization for a subset of the spectral complement with an uncertainty of 0.5% or less. The latter requirement is technically the most challenging. In particular, an approach for dealing with inter-detector gain variations is essential to avoid false polarization signals. We propose using rapid modulation of the input polarization state to overcome this problem, using a high-speed variable retarder in the camera design. Technologies for rapid retardance modulation include mechanically rotating retarders, liquid crystals, and photoelastic modulators (PEMs). We conclude that the latter are the most suitable.

photoelastic modulators (PEMs)↗
NASA NTRS2008

LEOMAC: A Future 'Global Atmospheric Composition Mission' (CACM) Concept

Resolution of important outstanding questions in air quality, climate change and ozone layer stability demands global observations of multiple chemical species with high horizontal and vertical resolution from the boundary layer to the stratopause. We present a mission concept that delivers the needed atmospheric composition observations, along with cloud ice and water vapor data needed for improvements in climate and weather forecasting models. The mission comprises ultraviolet and infrared nadir and microwave limb viewing instruments observing wide swaths each orbit. We review the scientific goals of the mission and the measurement capabilities this concept will deliver. We describe how precessing orbits offer significant improvements in temporal resolution and diurnal coverage compared to sun-synchronous orbits. Such improvements are needed to quantify the impact of critical 'fast processes' such as deep convection on the composition and radiative properties of the upper troposphere, a region where water vapor and ozone are strong but poorly understood greenhouse gases. This concept can serve as the 'Global Atmospheric Composition Mission' (GACM) recently recommended by the National Academy of Sciences decadal survey as one of 17 priority earth science missions for the coming decade.

chemistry↗